1st Year Full Book Tests

Name: Roll#: Class: Inter Part-I
Subject: Chemistry-11 Date: T.Code 5109

Test Type # Type 16 - Full Test - Board Paper Pattern - Marks=85
Syllabus: Full Book
1- Circle the correct one. (17x1=17)

1. Many elements have fractional atomic masses. This is because:
(A) The mass of the atom is itself fractional.
(B) Atomic masses are average masses of Isotopes.
(C) Atomic masses are average masses of isotopes.
(D) Atomic masses are average masses of isotopes proportional to their relative abundance.
2. A component having small value of K (distribution coefficient) mostly remains in the:
(A) Stationary phase (B) Mobile phase (C) Chromatographic tank (D) Solvent
3. The S.I unit of pressure is:
(A) Torr (B) mmHg (C) Pounds inch-2 (D) Nm-2
4. The commonly used unit of pressure by meteorologists is:
(A) Atmosphere (B) Pascal (C) Millibar (D) Pound inch-2
5. Acetone and chloroform are soluble in each other due to:
(A) Intermolecular hydrogen bonding (B) Dipole-dipole interaction (C) Instantaneous dipoles
(D) All of the above
6. Which is Pseudo solid?
(A) CaF 2 (B) Glass (C) NaCl (D) CaCl 2
7. Maximum number of electrons in f-subshell is:
(A) 2 (B) 6 (C) 10 (D) 14
8. Which of the foillowing has bond angle of 120o:
(A) BeCl2 (B) BF3 (C) CH4 (D) NH3
9. The molecular shape of SO3 is:
(A) Triangular planar (B) Tetrahedral (C) Pyramidal (D) Linear
10. The bond order of N2 molecule is:
(A) 1 (B) 2 (C) 3 (D) 4
11. The born-Haber cycle is the best application of law:
(A) Boyle's (B) Dalton's (C) Hess's (D) Graham's
12. Enthalpy of neutralization of all the strong acids and strong bases has the same value because:
(A) Neutralization leads to the formation of salt and water
(B) Strong acids and bases are ionic substances
(C) Acids always give rise to H+ions and bases always furnish OH- ions
(D) The net chemical change involves the combination of H+ and OH- ions to form water
13. pOH of water is:
(A) 2.0 (B) 4.0 (C) 6.0 (D) 7.0
14. The value of ionic product (Kw) of water at 25 oC is:
(A) 0.11 x 10-14 (B) 0.30 x 10-14 (C) 1.0 x 10-14 (D) 3.0 x 10-14
15. The PH of human blood is maintained at PH:
(A) 7.4 (B) 7.3 (C) 7.00 (D) 8.00
16. The molal boiling point constant is the ratio of the elevation in boiling point to:
(A) Molarity (B) Molality (C) Mole fraction of solvent (D) Mole fraction of solute
17. All radioactive disintegration nuclear reactions are of:
(A) First-order (B) Second-order (C) Third-order (D) Zero order
Name: Roll#: Class: Inter Part-I
Subject: Chemistry-11 Date: T.Code 5109
Test Type # Type 16 - Full Test - Board Paper Pattern - Marks=85
Syllabus: Full Book
(SECTION-I)
2- Write short answers to any EIGHT (8) of the following questions. (8x2=16)
(i) What is Avogadro’s number? Give equation to relate the Avogadro’s number and mass of an element. (ii)
Define chromatography. Give formula of distribution coefficient. (iii) Why deep sea divers take oxygen mixed with
an inert gas, Like (He)? (iv) Give reason for the lowest boiling point of hydride of group IV-A elements. (v) Define
allotropy with an example. (vi) Calculate mass of an electron when m e =1.758 x 1011 C. kg-1. (vii) Write down
two postulates of plank’s quantum theory of radiation. (viii) Describe state function with an example. (ix) Define
pH and give the pH of milk and eggs. (x) Give two applications of Buffer solution. (xi) Balance the following
equations by oxidation number method MnO2+ HCl → MnC l 2+ H 2O + C l 2 . (xii) What is Zero-order
reaction? Give one example.
3- Write short answers to any EIGHT (8) of the following questions. (8x2=16)
(i) Calculate the percentage of nitrogen in NH 3 . (ii) Justify how Mg atom is twice heavier than that of carbon
atom. (iii) What is the justification of two strong peaks in the mass spectrum for bromine; while for iodine only one
peak at 127 a.m.u , is indicated? (iv) Write down two applications of chromatography. (v) When energy is
expressed in ergs. (vi) Justify that SO2 is comparatively non-ideal at 273K but behaves ideally at 327Co. (vii)
What are Debye forces? Explain. (viii) Define ionic and covalent radii. (ix) Define enthalpy of neutralization with
one example. (x) Write down the equilibrium constant expression for the dissociation of PCl5. (xi) Balance the
ionic equations by ion-electron method. H 2AsO4+ C r 2O2−
7 → 3H 2AsO4+ 2C r
2+ . (xii) Define first order
reaction with example.
4- Write short answers to any Six (6) of the following questions. (6x2=12)
(i) What is mass spectrum? (ii) Define sublimate. Give two examples. (iii) Why water vapours do not behave
ideally at 273K? (iv) How will you prove that Cathode Rays travel in Straight Line? (v) Define Slow Neutron and
Fast neutron. (vi) What is origin of Hydrogen Spectrum? (vii) What should be the possible effect of change of
temperature at equilibrium stage. In Haber's process. (viii) Find out the pH of 0.1 m HCl solution. (ix) Determine
the oxidation number of Phosphorus in H3PO4.
(SECTION-II)
Note:-
Attempt any THREE (3) questions. (3x8=24)
5(a) NH3 can be produced by heating together two solids NH4Cl and Ca (OH)2 . If a mixture containing 100g of each solid
is heated then how many grams of NH3 is produced? Atomic mass of Ca = 40.
2N H 4CI + Ca(OH ) 2 ⟶ CaC I 2+ 2N H 3+ 2H 2O
Derive different values and units of general gas constant “R” by general gas equation.
(b)
6(a) Do you think that groups of the spectral lines of He+ are at different places than those for hydrogen atom? Give
reasons.
What is meant by the term hydrogen bonding? How does hydrogen bonding explain, the properties of proteins.
(b)
7(a) What is a chemical bond? Discuss the formation of ionic and covalent bonds. How does the electronegativity
difference differentiate between ionic and covalent bond?
How the enthalpy of a reaction is measured by glass calorimeter?
(b)
8(a) The solubility of PbF2 at 25oC is 0.64 g dm −3 0.64 g dm −3 . Calculate Ksp of PbF2. Atomic mass of
P b = 207.2 gmol −1 P b = 207.2 gmol −1 , Atomic mass of F = 19 g mol −1 F = 19 g mol −1 .
How depression in freezing point is measured by Beckmann’s Apparatus.
(b)
9(a) Define standard hydrogen electrode (SHE). How it is used to measure the electrode potential of copper?
Define order of reaction.
(b)

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Name: Roll#: Class: Inter Part-I

Subject: Chemistry-11 Date: T.Code 5109

1- Circle the correct one. (17x1=17)

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