Doc. No : TPR.YPG.SDS.

0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 1 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product Identifier
Material Name : Bituminous Binder
Other Names of Product: Bituminous Binder Fm2B2, Bituminous Binder Fm3B2
Relevant identified uses of the substance or mixture and uses advised against
It is used for manufacturing of coated roadstone.
1.2 Details of the supplier of the substance or mixture
Manufacturer/Supplier: Tüpraş
Adress : Türkiye Petrol Rafinerileri A.Ş. Genel Müdürlüğü KÖRFEZ/ KOCAELİ
Telephone : +90 262 316 30 00
Fax : +90 262 316 30 10-11
e-mail : [email protected]
[email protected]
1.3 Emergency Telephone Number
Company Telephone : +90 262 316 30 00
2. HAZARDS IDENTIFICATION
2.1 Classification of substance or mixture
Classification According to Regulation (EC) No 1272/2008

Flammable liquids, Category 3 H226

Skin corrosion/irritation, Category 2 H315

Aspiration hazard, Category 1 H304

Specific target organ toxicity-single exposure,

H336
Category 3,

Hazardous to the aquatic environment-

H411
Longterm Hazard, Category 2

2.2 Label Elements

Labelling According to Regulation (EC) No 1272/2008 (CLP/GHS)

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 2 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

Symbols:

GHS02 GHS07 GHS08 GHS09

Signal Word: Danger
Hazard statements: Physical Hazards
H226 Flammable liquid and vapor.
Health hazards
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
Environmental Hazards
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements:
Prevention : P210 Keep away from heat/sparks/open flames/hot surfaces - No smoking
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equipment.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P271 Use
only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face
protection.
Response : P301+P310 IF SWALLOWED: Immediately call a POISON CENTER
or doctor/physician.
P302 + P352 IF ON SKIN: Wash with plenty of water and soap.

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 3 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

P304 + P340 IF INHALED: Remove person to fresh air and keep

comfortable for breathing.
P331 Do NOT induce vomiting.
P391 Collect spillage.
Disposal : P501 Dispose of contents and container to appropriate waste site or
reclaimed in accordance with local and national regulations.
2.3 Other hazards
Slightly irritating to respiratory system.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substance
Risk Phreases
Chemical
CAS NO EINECS NO % Conc. (Regulation (EC) No
Composition
1272/2008)
- Flammable liquids,3 H226
- Skin corrosion/irritation,2
H315
- Aspiration hazard, 1 H304
- Specific target organ
It consists of
toxicity - single
hydrocarbons
8008-20-6 232-366-4 %45-50 exposure,3
having carbon numbers
H336
predominantly between
- Hazardous to the
C9 and C16.
aquatic environment –
Longterm Hazard, 2
H411

Carbon numbers
8052-42-4 232-490-9 predominantly greater
than C25 with high %50-%55 Not classified as hazardous.
carbon to hydrogen
ratios.
H400: Aquatic Acute 1
H220: Falm. Gas 1
7783-06-4 231-977-3 Hydrogen sulfide Trace H330: Acute Tox. 2
H335: STOT SE 3
H410: Aquatic Chronic 1
3.2 Mixtures
Not applicable

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 4 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

4. FIRST-AID MEASURES
4.1 Description of First Aid Measures
Inhalation: If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or
coughing, remove to fresh air. If symptoms persist obtain medical advice.
Skin Contact: Wash skin thoroughly with soap and water as soon as reasonably practicable.
Remove heavily contaminated clothing and wash underlying skin. If hot product causes
burns, the effected area should be flooded immediately with, or immersed in cold water for 15
minutes, or longer if pain persists. Burns should be covered with clean cotton or gauze, and
the casualty taken to hospital as soon as possible for examination and treatment. If redness,
swelling, pain and/or blisters occur, transport to the nearest medical facility for additional
treatment. When using high pressure equipment, injection of product under the skin can
occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital.
Do not wait for symptoms to develop.
Eye Contact: Wash eye thoroughly with copious quantities of water, ensuring eyelids are
held open. If redness, burning, blurred vision, or swelling persist transport to the nearest
medical facility for additional treatment.
Ingestion: If contamination of the mouth occurs, wash out thoroughly with water. Except as a
deliberate act, the ingestion or large amounts of product is unlikely. If it should occur, do not
induce vomiting; obtain medical advice.
4.2 Most important symptoms/effects, acute & delayed
Inhalation: If material enters lungs, signs and symptoms may include coughing, choking,
wheezing, difficulty in breathing, chest congestion, shortness of breath.
Skin Contact: Skin irritation signs and symptoms may include a burning sensation, redness,
swelling, and/or blisters.
Eye contact: Eye irritation signs and symptoms may include a burning sensation and a
temporary redness of the eye.
Ingestion: Swallowing can cause lung damage.
4.3 Indication of immediate medical attention and special treatment needed
There are no specific antidotes or other therapeutic measures, treat symptomatically.
5. FIRE-FIGHTING MEASURES
5.1 Extinguishing Media
Use foam, dry powder or water spray. Dry chemical powder, carbon dioxide, sand or earth
may be used for small fires only.

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 5 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

5.2 Special hazards arising from substance or mixture

Combustion results from toxic gases. It can burn at high temperatures.
5.3 Advice for fire-fighters
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
Use alcohol resistant foam, dry powder, water spray and sand. Fires in confined spaces
should be dealt with by trained personnel wearing approved breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Avoid breathing vapor or mist. Provide adequate ventilation. Put on appropriate personal
protective equipment.
6.2 Environmental precautions
Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other
appropriate barriers.
6.3 Methods and material for containment and cleaning up
Take precautionary measures against static discharges. For small liquid spills (< 1 drum),
transfer by mechanical means to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and
dispose of safely. Remove contaminated soil and dispose of safely. For large liquid spills (> 1
drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow
residues to evaporate or soak up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely. Shovel into a suitable clearly
marked container for disposal or reclamation in accordance with local regulations.
6.4 Reference to other sections
Refer to sections 8 and 13.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Avoid
inhaling vapour and/or mists. Avoid prolonged or repeated contact with skin. When using do
not eat or drink. When handling product in drums, safety footwear should be worn and proper
handling equipment should be used. The vapour is heavier than air, spreads along the
ground and distant ignition is possible. Earth all equipment. Use local exhaust ventilation if

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 6 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated
rags or cleaning materials in order to prevent fires.
7.2 Conditions for safe storage, including any incompatibilities
Drum and small container storage: Drums should be stacked to a maximum of 3 high. Use
properly labelled and closeable containers. Take suitable precautions when opening sealed
containers, as pressure can build up during storage. Tank storage: Tanks must be
specifically designed for use with this product. Bulk storage tanks should be diked (bunded).
Locate tanks away from heat and other sources of ignition. The vapour is heavier than air.
Beware of accumulation in pits and confined spaces. Electrostatic charges will be generated
during pumping. Electrostatic discharge may cause fire. Ensure electrical continuity by
bonding and grounding (earthing) all equipment to reduce the risk. The vapours in the head
space of the storage vessel may lie in the flammable/explosive range and hence may be
flammable.
7.3 Specific end use
Except as provided in Section 1.2 is not required to offer any specific suggestions.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters

Material Exposure Limits

Bitumen
No appropriate occupational exposure limits.
(CAS 8052-42-4)

Kerosene
No appropriate occupational exposure limits.
(CAS 8008-20-6)

8.2 Exposure controls

8.2.1 Appropriate engineering controls
Ensure good ventilation.
8.2.2 Personal protective precautions
Personal protective equipment:
Personal protective equipment (PPE) should meet recommended national standards.
Eyes: Chemical splash goggles (chemical monogoggles).
Skin: Protective clothing and gloves should be used.

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 7 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

Inhalation: Chemical resistant gloves are recommended. Safety glasses with side shields
are recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties

Property Test Unit Guarantee Test Method

Physical state Liquid

Odour Hydrocarbon

Flash point, min °C 60 EN ISO 2719

Softening point, max °C 200 EN 12846-2

9.2 Other Information

No relevant additional information available.
10. STABILITY AND REACTIVITY
10.1 Reactivity
Combustion results from toxic gases.
10.2 Chemical Stability
No hazardous reaction is expected when handled and stored according to provisions.
10.3 Possibility of Hazardous Reactions
Product vapors may form explosive mixtures with air.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition source.
10.5 Incompatible materials
Strong oxidising agents.
10.6 Hazardous decomposition products
Hazardous decomposition products are not expected to form during normal storage. Thermal
decomposition is highly dependent on conditions. A complex mixture of airborne solids,
liquids and gases including carbon monoxide, carbon dioxide, sulphur oxides and
unidentified organic compounds will be evolved when this material undergoes combustion or
thermal or oxidative degradation.

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 8 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Information given is based on product data, a knowledge of the components and the
toxicology of similar products.
Acute Oral Toxicity: Kerosene: LD50 (Rat) > 5000 mg/kg
Acute Dermal Toxicity: Kerosene: LD50 (Rabbit) >2000 mg/kg
Acute Inhalation Toxicity: Kerosene: LC50 (Rat) >0.005 mg/l, 4 h
Skin corrosion/irritation: Irritating to skin
Serious eye damage/irritation: Expected to be slightly irritating.
Respiratory or skin sensitisation: Not expected to be a sensitiser.
Germ cell mutagenicity: Not considered a mutagenic hazard.
Carcinogenicity: Not classified as a carcinogen.
Reproductive and Developmental Toxicity: Not expected to be a developmental toxicant.
Specific target organ toxicity - single exposure: High concentrations may cause central
nervous system depression resulting in headaches, dizziness and nausea; continued
inhalation may result in unconsciousness and/or death.
Specific target organ toxicity - repeated exposure: Kidney: caused kidney effects in male
rats which are not considered relevant to humans.
12. ECOLOGIAL INFORMATION
12.1 Toxicity
Toxic to aquatic life with long lasting eff ects
12.2 Persistence and degradability
Major constituents are expected to be inherently biodegradable. The volatile constituents will
oxidize rapidly by photochemical reactions in air.
12.3 Bioaccumulative potential
Contains constituents with the potential to bioaccumulate.
12.4 Mobility in soil
Evaporates within a day from water or soil surfaces. Large volumes may penetrate soil and
could contaminate groundwater. Contains volatile constituents. Floats on water.

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 9 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

12.5 Results of PBT and vPvB assessment

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
12.6 Other adverse effects
Films formed on water may affect oxygen transfer and damage organisms.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Material Disposal:
Recover or recycle if possible. It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to determine the proper waste
classification and disposal methods in compliance with applicable regulations. Do not dispose
into the environment, in drains or in water courses. Do not dispose of tank water bottoms by
allowing them to drain into the ground. This will result in soil and groundwater contamination.
Waste arising from a spillage or tank cleaning should be disposed of in accordance with
prevailing regulations, preferably to a recognised collector or contractor. The competence of
the collector or contractor should be established beforehand.
Container Disposal:
Send to drum recoverer or metal reclaimer. Drain container thoroughly. After draining, vent in
a safe place away from sparks and fire. Residues may cause an explosion hazard if heated
above the flash point. Do not puncture, cut or weld uncleaned drums. Do not pollute the soil,
water or environment with the waste container. Comply with any local recovery or waste
disposal regulations.
Local Legislation:
Disposal should be in accordance with applicable regional, national, and local laws and
regulations. Local regulations may be more stringent than regional or national requirements
and must be in compliance.
14. TRANSPORT INFORMATION
Land transport (ADR/RID):
14.1 UN Number : 3256
14.2 UN proper shipping name : ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S.
with flash point above 60°C, at above its flash point (contains bitumen and kerosene)
14.3 Transport hazard class(es) : 3
14.4 Packing group : III

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 10 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

14.5 Environmental hazards : Environmentally Hazardous

14.6 Special precautions for user : Refer to Chapter 7

Sea transport (IMDG Code):

14.1 UN Number : 3256
14.2 UN proper shipping name : ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S.
with flash point above 60°C, at above its flash point (contains bitumen and kerosene)
14.3 Transport hazard class(es) : 3
14.4 Packing group : III
14.5 Marine pollutant : Yes
14.6 Special precautions for user : Refer to Chapter 7

Air transport (IATA):

14.1 UN Number : 3256
14.2 UN proper shipping name : ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S.
with flash point above 60°C, at above its flash point (contains bitumen and kerosene)
14.3 Transport hazard class(es) : 3
14.4 Packing group : III
14.5 Environmental hazards :
14.6 Special precautions for user : Refer to Chapter 7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No data
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
The contents and format of this SDS are in accordance with EEC Commission Directive
1272/2008/EC and EEC Commission Regulation 1907/2006/EC (REACH).
15.2 National Regulations
This Safety Data Sheet, Environment and Urban Planning Ministry by December 13, 2014
date and 29204 numbered published in the Official Gazette of Hazardous Substances
Regulation on safety data sheets of mixtures' Environment and Forestry and the Ministry of
26 by December 2008, and 27092 (bis) Official Gazette published "Classification of

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 Doc. No : TPR.YPG.SDS.0710
Issue Date : 27.11.2013
SAFETY DATA SHEET BITUMINOUS Rev. No :2
BINDER Rev. Date : 26.11.2019
Page No : 11 / 11

This Safety Data Sheet is in accordance with Regulation (EC) No 1907/2006 (REACH).

Hazardous Substances and preparations Regulations on Packaging and Labelling 'base is

based.
16. OTHER INFORMATION
16.1 Other Information
The information presented about health, safety and environment issues in this safety data
sheet was given by considering of best knowledge and reliable sources at the date of its
preparation. Although maximum effort was shown, no warranty is expressed or implied
regarding the accuracy of these data or the results to be obtained from the use thereof.
Health and safety precautions and environmental advice noted in this data sheet may not be
accurate for all individuals and/or situations. It is the user’s obligation to evaluate and use
this product safely and to comply with all applicable laws and regulations. No statement
made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The
TÜPRAŞ shall not be responsible for any damage or injury resulting from abnormal use of
the material, from any failure to adhere to recommendations, or from any hazards inherent
in the nature of the material.
Abbreviations :
ADN: Accord Européen relatif au Transport International des Marchandises Dangereuses
par voie de Navigation du Rhin
ADR: Accord européen relatif au transport international des marchandises Dangereuses par
Route
CLP: Classification, Labelling and Packaging Regulation according to 1272/2008/EC
IMDG: International Maritime Danagerous Goods
IATA: International Air Transport Association
IMDG = International Maritime Dangerous Goods Code
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals
UVCB: Chemical Substances of Unknown or Variable Composition, Complex Reaction
Products and Biological Materials (US EPA)
TWA: Time weighted average
STEL: Short-term exposure limit.
16.2 Related Person
Competent Person Accreditation no: TSE GBF-A-0-2828

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