CHM211 2011 Past Question

DEPARTMENT OF CHEMISTRY
FEDERAL UNIVERSITY OF TECHNOLOGY, MINNA

FIRST SEMESTER EXAMINATION 2010/2011 SESSION
COURSE CODE: CHM211 UNITS: 2
COURSE TITLE: PHYSICAL CHEMISTRY II
TIME ALLOWED: 40 Minutes
INSTRUCTIONS: Answer all questions
The figure below is a phase diagram of carbon, use it to answer the following SIX questions
1. The phase with the highest density is---
2. W can may be produced by==
3. The triple points are – and --
4. Which of the phase can be used for drilling?
5. w and y are referred to as—and --
6. The basic phases found at v are ------
7. When the dG<0, the process is---
8. It feels cold when touched the process must be …
9. List three(3) factors which may affect rate of a chemical reaction
10. Define the terms in the equation ΔG = ΔH – TΔS
11. Give two (2) examples of intensive properties…
12. Which thermodynamic function is zero in a cyclic process?
1
13. Give an expression for the first order rate constant
From the diagram below answer the THREE questions that follow
II
[]
I
IV
III
14. The average rate of the reaction is represented by

A. I
B. II
C. III
D. IV
15. The instantaneous rate of the reaction can be found at
A. I
B. II
C. III
D. IV
16. The initial rate of the reaction is the slope of

A. I
B. II
C. III
D. IV
17. If one of the species involved in a reaction is colored. Such reaction can be monitored by
a
A. Manometer
B. Titrimeter
C. Colorimeter
D. AAS
2
18. If one of the species of a reaction is a gas --- method is suitable for monitoring such
reaction.
A. Manometer
B. Titrimetr
C. Colorimeter
D. pH meter
19. Hydrolysis of ethyl acetate can be monitored by

A. titrimetry
B. colorimetry
C. pH meter
D. manometry
20. It was observed that increase concentration of a specie in a chemical reaction had NO
effect on the rate of the reaction. The reaction is ---- order with respect to the specie
A. zero
B. first
C. second
D. third
21. Doubling the concentration of a reactant doubles the rate of the reaction. The reaction is
---- order with respect to the specie
A. zero
B. first
C. second
D. third
22. Doubling the concentration of a reactant quadruples the rate of the reaction. The reaction
is ---- order with respect to the specie
A. zero
B. first
C. second
D. third
23. It gives the number of molecule which takes part in a chemical reaction. What is it?
A. Order of a reaction
B. Rate constant
C. Molecularity
D. Rate law
24. Which of the following may NOT be determined experimentally?

3
A. Order
B. Rate constant
C. Rate of a reaction
D. Molecularity
25. The heat of a system measured at constant pressure may be taken as

A. Enthalpy
B. Entropy
C. Heat
D. Work
26. From the reaction, N 2 ( g ) +O2 ( g ) → 2 NO❑ ( g ) which of the following is not true about the
system?
A. Volume is constant
B. PΔV = 0
C. Moles of reacts = moles of product
D. PΔV ≠ 0
27. A test tube feels cold, the process taken place in it is

A. Endothermic
B. Exothermic
C. Adiabatic
D. Isochoric
Use the figure below to answer the ELEVEN questions that follow:
28. Y on the diagram represents

A. Gas
B. Solid
C. Liquid
D. Vapour
29. What phase is represented by ‘T’?
4
A. Vapour
B. Gas
C. Solid
D. Liquid
30. At point ‘V’ the phases that co-exist are

A. Solid and Gas only.
B. Solid and liquid only.
C. Gas, liquid and vapour only.
D. Liquid, solid and vapour only.
31. Only vapour is found at

A. X
B. U
C. Y
D. W
32. Z is the
A. Critical point
B. Boiling point
C. Melting point
D. Azeotropic point
33. From X to Y one witness

A. A drop in temperature
B. No change in temperature
C. An increase in pressure
D. An increase in volume
34. The diagram represents the phase diagram for

A. Carbon (IV) oxide
B. Kerosene
C. Water
D. Ethanol
35. Sublimation is possible while moving from ---- to ----

A. W - V
B. Y - X
C. T - W
D. V - S
5
36. Sporting activities are commonly possible at
A. X and Y
B. W and U
C. X and U
D. T and Y
37. Phases which coexist at ZV are

A. solid and vapour
B. liquid and solid
C. liquid and vapour
D. solid, liquid and vapour
38. Phases which coexist at ZV and WV are

A. solid and vapour
B. liquid and solid
C. liquid and vapour
D. solid, liquid and vapour
40. A sample of aluminum absorbed 9.86 J of heat and its temperature increased from 23.2ºC to
30.5ºC. What is the mass of the aluminum?
A. 65 g
B. 8.1 g
C. 1.5 g
D. 72 g
Section B
Answer any one question
1. When a student mixes 50.0 mL of a 0.0100 M HCl solution and50.0 mL of a 0.0100 M

NaOH solution in a coffee-cup calorimeter the temperature of the resultant solution rises
from 21.0°C to 21.4°C. Calculate the enthalpy change for the reaction.
2. Consider a cyclic process for an ideal gas in a cylinder with a frictionless piston. Draw a
graph to represent the process and show that wnet - qnet

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DEPARTMENT OF CHEMISTRY

FEDERAL UNIVERSITY OF TECHNOLOGY, MINNA

1. The phase with the highest density is---

2. W can may be produced by==

3. The triple points are – and --

4. Which of the phase can be used for drilling?

5. w and y are referred to as—and --

6. The basic phases found at v are ------

7. When the dG<0, the process is---

8. It feels cold when touched the process must be …

9. List three(3) factors which may affect rate of a chemical reaction

10. Define the terms in the equation ΔG = ΔH – TΔS

11. Give two (2) examples of intensive properties…

12. Which thermodynamic function is zero in a cyclic process?

14. The average rate of the reaction is represented by

16. The initial rate of the reaction is the slope of

19. Hydrolysis of ethyl acetate can be monitored by

24. Which of the following may NOT be determined experimentally?

25. The heat of a system measured at constant pressure may be taken as

27. A test tube feels cold, the process taken place in it is

28. Y on the diagram represents

29. What phase is represented by ‘T’?

30. At point ‘V’ the phases that co-exist are

31. Only vapour is found at

33. From X to Y one witness

34. The diagram represents the phase diagram for

35. Sublimation is possible while moving from ---- to ----

37. Phases which coexist at ZV are

38. Phases which coexist at ZV and WV are

1. When a student mixes 50.0 mL of a 0.0100 M HCl solution and50.0 mL of a 0.0100 M

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