GHS Label Elements, including precautionary statements:
Hazard Statements: H271 May cause fire or explosion; strong oxidizer H302 Harmful if swallowed H314 Causes severe skin burns and eye damage
Precautionary Statements: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P220 Keep/Store away from clothing and other combustible materials. P221 Take any precaution to avoid mixing with combustibles.
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P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P283 Wear fire/flame resistant/retardant clothing. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do not induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/physician. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use appropriate media to extinguish. P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations.
Potential Health Effects
Eyes May cause serious damage. Inhalation Causes irritation to the respiratory tract. Skin May causes skin burns and skin irritation. Prolonged or repeated skin exposure may cause dermatitis. Ingestion Causes irritation and pain.
NFPA Ratings HMIS Ratings
Health 2 Health 2 Flammability 0 Fire 0 Reactivity 1 Reactivity 1 Specific hazard OX
3. COMPOSITION/INFORMATION ON INGREDIENTS
EINECS# / Molecular Component Weight % CAS # Formula ELINCS# Weight Hydrogen 9.5-10.5 7722-84-1 231-765-0 H2O2 34.01 g/mol Peroxide Water Balance 7732-18-5 231-791-2 H2O 18.00 g/mol
4. FIRST-AID MEASURES
Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention. Inhalation Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Skin Flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention. Ingestion Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention.
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5. FIREFIGHTING MEASURES
Suitable (and unsuitable) Product is not flammable. Use water spray, alcohol-resistant foam, dry extinguishing media chemical or carbon dioxide. Use flooding quantities of water to cool containers. Special protective equipment Wear self-contained, approved breathing apparatus and full protective and precautions for firefighters clothing, including eye protection and boots. Specific hazards arising from Emits toxic fumes under fire conditions. (See also Stability and the chemical Reactivity section).
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, Do not handle until all safety precautions have been read and understood. protective equipment and Do not get in eyes, on skin, or on clothing. See section 8 for emergency procedures recommendations on the use of personal protective equipment. Environmental precautions Prevent spillage from entering drains. Any release to the environment may be subject to federal/national or local reporting requirements. Methods and materials for Neutralize spill with sodium bicarbonate or lime. Absorb spill with containment and cleaning up noncombustible absorbent material, then place in a suitable container for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Do not handle until all safety precautions have been read and understood. Do not get in eyes, on skin, or on clothing. See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use.
Conditions for safe storage, including any incompatibilities
Store in cool, dry well ventilated area. Isolate from combustible material. Store in the dark. Store in vented containers. Keep away from incompatible materials (see section 10 for incompatibilities).
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits Basis Entity
Hydrogen Peroxide 1 ppm (1.4 mg/m3) TWA ACGIH® TLV® 1 ppm (1.4 mg/m3) TWA OSHA PELs 1 ppm (1.4 mg/m3) TWA NIOSH RELs TWA: Time Weighted Average over 8 hours of work. TLV: Threshold Limit Value over 8 hours of work. REL: Recommended Exposure Limit PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit usually 15 minutes. IDLH: Immediately Dangerous to Life or Health WEEL: Workplace Environmental Exposure Levels CEIL: Ceiling
Personal Protection Eyes Wear chemical safety glasses with a face shield for splash protection.
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Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator. Skin Wear neoprene or nitrile gloves, apron and other protective clothing appropriate to the risk of exposure. Other Not Available
Other Recommendations Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. Have supplies and equipment for neutralization and running water available.
Odor No Odor Odor threshold Not Applicable pH Not Available Melting point/freezing point Not Available Initial boiling point and boiling range Not Available Flash point Not Flammable Evaporation rate Not Available Flammability (solid, gas) Not Flammable Upper/lower flammability or explosive limit Not Explosive Vapor pressure Not Available Vapor density Not Available Relative density 1.03 Solubility (ies) Completely soluble in water Partition coefficient: n-octanol/water Not Available Auto-ignition temperature Not Applicable Decomposition temperature Not Available
10. STABILITY AND REACTIVITY
Chemical Stability Stable
Possibility of Hazardous Reactions Will not occur. Conditions to Avoid Store out of direct light Incompatible Materials Brass, Copper, Powdered metals, Iron, Iron and iron salts, combustible materials Hazardous Decomposition Products Not Available
11. TOXICOLOGICAL INFORMATION
Acute Toxicity Hydrogen Peroxide Skin LD50 Dermal – rat – 4060 mg/kg Eyes Not Available Respiratory Not Available Ingestion LD50 Oral – mouse – 2000 mg/kg
Carcinogenicity IARC 3-Group 3: Not classifiable as to its carcinogenicity to humans (hydrogen peroxide). ACGIH A3: Confirmed animal carcinogen with unknown relevance to humans. NTP No components of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
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OSHA No components of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Signs & Symptoms of Exposure Skin Redness, burning, itching and pain. Eyes Eye burns, pain, watering eyes. Respiratory Coughing, shortness of breath, burning, choking, coughing, wheezing, laryngitis, headache or nausea. Ingestion Causes irritation and pain.
Chronic Toxicity Not Available
Teratogenicity Not Available Mutagenicity Not Available Embryotoxicity Not Available Specific Target Organ Toxicity Eyes, skin, respiratory system Reproductive Toxicity Not Available Respiratory/Skin Sensitization Not Available
12. ECOLOGICAL INFORMATION
Ecotoxicity Hydrogen Peroxide Aquatic Vertebrate Not Available Aquatic Invertebrate Not Available Terrestrial Not Available Persistence and Degradability Not Available Bioaccumulative Potential Not Available Mobility in Soil Not Available PBT and vPvB Assessment Not Available Other Adverse Effects Not Available
13. DISPOSAL CONSIDERATIONS
Waste Product or Users should review their operations in terms of the applicable federal/national or Residues local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residue. Product Users should review their operations in terms of the applicable federal/national or Containers local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container.
The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods.
14. TRANSPORTATION INFORMATION
US DOT UN2984, Hydrogen peroxide, aqueous solutions, 5.1, pg III TDG UN2984, HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS, 5.1, PG III IMDG UN2984, HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS 5.1, PG III Marine Pollutant No IATA/ICAO UN2984, Hydrogen peroxide, aqueous solutions, 5.1, pg III
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15. REGULATORY INFORMATION
TSCA Inventory Status All ingredients are listed on the TSCA Active inventory. DSL / NDSL All ingredients are listed on the DSL inventory. California Proposition 65 Not Listed Massachusetts: Toxic or Hazardous Substance List, Listed Right to Know New Jersey: Right to Know Hazardous Substance List Listed Pennsylvania: Hazardous Substance List Listed Rhode Island: Hazardous Substance List Listed SARA 304 Listed SARA 311 Acute Health Hazard, Fire Hazard SARA 312 Acute Health Hazard, Fire Hazard SARA 313 Not listed WHMIS Canada Class C: Oxidizing Material Class D2B: Poisonous and infectious material – Other effects - Toxic
16. OTHER INFORMATION
Revision Date
Created 05/24/2021
Disclaimer: The information provided in this Safety Data Sheet (“SDS”) is correct to the best of our knowledge, information and belief at the date of publication. The information in this SDS relates only to the specific Product identified under Section 1, and does not relate to its use in combination with other materials or products, or its use as to any particular process. Those handling, storing or using the Product should satisfy themselves that they have current information regarding the particular way the Product is handled, stored or used and that the same is done in accordance with federal, state and local law. WE DO NOT MAKE ANY WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. WE DO NOT ASSUME RESPOSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT.
