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    Class 11 Practicals

    Uploaded by

    Sehangshu Manna
    Chemistry students only

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Class 11 Practicals

    Uploaded by

    Sehangshu Manna
    10 views2 pages
    Chemistry students only

    Original Title

    class 11 practicals

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    Chemistry students only

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    10 views2 pages

    Class 11 Practicals

    Uploaded by

    Sehangshu Manna
    Chemistry students only

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    QUALITATIVE ANALYSIS OF INORGANIC COMPOUND

    Aim: To identify one acidic radical radical from given unknown inorganic salt.

    It is carried out in three steps.

    (A) Preliminary Examination:

    (B) Detection of Acidic Radical (anion):

    (C) Detection of Basic Radical (Cation):

    PRELIMINARY EXAMINATION:

    Flame Test: No characteristic flame (Cu2+, Ca2+ , Ba2+ ,Sr2+ ,Pb2+ ,

    Zn2+absent)

    Acidic (Anion) Radical


    Preliminary test with dilute HCl, Dil and Conc.Sulphuric acid

    Experiment Observation Inference


    1] Action of dil.HCl: Salt Solution is treated Nothing characteristics Absence of
    with dilute Hydro chloric acid Carbonate anion
    2]Action of dil.H2SO4:Salt is rubbed with dilute Nothing characteristics Absence of Acetate
    sulphuric acid anion
    3] Action of conc.H2SO4 : Salt is warmed with a colourless gas with may contain Cl– ions
    few drops of conc.H2SO4 . pungent smell (HCl) present
    evolved.
    the gas gives dense white fumes with Cl– ions may present
    ammonia solution(Glass rod ), then the salt
    may contain Cl– ions
    Salt solution acidified with dilute HNO3 on a curdy white precipitate Cl– ions present
    addition of silver nitrate solution soluble in ammonium
    hydroxide solution.

    Confirmatory test for Chloride anion


    Chromyl chloride test : Take 0.1 g salt and a Reddish orange gas
    pinch of solid potassium dichromate in a test is evolved
    tube, add conc. H2SO4 , heat
    and pass the gas evolved through sodium It becomes yellow
    hydroxide solution.
    Divide the solution into two parts.
    Acidify one part with acetic acid and add lead A yellow precipitate of lead Presence of Chloride
    acetate solution. chromate is formed. anion confirmed.
    Acidify the second part with dilute sulphuric After gentle shaking the
    acid and add 1 mL of amyl alcohol followed by organic layer turns blue.
    1 mL of 10% hydrogen peroxide.

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