KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION

CLASS: XII WORKSHEET No: 01

CHAPTER: SOLUTION TIME: 35 MINUTES

Q.1 Increasing the temperature of an aqueous solution will cause:

(a) decrease in molality (b) decrease in molarity
(c) decrease in mole fraction (d) decrease in % (w/w)
Q.2 The value of Henry’s constant KH is:
(a) greater for gases with higher solubility (b) greater for gases with lower solubility.
(c) constant for all gases. (d) not related to the solubility of gases
Q.3 Which of the following condition is not satisfied by an ideal solution?
(a) ΔHmixing = 0 (b) ΔVmixing = 0
(c) Raoult’s Law is obeyed (d) Formation of an azeotropic mixture
Q.4 If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be_
(a) 0.25 mol L-1 (b) 0.5 mol L-1
-1
(c) 5 mol L (d) 1.0 mol L-1
Q.5 If two liquids A and B form minimum boiling azeotrope at some specific composition then _____.
(a) A–B interactions are stronger than those between A–A or B–B.
(b) vapour pressure of solution increases because a greater number of molecules of liquids A and B can
escape from the solution.
(c) vapour pressure of solution decreases because a smaller number of molecules of only one of the
liquids escape from the solution.
(d) A–B interactions are weaker than those between A–A or B–B
Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate
answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Q.6 Assertion (A): Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points
either greater than both the components or less than both the components.
Reason (R): The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.
Q.7 Assertion (A): Soda bottles are sealed under high pressure.
Reason (R): High pressure increases the solubility of carbon dioxide gas
Answer the questions in short
Q.1 (a) Define Mole fraction: (b) Azeotropes
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Q.2 State the law co-relating the pressure & solubility of a gas in a liquid. State an application of this law.
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Q.3 What type of deviation is shown by mixture of ethanol and acetone? Give reason.
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Q.04 Write two differences between the solutions showing positive & negative deviation from
Raoult’s law.
Ans:
Solutions having Positive deviation Solutions having Negative deviation

Q.05 On mixing liquid X and liquid Y , the volume of the resulting solution increases _
(a) What type of deviation from Raoult’s law is shown by the resulting solution?
(b) What change in temperature would you observe after mixing liquids X and Y?
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(a) ___________________________________________________
(b) ___________________________________________________
Q.06 A solution of glucose (C6H12O6) in water is labelled as 10% by weight. What would be the molality
of the solution? (Molar mass of glucose = 180 g mol–1)
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Q.7 Give reason for followings
(a) Why are aquatic species more comfortable in cold water than in warm water?
(b) Deep sea divers are advised not to come to surface immediately from deep waters. Why?
(c) Cooking is faster in pressure cooker than in cooking pan
(d) Two liquids A and B boil at 120oC and 160oC respectively. Which of them has higher vapour
pressure at 70oC?
(e) Name the substances which are used by deep sea divers to neutralize the toxic effects of nitrogen
dissolved in the blood.

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 KENDRIYA VIDYALAYA SANGATHAN AHMEDABAD REGION
CLASS: XII WORKSHEET No: 02
CHAPTER: SOLUTION TIME: 35 MINUTES
Q.1 Colligative properties depend on:
(a) the nature of the solute (b) the number of solute particles in solution
(c) the physical properties of solute (d) the nature of the solvent
Q.2 The most suitable colligative property to determine molecular weight of biomolecules is:
(a) Lowering of vapour pressure (b) Osmotic pressure
(c) Elevation of boiling point (d) Depression of freezing point
Q.3 Which has highest boiling point:
(a) 1 M Glucose (b) 1 M NaCl
(c) 1 M CaCl2 (d) 1 M AlF3
Q.4 A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small amount
of ‘A’ is added to the solution. The solution is _________.
(a) saturated (b) supersaturated
(c) unsaturated (d) concentrated
Q.5 The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are_____.
(a) 2, 2 and 2 (b) 2, 2 and 3
(c) 1, 1 and 2 (d) 1, 1 and 1

Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate
answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Q.6 Assertion(A): Boiling point of 0.1 M KCl solution is higher than 0.1 M Glucose solution.
Reason: Glucose is a non-electrolyte while KCl molecule dissociates in aqueous state.
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Q.07 Assertion (A): Human blood cell swell-up when it is placed in a NaCl solution having concentration more
than 0.9%.
Reason (R): Osmosis involves movement of solvent molecules from its higher concentration to its lower concentration.

Answer the questions in short

Q.1 Define (a) Abnormal molar mass: (b) van’t Hoff factor
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Q.2 Give reasons:
(a) RBC shrink when placed in saline water but swell in distilled water.
(b) 0.1 M KCl has higher boiling point than 0.1 M Glucose.
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Q.3 A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of water. This
solution has a boiling point of 100.420C. What mass of glycerol was dissolved to make this solution?
(Kb for water = 0.512 K Kg mol -1)
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Q.4 A solution containing 15 g urea (molarmass= 60 g mol–1) per liter solution in water has the Same
osmotic pressure (isotonic) as a solution of glucose (molar mass= 180 g mol –l) in water. Calculate the
mass of glucose present in one liter of its solution.
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Q.5 Calculate the freezing point of a solution when 20 g of CaCl2 (M=111 g mol -1) was dissolved in 500
g of water, assuming CaCl2 undergoes complete ionization. (Kf for water = 1.86 K kg mol-1)
OR
Calculate the boiling points of solution when 2 gm of Na2SO4 (molecular mass 142 gm/mol) was
dissolved in 50 gm of water assuming Na2SO4 undergoes complete ionization. (Kb for water = 0.52 K Kg
mol-1)
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Q.6 A 5% solution (by mass ) of cane sugar in water has freezing point of 271 K. Calculate the freezing
point of 5% solution (by mass ) of glucose in water
(Molecular mass: Glucose C6H12O6 : 180 amu; Cane –sugar C12H22O11: 342 amu)
OR
3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62K.
Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated)
(Given molar mass of benzoic acid = 122 g mol -1, Kf for benzene = 4.9 K kg mol -1)
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