Second Law
Second Law
Heat losses to
the surrounding air from the steam as it passes through the pipes and other components
are estimated to be about 8 GJ/h. If the waste heat is transferred to the cooling water at
a rate of 145 GJ/h, determine (a) net power output and (b) the thermal efficiency of this
Ans.
𝑄𝐿 750 𝑘𝐽/𝑚𝑖𝑛
𝐶𝑂𝑃 = = = 2.08
𝑊net, in 6 𝑘𝑊 𝑥 60
Rate of heat discharge to the outside air
Ans.
Specific heat of watermelons, c = 4.2 kJ/kg.oC.
The total amount of heat that needs to be removed from the watermelons
Optimistic since heat gain of the refrigerator through its walls, door, etc. is neglected
Ans.
For reversible cyclic devices, =
𝑇 = 𝑇 = 297 𝑥 650/250 = 772.2 K
ηth = 1 - =1- .
= 61.5 %
Ans.
The highest thermal efficiency a heat engine operating between two
specified temperature limits can have is the Carnot efficiency
Answer: The rates of heat supply and heat rejection of a power plant are given.
The power output and the thermal efficiency of this power plant are to be
determined.
2: Heat losses from the working fluid at the pipes and other
components are taken into consideration.
(b) The thermal efficiency of the plant is determined from its definition,
̇ ,
ƞℎ= ̇
= 127/280 = 0.454 = 45.4 %
6–21: An automobile engine consumes fuel at a rate of 28 L/h and delivers 60 kW
of power to the wheels. If the fuel has a heating value of 44,000 kJ/kg and a
density of 0.8 g/cm3 , determine the efficiency of this engine.
Answer : The power output and fuel consumption rate of a car engine are given.
The thermal efficiency of the engine is to be determined.
Answer: The power consumption and the cooling rate of an air conditioner are
given. The COP and the rate of heat rejection are to be determined.
𝑄̇ 750 𝑘𝐽/𝑚𝑖𝑛 1 𝑘𝑊
𝐶𝑂𝑃 = = ∗ = 2.08
𝑊̇ , 6 𝑘𝑊 60 𝑘𝐽/𝑚𝑖𝑛
(b) The rate of heat discharge to the outside air is determined from the energy
balance,
Answer: The COP and the power consumption of a refrigerator are given. The
time it will take to cool 5 watermelons is to be determined.
Analysis The total amount of heat that needs to be removed from the
watermelons is
That is, this refrigerator can remove 1.125 kJ of heat per second. Thus the time
required to remove 2520 kJ of heat is
∆𝑡 = ̇
= = 2240 𝑠 = 37.3 𝑚𝑖𝑛
. /
This answer is optimistic since the refrigerated space will gain some heat during
this process from the surrounding air, which will increase the work load. Thus, in
reality, it will take longer to cool the watermelons.
6–72: A Carnot heat engine receives 650 kJ of heat from a source of unknown
temperature and rejects 250 kJ of it to a sink at 24°C. Determine (a) the
temperature of the source and (b) the thermal efficiency of the heat engine.
Answer: The sink temperature of a Carnot heat engine and the rates of heat supply
and heat rejection are given. The source temperature and the thermal efficiency of
the engine are to be determined.
𝑇 = 𝑇 = ∗ 297 𝐾 = 772.2 𝐾
(b) The thermal efficiency of a Carnot heat engine depends on the source and the
sink temperatures only, and is determined from
ƞ ℎ,
=1− =1− = 0.615 𝑜𝑟 61.5%
.
6–73: A heat engine operates between a source at 550°C and a sink at 25°C. If
heat is supplied to the heat engine at a steady rate of 1200 kJ/min, determine the
maximum power output of this heat engine.
Answer: The source and sink temperatures of a heat engine and the rate of heat
supply are given. The maximum possible power output of this engine is to be
determined.
Analysis The highest thermal efficiency a heat engine operating between two
specified temperature limits can have is the Carnot efficiency, which is determined
from
Ƞ ℎ,
= ƞ ℎ,
= 1− = 1− = 0.638 𝑜𝑟 63.8%
Then the maximum power output of this heat engine is determined from the
definition of thermal efficiency to be
Assumptions 1 The power plant operates steadily. 2 The kinetic and potential
energy changes are zero.
Analysis (a) The rate and the amount of heat inputs to the power plant are
̇
𝑄̇ = ,
= = 937.5𝑀𝑊
ղ .
The amount and rate of coal consumed during this period are
. ∗
𝑚 = = = 2.893 ∗ 10 𝑘𝑔
/
. ∗
𝑚̇ = = = 33.48𝑘𝑔/𝑠
∆ ∗
(b) Noting that the air-fuel ratio is 12, the rate of air flowing through the furnace is
Answer: The COP and the refrigeration rate of a refrigerator are given. The power
consumption of the refrigerator is to be determined.
Analysis Since the refrigerator runs one-fourth of the time and removes heat from
the food compartment at an average rate of 800 kJ/h, the refrigerator removes heat
at a rate of
when running. Thus the power the refrigerator draws when it is running is
̇ /
𝑊̇ , = = = = 0.40𝑘𝑊
.
6–44 When a man returns to his well-sealed house on a summer day, he finds that
the house is at 32°C. He turns on the air conditioner, which cools the entire house
to 20°C in 15 min. If the COP of the air-conditioning system is 2.5, determine the
power drawn by the air conditioner. Assume the entire mass within the house is
equivalent to 800 kg of air for which cv 0.72 kJ/kg · °C and cp 1.0 kJ/kg · °C.
Analysis Since the house is well-sealed (constant volume), the total amount of heat
that needs to be removed from the house is
This heat is removed in 15 minutes. Thus the average rate of heat removal from the
house is
𝑄 6912𝑘𝐽
𝑄̇ = = = 7.68𝑘𝑊
∆𝑡 15 ∗ 60𝑠
Using the definition of the coefficient of performance, the power input to the air-
conditioner is determined to be
̇ .
𝑊̇ , = = = 3.07𝑘𝑊
.
6–46 Determine the COP of a refrigerator that removes heat from the food
compartment at a rate of 5040 kJ/h for each kW of power it consumes. Also,
determine the rate of heat rejection to the outside air.
The rate of heat rejection to the surrounding air, per kW of power consumed, is
determined from the energy balance,
Analysis The amount of heat the resistance heaters supply to the house is equal to
he amount of electricity they consume. Therefore, to achieve the same heating
effect, the house must be supplied with 1200 kWh of energy. A heat pump that
supplied this much heat will consume electrical power in the amount of
𝑄̇ 1200𝑘𝑊ℎ
𝑊̇ , = = = 500𝑘𝑊ℎ
𝐶𝑂𝑃 2.4
which represent a savings of 1200 – 500 = 700 kWh. Thus the homeowner would
have saved
Answer: The rate of heat loss, the rate of internal heat gain, and the COP of a heat
pump are given. The power input to the heat pump is to be determined.
Analysis The heating load of this heat pump system is the difference between the
heat lost to the outdoors and the heat generated in the house from the people,
lights, and appliances,
Using the definition of COP, the power input to the heat pump is determined to be
𝑄̇ 56000𝑘𝐽/ℎ 1𝑘𝑊
𝑊̇ , = = = 6.22𝑘𝑊
𝐶𝑂𝑃 2.5 3600𝑘𝐽/ℎ
6–53 Consider a building whose annual air-conditioning load is estimated to be
120,000 kWh in an area where the unit cost of electricity is $0.10/kWh. Two air
conditioners are considered for the building. Air conditioner A has a seasonal
average COP of 3.2 and costs $5500 to purchase and install. Air conditioner B has
a seasonal average COP of 5.0 and costs $7000 to purchase and install. All else
being equal, determine which air conditioner is a better buy.
Assumptions The two air conditioners are comparable in all aspects other than the
initial cost and the efficiency.
Analysis The unit that will cost less during its lifetime is a better buy. The total
cost of a system during its lifetime (the initial, operation, maintenance, etc.) can be
determined by performing a life cycle cost analysis. A simpler alternative is to
determine the simple payback period. The energy and cost savings of the more
efficient air conditioner in this case is
= 13,500 kWh/year
Therefore, the more efficient air-conditioner B will pay for the $1500 cost
differential in this case in about 1 year.
Discussion A cost conscious consumer will have no difficulty in deciding that the
more expensive but more efficient air-conditioner B is clearly the better buy in this
case since air conditioners last at least 15 years. But the decision would not be so
easy if the unit cost of electricity at that location was much less than $0.10/kWh, or
if the annual air-conditioning load of the house was much less than 120,000 kWh.
Answer: The source and sink temperatures of a geothermal power plant are given.
The maximum thermal efficiency is to be determined.
Analysis The highest thermal efficiency a heat engine operating between two
specified temperature limits can have is the Carnot efficiency, which is determined
from
Answer: An inventor claims to have developed a heat engine. The inventor reports
temperature, heat transfer, and work output measurements. The claim is to be
evaluated.
Analysis The highest thermal efficiency a heat engine operating between two
specified temperature limits can have is the Carnot efficiency, which is determined
from
𝑇 290𝐾
ղ , =ղ , =1− =1− = 0.42 𝑜𝑟 42%
𝑇 500𝐾
ƞ = = = 0.429 𝑜𝑟 42.9%
which is greater than the maximum possible thermal efficiency. Therefore, this
heat engine is a PMM2 and the claim is false.
6–80 A geothermal power plant uses geothermal water extracted at 160°C at a rate
of 440 kg/s as the heat source and produces 22 MW of net power. If the
environment temperature is 25°C, determine (a) the actual thermal efficiency, (b)
the maximum possible thermal efficiency, and (c) the actual rate of heat rejection
from this power plant.
Assumptions 1 The power plant operates steadily. 2 The kinetic and potential
energy changes are zero. 3 Steam properties are used for geothermal water.
Properties Using saturated liquid properties, the source and the sink state
enthalpies of geothermal water are
𝑇 = 160℃
𝑥 =0
ℎ = 675.47 𝑘𝐽/𝑘𝑔
𝑇 = 25℃
𝑥 =0
ℎ = 104.83 𝑘𝐽/𝑘𝑔
Analysis (a) The rate of heat input to the plant may be taken as the enthalpy
difference between the source and the sink for the power plant
𝑄̇ = 𝑄̇ − 𝑊̇ , = 251.1 − 22 = 229.1 MW
𝐶𝑂𝑃 , = = = 14.5
The rate of heat removal from the refrigerated space is determined from the
definition of the coefficient of performance of a refrigerator,
𝑄̇ 300𝑘𝐽/𝑚𝑖𝑛 37.36𝑘𝐽
𝑊̇ , , = = = = 0.623𝑘𝑊
𝐶𝑂𝑃 , 8.03 𝑚𝑖𝑛
6–91 An inventor claims to have developed a refrigeration system that removes
heat from the closed region at -12°C and transfers it to the surrounding air at 25°C
while maintaining a COP of 6.5. Is this claim reasonable? Why?
which is above the maximum value. Therefore, these measurements are not
reasonable.
6–95 A heat pump is used to maintain a house at 22°C by extracting heat from the
outside air on a day when the outside air temperature is 2°C. The house is
estimated to lose heat at a rate of 110,000 kJ/h, and the heat pump consumes 5 kW
of electric power when running. Is this heat pump powerful enough to do the job?
Answer: A heat pump maintains a house at a specified temperature. The rate of
heat loss of the house and the power consumption of the heat pump are given. It is
to be determined if this heat pump can do the job.
Analysis The power input to a heat pump will be a minimum when the heat pump
operates in a reversible manner. The coefficient of performance of a reversible heat
pump depends on the temperature limits in the cycle only, and is determined from
1 1
𝐶𝑂𝑃 , = = = 14.75
𝑇 2 + 273𝐾
1− 1−
𝑇 22 + 273𝐾
The required power input to this reversible heat pump is determined from the
definition of the coefficient of performance to be
𝑄̇ 110000𝑘𝐽/ℎ 1ℎ
̇
𝑊 , , = = = 2.07𝑘𝑊
𝐶𝑂𝑃 14.75 3600𝑠
This heat pump is powerful enough since 5 kW > 2.07 kW.
6–96 The structure of a house is such that it loses heat at a rate of 5400 kJ/h per °C
difference between the indoors and outdoors. A heat pump that requires a power
input of 6 kW is used to maintain this house at 21°C. Determine the lowest outdoor
temperature for which the heat pump can meet the heating requirements of this
house.
Answer: A heat pump that consumes 5-kW of power when operating maintains a
house at a specified temperature. The house is losing heat in proportion to the
temperature difference between the indoors and the outdoors. The lowest outdoor
temperature for which this heat pump can do the job is to be determined.
Analysis Denoting the outdoor temperature by TL, the heating load of this house
can be expressed as
Equating the two relations above and solving for TL, we obtain
𝑇 = 259.7 K = -13.3°C
6–97 The performance of a heat pump degrades (i.e., its COP decreases) as the
temperature of the heat source decreases. This makes using heat pumps at locations
with severe weather conditions unattractive. Consider a house that is heated and
maintained at 20°C by a heat pump during the winter. What is the maximum COP
for this heat pump if heat is extracted from the outdoor air at (a) 10°C,
(b) -5°C, and (c) -30°C?
1 1
𝐶𝑂𝑃 , = = = 29.3
𝑇 10 + 273𝐾
1− 1−
𝑇 20 + 273𝐾
1 1
𝐶𝑂𝑃 , = = = 11.7
𝑇 −5 + 273𝐾
1− 1−
𝑇 20 + 273𝐾
1 1
𝐶𝑂𝑃 , = = = 5.86
𝑇 −30 + 273𝐾
1− 1−
𝑇 20 + 273𝐾
6–99 A Carnot heat pump is to be used to heat a house and maintain it at 20°C in
winter. On a day when the average outdoor temperature remains at about 2°C, the
house is estimated to lose heat at a rate of 82,000 kJ/h. If the heat pump consumes
8 kW of power while operating, determine (a) how long the heat pump ran on that
day; (b) the total heating costs, assuming an average price of 8.5¢/kWh for
electricity; and (c) the heating cost for the same day if resistance heating is used
instead of a heat pump.
Answer: A Carnot heat pump consumes 8-kW of power when operating, and
maintains a house at a specified temperature. The average rate of heat loss of the
house in a particular day is given. The actual running time of the heat pump that
day, the heating cost, and the cost if resistance heating is used instead are to be
determined.
Analysis (a) The coefficient of performance of this Carnot heat pump depends on
the temperature limits in the cycle only, and is determined from
1 1
𝐶𝑂𝑃 , = = = 16.3
𝑇 2 + 273𝐾
1− 1−
𝑇 20 + 273𝐾
The amount of heat the house lost that day is
Then the required work input to this Carnot heat pump is determined from the
definition of the coefficient of performance to be
𝑄 1968000𝑘𝐽
𝑊 , = = = 120736𝑘𝐽
𝐶𝑂𝑃 16.3
Thus the length of time the heat pump ran that day is
𝑊 , 120736𝑘𝐽
∆𝑡 = = = 15092 𝑠 = 4.19 ℎ
𝑊̇ , 8𝑘𝐽/𝑠
(c) If resistance heating were used, the entire heating load for that day would have
to be met by electrical energy. Therefore, the heating system would consume
1,968,000 kJ of electricity that would cost
1𝑘𝑊ℎ 0.085$
𝑁𝑒𝑤 𝐶𝑜𝑠𝑡 = 𝑄 ∗ 𝑝𝑟𝑖𝑐𝑒 = (1968000𝑘𝐽) = $46.47
3600𝑘𝐽 𝑘𝑊ℎ
6–100 A Carnot heat engine receives heat from a reservoir at 900°C at a rate of
800 kJ/min and rejects the waste heat to the ambient air at 27°C. The entire work
output of the heat engine is used to drive a refrigerator that removes heat from the
refrigerated space at -5°C and transfers it to the same ambient air at 27°C.
Determine (a) the maximum rate of heat removal from the refrigerated space and
(b) the total rate of heat rejection to the ambient air.
Analysis (a) The highest thermal efficiency a heat engine operating between two
specified temperature limits can have is the Carnot efficiency, which is determined
from
𝑇 300𝑘
ղ , =ղ , =1− = 1− = 0.744
𝑇 1173𝑘
Then the maximum power output of this heat engine is determined from the
definition of thermal efficiency to be
The rate of heat removal from the refrigerated space will be a maximum if a Carnot
refrigerator is used. The COP of the Carnot refrigerator is
1 1
𝐶𝑂𝑃 , = = = 8.37
𝑇 27 + 273𝐾
−1 −1
𝑇 −5 + 273𝐾
Then the rate of heat removal from the refrigerated space becomes
And