2023 MXene Based Polarization Insensitive
2023 MXene Based Polarization Insensitive
2023 MXene Based Polarization Insensitive
MXene-Based Polarization-Insensitive
UV-VIS-NIR Meta-Absorber
MUHAMMAD QASIM MEHMOOD 1 , (Senior Member, IEEE),
AQIB RAZA SHAH1 , (Member, IEEE), MUHAMMAD ASHAR NAVEED2 ,
NASIR MAHMOOD3 , (Member, IEEE), MUHAMMAD ZUBAIR 3 , (Senior Member, IEEE),
AND YEHIA MASSOUD 3 , (Fellow, IEEE)
1 MicroNano Laboratory, Department of Electrical Engineering, Information Technology University (ITU) of the Punjab, Lahore 54600, Pakistan
2 Department of Electrical and Computer Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588, USA
3 Innovative Technologies Laboratories (ITL), King Abdullah University of Science and Technology (KAUST), Thuwal 23955, Saudi Arabia
ABSTRACT The concept of achieving perfect absorption of electromagnetic (EM) waves has engendered
substantial interest in diverse applications, encompassing photoelectric conversions, infrared imaging,
energy harvesting, and photovoltaics. Conventionally, absorber materials of choice have revolved around
the utilization of refractory metals. However, this article proposes a pioneering proposition that uses quasi-
two-dimensional (quasi-2D) material i.e., MXene, and uses ceramics material aluminum nitride (AlN)
to forge a polarization-insensitive broadband absorber. This ultra-broadband meta-absorber showcases an
expanse of absorbance across a comprehensive spectral range, spanning from the ultraviolet (UV) to Near-
infrared (NIR) regions, specifically extending from 200 nm to 2000 nm. To previse the angular stability
of the meta-absorber, the absorptivity was examined under oblique incidence in both transverse electric
(TE) and transverse magnetic (TM) polarizations exhibiting the robustness of broadband absorber. MXene
shows exceptional mechanical flexibility, facilitating seamless integration into flexible electronics. Their
large specific surface area holds significant promise for high-performance energy storage in applications
including energy harvesting, photovoltaics, solar cells, and sensors. These unique characteristics position
them at the forefront of material science, driving advancements in next-generation technologies.
from ultraviolet to visible [21]. By vertical incident light, AlN crucial in electromagnetic wave absorption. AlN finds
Jiang et al. suggested the broadband solar absorber, which significant use in electromagnetic wave absorbers, crucial for
spans the visible to the near-infrared regime and achieves anechoic chambers in EMC testing and in radar-absorbing
efficient absorption of 90 % [22]. Refractory metals like materials for stealth technology. Additionally, AlN-based
nickel (Ni), titanium nitride (TiN), zirconium nitride (ZrN), absorbers enhance signal quality and reduce interference in
chromium (Cr), and tungsten (W) have also been examined wireless devices and antennas. AlN’s electrical properties
for a number of efficient absorbers [23], [24], [25], [26], [27]. contribute to its effectiveness in absorbing electromagnetic
Shafique et al. demonstrated VN/SiO2 based meta-absorber waves, improving performance in various essential applica-
for solar thermophotovoltaic (STPV) system with 99% effi- tions [49]. In literature, Ahmed et al. explored the potential
ciency [28]. Similarly in another study TiN was explored by of 2D titanium carbide for the preparation and performance
Hou et al. for achieving >90% absorption in a waveband of lithium-ion batteries [50]. In 2020, Ali et al. suggested
ranging from 400 to 2000 nm [29]. In another investigation, the wide-angle broadband absorber employing the MIM
tungsten metal was explored for high absorption demon- structure based on MXene and gold nanoparticles [51].
stration in the visible range by utilizing the polarization Houran et al. propose a high-tunability MXene-based meta-
insensitive cylindrical geometry [30]. Such refractory met- material absorber with subwavelength nanorods, achieving
als based meta-absorbers exhibits perfect absorption along over 80% absorption in the 1150-2500 nm infrared range
with exceptional high temperature tolerance making them [52]. The author introduces a multilayer absorber, incorporat-
ideal candidate for photovoltaic, and energy harvesting, etc. ing 2D Ti3C2Tx (MXene) and top-mounted titanium nitride
applications. (TiN). It achieves over 85% absorption in the 400-1600 nm
Two-dimensional (2D) materials have drawn quite a bit of spectrum under normal incidence [53]. Since then MXene
attention in recent years because of their unique electrical, has demonstrated significant advancements in real-world
optical, mechanical, and thermal capabilities along with thin applications such as energy storage, electromagnetic interfer-
layer thickness, which allows them to be easily integrated ence (EMI) shielding, and flexible electronics. However, the
into nanoscale devices [31], [32], [33], [34]. Graphene is scalability of MXene synthesis, sensitivity to environmental
the most well-known 2D material; it has been explored in conditions, and the integration of MXene into existing sys-
numerous disciplines due to its exceptional electrical conduc- tems or devices present notable technical challenges. It can
tivity, mechanical strength, low loss, and adjustable band gap still be used to overcome the difficulty in designing an ultra-
[35], [36], [37]. Recently, researchers have been examining broadband meta-absorber, and this will have a significant
a new class of quasi-two-dimensional (quasi-2D) materi- impact on the advancement of photonic devices.
als. Typically, quasi-2D materials are thin films or layered In this paper, we put forth a pioneering concept for an
materials with a thickness that is small enough to cause ultra-broadband meta-absorber that harnesses the exceptional
quantum confinement effects in the electronic structure but properties of MXene material. Through rigorous analy-
large enough to preserve some of the 3D features of the sis using the advanced simulation tool CST Microwave
bulk material, transition metal dichalcogenides (TMDs), such Studio, we conducted a comprehensive investigation into
as MoS2 and WS2 , layered oxides, such as SrTiO3 and the absorption characteristics of the MXene-based meta-
LaAlO3 , and MXene [38]. MXene being a quasi-2D material, absorber. The suggested meta-absorber exhibits a profound
its compound consist of carbonitrides, carbides, and transi- ability to effectively capture and assimilate the incident
tion metals, it possesses qualities that fall in between those energy of both transverse electric (TE) and transverse mag-
of a true 2D material and a bulk 3D material [39], [40]. netic (TM) polarizations, leading to an impressive state of
Its ultrathin structure, which has a thickness of only a few polarization insensitivity through meticulous manipulation
nanometers, causes the quantization of electronic states in the of the thickness and configuration of the MXene layer. The
out-of-plane direction while preserving the bulk material’s proposed design achieves efficient absorption in the visible
three-dimensional characteristics in the in-plane direction. to the near-infrared spectral range. It shows great stability at
As a result, unique electrical, optical, and mechanical prop- an oblique incidence of light and proclaims great potential of
erties arise that are highly tunable and suitable for a range applications such as energy harvesting, photodetectors, solar
of applications [41], [42], [43], [44]. Molecular formula of cells, photovoltaic and sensors, etc.
MXene can be represented as Mn+1 Xn Tx where M, X, and T
stand for the transition metal, carbon (C) or N= Nitrogen (N) II. DESIGN AND MODELING
and functional groups (OH, -F, -O) respectively [45]. Because The ultra-broadband meta-absorber has a three-layered struc-
of better stability, larger specific surface, peculiar dielec- ture, the upper layer is made up of MXene with a square-
tric multilayer, and semiconductor characteristics and unique shaped resonator, the middle layer is of aluminum nitride and
electrical and optical features MXene is an excellent choice the bottom grounded layer is of also MXene. The schematics
for optical devices, particularly for absorbers [46], [47], [48]. of the absorber are shown in Fig. 1 (a-d). The top and 3D view
AlN offers high electrical resistivity and a wide bandgap of the meta-atom are depicted in Fig. 1 (a), (b) along with the
(6.0-6.2 eV), making it ideal for insulation and high-power 3D view of the metasurface in Fig. 1(c). The MXene has high
electronics. Its notable dielectric constant (8.5-9.5) makes refractive index (n) and absorption coefficient (k), making it
130288 VOLUME 11, 2023
M. Q. Mehmood et al.: MXene-Based Polarization-Insensitive UV-VIS-NIR Meta-Absorber
below [14],
q
eink0 d = X ± i 1 − X 2 , (13)
where X = 2S (1−1S2 +S2 ) .
21 11 21
The mathematical equations employed leverage the
absorber’s impedance and refractive index to ascertain the
intrinsic properties of the meta-absorber, specifically its rela-
tive permittivity and permeability. These calculations involve
rigorous analysis and precise computations to derive accurate
values that characterize the behavior of the meta-absorber
in absorbing electromagnetic radiation. The permeability can
be calculated as the product of the refractive index and the
impedance, whereas the permittivity can be written as the
ratio of the absorber’s impedance to its refractive index.
To find the permittivity (εr ) of meta-absorber we use the
expression which can written as [14], [58],
FIGURE 7. Complex intrinsic parameter of the proposed absorber.
εr = n Z,
(a) Refractive index of meta-absorber (b) Permittivity of meta- absorber. (14)
(c) Complex permeability of absorber.
while for permeability (µr ) we can use the equation 15.
remains constant and incidence of wave is normal, at the µr = nZ. (15)
shorter wavelength absorption spectra deteriorate therefore Complex refractive index of the proposed absorber is depicted
decreasing the absorption efficiency. in the Fig.7 (a). Fig. 7(b) and 7(c) illustrate the permeability
After analyzing the physical parameters effect on and permittivity of absorber respectively. The value of the
the absorption characteristics, it is essential to extract loss tangent is a crucial factor that governs a meta-absorber’s
the complex frequency-dependent scattering parameters ability to absorb energy. The incident electromagnetic wave
(S-parameters) of the meta-absorber at optimized dimen- is more likely to be absorbed when the loss tangent value
sions, in order to further scrutinize its performance. These is higher because there is more energy dissipated within
variables, including the refractive index, permittivity, and per- the material. It is crucial to evaluate and optimize the loss
meability, serve as vital in determining the electromagnetic tangent value of the material employed in the meta-absorber
response of the absorber. Using the transmission line theory design. It can be observed from Fig.7 (b) the imaginary part of
and a multi-layer model, the permittivity and permeability permittivity is larger than its real part leading to an absorption
may be calculated from the measured transmission (S21 ) due to higher loss tangent. Mathematically loss tangent can be
and reflection (S11 ) S-parameters, respectively. While the written as
permeability describes the material’s magnetic qualities in
tanδ = ε′′ ε ′ ,
reaction to an external magnetic field, the permittivity of the (16)
absorber demonstrates its capacity to store electric charge where ε′ is real part and ε′′ is the imaginary part
when subjected to an electric field. These factors have a sub- relative permittivity (εr ).Through comprehensive scrutiny,
stantial impact on the meta-absorber’s resonance frequency, we have extensively analyzed the absorption properties of the
bandwidth, and efficiency. For designing and performance meta-absorber under various parametric and operational cir-
optimizations of the absorber, proper characterization of these cumstances. By extracting the meta-absorber’s s-parameters
parameters is mandatory. When an electromagnetic wave and meticulously refining the design parameters, we have
is normally incident on metasurface interface then S21 as precisely determined its relative permittivity and permeabil-
coefficient of transmission can be written mathematically ity. Our conclusive outcomes unequivocally establish the
as S21 = Teiko d , where, k0 is the wavenumber and d is indispensability of achieving an impedance of unity for
the thickness of structure and S11 as reflection coefficient. attaining maximum absorption efficiency. These compelling
The S-parameter are correlated to the refractive index and findings exert a profound impact on the design and advance-
impedance z as ment of meta-absorbers, significantly influencing their mul-
tifaceted applications in the realms of optics, STPV, energy
R01 (1 − ei2nko d )
S11 = , (11) harvesting, photovoltaic, and designing plasmonic absorbers.
(1 − R201 ei2nko d ) To emphasize the novelty and wide-ranging capabilities
(1 − R201 )einko d ) of our proposed design compared to other MXene-based
S21 = , (12) absorbers, we meticulously conducted an exhaustive survey.
(1 − R201 ei2nko d )
We have also compiled and summarized recent research on
−1
whereas R01 = Zz+1 . The refractive index of absorber can MXene-based absorbers in Table 1 to provide a comprehen-
be find by inverting the equations 11 and 12 which is given sive overview.
TABLE 1. Comparison between MXene based absorbers. [6] L. Li, H. Zhao, C. Liu, L. Li, and T. J. Cui, ‘‘Intelligent metasurfaces:
Control, communication and computing,’’ eLight, vol. 2, no. 1, p. 7,
May 2022.
[7] Y. Li, C. T. Chan, and E. Mazur, ‘‘Dirac-like cone-based electromag-
netic zero-index metamaterials,’’ Light, Sci. Appl., vol. 10, no. 1, p. 203,
Sep. 2021.
[8] S. Yin, E. Galiffi, and A. Alù, ‘‘Floquet metamaterials,’’ eLight, vol. 2,
no. 1, pp. 1–13, May 2022.
[9] V. Joy, A. Dileep, P. V. Abhilash, R. U. Nair, and H. Singh, ‘‘Metasurfaces
for stealth applications: A comprehensive review,’’ J. Electron. Mater.,
vol. 50, no. 6, pp. 3129–3148, Jun. 2021.
[10] M. Q. Mehmood, J. Seong, M. A. Naveed, J. Kim, M. Zubair, K. Riaz,
Y. Massoud, and J. Rho, ‘‘Single-cell-driven tri-channel encryption meta-
displays,’’ Adv. Sci., vol. 9, no. 35, Dec. 2022, Art. no. 2203962.
[11] J. Qin, S. Jiang, Z. Wang, X. Cheng, B. Li, Y. Shi, D. P. Tsai, A. Q. Liu,
W. Huang, and W. Zhu, ‘‘Metasurface micro/nano-optical sensors: Prin-
ciples and applications,’’ ACS Nano, vol. 16, no. 8, pp. 11598–11618,
Aug. 2022.
[12] N. I. Landy, S. Sajuyigbe, J. J. Mock, D. R. Smith, and W. J. Padilla,
‘‘Perfect metamaterial absorber,’’ Phys. Rev. Lett., vol. 100, May 2008,
Art. no. 207402.
[13] Y. Cheng, J. Liu, F. Chen, H. Luo, and X. Li, ‘‘Optically switchable
broadband metasurface absorber based on square ring shaped photocon-
ductive silicon for terahertz waves,’’ Phys. Lett. A, vol. 402, Jun. 2021,
Art. no. 127345.
[14] M. A. Naveed, R. M. H. Bilal, A. A. Rahim, M. A. Baqir, and M. M. Ali,
‘‘Polarization-insensitive dual-wideband fractal meta-absorber for tera-
hertz applications,’’ Appl. Opt., vol. 60, no. 29, pp. 9160–9166, 2021.
IV. CONCLUSION [15] Z. Li, E. Palacios, S. Butun, and K. Aydin, ‘‘Visible-frequency metasur-
The current study proposed a novel ultra-broadband meta- faces for broadband anomalous reflection and high-efficiency spectrum
absorber with a square-shaped geometry employing a quasi- splitting,’’ Nano Lett., vol. 15, no. 3, pp. 1615–1621, Mar. 2015.
[16] W. Li, X. Hu, J. Wu, K. Fan, B. Chen, C. Zhang, W. Hu, X. Cao, B. Jin,
2D material MXene. The computational analyses are used to Y. Lu, J. Chen, and P. Wu, ‘‘Dual-color terahertz spatial light modulator for
analyze the absorption performance of the proposed design. single-pixel imaging,’’ Light, Sci. Appl., vol. 11, no. 1, p. 191, Jun. 2022.
Our study demonstrates that the meta-absorber absorbs more [17] N. Mahmood, J. Kim, M. A. Naveed, Y. Kim, J. Seong, S. Kim, T. Badloe,
M. Zubair, M. Q. Mehmood, Y. Massoud, and J. Rho, ‘‘Ultraviolet–visible
than 85% broadband from UV to Near-IR (200 nm to multifunctional vortex metaplates by breaking conventional rotational
2000 nm). Furthermore, the proposed absorber’s design symmetry,’’ Nano Lett., vol. 23, no. 4, pp. 1195–1201, Feb. 2023, doi:
robustness and angular stability are tested by exciting with 10.1021/acs.nanolett.2c04193.
[18] S. Zhang, C. L. Wong, S. Zeng, R. Bi, K. Tai, K. Dholakia, and M. Olivo,
TE and TM polarizations, indicating that the absorber keeps ‘‘Metasurfaces for biomedical applications: Imaging and sensing from a
absorbance above 80% at oblique incidence angles ranging nanophotonics perspective,’’ Nanophotonics, vol. 10, no. 1, pp. 259–293,
from 0◦ to 70◦ . Furthermore, the geometrical parameters’ Sep. 2020.
[19] M. A. Naveed, J. Kim, M. A. Ansari, I. Kim, Y. Massoud, J. Kim,
impact on the absorption characteristics of the proposed D. K. Oh, T. Badloe, J. Lee, Y. Kim, D. Jeon, J. Choi, M. Zubair,
design has been briefly scrutinized. The MXene (quasi 2D-) M. Q. Mehmood, and J. Rho, ‘‘Single-step fabricable flexible metadisplays
and AlN metamaterials employed in the suggested design for sensitive chemical/biomedical packaging security and beyond,’’ ACS
Appl. Mater. Interfaces, vol. 14, no. 27, pp. 31194–31202, Jul. 2022.
provide various advantages, including high surface area, [20] S. Chen, W. Liu, Z. Li, H. Cheng, and J. Tian, ‘‘Metasurface-empowered
variable electrical conductivity, and strong light interaction, optical multiplexing and multifunction,’’ Adv. Mater., vol. 32, no. 3,
making it a potential application in the field of STPV, energy Jan. 2020, Art. no. 1805912.
[21] Q. Chen, J. Gu, P. Liu, J. Xie, J. Wang, Y. Liu, and W. Zhu, ‘‘Nanowire-
harvesting, photovoltaic, designing plasmonic absorbers, etc. based ultra-wideband absorber for visible and ultraviolet light,’’ Opt. Laser
Technol., vol. 105, pp. 102–105, Sep. 2018.
REFERENCES [22] X. Jiang, T. Wang, Q. Zhong, R. Yan, and X. Huang, ‘‘Ultrabroadband
light absorption based on photonic topological transitions in hyperbolic
[1] D. R. Smith, J. B. Pendry, and M. C. K. Wiltshire, ‘‘Metamaterials and metamaterials,’’ Opt. Exp., vol. 28, no. 1, p. 705, 2020.
negative refractive index,’’ Science, vol. 305, no. 5685, pp. 788–792, 2004. [23] R. M. H. Bilal, S. Zakir, M. A. Naveed, M. Zubair, M. Q. Mehmood,
[2] M. A. Naveed, J. Kim, I. Javed, M. A. Ansari, J. Seong, Y. Massoud, and Y. Massoud, ‘‘Nanoengineered nickel-based ultrathin metamaterial
T. Badloe, I. Kim, K. Riaz, M. Zubair, M. Q. Mehmood, and J. Rho, absorber for the visible and short-infrared spectrum,’’ Opt. Mater. Exp.,
‘‘Novel spin-decoupling strategy in liquid crystal-integrated metasurfaces vol. 13, no. 1, pp. 28–40, 2023.
for interactive metadisplays,’’ Adv. Opt. Mater., vol. 10, no. 13, Jul. 2022, [24] S. Ijaz, A. S. Rana, Z. Ahmad, B. Rehman, M. Zubair, and M. Q. Mehmood,
Art. no. 2200196. ‘‘Exploiting zirconium nitride for an efficient heat-resistant absorber and
[3] I. Javed, J. Kim, M. A. Naveed, D. K. Oh, D. Jeon, I. Kim, M. Zubair, emitter pair for solar thermophotovoltaic systems,’’ Opt. Exp., vol. 29,
Y. Massoud, M. Q. Mehmood, and J. Rho, ‘‘Broad-band polarization- no. 20, pp. 31537–31548, 2021.
insensitive metasurface holography with a single-phase map,’’ ACS Appl. [25] S. Mehrabi, ‘‘Ultra-broadband nanostructured metamaterial absorber
Mater. Interfaces, vol. 14, no. 31, pp. 36019–36026, Aug. 2022. based on stacked square-layers of TiN/TiO2 ,’’ Opt. Mater. Exp., vol. 12,
[4] A. J. Satti, M. A. Naveed, I. Javed, N. Mahmood, M. Zubair, no. 6, pp. 2199–2211, 2022.
M. Q. Mehmood, and Y. Massoud, ‘‘A highly efficient broadband multi- [26] S. Shrestha, Y. Wang, A. C. Overvig, M. Lu, A. Stein, L. D. Negro, and
functional metaplate,’’ Nanosc. Adv., vol. 5, no. 7, pp. 2010–2016, 2023. N. Yu, ‘‘Indium tin oxide broadband metasurface absorber,’’ ACS Photon.,
[5] M. A. Naveed, M. A. Ansari, I. Kim, T. Badloe, J. Kim, D. K. Oh, vol. 5, no. 9, pp. 3526–3533, Sep. 2018.
K. Riaz, T. Tauqeer, U. Younis, M. Saleem, M. S. Anwar, M. Zubair, [27] R. M. H. Bilal, M. A. Saeed, M. A. Naveed, M. Zubair, M. Q. Mehmood,
M. Q. Mehmood, and J. Rho, ‘‘Optical spin-symmetry breaking for high- and Y. Massoud, ‘‘Nickel-based high-bandwidth nanostructured metama-
efficiency directional helicity-multiplexed metaholograms,’’ Microsystems terial absorber for visible and infrared spectrum,’’ Nanomaterials, vol. 12,
Nanoengineering, vol. 7, no. 1, pp. 1–7, Mar. 2021. no. 19, p. 3356, Sep. 2022.
[28] A. Shafique, M. A. Naveed, S. Ijaz, M. Zubair, M. Q. Mehmood, [49] Z. An, C. Men, Z. Xu, P. K. Chu, and C. Lin, ‘‘Electrical properties of
and Y. Massoud, ‘‘Highly efficient vanadium nitride based metasur- AlN thin films prepared by ion beam enhanced deposition,’’ Surf. Coatings
face absorber/emitter for solar-thermophotovoltaic system,’’ Mater. Today Technol., vol. 196, nos. 1–3, pp. 130–134, Jun. 2005.
Commun., vol. 34, Mar. 2023, Art. no. 105416. [50] B. Ahmed, D. H. Anjum, Y. Gogotsi, and H. N. Alshareef, ‘‘Atomic layer
[29] D. Huo, X. Ma, H. Su, C. Wang, and H. Zhao, ‘‘Broadband absorption deposition of SnO2 on MXene for Li-ion battery anodes,’’ Nano Energy,
based on thin refractory titanium nitride patterned film metasurface,’’ vol. 34, pp. 249–256, Apr. 2017.
Nanomaterials, vol. 11, no. 5, p. 1092, Apr. 2021. [51] W. Ali, M. F. Mideksa, K. Hou, H. Li, X. Wang, and Z. Tang, ‘‘All-solution-
[30] R. M. H. Bilal, M. A. Baqir, P. K. Choudhury, M. A. Naveed, M. M. Ali, and processed ultrahigh broadband and wide-angle perfect absorber based on
A. A. Rahim, ‘‘Ultrathin broadband metasurface-based absorber comprised Mxene–gold nanoparticles,’’ Adv. Opt. Mater., vol. 8, no. 21, Nov. 2020,
of tungsten nanowires,’’ Results Phys., vol. 19, Dec. 2020, Art. no. 103471. Art. no. 2000447.
[31] X. Luo, ‘‘Subwavelength optical engineering with metasurface waves,’’ [52] M. A.Houran, A. Armghan, M. A. Baqir, K. Aliqab, M. Saqlain, and
Adv. Opt. Mater., vol. 6, no. 7, Apr. 2018, Art. no. 1701201. M. Alsharari, ‘‘MXene nanorods-based metasurface wideband absorber for
[32] S. Zakir, R. M. H. Bilal, M. A. Naveed, M. A. Baqir, M. U. A. Khan, infrared regime,’’ Int. J. Thermal Sci., vol. 193, Nov. 2023, Art. no. 108452.
M. M. Ali, M. A. Saeed, M. Q. Mehmood, and Y. Massoud, ‘‘Polarization- [53] M. A. Houran, B. Adhavan, M. A. Baqir, and M. Saqlain, ‘‘Polarization-
insensitive, broadband, and tunable terahertz absorber using slotted-square insensitive and wide-angle MXene-TiN-based wideband absorber oper-
graphene meta-rings,’’ IEEE Photon. J., vol. 15, no. 1, pp. 1–8, Feb. 2023. ating in the visible and near-infrared regime,’’ Opt. Quantum Electron.,
[33] D. Lee, S. So, G. Hu, M. Kim, T. Badloe, H. Cho, J. Kim, H. Kim, vol. 55, no. 7, p. 572, Jul. 2023.
C.-W. Qiu, and J. Rho, ‘‘Hyperbolic metamaterials: Fusing artificial struc- [54] Pfluger. Refractive Index (TIC). [Online]. Available: https://
tures to natural 2D materials,’’ eLight, vol. 2, no. 1, pp. 1–23, Dec. 2022. refractiveindex.info/
[34] P. Wu, L. Ye, L. Tong, P. Wang, Y. Wang, H. Wang, H. Ge, Z. Wang, Y. Gu, [55] J. Pflüger, J. Fink, W. Weber, K. P. Bohnen, and G. Crecelius, ‘‘Dielectric
K. Zhang, Y. Yu, M. Peng, F. Wang, M. Huang, P. Zhou, and W. Hu, ‘‘Van properties of TiCx , TiNx , VCx , and VNx from 1.5 to 40 eV determined
der Waals two-color infrared photodetector,’’ Light, Sci. Appl., vol. 11, by electron-energy-loss spectroscopy,’’ Phys. Rev. B, Condens. Matter,
no. 1, p. 6, Jan. 2022. vol. 30, no. 3, p. 1155, 1984.
[56] M. A. Naveed, R. M. H. Bilal, M. A. Baqir, M. M. Bashir, M. M. Ali,
[35] D. S. L. Abergel, V. Apalkov, J. Berashevich, K. Ziegler, and
and A. A. Rahim, ‘‘Ultrawideband fractal metamaterial absorber made of
T. Chakraborty, ‘‘Properties of graphene: A theoretical perspective,’’ Adv.
nickel operating in the UV to IR spectrum,’’ Opt. Exp., vol. 29, no. 26,
Phys., vol. 59, no. 4, pp. 261–482, Jul. 2010.
p. 42911, 2021.
[36] K. Wang, B. Zheng, M. Mackinder, N. Baule, H. Qiao, H. Jin, T. Schuelke,
[57] R. M. H. Bilal, M. A. Naveed, M. A. Baqir, M. M. Ali, and A. A. Rahim,
and Q. H. Fan, ‘‘Graphene wrapped MXene via plasma exfoliation for
‘‘Design of a wideband terahertz metamaterial absorber based on
all-solid-state flexible supercapacitors,’’ Energy Storage Mater., vol. 20,
pythagorean-tree fractal geometry,’’ Opt. Mater. Exp., vol. 10, no. 12,
pp. 299–306, Jul. 2019.
p. 3007, 2020.
[37] D. Yan and J. Li, ‘‘Tuning control of dual-band terahertz perfect absorber [58] S. Chejarla, S. R. Thummaluru, and R. K. Chaudhary, ‘‘Flexible meta-
based on graphene single layer,’’ Laser Phys., vol. 29, no. 4, Apr. 2019, material absorber with wide incident angle insensitivity for conformal
Art. no. 046203. applications,’’ Electron. Lett., vol. 55, no. 3, pp. 133–134, Feb. 2019.
[38] A. P. Balan, ‘‘Non-van der Waals quasi-2D materials; recent advances in [59] Y. Jia, T. Wu, G. Wang, J. Jiang, F. Miao, and Y. Gao, ‘‘Visible and
synthesis, emergent properties and applications,’’ Mater. Today, vol. 58, near-infrared broadband absorber based on Ti3 C2 Tx MXene-Wu,’’ Nano-
pp. 164–200, Sep. 2022. materials, vol. 12, no. 16, p. 2753, Aug. 2022.
[39] J.-C. Lei, X. Zhang, and Z. Zhou, ‘‘Recent advances in MXene: Prepa- [60] W. Cui, L. Li, W. Xue, H. Xu, Z. He, and Z. Liu, ‘‘Enhanced absorption
ration, properties, and applications,’’ Frontiers Phys., vol. 10, no. 3, for MXene/Au-based metamaterials,’’ Results Phys., vol. 23, Apr. 2021,
pp. 276–286, Jun. 2015. Art. no. 104072.
[40] V. Pacheco-Peña, T. Hallam, and N. Healy, ‘‘MXene supported surface [61] Y. Ren, ‘‘Ultra-broadband and wide-angle solar absorber for the mxene
plasmons on telecommunications optical fibers,’’ Light, Sci. Appl., vol. 11, grating metamaterials,’’.
no. 1, p. 22, Jan. 2022. [62] K. Chaudhuri, M. Alhabeb, Z. Wang, V. M. Shalaev, Y. Gogotsi, and
[41] G. Chen, L. Zhang, X. Fan, and H. Wu, ‘‘Interfacial and defect polariza- A. Boltasseva, ‘‘Highly broadband absorber using plasmonic titanium car-
tion in MXene-like laminated spinel for electromagnetic wave absorption bide (MXene),’’ ACS Photon., vol. 5, no. 3, pp. 1115–1122, Mar. 2018.
application,’’ J. Colloid Interface Sci., vol. 588, pp. 813–825, Apr. 2021.
[42] X. Li, C. Wen, L. Yang, R. Zhang, X. Li, Y. Li, and R. Che, ‘‘MXene/FeCo
films with distinct and tunable electromagnetic wave absorption by mor- MUHAMMAD QASIM MEHMOOD (Senior
phology control and magnetic anisotropy,’’ Carbon, vol. 175, pp. 509–518, Member, IEEE) received the B.S. degree in elec-
Apr. 2021. tronic engineering from International Islamic Uni-
[43] L. Cao H. Chu, H. Pan, R. Wang, Y. Li, S. Zhao, D. Li, H. Zhang, versity Islamabad (IIUI), in 2008, the M.S. degree
and D. Li, ‘‘Nonlinear optical absorption features in few-layered hybrid from the Ghulam Ishaq Khan Institute (GIKI),
Ti3 C2 (OH)2 /Ti3 C2 F2 MXene for optical pulse generation in the NIR in 2010, and the Ph.D. degree from the National
region,’’ Opt. Exp., vol. 28, no. 21, pp. 31499–31509, 2020. University of Singapore, in January 2016.
[44] F. Pan, L. Yu, Z. Xiang, Z. Liu, B. Deng, E. Cui, Z. Shi, X. Li, and W. Lu, He joined the National University of Singapore,
‘‘Improved synergistic effect for achieving ultrathin microwave absorber of as a Ph.D. Scholar. He is currently a Chairperson
1D Co nanochains/2D carbide MXene nanocomposite,’’ Carbon, vol. 172, and an Associate Professor with the Department
pp. 506–515, Feb. 2021. of Electrical Engineering, Information Technology University (ITU) of the
[45] Y. Li, F. Meng, Y. Mei, H. Wang, Y. Guo, Y. Wang, F. Peng, F. Huang, and Punjab, Lahore, Pakistan, where he is also the Director of a Vibrant with
Z. Zhou, ‘‘Electrospun generation of Ti3 C2 Tx MXene@graphene oxide the MicroNano Laboratory. His research interests include optics and nano-
hybrid aerogel microspheres for tunable high-performance microwave
photonics, more precisely it included the demonstration of exotic phenomena
absorption,’’ Chem. Eng. J., vol. 391, Jul. 2020, Art. no. 123512.
(via ultra-thin nano-structured devices) e.g., on-chip orbital angular manip-
[46] X. Han, Y. Huang, L. Ding, Y. Song, T. Li, and P. Liu, ‘‘Ti3 C2 Tx MXene
ulation, beam-steering, spin-orbital coupling, 3-D holography, polarization
nanosheet/metal–organic framework composites for microwave absorp-
tion,’’ ACS Appl. Nano Mater., vol. 4, no. 1, pp. 691–701, 2020.
filtering, and light absorption. He is a member of the Pak-ICTP Alumni
[47] P. Liu, S. Chen, M. Yao, Z. Yao, V. M. H. Ng, J. Zhou, Y. Lei, Z. Yang,
Society. He was a recipient of the 2023 ICO/ICTP Gallieno Denardo Award
and L. B. Kong, ‘‘Double-layer absorbers based on hierarchical MXene for his remarkable contributions to the field of nano-optics and meta-
composites for microwave absorption through optimal combination,’’ J. photonics. He has listed among the top 2% of scientists in the Global list
Mater. Res., vol. 35, no. 11, pp. 1481–1491, Jun. 2020. (of 2021 and 2022) released by Stanford University. He is the Chair of the
[48] A. K. Thakur, R. Sathyamurthy, R. Saidur, R. Velraj, I. Lynch, and IEEE APS/CAS/MTT/SSC Joint Chapter, Lahore Section; and an Advisor
N. Aslfattahi, ‘‘Exploring the potential of MXene-based advanced of ITU’s SPIE and OPTICA Chapters, Pakistan. He works closely with
solar-absorber in improving the performance and efficiency of a solar- other national and international societies to promote science by organizing
desalination unit for brackish water purification,’’ Desalination, vol. 526, student development and outreach programs, such as symposiums, seminars,
Mar. 2022, Art. no. 115521. internships, project competitions, and awareness sessions.
AQIB RAZA SHAH (Member, IEEE) received MUHAMMAD ZUBAIR (Senior Member, IEEE)
the B.Sc. degree in electrical engineering from the received the Ph.D. degree in computational elec-
University of Engineering and Technology (UET) tromagnetics (CEM) from the Polytechnic Uni-
Peshawar, Pakistan, in 2021, and the master’s versity of Turin, Italy. He is currently a Research
degree in electrical engineering from Information Scientist with the Innovative Technologies Labo-
Technology University (ITU), Lahore, Pakistan, ratories, King Abdullah University of Science and
in 2023. Technology. Before joining KAUST, he was an
Upon the completion of the B.Sc. degree in elec- Associate Professor and the Department Chair of
trical engineering, he became a Graduate Student the Department of Electrical Engineering, Infor-
Fellow (GSF) with ITU. Throughout his master’s mation Technology University, Lahore. He was a
program, he was actively engaged as a Research Assistant with the Micro- Postdoctoral Research Fellow with the SUTD-MIT International Design
Nano Research Laboratory, ITU. His research interests include the design Centre, Singapore, before joining ITU. His Ph.D. research was carried out
and simulation of optical metasurfaces, 2-D materials, photonics devices, with the Antenna and EMC Laboratory (LACE) of the Polytechnic Uni-
machine learning, deep learning, and utilizing artificial intelligence for versity of Turin, where he worked on computational EM projects funded
medical diagnosis. He proudly holds the memberships of IEEE and SPIE. by the Army Research Laboratory (ARL) in collaboration with Boston
University, USA. During the Postdoctoral Research, he has been working on
various research projects related to fractional methods in electromagnetics
funded by the Air Force Office of Scientific Research (AFOSR)/Asian Office
of Aerospace Research and Development (AOARD) and the Singapore
Temasek Laboratories (TL). He is the principal author of his book on Elec-
tromagnetic Fields and Waves in Fractional Dimensional Space (Springer,
NY, USA). He has contributed more than 150 scientific works in journals and
conferences of international repute. He has been selected for the URSI Young
Scientist Award (YSA) in the URSI General Assembly (GASS), in 2021.
He has been awarded the Punjab Innovation Research Challenge Award
(PIRCA), in 2021. He has been an Associate Editor of IEEE Access and
MUHAMMAD ASHAR NAVEED received the an Editorial Board Member of IET Microwaves, Antennas and Propagation,
master’s degree from Information Technology PLOS One, and International Journal of Antennas and Propagation.
University, in 2020. He is a Graduate Student with
the Electrical and Computer Engineering Depart-
ment, University of Nebraska-Lincoln. YEHIA MASSOUD (Fellow, IEEE) is currently
Previously, he was associated as a Research the Director of the Innovative Technologies Lab-
Associate with the MicroNano Laboratory, Infor- oratories (ITL), King Abdullah University of Sci-
mation Technology University. He is the author or ence and Technology (KAUST). He has been a
coauthor of various peer-reviewed journals; and PI or a Co-PI of more than 50 million dollars of
IEEE, SPIE, and OSA conference papers. His funded research from NSF, DOD, SRC, and the
research interests include the design and simulation of solar cells, optical industry. He has published more than 500 papers
metasurfaces, chiral meta-structures, 2-D materials, MEMS, and phononic in leading peer-reviewed journals and conference
devices. publications. His current research interests include
the design of state-of-the-art innovative technolog-
ical solutions that span a broad range of technical areas, including smart
cities, autonomy, smart health, smart mobility, embedded systems, nanopho-
tonics, and spintronics. His research group was responsible for developing
the world’s first realization of compressive sensing systems for signals,
which provided an unprecedented one-order of magnitude savings in power
consumption and significant reductions in size and cost and has enabled
the implementation of self-powered sensors for smart cities and ultra-low-
power biomedical implantable devices. He was selected as one of ten MIT
Alumni Featured by the MIT’s Electrical Engineering and Computer Science
Department, in 2012. He was a recipient of the Rising Star of Texas Medal,
NASIR MAHMOOD (Member, IEEE) received the National Science Foundation CAREER Award, the DAC Fellowship, the
the Ph.D. degree in electrical engineering from Synopsys Special Recognition Engineering Award, and several best paper
the National University of Sciences and Technol- awards. He has served on the IEEE CAS Award Nomination Committee,
ogy (NUST), Pakistan. He is currently a Post- the IEEE Mac Valkenburg Award Committee, the IEEE CAS Fellow Com-
doctoral Research Fellow with the Innovative mittee, the IEEE Rebooting Computing Steering Committee, and the IEEE
Technologies Laboratories (ITL), Electrical and Nanotechnology Council. He served as the 2016 IEEE MWSCAS Technical
Computer Engineering (ECE) Department, King Program Co-Chair, the 2009 General Program Co-Chair, and the 2007 Tech-
Abdullah University of Science and Technology nical Program Co-Chair for the ACM Great Lakes Symposium on VLSI.
(KAUST), Saudi Arabia, under the supervision of He has served as an Editor for the Mixed-Signal Letters and The Americas,
Prof. Yehia Massoud. He completed his research an Associate Editor for IEEE Transactions on Very Large Scale Integration
work through collaboration with the University of Birmingham, U.K., and (VLSI) Systems and IEEE Transactions on Circuits and systems—I: Regular
the Pohang University of Science and Technology, South Korea. He has con- Papers, and a Guest Editor for a Special Issue for Transactions on Circuits and
tributed various research works in peer-reviewed journals and international systems—I: Regular Papers. He was also named a Distinguished Lecturer by
conferences. His current area of research is 2-D-metamaterials, meta-optics the IEEE Circuits and Systems Society.
and -photonics, and optical system design. He is a member of SPIE and OSA.