Chapter 1,2,3,6,7,8

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No. of Questions: 33
2024-25
HALF YEARLY EXAMINATION,
CHEMISTRY
TIME :3 Hrs. ] CLASS XII [ M. M. : 70
General Instructions -
There are 33 questions in this question paper with internal choice.
2. SECTION A consists of 16 multiple choice questions carryng 1 mark each.
3. SECTION Bconsists of 5 very short answer guestions carrying 2 marks
each.
4. SECTIONC consists of 7short answer questions carrying 3 marks each.
5. SECTIOND consists of 2 case based questions carrying 4 marks each.
6. SECTIONE consists of 3long answer questions carrying 5 marks each.
7. All questions are compulsory
(SECTION-AJ
Q.1 What is the mole fraction of 52 m aqueous solution of methyl alcohol: 1
(a) 0·1 (b) 0-19
(©), 0-086 (d) 0-05
Q.2 Choose the odd one out:
(a) Daniel cell (b) Concentration cell
(c) Voltaic cell (d) Galvanic cell
Rate law for the reaction A+ B Cis found to be R = KIAIBI
If the volume is reduced to its half then the rate of the reaction will be : 1
(a) Halved (b) Doubled
(c) Quadrupled (a) One fourth
1
Chloroform on exposure to air in the presence of sunlight gives:
(a) Phosphoryl chloride (b) Phosphine
(C) Phosgene (d) Phosphorus oxytrichloride
IUPAC name of cumene is : 1

(a) Isobutyl benzene (b) Isopropyl benzene


(c) 2-methoxy phenol () 2, 4, 6-trinitro
phenol
XIUChemistry/KA-151
Molecularity is .
Correct statement about
(a) It can be zero
than three
(b) It i_ not greater
exparimentally
{c) It is measured
measured for complex and elementary reactions.
(d) It can be
Q.7
Through the solution of CuSO, a current of 5A is passed for 30 min calculate the
g/mol) :
amount of copper deposited (molar mass of Cu = 63-5
(a) 3-40 (6) 2-96
(c) 1·108 (d) 4-66
Q.8 The product obtained when benzyl alcohol is treated with Cu at 573 K . 1

(a) Acetone (b) 2-acetoxy benzoic acid


(c) Salicylic acid (d) Benzaldehyde
Q.9 Ketone reacts with X to give ketal. X is :
(a) Ethanol (b) Glycerol
(c) Glycol (d) Methanol
Q.10 The degree of dissociation of Ni(NO,), is 0-6. Calculate the Vant hoff
factor : 1

(a) 3-2 (b) 2:2


(c) 4-1 (d) 2-1
The species which attacks the ring in Riemer Tienmann reaction is :
(a) Cr (b) :CCI,
(c) :cC1, (d) CHC,*
1
Q.12 During electrolysis of aqueous NaCI at cathode :
(a) Oxygen is liberated
(b) Sodium is deposited
(c) Hydrogen is liberated
(d) Chlorine is liberated
of two
Directions (Q. No. 15-18) : Each of the following questions consists
statements, one is Assertion and the other is Reason. Give answer : the
(a) Both Assertion and Reason are correct and Reason 1s a correct explanation of
Assertion.
explanation
(b) Both Assertion and Reason are correct but Reason 1s not the acorrect
of the Assertion.
XIVChemistry/KA-151 |2 ]
(c) Assertion is correct but Reason is incorrect.
(d) Both the Assertion and Reason are incorrect.
alcohols do Oxidation ).
Q.13 Assertion : Tertiary not undergo
Reason : Tertiary alcohols do not have alpha hydrogen
Assertion : Only primary haloalkane reacts with sodium alkoxide to form
Q.14
ether. b 1

Reason : Primary haloalkanes get stablised due to hypercongugauon.


reaction of carbonyl
Q.15 Assertion: Carboxylic acid does not give characterstie
1
group.
Reason : Carbonyl group in acid is resonance stabilized.
Q.16 Assertion : Haloarenes cannot undergo nucleophilic substitution. 1

Reason : Haloarenes show -R effect.


[SECTION-B]
Q.176 Vinyl halide does not undergo nucleophilic substitution easily. Why ? 2

(b) Write the IUPAC nanme and structure of chloral.


0.18(a) Production of ammonia in dry cellshould obstruct with the flow of current but
practically this does not happen. Why ? 2

(b) How Am can be calculated for water.


Differentiate between order and molecularity. 2
OR
Half lifeof a first order reaction is 60s. Calculate the time in which reactant is
reduced to 60%.
Q.20 Give a test to distinguish between : 2
(a) Ethanol and phenol
(b) Ethanal and formic acid
Calculate the potential of the cell at 28 : 2

Zn/Zn* (01 M) I Agt (0-03 M)/Ag


Given E° for Znt/Zn =-0.76 V, ABVAB=080 V, R =8314 J mo-!,
F=96500 C mol-!
[SECTION-C]
Q.22 For a reaction the activation energ for backward reaction exceeds activation
energy lOr Torward reaetinn by 2RT. The PreePonential factor for forwardreaction
reaction.
than that of backward
is 4 times more
XII/Chemistry/KA-1S1 Calculate
AG -nâ nfs. AGO at 300K.
3
OR
(a) Define activation energy.
(b) The balf Jife periods or a reaction at a given pressure are :
P(mm Hg) 20 40 80
6"4 3·2
T2 (seconds) 1:6
What is the order of the reaction 9
Q.23 The degree of dissociation of Ca(NO,), in a dilute aqueous solution, containing
7-0 gof salt per 100 g f water at 100°C is 70%. If the vapour pressure of water
at 100°C is 760 mm, calculate the vapour pressure of the solution. 3
Q.24(a) Given Fe?+ + 2e ’ Fe (s) E° =-0"47 V 3
Fet + e Fe2+ E° = + 0-77 V

Calculate standard reduction potential for Fe* to Fe.


(b) Write the name of a chemical substance which is used to prevent corrosion.
Q25 Explain the following reactions : 3

(a) Stephen reaction


(b) Aldol condensation reaction
A primary alkyl halide (A), C,H,Br reacted with hot alcoholic KOH to give
compound (B). Compound (B) reacted with HBr to give (C), which is an isomer
of (A). When (A) was reacted with sodium metal, it gave a compound (D), CHg
which was different than the compound when n-butyl bromide was reacted with
sodium. Give the structural formula of A, B, C and D and write equations of all
3
the reactions.
3
Q27a) Give reason :
(1) Though haloalkanes are polar in nature but insoluble in water. Why ?
() naloalkanes with alcoholic KOH undergo elemination reaction. Why ?
(by Complete the reaction :
CH,CCH),CH =CH, +HBr 3
Q28 Give reason
There are two NH, groups in semicarbazide however only one participates in the
reaction.
In
Why ?
(b} the reaction of derivatives, PH is maintained between
Why ? aldehyde
3 to 5. with ammonia
(X
Benzaldehyde
XIVChemistry/kA-151
does not give fehling's test. Why ?
[SECTION-D]
Directions (Q. No. 31-32): The following questions are case-based questions.
4 marks each.
Each question has an internal choice and carries
of a solvent in Solution is less th¡n that of the pure solvent.
Vapour pressure
non-volatile solute is added to a
Vapour pressure of solution decreases when a
which are connected with
volatile solvent. There are many properties of solutions
4
this decrease of vapour pressure, These are :
Relative lowering of vapour pressure of the solvent
Elevation of boiling point of the solvent
Depression of freezing point of the solvent
Osmotic pressure of the solution
(a) What is meant by colligative properties ? Give two examples for the same.
(b) Define cryoscopic constant
(c) What is meant by freezing point depression ? Draw a graph of vapour pressure
Vs Temperature to show depression in freezing point.
OR
(d) The boiling point of benzene is 353-23 K. When 152 g of a non-volatile
solute was dissolved in 75g of benzene, the boiling point is raised to
354-11 K. Kb is 4-9 KK.g Mol-.
Calculate the mnolar mass of the solute.
Q.30 The order of a reaction is sometimes altered by conditions. There are many
reactions which obey first order rate law although they are higher order reactions.
Consider the hydrolysis of ethyl acetate which is a chemical reaction between
ethyl acetate and water. In reality, it is a second order reaction and concentration
of both ethyl acetate and water affect the rate of the reaction, But water is taken
in large excess for hydrolysis, thereiore, concentration of water is not altered
much during the reaction. Thus, the rate of reaction is affected by concentration
of ethyl acetate only.
(a) Define Pseudo first order reaction.
(b) Mention one example of zero order reaction.
(c) For a reaction
2H,0,2H,0+ 0,
The fate law is given as R = K[H,Ozll Write the mechanism of the reaction.
XIVChemistry/KA-151 |5 ]
OR
for 99-9% Completion of the first order
(a) Show that time required
10 times of Ly2 for first order chemical reaction.
kolbtyykmore
reaction is
(SECTION-E]
2.5Ha) Aquatic soecies are more comtoraole in cold waters than in warm waters
RBC swell up and finally burst when placed in 0-1% NaCl solution,
{c) What are jdeal solutions ? Write two examples.
(d) 2g of CH, COOH dissolved in 25 g of benzene shows depression in
point equal to 1-62 K. Molar freezing point depression constant fr benzene isfreezing
4-9 Kkg mo-!, What is the percentage association of acid if it forms a dimer in
solution ?
OR
(a) IfN, gas is bubbled through water at 293 K, how many millimoles of N, gas would
dissolve in 1 litre of water ? Assume that N, exerts a partial pressure of 0-987 bar.
Given that Henry's law constant for N, at 293 K is 76-48 k bar.
(b) Calculate the depression in the freezing point of water when 10 g of
CHCH,CHCICOOH is added to 250 g of water. Ka = 1·4 x 10,
Kf = 186 K kg mol-.
Q.32(a) Write the mechanism of ether formation by the dehydration of
alcohol.
(b) How are the following
conversions carried out :
(i) Ethanal to propanal
(ii) Methanol to propyne
OR
An aromaic compound 'A' on treatment with
'B' & C', Both CHCI,/KOH gives two compou
'B' & 'C' Same product D' when distilled ith Zn dust.
gives
Oxidation of D' gives E having formula CH0O The sodium salt ofE' 0n
heating with sodalime gives 'F' which may also be obtained by distilling 'A' with
Zn dust. ldentify A' to
F'.
Arrange the following in increasing order of acidic strength Benzoic acid;
4-Nitrobenzoic acid:)3,
(b) An organc 4-Dinitrobenzoic acid)4-Methoxybenzoic acid. oxygen.
compound contains 69-77% carbon, l1-63% hydrogen and 1rest
The molecular
mass of the reagent
hut forms addition compoundcomnound is 86. It does not reduce Tollen's
with sodium hydrogensulphite and give positive
XIUChemistry/KA-151
|61
iodofonn test.
On vigorous
oxidation it gives ethanoic and propanoic acid.
Write
the name and structure of associated
the compound. Write all the reactions.
OR
Complete each synthesis by giving missing starting material. reagent or
products :
CH,CH, COOH
KMnO4 SOCl,
KOH, heat heat
COOH

HNCONHNH, D
fe) CçH,CHO

[Ag(NH) CHO NaCNHCI


(e)
CHO COOH

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