Atomic Structure Success Preacher

‫ٹسیٹرشوعرکےنےسےلہپدروداپکالزیمڑپںیھ۔‬
‫رکسماےترںیہاوروخایشںابےتٹنرںیہ۔‬،‫ےتسنہرںیہ‬

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Physical Chemistry Unit 2:

Atomic Structure

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Atomic Structure Success Preacher

Q.1 When alumina placed in the path of cathode rays, it glows ______.
A. Yellow B. Black
C. Green D. Red
Q.2 Which of following sub atomic particle is not the constituent of all elements?
A. Electron B. Proton
C. Neutron D. All of these are basic components
Q.3 If we observe an element with an atomic number of “24” in its +2 ionic form, predict the
number of electrons present in azimuthal quantum number “l= 0 and l=2” respectively.
A. 6,3 B. 12,4
C. 6,4 D. 12,3
Q.4 The wave number of the light emitted by a certain source is 2 x 106 m-1. The wavelength of
this light will be:
A. 500 nm B. 500 m
C. 200 nm D. 5 x 107 m
Q.5 We have four subshells labelled as “4s,5p,3d,3f”. Arrange these subshells on the basis of their
increasing energy.
A. 3f > 5p > 3d > 4s B. 5p > 3f > 4s > 3d
C. 5p > 3f > 3d > 4s D. 3f > 5p > 4s > 3d
Q.6 Which of following relation is not correct?
A. No of electrons in an orbital = 2(2l+1) B. Group No = Number of electrons in its valence
shell
C. No of shells = Period number D. All of these are correct
Q.7 Which of following d-orbital is exceptional with respect to others?
A. dxy B. dx2-y2
C. dyz D. dz2
Q.8 Which of following statement is not correct?
A. The maximum number of electrons B. An orbital can attain maximum 2 electrons in it
executed by 3f are 14
C. Hund’s rule is only necessary for getting D. All of these are correct statements
the electronic configuration in group
IVA, VA and VIA elements
Q.9 The limiting line of Balmer series lies in ________ region.
A. Ultraviolet B. Infrared
C. Visible D. X-rays
Q.10 As an electron move from lower orbit to higher orbits, which of following statement does not
corresponds to this condition?
A. Electron goes to higher orbit by B. Electron present in higher orbit has greater
absorbing specific amount of energy amount of energy as compared to lower
C. Electron present in higher orbit has equal D. Electrons present in higher orbit can come
space to revolve in circular orbit as back to the lower orbit by releasing specific
compared to lower orbit amount of energy

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Atomic Structure Success Preacher

Q.11 How many number of electrons can be found with the given quantum number values?
“n=2, l=1, s=+1/2”
A. 2 B. 1
C. 6 D. 3
Q.12 Which of following set of quantum number represent the highest amount of energy?
n l m s
A. 2 1 1 +1/2
B. 3 3 2 +1/2
C. 4 2 3 +1/2
D. 4 3 2 0
Q.13 How many numbers of electrons can be accommodated in the given set of quantum
number values? “n=3, l=2, m=0, s= +1/2”
A. 18 B. 10
C. 2 D. 1
Q.14 Which of following element in its “+2” ionic form has the maximum number of unpaired
electrons in its valence shell?
A. Copper B. Zinc
C. Chromium D. Manganese
Q.15 The value of Planck’s constant along with its SI unit is:
A. 6.63 x 10-34 B. 6.63 x 10-38 JS
C. 6.63 x 10-34 Js D. 6.63 x 10-34 J/s
Q.16 Which of following does not increase with the increase in energy of photon?
A. Frequency B. Wave number
C. Wavelength D. All of these increases
Q.17 How many number of electrons can be accommodated in subshell “l=2” in second shell?
A. 6 B. 10
C. 14 D. 0
Q.18 The number of d-electrons in Fe+2 is not equal to:
A. P electrons in Neon B. S electrons in Mg
C. D electrons in Fe D. P electrons in Ar.
Q.19 Which of following are isoelectronic species?
i. He
ii. Ne
iii. F-
iv. NH3
A. II and III only B. I, II and III
C. II, III and IV only D. I, II, III and IV
Q.20 An orbital which is double dumb-bell shaped is:
A. s-orbital B. p-orbital
C. d-orbital D. f-orbital
Q.21 The ionic specie having the more protons as compared to electrons is:
A. Na+ B. Mg+2

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Atomic Structure Success Preacher

C. Al+3 D. All of these

Q.22 Which of following set of quantum number is not possible?
A. n=2, l=1, m=1, s=+1/2 B. n=2, l=0, m=0, s=+1/2
C. n=2, l=1, m=+2, s=+1/2 D. n=2, l=1, m=0, s=-1/2
Q.23 If an electron jumps from higher orbit (n=7) to lower orbit (n=3), the series obtained is known
as:
A. Paschen series B. Brackett series
C. Lyman Series D. Pfund series
Q.24 There are three orbits with the supposed names and energy as follows:
i. n=2, Energy = 20KJ
ii. n=3, Energy = 30KJ
iii. n=4, Energy = 40KJ
The electron is present in “n=1 with the energy=10KJ”. If a photon of energy 15KJ is absorbed
by this electron, it will goes to n=?
A. 2 B. 3
C. In between 2 and 3 D. Will not jump to higher orbit
Q.25 Which of following relation is correct with respect to energy and radius of electron revolving
in hydrogen atom?
A. E2- E1 > E3 - E2 > E4 - E3 B. r 2 - r 1 < r3 - r 2 < r 4 - r 3
C. Both of these are correct D. Both are incorrect
Q.26 How many times the mass of electron is heavier than proton?
A. 4 times B. 1836 times
C. 1840 times D. None of these
Q.27 An element with proton number=28 and mass number=58 is forced to lose its three electrons
to get “+3” ionic form. Which of following will be affected by this lose of electrons?
A. Atomic number B. Atomic mass
C. No of neutrons D. None of these are affected
Q.28 In the ground state of an atom, electron is present:
A. In the nucleus B. In the second shell
C. Nearest to the nucleus D. Farthest from the nucleus
Q.29 Which of following has same number of electrons as alpha particles?
A. Electrons present in He B. Electron present in B+
C. Electrons present in H+ D. Electrons present in H
Q.30 Which of following element has maximum number of protons revolving around the nucleus
of an atom?
A. Sodium B. Aluminium
C. Sulphur D. None of these
Q.31 The unit of Rydberg’s constant is:
A. Equal to unit of length B. Equal to unit of Energy
C. Reciprocal of unit of energy D. Reciprocal of unit of length
Q.32 If we have length one meter and passes the photon of different radiations over it, which of
following will has the highest wave number?

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Atomic Structure Success Preacher

A. Gamma rays B. Micro waves

C. Ultra violet rays D. Infrared
Q.33 Mass of electron in grams is:
A. 9.1095 x 10-31 B. 9.1095 x 10-28
C. 9.1085 x 10-34 D. 9.1095 x 10-29
Q.34 Quantum number which gives us the information about the number of degenerate orbitals is:
A. Principal B. Azimuthal
C. Magnetic D. Spin
Q.35 Which of following relation is incorrect?
A. 2n2 = No of electrons in a shell B. 2(2l+1) = No of electrons in a subshell
C. 2l + 1 = No of orbitals in a subshell D. n2 = No of electrons in a orbital
Q.36 Quantum number, which cannot be zero, positive integers (Cannot be negative), integers
upto infinity is:
A. Principal B. Azimuthal
C. Magnetic D. Spin
Q.37 The no of electrons with positive spin in an element with atomic number = 11 is:
A. 11 B. 5
C. 6 D. 0
Q.38 Number of electrons that can be accommodated in “n=4” is:
A. 10 B. 14
C. 18 D. 32
Q.39 There is no difference between 1s and 2s regarding:
A. Energy B. Shape
C. Size D. All are same
Q.40 Copper and chromium do not follow the ________ rule while writing the electronic
configuration.
A. Aufbau principle B. Pauli’s exclusion principle
C. Hund’s rule D. All of these are violated

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