MONTHLY TEST D and F Block and Coordination Compounds KENDRIYA VIDYALAYA RAJKOT

KENDRIYA VIDYALAYA RAJKOT, GUJARAT 2023-24
CLASS – XII MONTHLY TEST (AUGUST) TIME: 01½ Hr.

SUBJECT – CHEMISTRY M.M: 40
SECTION - A MCQs ½ MARKS QUESTIOINS (½ × 14 =07 MARKS)
Q.1 Which of the following lanthanoid ions is diamagnetic? (At. nos. Ce = 58, Sm = 62, Eu = 63, Yb = 70)
(A) Ce2+ (B) Sm2+ (C) Eu2+ (D) Yb2+
Q.2 How many ‘d’ electrons are in present Cr2+ ion

(A) 04 (B) 05 (C) 06 (D) 03
Q.3 Formation of coloured solution is possible when metal ion in the compound contains
(A) paired electrons (B) unpaired electrons (C) lone pair of electrons (D) Crystal lattice
Q.4 Which pair of compounds is expected to show similar colour in aqueous medium?
(A) FeCl2 and CuCl2 (B) VOCl2 and CuCl2 (C) VOCl2 and FeCl2 (D) FeCl2 and MnCl2
Q.5 Zr and Hf have almost equal atomic and ionic radii because of
(A) Diagonal relationship (B) Lanthanoid contraction
(C) Actinoid contraction (D) Belonging to the same group
Q.6 When 1 mol of CrCl3 . 6H2O is treated with excess of AgNO3, 3 moles of AgCl are obtained. The
formula of the complex is
[A] [CrCl3(H2O)3] . 3H2O [B] [CrCl2(H2O)4]Cl . 2H2O
[C] [CrCl(H2O)5]Cl2 . H2O [D] [Cr(H2O)6]Cl3
Q.7 Which of the following compounds is a double salt?

[A] Potassium permanganate [B] Ferrous ammonium sulphate
[C] Ammonium chromate [D] all the given.
Q.8 Which of the following is the correct order of spectro chemical series?
[A] [B]
[C] [D]
Q.9 By which hybrid octahedral structure is found?

[A] [B] [C] [D]
Q.10 Which of the following complex is heteroleptic?

[A] [Cr(NH3)6]3+ [B] [Fe(NH3)4Cl2]+ [C] [Mn(ONO)6]4- [D] [Co(en)3] Cl3
Q.11 Co-ordinate number, oxidation number, number of electron in d-orbital and number of unpaired
electron of central metal Cobalt in [ Co ( N H 3 )5 C O3 ] Cl ?
[A] 6, 3, 6, 0 [B] 7, 2, 7, 1 [C] 6, 2, 7, 3 [D] 7, 1, 6, 4
Q.12 What is the relation of octahedral with tetrahedral complex for splitting energy of crystal
field theory?
[A] [B] [C] [D]
Q.13 Which of the following cannot act as ligand?

[A] [B] [C] [D]
Q.14 The CFSE for octahedral [CoCl6]4- is 18,000 cm-1. The CFSE for tetrahedral [CoCl4]2- will be
[A] 18,000 cm-1 [B] 16,000 cm-1 [C] 8,000 cm-1 [D] 20,000 cm-1
SECTION - B 01 MARKS QUESTIOINS (01 × 10 =10 MARKS)
Q.1 (a) What is the hybridization state of nickel in [Ni(CN)4]2−

(b) Draw the structure of [Ni(CN)4]2−
Q.2 On the basis of crystal field theory, write the electronic configuration of d 4 in terms of t2g and eg in an
octahedral field when (i) Δ0 > P (ii) Δ0 < P
Q.3 Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical
isomers?
Q.4 What is the coordination entity formed when excess of aqueous KCN is added to an aqueous solution of
copper sulphate? Why is it that no precipitate of copper sulphide is obtained when H 2S(g) is passed through
this solution?
Q.5 Transition elements exhibit their highest oxidation state in their oxides not in Fluorides.
Q.6 Explain why, Zn (II) salts are white while Mn (VII) are deep purple in colour?
Q.7 Why HCl cannot be used in place of sulphuric acid to acidify KMnO4 solution in volumetric analysis
Q.8 Transition metal salts exhibit particular colour.
Q.9 Name the lanthanoid element which forms tetra positive ions in the aqueous solution.
Q.10 Why the chemistry of actinoids is not as smooth as lanthanoids.
SECTION - C 02 MARKS QUESTIOINS (02 × 03 =06 MARKS)
Q.11 (i) Write the IUPAC name and type of isomerism shown by following complex compounds
(a) [Co(NH3)5(NO2)](NO3)2 (b) [Pt(NH3)(H2O)Cl2]
Q.12 A cationic complex has two isomers A & B. Each has one Co 3+, five NH3, one Br and one SO42-. A gives
a white precipitate with BaCl2 solution while B gives a yellow precipitate with AgNO3 solution.
(a) What are the possible structures of the complexes A and B?
(b) Write the name of structural isomerism shown by A and B.
Q.13 [NiCl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?
SECTION - D 03 MARKS QUESTIOINS (03 × 03 =09 MARKS)
Q.14 Write the formulas for the following coordination compounds: (ANY THREE)
(a) tris-(ethane-1, 2-diamine) chromium(III) chloride
(b) amminebromidochloridonitrito-N-platinate(II)
(c) dichloridobis(ethane-1, 2-diamine)platinum(IV) nitrate
(d) iron(III) hexacyanoferrate(II)
Q.15 For the complex [Fe(en)2Cl2]Cl identify : ½×6=03
(a) name of the complex.
(b) the co-ordination number and oxidation No. of Iron.
(c) the hybrid orbitals and the shape of the complex.
(d) the magnetic behaviour of the complex.
(e) No. and structure of geometrical isomers.
(f) whether there is an optical isomer also.
Q.16 (a) What is lanthanide contraction?
(b) What are the consequences of lanthanide contraction? (Any 03)
SECTION - E 04 MARKS QUESTIOINS (04 × 02 =08 MARKS)
Q.17 Answer the following: The Elements of 3d transition series are given as:
Atomic No 21 22 23 24 25 26 27 28 29 30
Element Sc Ti V Cr Mn Fe Co Ni Cu Zn
(a) Write the element which is not regarded as transition element.
(b) Write the element which can show an oxidation state of +1.
(c) Which element is soft?
(d) Which element shows maximum number of oxidation states.
(e) Which element has the highest melting point?
(f) Which element shows only +3 state?
(g) Which element shows positive E0M2+/M (E0M2+/M = +ve)
(h) Name the oxo metal anions of the first series of transition metals in which the metal exhibits
the oxidation state equal to its group number
Q.18 (a) When a chromite ore ‘A’ is fused with sodium carbonate in free excess of air and the product is
dissolved in water, a yellow solution of compound ‘B’ is obtained. After treatment of this yellow
solution with sulphuric acid compound ‘C’ can be crystallize from the solution. When compound ‘C’ is
treated with KCl orange crystals of ‘D’ is crystallizes out. Identify ‘A’ to ‘D’ and write the reaction from
‘A’ to ‘B’.
(b) How does the potassium dichromate reacts with following and write the ionic equations with:
(i) iodide (ii) Fe(II) ions (iii) H2S
Write the ionic equations for the reactions.
***********THE END**********

MONTHLY TEST D and F Block and Coordination Compounds KENDRIYA VIDYALAYA RAJKOT

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KENDRIYA VIDYALAYA RAJKOT, GUJARAT 2023-24

CLASS – XII MONTHLY TEST (AUGUST) TIME: 01½ Hr.

Q.2 How many ‘d’ electrons are in present Cr2+ ion

Q.7 Which of the following compounds is a double salt?

Q.9 By which hybrid octahedral structure is found?

Q.10 Which of the following complex is heteroleptic?

Q.13 Which of the following cannot act as ligand?

SECTION - B 01 MARKS QUESTIOINS (01 × 10 =10 MARKS)

Q.1 (a) What is the hybridization state of nickel in [Ni(CN)4]2−

SECTION - C 02 MARKS QUESTIOINS (02 × 03 =06 MARKS)

SECTION - E 04 MARKS QUESTIOINS (04 × 02 =08 MARKS)

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