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Atomic Structure Assignment

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36 views3 pages

Atomic Structure Assignment

gg

Uploaded by

DR. SK. JENA
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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ASSIGNMENT

SUBJECT: Physical Chemistry Chapter: Atomic Structure

READ THE INSTRUCTIONS CAREFULLY

1. This assignment consists of Twenty Questions.

2. In each question has four alternatives, out of which only one is correct. Choose the correct

alternative.

3. For each correct answer carries 3 marks whereas 1 mark will be deducted for each wrong

answer.

Single Correct Type Questions


1. The ratio of the energy of a photon of 2000Å wavelength radiation to that of 4000Å radiation is
(A) 1/2 (B) 4 (C) 1/2 (D) 2

2. The energy of electron is maximum at


(A) Nucleus (B) Ground state
(C) First excited state (D) Infinite distance from the nucleus

3. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon
(A) 3 s (B) 2p (C) 2 s (D) 1s

4. The third line in Balmer series corresponds to an electronic transition between which Bohr's orbits
in hydrogen
(A) 5 → 3 (B) 5 → 2 (C) 4 → 3 (D) 4 → 2

5. The orbital angular momentum of an electron in 2 s orbital is:


1
(A) +  (B) Zero (C) (D) 2
2 2 2 2

6. Which quantum number is not related with Schrodinger equation


(A) Principal (B)Azimuthal (C) Magnetic (D) Spin

7. The shortest wavelength of He atom in Balmer series is x , then longest wavelength in the
Paschene series of Li+2 is
36x 16x 9x 5x
(A) (B) (C) (D)
5 7 5 9

8. An electron in a hydrogen atom in its ground state absorbs energy equal to the ionisation energy
of Li+2 . The wavelength of the emitted electron is:
(A) 3.32Å (B) 1.17Å (C) 2.32nm (D) 3.33pm

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9. An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E respectively.
What is the qualitative order of their de Broglie wavelengths?
(A) e  p =  (B) p =   e (C) p  e   (D)    e »p

10. →Li+3 ( g) + 3e− is 19800kJ / mole &IE1 for Li is 520 then IE2 & IE3
Given H for the process Li(g) ⎯⎯⎯

of Li+ are respectively (approx, value)


(A) 7505,11775 (B) 520,19280 (C) 11775,19280 (D) Data insufficient

11. The ratio of difference in wavelengths of 1st and 2nd lines of Lyman series in H -like atom to

difference in wavelength for 2 nd and 3rd lines of same series is:


(A) 2.5: 1 (B) 3.5: 1 (C) 4.5: 1 (D) 5.5: 1

12. If radius of second stationary orbit (in Bohr's atom) is R . Then radius of third orbit will be
(A) R / 3 (B) 9R (C) R / 9 (D) 2.25R

13. The ratio of wave length of photon corresponding to the -line of Lyman series in H-atom and
-line of Balmer series in He+ is
(A) 1: 1 (B) 1: 2 (C) 1: 4 (D) 3: 16

14. Three energy levels P,Q,R of a certain atom are such that EP  EQ  ER . If  1 , 2 and 3 are the

wave length of radiation corresponding to transition R → Q;Q → P and R → P respectively. The


correct relationship between  1 , 2 and 3 is

1 1 1 2 1 1
(A)  1 + 2 = 3 (B) = + (C) 3 = 12 (D) = +
 3  1 2  3  1 2

15. (
The value of ( n2 + n1 ) and n22 − n21 ) for He+ ion in atomic spectrum are 4 and 8 respectively. The

wavelength of emitted photon when electron jump from n2 to n1 is

32 9 9 32
(A) R (B) R (C) (D)
9 H 32 H 32RH 9RH

16. Number of possible spectral lines which may be emitted in bracket series in H atom, if electrons

present in 9th excited level returns to ground level, are


(A) 21 (B) 6 (C) 45 (D) 5

17. The first use of quantum theory to explain the structure of atom was made by:
(A) Heisenburg (B) Bohr (C) Planck (D) Einstein

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18. The wavelength associated with a golf weighing 200 g and moving at a speed of 5m / h is of the
order

(A) 10−10 m (B) 10−20 m (C) 10−30 m (D) 10−40 m

19. The longest wavelength of He+ in Paschen series is " m ", then shortest wavelength of Be+3 in
Paschen series is (in terms of m ):
5 64 53 7
(A) m (B) m (C) m (D) m
36 7 8 64

20. What is uncertainity in location of a photon of wavelength 5000Å if wavelength is known to an


accuracy of 1pm ?

(A) 7.96  10−14 m (B) 0.02m (C) 3.9  10−8 m (D) none

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