Phase Change Materials (PCMS) : Classification and Properties
Phase Change Materials (PCMS) : Classification and Properties
Introduction
hase Change Materials (PCMs) are substances that undergo a physical change, typically from
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solid to liquid or vice versa, while absorbing or releasing a significant amount of heat energy.
This unique property makes them invaluable for thermal energy storage and management
applications.
Classification of PCMs
PCMs can be classified based on several criteria, including:
● S olid-Liquid PCMs:These are the most common type, absorbing and releasing heat during
the melting and solidification process.
● Solid-Solid PCMs:These undergo a phase change between two solid states, often with
different crystal structures.
● Liquid-Gas PCMs:These absorb and release heat during evaporation and condensation.
● O rganic PCMs:Derived from natural or synthetic sources, they are typically non-corrosive,
non-toxic, and have good chemical stability. Examples include fatty acids, paraffins, and
sugar alcohols.
● Inorganic PCMs:Derived from mineral sources, they often have high latent heat storage
capacity but can be corrosive and have lower thermal conductivity. Examples include salt
hydrates, metal alloys, and eutectic mixtures.
● E ncapsulated PCMs:PCMs enclosed in a protective shell to prevent leakage and improve
compatibility with other materials.
● Microencapsulated PCMs:PCMs encapsulated in microscopic capsules for enhanced heat
transfer and stability.
Properties of PCMs
Several key properties determine the suitability of a PCM for a specific application:
● L atent Heat:The amount of heat absorbed or released during the phase change. A high
latent heat is desirable for efficient energy storage.
● Melting/Freezing Point:The temperature at which the phase change occurs. It should
match the desired operating temperature of the system.
● Specific Heat:The amount of heat required to raise the temperature of a unit mass of the
PCM by one degree.
● Thermal Conductivity:The rate at which heat is transferred through the PCM. A high
thermal conductivity is beneficial for efficient heat transfer.
● Volume Change:The change in volume during the phase change. A minimal volume change
is preferred to avoid mechanical stress.
● Supercooling:The tendency of a liquid to cool below its freezing point without solidifying. A
low supercooling tendency is desirable.
● Chemical Stability:The ability of the PCM to maintain its properties over repeated cycles of
melting and solidification.
● Compatibility:The ability of the PCM to be compatible with other materials in the system,
such as containers, heat transfer fluids, and structural components.
● Toxicity and Flammability:Important considerations for safety and environmental impact.
Applications of PCMs
PCMs have a wide range of applications, including:
● uilding energy efficiency:Temperature regulation in walls, roofs, and floors.
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● Textiles:Thermal comfort in clothing.
● Solar energy storage:Storing thermal energy for heating and cooling.
● Food packaging:Maintaining product temperature.
● Electronics cooling:Thermal management of electronic devices.