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SDS 16840 Jotamastic 90 Wintergrade Comp B Euk GB

safety datasheet

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0% found this document useful (0 votes)
44 views15 pages

SDS 16840 Jotamastic 90 Wintergrade Comp B Euk GB

safety datasheet

Uploaded by

Lao She
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 15

Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758

SAFETY DATA SHEET

Jotamastic 90 Wintergrade Comp B


SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier
Product name : Jotamastic 90 Wintergrade Comp B
Product code : 16840
Product description : Hardener.
Product type : Liquid.
Other means of : Not available.
identification
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use in coatings - Industrial use
Use in coatings - Professional use
1.3 Details of the supplier of the safety data sheet
Jotun A/S Jotun Paints (Europe) Ltd.
P.O.Box 2021 Stather Road
3202 Sandefjord Flixborough, Scunthorpe
Norway North Lincolnshire
Tel: + 47 33 45 70 00 DN15 8RR
Fax: +47 33 45 72 42 England
E-mail: [email protected]
Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
1.4 Emergency telephone number
National advisory body/Poison Centre
Telephone number : Contact NHS Direct; phone 0845 4647 or 111. Open 24/7.
Supplier
Telephone number : +47 33 45 70 00 Jotun Norway (head office)
1,2 16840 Industrial applications, Professional applications, Used by spraying.

^(ValidationDate)
1

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to UK CLP/GHS
Flam. Liq. 3, H226
Skin Irrit. 2, H315
Eye Dam. 1, H318
STOT SE 3, H335
STOT SE 3, H336
The product is classified as hazardous according to UK CLP Regulation SI 2019/720 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 1/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 2: Hazards identification


Hazard pictograms :

Signal word : Danger.


Hazard statements : H226 - Flammable liquid and vapour.
H315 - Causes skin irritation.
H318 - Causes serious eye damage.
H335 - May cause respiratory irritation.
H336 - May cause drowsiness or dizziness.
Precautionary statements
General : Not applicable.
Prevention : P280 - Wear protective gloves. Wear eye or face protection.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P261 - Avoid breathing vapour.
Response : P304 + P312 - IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P362 + P364 - Take off contaminated clothing and wash it before reuse.
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage : P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Supplemental label : EUH208 - Contains ethylenediamine. May produce an allergic reaction.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards


Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients


3.2 Mixtures : Mixture

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 2/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 3: Composition/information on ingredients


Product/ingredient name Identifiers % Classification Type
butan-1-ol REACH #: ≥10 - <25 Flam. Liq. 3, H226 [1] [2]
01-2119484630-38 Acute Tox. 4, H302
EC: 200-751-6 Skin Irrit. 2, H315
CAS: 71-36-3 Eye Dam. 1, H318
Index: 603-004-00-6 STOT SE 3, H335
STOT SE 3, H336
ethylenediamine REACH #: <1 Flam. Liq. 3, H226 [1] [3]
01-2119480383-37 Acute Tox. 4, H302
EC: 203-468-6 Acute Tox. 3, H311
CAS: 107-15-3 Acute Tox. 4, H332
Skin Corr. 1B, H314
Eye Dam. 1, H318
Resp. Sens. 1B, H334
Skin Sens. 1B, H317
Aquatic Chronic 3,
H412
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures


4.1 Description of first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Flush
contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated
promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly
before reuse.

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 3/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 4: First aid measures


Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.

See toxicological information (Section 11)

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture


Hazards from the : Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard.
substance or mixture In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion.

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 4/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 5: Firefighting measures


Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
nitrogen oxides

5.3 Advice for firefighters


Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

6.3 Methods and material for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

6.4 Reference to other : See Section 1 for emergency contact information.


sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 5/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 7: Handling and storage


Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in
eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep
container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before handling or use.
Seveso Directive - Reporting thresholds
Danger criteria
Category Notification and MAPP Safety report threshold
threshold
P5c 5000 tonne 50000 tonne
See Technical Data Sheet / packaging for further information.

7.3 Specific end use(s)


Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
butan-1-ol EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 154 mg/m³ 15 minutes.
STEL: 50 ppm 15 minutes.
Biological exposure indices
No exposure indices known.

Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to


procedures national guidance documents for methods for the determination of hazardous
substances will also be required.
DNELs/DMELs

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 6/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 8: Exposure controls/personal protection


Product/ingredient name Type Exposure Value Population Effects
butan-1-ol DNEL Long term Oral 1.5625 mg/General Systemic
kg bw/day population
DNEL Long term Dermal 3.125 mg/ General Systemic
kg bw/day population
DNEL Long term 55.357 mg/General Systemic
Inhalation m³ population
DNEL Long term 155 mg/m³ General Local
Inhalation population
DNEL Long term 310 mg/m³ Workers Local
Inhalation
ethylenediamine DNEL Long term Oral 0.11 mg/ General Systemic
kg bw/day population
DNEL Long term 6.25 mg/m³ General Systemic
Inhalation population
DNEL Long term 25 mg/m³ Workers Systemic
Inhalation
PNECs
Product/ingredient name Compartment Detail Value Method Detail
butan-1-ol Fresh water 0.082 mg/l -
Marine 0.0082 mg/l -
Sewage Treatment 2476 mg/l -
Plant
Fresh water sediment 0.178 mg/kg dwt -
Marine water sediment 0.0178 mg/kg dwt -
Soil 0.015 mg/kg dwt -

8.2 Exposure controls


Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapour or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying to ISO 16321-1:2022 should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be
required instead.
Skin protection
Hand protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or
combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use, storage, maintenance and
replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material.
Always ensure that gloves are free from defects and that they are stored and used correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical damage and poor
maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has
occurred.

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 7/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 8: Exposure controls/personal protection


Gloves
Wear suitable gloves tested to ISO 374-1:2016.
Recommended, gloves(breakthrough time) > 8 hours: neoprene (> 0.35 mm), nitrile rubber (> 0.75 mm)
May be used, gloves(breakthrough time) 4 - 8 hours: butyl rubber (> 0.4 mm), Viton® (> 0.7 mm), 4H/Silver
Shield® (> 0.07 mm), Teflon (> 0.35 mm), polyvinyl alcohol (PVA) (> 0.3 mm)
Not recommended, gloves(breakthrough time) < 1 hour: PVC (> 0.5 mm)

For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the
supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk assessment.
Body protection : Use chemical-resistant protective suit / disposable overall.
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. Use respiratory mask with charcoal and dust filter
when spraying this product, according to EN 14387 (as filter combination A2-P2). In
confined spaces, use compressed-air or fresh-air respiratory equipment. When use
of roller or brush, consider use of charcoalfilter.
Environmental exposure : Do not allow to enter drains or watercourses.
controls

SECTION 9: Physical and chemical properties


The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

9.1 Information on basic physical and chemical properties


Appearance
Physical state : Liquid.
Colour : Clear
Odour : Characteristic.
Odour threshold : Not applicable.
Melting point/freezing point : Not applicable.
Initial boiling point and : Lowest known value: 119°C (246.2°F) (butan-1-ol).
boiling range
Flammability : Not applicable.
Upper/lower flammability or : 1.4 - 11.3%
explosive limits
Flash point : Closed cup: 35°C (95°F)
Auto-ignition temperature : Lowest known value: 355°C (671°F) (butan-1-ol).
Decomposition temperature : Not available.
pH : Not applicable.
Viscosity : Kinematic (40°C): >20.5 mm2/s
Solubility(ies) :
Media Result
cold water Not soluble
hot water Not soluble
Partition coefficient: n-octanol/ : Not available.
water

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 8/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 9: Physical and chemical properties


Vapour pressure : Highest known value: <1 kPa (<7.5 mm Hg) (at 20°C) (butan-1-ol).
Evaporation rate : 0.44 (butan-1-ol) compared with butyl acetate
Density : 1 g/cm³
Vapour density : Highest known value: 2.6 (Air = 1) (butan-1-ol).
Explosive properties : Not available.
Oxidising properties : Not available.
Particle characteristics
Median particle size : Not applicable.

9.2 Other information


No additional information.

SECTION 10: Stability and reactivity


10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous : Decomposition products may include the following materials: carbon monoxide,
decomposition products carbon dioxide, smoke, oxides of nitrogen.

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
butan-1-ol LD50 Oral Rat 790 mg/kg -
ethylenediamine LC50 Inhalation Vapour Rat 7 mg/l 4 hours
LD50 Dermal Rabbit 730 uL/kg -
LD50 Oral Rat 1200 mg/kg -
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapours) (dusts
(ppm) (mg/l) and mists)
(mg/l)
Jotamastic 90 Wintergrade Comp B 2500 33333.3 N/A N/A N/A
butan-1-ol 500 N/A N/A N/A N/A
ethylenediamine 500 300 N/A 11 N/A
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
ethylenediamine Eyes - Severe irritant Rabbit - 24 hours 750 -
ug
Eyes - Severe irritant Rabbit - 750 ug -
Skin - Moderate irritant Rabbit - 450 mg -
Skin - Severe irritant Rabbit - 24 hours 10 -
mg
Sensitisation

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 9/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 11: Toxicological information


Product/ingredient name Route of Species Result
exposure
ethylenediamine skin Mammal - species Sensitising
unspecified
Mutagenicity
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Reproductive toxicity
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
butan-1-ol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : May cause drowsiness or dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
General : No known significant effects or critical hazards.
Other information : None identified.

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 10/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 12: Ecological information


12.1 Toxicity
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
not classified as hazardous to the environment, but contains substance(s) hazardous to the environment. See section
3 for details.
Product/ingredient name Result Species Exposure
ethylenediamine Acute EC50 100000 μg/l Fresh water Algae - Green algae - Chlorella 96 hours
pyrenoidosa
Acute LC50 115.7 mg/l Fresh water Fish - Fathead minnow - 96 hours
Pimephales promelas
Chronic NOEC 160 μg/l Fresh water Daphnia - Water flea - Daphnia 21 days
magna
Conclusion/Summary : No known significant effects or critical hazards.
12.2 Persistence and degradability
Conclusion/Summary : Not available.

12.3 Bioaccumulative potential


Product/ingredient name LogPow BCF Potential
butan-1-ol 1 - low
ethylenediamine -7.02 - low

12.4 Mobility in soil


Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment


This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste : Yes.
Waste catalogue
Waste code Waste designation
08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances
Packaging

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 11/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 13: Disposal considerations


Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Type of packaging Waste catalogue
CEPE Guidelines 15 01 10* packaging containing residues of or contaminated by
hazardous substances
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 14: Transport information


ADR/RID ADN IMDG IATA
14.1 UN number UN1263 UN1263 UN1263 UN1263

14.2 UN proper Paint Paint Paint Paint


shipping name
14.3 Transport 3 3 3 3
hazard class(es)

14.4 Packing III III III III


group
14.5 No. No. No. No.
Environmental
hazards
Additional information
ADR/RID : Hazard identification number 30
Tunnel code (D/E)
ADR/RID: Viscous substance. Not goods of class 3, ref. 2.2.3.1.5 (only applicable to
receptacles < 450 litre capacity).
IMDG : Emergency schedules F-E, S-E
IMDG: Viscous substance. Transport in accordance with 2.3.2.5 of the IMDG Code
(only applicable to receptacles < 450 litre capacity).

14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

14.7 Transport in bulk : Not available.


according to IMO
instruments

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 12/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
UK (GB)/REACH
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
Intrinsic property Ingredient name Status Reference Date of
number revision
Substance of ethylenediamine Recommended D(2021) 12.04.2023
equivalent concern for 4569-DC
human health

Ozone depleting substances


Not listed.

Prior Informed Consent (PIC)


Not listed.

Persistent Organic Pollutants


Not listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c

EU regulations
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Air
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Water
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 13/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 15: Regulatory information


Not listed.
15.2 Chemical safety : This product contains substances for which Chemical Safety Assessments are still
assessment required.

SECTION 16: Other information


Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms GB CLP = UK CLP (EC No 1272/2008) on the Classification, Labelling and
Packaging of Substances and Mixtures as amended by (EU Exit) Regulations 2019
No. 720 and amendments
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = GB CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Skin Irrit. 2, H315 Calculation method
Eye Dam. 1, H318 Calculation method
STOT SE 3, H335 Calculation method
STOT SE 3, H336 Calculation method
Full text of abbreviated H statements
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications
Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Chronic 3 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
Eye Dam. 1 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Resp. Sens. 1B RESPIRATORY SENSITISATION - Category 1B
Skin Corr. 1B SKIN CORROSION/IRRITATION - Category 1B
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1B SKIN SENSITISATION - Category 1B
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - Category 3
Date of printing : 05.04.2024
Date of issue/ Date of : 05.04.2024
revision
Date of previous issue : 21.04.2023
Version : 1.03
Notice to reader

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 14/15
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Jotamastic 90 Wintergrade Comp B

SECTION 16: Other information


The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and
practical experience. Jotun's products are considered as semi-finished goods and as such, products are often
used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the product
itself. Minor product variations may be implemented in order to comply with local requirements. Jotun
reserves the right to change the given data without further notice.

Date of issue/Date of revision : 05.04.2024 Date of previous issue : 21.04.2023 Version : 1.03 15/15

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