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XI-Unit 2 Structure of Atom

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XI-Unit 2 Structure of Atom

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mail2shresthraj
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© © All Rights Reserved
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VISHWA BHARATI PUBLIC SCHOOL, NOIDA

CLASS: XI (2024-25)
SUBJECT: CHEMISTRY
Assignment Type: Objective and Subjective Questions
Unit/Topic: Unit 2- Structure of Atom Prepared By: Ms. Pragya Pant

A. Multiple Choice Questions


1. The wavelength associated with a golf ball weighing 200g and moving at a speed of 5m/h
is of the order
(a) 10–10 m (b) 10–20 m
(c) 10–30 m (d) 10–40 m

2. The number of nodal planes in a px orbital is


(a) One (b) Two
(c) Three (d) Zero

3. A 3p orbital has
(a) Two angular nodes (b) Two spherical nodes
(c) One spherical & one angular node (d) One spherical & two angular nodes

4. The radius of which of the following orbit is same as that of the first Bohr’s orbit of
hydrogen atom?
(a) He+ (n = 2) (b) Li2+ (n = 2)
2+
(c) Li (n = 3) (d) Be3+ (n = 2)

5. The correct ground state electronic configuration of chromium atom is:


(a) [Ar] 3d54s1 (b) [Ar] 3d44s2
(c) [Ar] 3d64s0 (d) [Ar] 4d55s1

6. The orbital diagram in which the Aufbau principle is violated is:


2s 2p 2s 2p
(a) (b)

2s 2p 2s 2p
(c) (d)

7. The ratio of the energy of a photon of wavelength 2000Å to that of wavelength 4000Å is:
(a) 1/4 (b) 4
(c) 1/2 (d) 2

8. Which of the following sets of quantum numbers is not possible


(a) n = 3, l = 2, m = 0, s = – ½ (b) n = 3, l = 2, m = –2, s = – ½
(c) n = 3, l = 3, m = –3, s = + ½ (d) n = 3, l = 1, m = 0, s = + ½

9. Which of the following is responsible to rule out the existence of definite paths or
trajectories of electrons?
(a) Pauli’s exclusion principle (b) Heisenberg’s uncertainty principle
(c) Hund’s rule of maximum multiplicity (d) Aufbau principle

Vbpsnoida/XI/2024-25/Chemistry
10. Total number of orbitals associated with third shell will be
(a) 2 (b) 4
(c) 9 (d) 3

B. Subjective Questions

11. Calculate the wave number for the shortest wavelength transition in the Balmer series of
atomic hydrogen.

12. Calculate the energy and frequency of the radiation emitted when an electron jumps from n
= 3 to n = 2 in a hydrogen atom.

13. When a photon of frequency 1.0×1015 s–1 was allowed to hit a metal surface, an electron
having 1.988 × 10–19 J of kinetic energy was emitted. Calculate the threshold frequency of
this metal. Show that an electron will not be emitted if a photon with a wavelength equal to
600 nm hits the metal surface.

14. Chlorophyll present in green leaves of plants absorbs light at 4.620 × 1014 Hz. Calculate the
wavelength of radiation in nanometer. Which part of the electromagnetic spectrum does it
belong to?

15. Table-tennis ball has a mass of 10 g and a speed of 90 m/s. If speed can be measured with
an accuracy of 4% what will be the uncertainty in speed and position?

16. With what velocity must an electron travel so that its momentum is equal to that of a photon
of wavelength 560nm?

17. The angular momentum of an electron in Bohr’s orbit of hydrogen atom is 4.22 × 10-34 kg
m2 s-1. Calculate the wavelength of the spectral line when the electron falls from this level
to the next lower level.

18. Which state of the triply ionised Be 3+ ion has the same orbital radius as that of the ground
state hydrogen atom?

19. How many orbitals are present in the subshells with:


(a) n = 3, l = 2
(b) n = 4, l = 3
(c) n = 5, l = 1

20. Give the electronic configurations and the number of unpaired electrons for:
(a) Cu2+
(b) Fe2+
(c) S2-
(d) Na+
(e) K

Vbpsnoida/XI/2024-25/Chemistry

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