Solid State


 Marked questions are recommended for Revision.
 fpfUgr iz'u nksgjkus ;ksX; iz'u gSA

PART - I : SUBJECTIVE QUESTIONS

Hkkx - I : fo"k;kRed iz'u ¼SUBJECTIVE QUESTIONS½
Section (A) : Basics of solid state
[k.M (A) : Bksl izkoLFkk ds ekSfyd ¼vk/kkjHkwr½ rF;
Commit to memory :
angle
Contribution of a particle = (for 2D unit cell).
360º

;kn j[kus ;ksX; rF; %

dks.k
,d d.k dk ;ksxnku = (2D bdkbZ lsy ds fy,).
360º
A-1. Classify each of the following solids.
(a) Tetra phosphorus decoxide (P4O10) (b) Graphite
(c) Brass (d) Ammonium phosphate [(NH4)3 PO4 ]
(e) SiC (f) Rb
(g) 2 (h) LiBr
(i) P4 (j) Si
(k) Plastic.
fuEu esa ls izR;sd Bksl dks oxhZd`r dhft, %
(a) VsªVk QkLQksjl MsdksvkWDlkbM (P4O10) (b) xzsQkbV
(c) czkal (d) veksfu;e
QkWLQsV [(NH4)3 PO4 ]
(e) SiC (f) Rb
(g) 2 (h) LiBr
(i) P4 (j) Si
(k) IykfLVd
Ans. Ionic – LiBr, (NH4)3PO4; Metallic – Brass, Rb; Molecular – P4O10, 2, P4
Network – SiC, Graphite, Si, Amorphous – Plastic
Ans. vk;fud – LiBr, (NH4)3PO4; /kkfRod– czkWl, Rb, vkf.od – P4O10, 2, P4
usVodZ – SiC, xzsQkbV, Si , vfØLVyh; – IykfLVd
A-2. Given below are two dimension lattices with nicely shaded regions.You just have to find the
contributions (in fractions) of particles marked to the shaded regions and the total number of particles in
the regions.
uhps f}foeh; tkydks esa dqN Hkkx Nk;kafdr gSA vkidks Nk;kafdr Hkkxksa esa vkus okys d.kksa ds Hkkx ¼fHkUu esa½ dh
x.kuk djuh gS \ rFkk Nk;kafdr Hkkx esa d.kksa dh la[;k Hkh Kkr dhft;s \
(a) (b) (a) (b) (a) (b)
(iv) (a)

(a)

(b)
(i) (ii) (iii) (v)
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 Solid State
Figure (fp=k)
Ans. Ques. (a) (b) Total particles ¼dqy d.kksa dh la[;k½
(i) 1/4 1 2
(ii) 1/2 1/4 2
(iii) 1/6 1/2 2
(iv) 1/6 – 1/2
(v) 1/3 1/6 1
A-3. What are the crystallographic parameter of hexagonal, monoclinic and triclinic unit cell respectively.
"kV~dks.kh; ,dd dkssf"Bdk] ,durk{k ,dd dksf"Bdk rFkk f=kuok{k ,dd dksf"Bdk ds fy, fØLVyksxzkfQd eki Øe
crkb;s\.
Ans.
Unit cell
Crystal System Features Examples
found
abc
Monoclinic sulphur, PbCrO4, Na2SO4.10H2O,
Monoclinic α = γ = 90°; S, EC
Na2B4O7.10H2O.
β  120°,  90°,  60°

Hexagonal a=bc S Graphite, ZnO, CdS, Mg, PbI2, SiC.

α = β = 90°, γ = 120°
abc
Triclinic S K2Cr2O7, CuSO4.5H2O, H3BO3.
α  β  γ  90°
Ans.
fØLVy ik;h tkus okyh
ekiØe mnkgj.k
fudk; ,dd dksf"Bdk;sa
abc
,durk{k lYQj, PbCrO4, Na2SO4.10H2O,
,durk{k α = γ = 90°; S, EC
Na2B4O7.10H2O.
β  120°,  90°,  60°
"kV~dks.kh; a=bc S xzsQkbV, ZnO, CdS, Mg, PbI2, SiC.
α = β = 90°, γ = 120°
abc
f=kurk{k S K2Cr2O7, CuSO4.5H2O, H3BO3.
α  β  γ  90°

Section (B) : Simple Cubic Structure & BCC

[k.M (B) : ljy ?kuh; lajpuk rFkk BCC
Commit to memory :
ZM
Density =
NA  a3

;kn j[kus ;ksX; rF; %

ZM
?kuRo =
NA  a3

B-1. Following diagrams show identical cubes such that edge of cube2 lies exactly in the middle of one of
the faces of Cube1 and Cube 4 has a corner at the body center of the Cube3. Find the contributions (in
fraction) of the spheres shown to each of the cubes.

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 Solid State
Atom

4
1
Atom
2 3
fuEu fp=k esa leku ?ku 2 dk dksj ?ku 1 ds ,d Qyd ds Bhd e/; esa fLFkr gS rFkk ?ku 4 dk ,d dksuk ?ku 3 ds
dk; dsUnzh; fLFkfr esa mifLFkr gSA fp=k esa n'kkZ;s x;s xksyksa ds fy, izR;sd ?ku }kjk fn;k x;k Hkkx ¼fHkUu esa½ Kkr
dhft, \
ijek.kq

4
1

2 3 ijek.kq
Ans. Cube1 - 1/2 ; Cube2 - 1/4 ; Cube3 - 1 ; Cube4 - 1/8
Ans. ?ku 1 - 1/2 ; ?ku 2 - 1/4 ; ?ku 3 - 1 ; ?ku 4 - 1/8
B-2. The inter metallic compound Li Ag crystallizes in a cubic lattice in which both lithium and silver atoms
have coordination no. of 8. To what crystal class does the unit cell belong?
,d vUrj /kkfRod ;kSfxd Li Ag ,d ?kuh; tkyd ds :i esa fØLVyhd`r gksrk ftlesa fyfFk;e rFkk lhYoj nksuksa
ijek.kqvksa dh leUo; la[;k 8 gSA rc ,dd dksf"Bdk fdl izdkj fØLVy oxZ ls lEcfU/kr gS ?
Ans. BCC
B-3. Chromium metal crystallizes with a body centered cubic lattice. The length of the unit cell is found to be
287 pm. Calculate the atomic radius. What would be the density of chromium in g/cm 3.
Øksfe;e /kkrq dk; dsfUnzr ?kuh; tkyd esa fØLVyhd`r gksrh gSA ;fn ,dd dksf"Bdk dh yECkkbZ 287 pm gS rks
ijek.oh; f=kT;k dh x.kuk djksA Øksfe;e dk ?kuRo g/cm3 esa D;k gksxkA
Ans. 124.27 pm, density = 7.30 g cm –3 124.27 pm, ?kuRo = 7.30 g cm–3

Section (C) : HCP & CCP structures

[k.M (C) : HCP rFkk CCP lajpuk
Commit to memory :
For CCP : a = b = c = 2 2 R, Z = 4, Coordination number = 12
8
For HCP : a = 2R, b = 2R, c = 2h and h = R, Z = 6, Coordination number = 12
3

;kn j[kus ;ksX; rF; %

CCP ds fy, : a = b = c = 2 2 R, Z = 4, leUo; la[;k = 12
8
HCP ds fy, : a = 2R, b = 2R, c = 2h rFkk h = R, Z = 6, leUo; la[;k = 12
3

C-1. In which type of 3D arrangement have Ist and IV layer’s of sphere are identical.
fdl izdkj dh 3D O;oLFkk esa xksydksa dh Ist rFkk IV ijrsa leku gksrh gSA
Ans. ABC-ABC-Arrangement (CCP unit cell).
ABC-ABC-O;oLFkk (CCP ,dd dksf"Bdk).

C-2. Metallic magensium has a hexagoanl close-packed structure and a density of 1.74 g/cm 3. Assume
magnesium atoms to be spheres of radius r. 74.1% of the space is occupied by atoms. Calculate the
volume of each atom and the atomic radius r. (Mg = 24.31)
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 Solid State
/kkfRod eSfXu'kh;e "kV~dks.kh; fufcM ladqfyr ljapuk j[krk gSA bldk ?kuRo 1.74 g/cm3 gSA ekukfd eSaXfu'kh;e
ijek.kq f=kT;k r ds xkksyd gS ijek.kqvksa }kjk 74.1% LFkku ?ksjk tkrk gS] rc izR;sd ijek.kq dk vk;ur rFkk
ijekf.od f=kT;k dh x.kuk dhft,A (Mg = 24.31)
Ans. 1.72 × 10–23 cm3, 1.60 Å
C-3. Consider a corner atom of Ist layer of an HCP unit cell showing alternate AA layers. Find
(i) Find identical atoms (III layer) with respect to the distances from the atom 1.
(ii) Arrange the distances in ascending order.
e d
g Layer A
f c
a b

Layer A
Atom 1
fp=k esa n'kkZ;s HCP bdkbZ dksf"Bdk dh ,dkUrfjr AA ijr ds ,d dksus ds ijek.kq ds fy, Kkr dhft,A
(i) (III ijr esa) ijek.kq 1 ls nwjh ds lUnHkZ esa leku ijek.kqvksa dks Kkr dhft, \
(ii) nwjh ds c<+us ds Øe esa ijek.kqvksa dks O;ofLFkr dhft;sA

Ans. (i) b, f, g are identical; c, e are identical. (ii) da < [db = df = dg]< [dc = de]< dd
Ans. (i) b, f, g le:ih gS ( c, e le:ih gSA (ii) da < [db = df = dg] < [dc = de]< dd

C-4. Following figure shows an FCC unit cell with atoms of radius r marked 1(corner), 2(face center), 3(face
center). A quadrilateral is also shown by joining the centers of 4 face centered atoms.
Find : (i) The distances between atoms 1 & 2, 2 & 3 and 1 & 3.
(ii) The shape and dimensions of the quadrilateral.
r, f=kT;k ds ijek.kqvksa }kjk fp=k esa n'kkZ;s vuqlkj FCC bdkbZ dksf"Bdk dk fuekZ.k djrs gSA bu ijek.kqvksa dks 1(dksus
dk), 2(Qyd dsUnzh;), 3(Qyd dsUnzh;) vadu fn;k x;k gSA pkjksa Qyd dsUnzh; ijek.kqvksa ds dsUnzks dks tksM+dj ,d
quadrilateral Hkh fn[kk;k x;k gSA Kkr dhft,A
(i) 1 o 2, 2 o 3 rFkk 1 o 3 ijek.kqvksa ds e/; dh nwfj;k¡
(ii) (quadrilateral) dh vkd`fr rFkk foek;s

Figure (fp=k)
Ans. (i) 2r, 2r, 2 3r ; (ii) Square, side = 2r.
Ans. (i) 2r, 2r, 2 3r ; (ii) oxZ] lrg = 2r.

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 Solid State
C-5. Aluminium metal (atomic weight = 27g) crystallises in the cubic system with edge length 4.0Å. The
density of metal is 27/16 amu/ Å3. Determine the unit cell type and calculate the radius of the Aluminium
metal.
,Y;qfefu;e /kkrq (ijek.kq Hkkj = 27g), ?kuh; ra=k esa fØLVyhd`r gksrk gSA ftlds fdukjs dh yEckbZ 4.0Å gS rFkk
?kuRo 27/16 amu/ Å3 gSA bdkbZ dksf"Bdk ds izdkj rFkk ,Y;qfefu;e /kkrq ds ijek.kq dh f=kT;k dk fu/kkZj.k dhft;s\
Ans. FCC, 2Å
C-6. “Tom” cat arranges the glass balls, in a particular 3D array; that two ( I and II) continuous layer are not
identical, but all (I and III) alternative layers are identical, this type of arrangement is known as :
“Vkse (Tom)” fcYyh, dk¡p dh xsUnksa dks 3D O;oLFkk esa ,d fuf'pr vuqØe esa bl izdkj O;ofLFkr djrh gSA fd
xsUnksa dh nks (I rFkk II) yxkrkj ijrsa leku ugha gS ijUrq lHkh ,dkUrfjr (I rFkk III) ijrsa leku gksrh gSA ijrksa bl
izdkj dh O;oLFkk dk uke gS %
Ans. ABAB............type arrangement (unit cell = HCP).
ABAB............izdkj dh O;oLFkk (,dd dksf"Bdk = HCP).

Section (D) : Voids

[k.M (D) : fjfDrdk;sa
Commit to memory :
Radius ratio = 0.155, 0.225, 0.414, 0.732 for triangular, tetrahedral, octahedral, cubic void respectively.

;kn j[kus ;ksX; rF; %

f=kT;k vuqikr = 0.155, 0.225, 0.414, 0.732 Øe'k% f=kdks.kh;] prq"Qydh;] v"VQydh;] ?kuh; fjfDrdkvksa ds
fy,
D-1. A student wants to arrange 4 identical spheres(of radius R) on a two dimensional floor as close as
possible.Finally he could arrange them.Identify the type and dimensions of the figure obtained by
joining their centers. Could he occupy the whole available space, if not, then what type of voids were
generated.Calculate their number and radius of small ball that can be fitted in them.
,d fo|kFkhZ 4 leku xksyksa dks (R f=kT;k ds) f}foeh; Q'kZ ij vf/kdre ladqy voLFkk esa O;ofLFkr dj ikrs gSA
buds dsUnzksa dks tksM+us ij cuh vkd`fr rFkk mldh foek;sa dks Kkr dhft;s \ D;k og miyC/k lEiw.kZ LFkku dks iw.kZr%
Hkj ik;sxsa\ ;fn ugha] rc fdl izdkj dh fjfDr;k¡ mRiUu gksxha \ mu fjfDr;ksa dh la[;k dh x.kuk dhft;s \ rFkk
ml NksVh ckWy dh la[;k rFkk f=kT;k dh x.kuk dhft;s tks bu fjfDr;ksa dks Hkj lds \
Ans. No, Rhombous: 2R, 60º, 120º ; Triangular voids; 2 voids, 0.155 R.
Ans. ugha] leprqZHkqft; (Rhombous) 2R, 60º, 120º ; f=kdks.kh; fjfDr;k¡ : 2, 0.155 R.
D-2. Illustrate an octahedral void in the close packing of spheres. Why is it so called ?
Xkksyksa ds fufcM+ ladqyu esa v"VQydh; fNnz dks le>kb,A bls ,slk D;ksa dgrs gSa \
Sol. Octahedral void is present at the body center, which is formed by six face centered atoms and it consist
at triangle faces.

3 2
4 1

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 Solid State
Sol. N% Qyd dsfUnzr ijek.kqvksa }kjk fufeZr dk; dsUnz esa v"VQydh; fjfDr mifLFkr gksrh gSA rFkk ;g f=kdks.kh; Qyd
j[krk gSA
5

3 2
4 1

D-3. The number of tetrahedral and octahedral voids in hexagonal primitive unit cell are _______ and
_______.
"kV~dksk.kh; vk| ,dd dksf"Bdk esa prq"Qydh; rFkk v"BQydh; fjfDr;ksa dh la[ ;k _______ rFkk _______ gSA
Ans. 12 and (rFkk) 6

D-4. What is the number and closest distance between two octahedral voids and two tetrahedral voids in fcc
unit cell ?
fcc ,dd dksf"Bdk esa v"VQydh; fjfDr;ksa ds e/; rFkk prq"Qydh; fjfDr ds e/; U;wure nwj h rFkk budh la[;k
crkb;s\
a a
Ans. 4, 8, ,
2 2

Section (E) : Radius ratio rule and Type of ionic structures

[k.M (E) : f=kT;k vuqikr fu;e rFkk vk;fud lajpukvksa ds izdkj
Commit to memory :
Radius ratio = 0.155, 0.225, 0.414, 0.732 for triangular, tetrahedral, octahedral, cubic void respectively.

;kn j[kus ;ksX; rF; %

f=kT;k vuqikr = 0.155, 0.225, 0.414, 0.732 Øe'k% f=kdks.kh;] prq"Qydh;] v"VQydh;] ?kuh; fjfDrdkvksa ds
fy,
E-1. Suggest the probable structues of the unit cells of following each compound with the help of given data
fn;s x;s vkdM+ksa dh lgk;rk ls fuEu izR;sd ;kSfxd dh ,dd dksf"Bdk dh lEHkkfor ljapuk crkb;s %
Cationic radius Anionic radius
/kuk;u f=kT;k _.kk;u f=kT;k
(a) RbBr 1.48 Å 1.95 Å
(b) MeTe 0.65 Å 2.21 Å
(c) MgO 0.65 Å 1.40 Å
(d) BaO 1.35 Å 1.40 Å
Ans. (a) CsCl type (izdkj) (b) ZnS type (izdkj) (c) NaCl type (izdkj) (d) CsCl type (izdkj)

E-2. Why does ZnS not crystallize in the NaCl structure?

ZnS fØLVy NaCl fØLVy dh rjg D;ksa ugh ik;k tkrk gS \
r 2
Ans. In case of ZnS radius ratio is Zn = 0.402.
rS2–
That's why Zn2+ ion is present in tetrahedral void. If Zn2+ ion is present in octahedral void [For NaCl type
structure] then anion-anion contact is there and compound become unstable. That's why. ZnS not
crystallize in the NaCl structure.

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 Solid State
rZn2
mÙkj- ZnS dh fLFkfr esa f=kT;k vuqikr = 0.402 gSA
rS2–
Zn2+ vk;u prq"Qydh; fjfDr esa mifLFkr gSA ;fn Zn2+ vk;u v"VQydh; fjfDr ¼NaCl çdkj dh lajpuk ds fy,½
esa mifLFkr gksrs rc ;gk¡ _.kk;u&_.kk;u lEidZ esa gksrs gS rFkk ;kSfxd vLFkk;h gks tkrk gSA blfy, ZnS, NaCl
lajpuk esa fØLVyhd`r ugha gksrk gSA
E-3. Try to answer the following:
(i) In Zinc Blende structure there is one Zn+2 ion per S2– ion.But the radius ratio lies in the range of
Tetrahedral void and there are two tetrahedral voids available per S2–.Can you give the idea about the
arrangement of the lattice.
(ii) What is the striking difference between the Fluorite and the Anti-fluorite structures.
fuEu dk mÙkj nhft, :
(i) ftad Cys.M lajpuk esa izR;sd S2– vk;u ds fy, ,d Zn2+ vk;u gksrk gSA ysfdu prq"Qydh; fjfDrdk dh ijkl
es f=kT;h; vuqikr j[kk x;k gS rFkk izR;sd S2– ds fy, nks prq"Qydh; fjfDrdk,¡ gSA D;k vki tkyd dh O;oLFkk
ds fy, dksbZ ;kstuk ns ldrs gSA
(ii) ¶yksjkbV rFkk ,UVh&¶yksjkbV lajpuk ds chp eq[; vUrj D;k gSA
Ans. (i) Zn2+ ions occupy alternate Tetrahedral holes ; (ii) Anti-Flourite: Anions in FCC and Cations in
Tetrahedral holes, Fluorite: Cations in FCC and Anions in Tetrahedral holes
Ans. (i) Zn2+ vk;u ,dkUrfjr prq"Qyd fNnz esa fLFkr gS ; (ii) ,UVh ¶yksjkbV FCC esa _.kk;u rFkk prq"Qydh; fNnz esa
/kuk;u ¶yksjkbV FCC es /kuk;u rFkk prq"Qydh; fNnz esa _.kk;u
E-4. KBr crystallizes in NaCl type of unit cell. K+ radius = 1.33Å, Br¯ radius = 1.95 Å
(a) How many K+ ions and how many Br¯ ions are in each unit cell?
(b) Assuming the additivity of ionic radii, what is a ?
(c) Calculate the density of a perfect KBr crystal.
(d) What minimum value of r+/r– is needed to prevent anion-anion contact in this structure.
KBr dk fØLVy NaCl dh ,dd dksf"Bdk dh rjg gS ftlesa K+ f=kT;k = 1.33Å , Br¯ f=kT;k = 1.95 Å gSA
(a) izR;sd ,dd dksf"Bdk essa K+ rFkk Br¯ vk;u fdrus&fdrus gksaxs \
(b) ;g ekurs gq;s fd vk;fud f=kT;k,¡ tksM+h tk ldrh gSA a dk eku crkb;sA
(c) iw.kZ KBr fØLVy dk ?kuRo dh x.kuk djksA
(d) lajpuk esa & _.kk;u lEidZ dks jksdus ds fy, r+/r– dk U;wure eku D;k gksxk \
Ans. (a) K+ ion = 4 & Br¯ ion = 4 (b) 6.56 Å (c) 2.80 g/cm3 (d) 0.414
Ans. (a) K vk;u = 4 rFkk Br¯ vk;u = 4
+ (b) 6.56 Å (c) 2.80 g/cm3 (d) 0.414
Section (F) : Crystal defects and Properties of solids
[k.M (F) : fØLVy =kqfV;k¡ ¼nks"k½ rFkk Bkslksa ds xq.k
Commit to memory :
Stoichiometric - The formula of compound remains same even after presence of these defects.
Non-stoichiometric - The formula of compound will get modified because of the presence of these
defects.
 th – exp 
% missing units = 
    100% (Schottky Defects)
th
Locations of electrons in metal excess defect are also known as color centres (F-centres).

;kn j[kus ;ksX; rF; %

jllehdj.k nks"k - bu =kqfV;ksa mifLFkfr esa ;ksfxd dk lw=k leku cuk jgrk gSA
vjllehdj.k nks"k - bu =kqfV;ksa mifLFkfr esa ;ksfxd dk lw=k ifjofrZr gks tkrk gSA
 th – exp 
foyqIr bdkb;ksa dk % = 
 th   100% ('kkWVdh =kqfV)

/kkrq vkf/kD; =kqfV esa bysDVªkWu dh fLFkfr;ka] jax dsUnzd (F-dsUnz) dgykrs gSA
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 Solid State
F-1. What do you understand by imperfections in ionic crystals ? Name the types of imperfections which
generally occur in ionic crystals.
vk;fud fØLVy esa nks"kksa dk D;k eryc gksrk gSA vk;fud fØLVy esa lkekU;r% ik;s tkus okys nks"kksa ds uke crkvksA
Ans. Imperfections in solids : Any deviation from the perfectly ordered arrangement constitutes a defect or
imperfection. These defect are sometimes called thermodynamic defects because the number of these
defects depends on the temperature.
(i) Stoichiometric point defects : Schottky Defects, Interstitial Defects, Frenkel Defects.
(ii) Non-Stoichiometric defects : Metal excess defects, Metal deficiency defects.
mÙkj- Bkslksa esa viw.kZrk ¼nks"k ;k =kqfV;k¡½ : Bksl esa iw.kZr% Øec) O;oLFkk ls fdlh Hkh izdkj dk fopyu viw.kZrk ;k nks"k gksrk
gSA bu =kqfV;ksa ¼nks"k½ dks lkekU;r% Å"eh; nks"k ¼Å"eh; =kqfV;k¡½ dgk tkrk gSA D;ksafd dh cgqr ls nks"k] rki ij fuHkZj
djrs gSA
(i) jllehdj.kfefr nks"k % 'kkWVdh nks"k] vUrjkdk'kh nks"k] Ýsady =kqfV;k¡ ¼nks"k½
(ii) vjllehdj.kfefr nks"k % /kkrq vkf/kD; =kqfV;k¡] /kkrq U;wurk] =kqfV;k¡ ¼nks"k½

F-2. How would you explain that (i) non-stoichiometric NaCl is yellow ; (ii) non-stoichiometric ZnO is yellow ?
budks fdl izdkj ls le>k;saxsA (i) vjllehdj.kferh; NaCl ihyk gS ( (ii) vjllehdj.kferh; ZnO ihyk gS \
Ans. The reason of both is the presence of electron in anionic vacancies which is known as F-center.
mÙkj- mijksDr nksuksa esa _.kk;fud fjfDr;ksa esa bysDVªkWu mifLFkr gksrs gS] blfy, bls F-dsUnz dgrs gSA
F-3. Account the following: Silicon is an insulator but silicon doped with phosphorus acts as a
semiconductor.
fuEu ij fVIi.kh fyf[k,% flfydu ,d dqpkyd gS ijUrq flfydu dks QkLQkWjl ds lkFk lefefJr djus ij ;g ,d
v)Zpkyd ds leku O;ogkj djrk gSA
Ans. Silicon doped with phosphorus forms n - type of semiconductor. Phosphorus contains one extra
electron than silicon which can move easily through the crystal and is responsible for semiconductor
properties.
mÙkj- flfydu QkLQkWjl ds lkFk lefefJr gksdj n-izdkj ds v)Zpkyd dk fuekZ.k djrk gSA QkLQkWjl flfydu dh
rqyuk esa ,d vfrfjDr bysDVªkWu j[krk gS tksfd lEiw.kZ fØLVy esa ljyrk ls xfreku jgrk gSA ;g v)Zpkyd xq.kksa
ds fy, mrjnk;h gksrk gSA
F-4. How does the conductivity of a semiconductor change if its temperature is raised?
,d v)Zpkyd dh oS|qr pkydrk fdl izdkj ifjofrZr gksrh gSA ;fn blds rki esa o`f) dh tkrh gS \
Ans. In semiconductor fairly small band gap is present between valence band (filled with electrons) and
conduction band (lowest unoccupied energy band). Increase in temperature gives thermal energy to
some of the electrons and they move to conduction band and change the conductivity of semiconductor
(Increase).
mÙkj- v)Zpkyd esa l;kstadrk cSUM (bysDVªkWu ;qDr cSUM) rFkk pkyd cSaUM (fuEure ÅtkZ okyk fjDr cSUM) ds e/; ÅtkZ
vUrjky de gksrk gSA rki esa o`f) djus ij izkIr Å"eh; ÅtkZ ls dqN bysDVªkWu pkyu cSaUM esa LFkkukUrfjr gks tkrs
gS] rFkk v)Zpkyd dh pkydrk esa ifjorZu dj nsrs gSA (o`f))

PART - II : ONLY ONE OPTION CORRECT TYPE

Hkkx-II : dsoy ,d lgh fodYi çdkj (ONLY ONE OPTION CORRECT TYPE)

Section (A) : Basics of solid state

[k.M (A) : Bksl izkoLFkk ds ekSfyd ¼vk/kkjHkwr½ rF;
A-1. Which of the following is/are pseudo solids ?
. KCI . Barium chloride dihydrate
. Rubber V. Solid cake left after distillation of coal tar
(A) , (B) ,  (C*) , V (D) only 

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fuEu esa dkSulk Nne~ vfØ; Bksl gS \
. KCI . csfj;e DyksjkbM MkbgkbMªsV
. jcj V. dksyrkj ds vklou ds ckn cpk gqvk Bksl dsd
(A) , (B) ,  (C*) , V (D) dsoy 

A-2. The smallest repeating pattern which when repeated in three dimensions results in the crystal of the
substance is called
(A) Space lattice (B) Crystal lattice (C*) Unit cell (D) coordination number
f=kfoe esa lw{eÙke iquoZjkfrZr vuqØe ftlds ifj.kkeLo:i] ,d inkFkZ fØLVy dk fuekZ.k gksrk gSA og dgykrk gSA
(A) f=kfoe tkyd (B) fØLVy tkyd (C*) ,dd dksf"Bdk (D) leUo; la[;k

A-3. The crystal system for which a  b  c and  =  =  = 900 is said to be :

(A) triclinic (B) tetragonal (C) cubic (D*) orthorhombic
fØLVy fudk; ftlds fy, a  b  c rFkk  =  =  = 90 dks dgk tk ldrk gSA
0

(A) f=kurk{k (B) f}lEyeck{k (C) ?kuh; (D*) fo"keyEck{k

A-4. Which of the following are the correct axial distance and axial angles for rhombohedral system?
f=kleurk{k fudk; ds fy, v{kh; nwjh rFkk v{kh; dks.k dk dkSulk ;qXe lgh gS \
(A*) a = b = c,  =  =  900 (B) a = b  c,  =  =  = 900
(C) ab c,  =  =  = 900 (D) ab c,   900
A-5. Choose the correct statements
(A*) equivalent points in unit cells of a periodic lattice lie on a Bravais lattice
(B) equivalent points in unit cells of a periodic lattice do not lie on a Bravais lattice
(C) There are four Bravais lattices in two dimensions
(D) There are five Bravais lattices in three dimensions
lgh dFku dk p;u djksA
(A*) ,d vko`fr tkyd ds ,dd dksf"Bdk esa lerqY;kad fcUnq czsfol tkyd ij fLFkr gksrs gSaA
(B) ,d vko`fr tkyd ds ,dd dksf"Bdk esa lerqY; fcUnw czsfol tkyd ij ugha gksrs gSA
(C) f}fofe; ry esa pkj czsfol tkyd gksrs gSaA
(D) f=kfoe ry esa ik¡p czsfol tkyd gksrs gSA

A-6. The crystal system of a compound with unit cell dimensions, a = 0.387 and b = 0.387 and c = 0.504nm
and  =  = 90º and  = 120º is :
(A) Cubic (B*) Hexagonal (C) Orthorhombic (D) Rhombohedral
,d ;kSfxd ds fy, dkSuls izdkj ds fØLVy fudk; dh ,dd dks f"Bdk dh foek,sa, a = 0.387 rFkk b = 0.387 rFkk
c = 0.504nm rFkk  =  = 90º rFkk  = 120º gSA
(A) ?kuh; (B*) "kV~dks.kh; (C) fo"eyEck{k (D) f=kleurk{k

Section (B) : Simple Cubic Structure & BCC

[k.M (B) : ljy ?kuh; lajpuk rFkk BCC
B-1. Body centred cubic lattice has co–ordination number of :
dk; dsfUær ?kuh; tkyd esa milgla;kstd la[;k gS :
(A*) 8 (B) 12 (C) 6 (D) 4
B-2. Iron has body centred cubic lattice structure. The edge length of the unit cell is found to be 286 pm.
What is the radius of an iron atom?
vk;ju dk; dsfUnz; ?kuh; tkyd ljapuk j[krk gSA ftldh ,dd dksf"Bdk dksj yEckbZ 286 pm gSA vk;ju
ijek.kq dh f=kT;k D;k gS ?
(A*) r = 124 pm (B) r = 128 pm (C) r = 124 Å (D) r = 128 Å

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B-3. A metal crystallizes in a body centered cubic lattice (bcc) with the edge of the unit cell 5.2Å. The
distance between the two nearest neighbour is
,d /kkrq dk; dsfUnzr ?kuh; lajpuk ¼tkyd½ (bcc) esa fØLVyd`r gksrh gSa bldh ,dd dksf"Bdk dksj yEckbZ 5.2Å
bl O;oLFkk esa nks fudVorhZ ijek.kq ds e/; dh nwjh crkb;sA
(A) 10.4 Å (B*) 4.5 Å (C) 5.2Å (D) 9.0Å
B-4. At room temperature, Polonium cryatsllises in Cubic primitive cell. If edge length is 3.0 Å, calculate the
theoretical density of Po. (Atomic wt of Po = 207g)
dejs ds rki ij iksyksfu;e izk:fid ?kuh; dksf"Bdk ds :i esa fØLVyhd`r gksrk gSA ;fn fdukjs dh yEckbZ 3.0 Å gS]
rc Po ds lS)kfUrd ?kuRo dh x.kuk dhft;s \ (Po dk ijek.kq Hkkj = 207g)
(A) 25/3 amu/ Å 3 (B*) 23/3 amu/ Å 3 (C) 21/3 amu/ Å 3 (D) 27/3 amu/ Å 3
B-5. Lithium crystallizes in a body centered cubic lattice. How many next–nearest neighbors does each Li
have?
yhfFk;e dk; dsUnzh; ?kuh; tkyd lajpuk esa fØLVyhd`r gksrk gS rks izR;sd Li ijek.kq ds fdrus vxys fudVre
(next–nearest) ijek.kq gksxsa \
(A*) 6 (B) 8 (C) 12 (D) 4
B-6. Consider a Body Centered Cubic(bcc) arrangement, let de, dfd, dbd be the distances between
successive atoms located along the edge, the face-diagonal, the body diagonal respectively in a unit
cell.Their order is given by:
,d dk; dsfUnz; ?kuh; O;oLFkk (bcc) dk voyksdu dhft,] ekuk fd ,d ,dd dksf"Bdk esa de, dfd, dbd Øe'k% dksj]
Qyd fod.kZ] dk; fod.kZ ds vuqfn'k fLFkr nks Øekxr ijek.kqvksa ds chp dh nwjh;k¡ gSaA budk Øe fuEu ds }kjk
fn;k tkrk gSaA
(A) de < dfd < dbd (B) dfd > dbd > de (C*) dfd > de > dbd (D) dbd > de > dfd,

Section (C) : HCP & CCP structures

[k.M (C) : HCP rFkk CCP lajpuk
C-1. How many number of atoms are completely inside the HCP unit cell ?
(A) Exactly 6 (B) > 6 (C*) < 6 (D) 12
HCP ,dd dksf"Bdk esa fdrus ijek.kq iw.kZr% vUnj mifLFkr gksrs gS \
(A) dsoy 6 (B) > 6 (C*) < 6 (D) 12

C-2. The shortest distance between Ist and Vth layer of HCP arrangement is :
HCP O;oLFkk esa Ist rFkk Vth ijr ds e/; dh lcls de nwjh gS %
2 3 2 3
(A*) 8 r (B) 4 r (C) 16 r (D) 8 r
3 2 3 2
C-3. Volume of HCP unit cell is :
HCP ,d dksf"Bdk dk vk;ru gS %
(A*) 24 2 r3 (B) 8 2 r3 (C) 16 2 r3 (D) 24 3 r3
C-4. Fraction of empty space in ABAB type arrangement in 3D :
ABAB izdkj dh 3D esa ABAB izdkj dh O;oLFkk ls fjDr LFkku dk izHkkt gSA
(A) 0.74 (B*) 0.26 (C) 0.68 (D) 0.32
C-5. What is the hight of an HCP unit cell ?
HCP ,dd dksf"Bdk dh Å¡pkbZ D;k gS \
3 3 2 2
(A) a (B) a (C*) × 2a (D) a
2 2 3 3
C-6. What is the number of atoms in a unit cell of face-centred cubic crystal?
Qyd dsfUnzr ?kuh; fØLVy dh ,d ,dd dksf"Bdk dh ijek.kqvksa dh la[;k D;k gS \
(A*) 4 (B) 6 (C) 2 (D) 1

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 Solid State
C-7. Which of the following shaded plane in fcc lattice contains arrangement of atoms as shown by circles :
dkSulk Nk;k;qDr ry Qyd dsfUnzr ?kuh; (fcc) O;oLFkk esa ik;k tkrk gSA tgk¡ ijek.kqvksa dh O;oLFkk o`Ùk ds vuqlkj
fn[kkbZ xbZ gS :

Figure ¼fp=k½

(A) (B) (C*) (D)

C-8. Copper crystallises in a structure of face centerd cubic unit cell. The atomic radius of copper is 1.28 Å.
What is axial length on an edge of copper?
dkWij Qyd dsfUnzr ,dd dksf"Bdk lajpuk esa fØLVyhd`r gksrk gSA ftlesa dkWij dh ijek.kq f=kT;k 1.28 Å gSA
dkWij ds fdukjs ij v{kh; yEckbZ Kkr djks %
(A) 2.16 Å (B*) 3.62 Å (C) 3.94 Å (D) 4.15 Å
C-9. The maximum percentage of available volume that can be filled in a face centred cubic system by
atoms is-
FCC lajpuk esa miyC/k vk;ru dk % tks fd ijek.kqvksa }kjk Hkjk tkrk gS] og gS&
(A*) 74% (B) 68% (C) 34% (D) 26%
C-10. In a face centred cubic lattice the number of nearest neighbours for a given lattice point are :
Qyd dsUnzh; ?kuh; tkyd esa fn;s x;s tkyd fcUnq ds fy, fudVre lehiorhZ ijek.kqvksa dh la[;k gS %
(A) 6 (B) 8 (C*) 12 (D) 14
C-11. Which one of the following schemes of ordering closed packed sheets of equal sized spheres does not
generate close packed lattice.
fuEu esa ls dkSulk Øe leku vkdkj ds xksys dh ijr ls fufcM+ ladqyu ugha cukrk gSA
(A) ABCABC (B) ABACABAC (C*) ABBAABBA (D) ABCBCABCBC

Section (D) : Voids

[k.M (D) : fjfDrdk;sa
D-1. If the anions (A) form hexagonal closest packing and cations (C) occupy only 2/3 octahedral voids in it,
then the general formula of the compound is
;fn _.kk;u (A) "k"Vdks.kh; fufcM+ ladqyu cukrs gS rFkk blesa /kuk;u (C) dsoy 2/3 v"VQydh; fNnzksa dks ?ksjrs gS
rks ;kSfxd dk lkekU; lw=k Kkr djksA
(A) CA (B) CA2 (C*) C2A3 (D) C3A2
D-2. You are given 4 identical balls. What is the maximum number of square voids and triangular voids (in
separate arrangements) that can be created ?
vkidks pkj leku xsans nh xbZ gS a oxZ fjfDrdkvksa o f=kHkqth; fjfDrdkvksa ¼i`Fkd~ foU;kl esa½ dh vf/kdre la[;k D;k
gS] tks izkIr fd;s tk ldrs gksa ?
(A*) 1, 2 (B) 2, 1 (C) 3, 1 (D) 1, 3
D-3. The empty space between the shaded balls and hollow balls as shown in the
diagram is called
(A) hexagonal void
(B*) octahedral void
(C) tetrahedral void
(D) double triangular void

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 Solid State
la;ksftr rFkk [kks[kyh ckWy ds e/; [kkyh LFkku dks fp=kkuqlkj fn[kk;k x;k gS] bls
dgrs gS %
(A) "k"V~dks.kh; fNnz
(B*) v"VQydh; fNnz
(C) prq"Qydh; fNnz
(D) f}f=kdks.kh; fNnz

D-4. In the close packed structure of AB type solid have cation radius of 75 pm, what would be the maximum
and minimum sizes of the anions which formed voids in unit cell ?
(A) r –minmum = 101.45, r –maximum = 303.3 pm (B) r –minmum = 105.45, r –maximum = 300.3 pm
– –
(C*) r minmum = 102.45, r maximum = 333.3 pm (D) r –minmum = 98.4, r –maximum = 333.3 pm
,d AB izdkj ds Bksl dh fufcM ladqfyr lajpuk esa /kuk;u dh f=kT;k 75 pm gSA rc ,dd dksf"Bdk esa +_.kk;uksa
dk vf/kdre fuEure vkdkj D;k gksxk tks fd ,dd dksf"Bdk esa fjfDr;ksa dk fuekZ.k djrs gS \
(A) r –U;wure = 101.45, r –vf/kdre = 303.3 pm (B) r –U;wure = 105.45, r –vf/kdre = 300.3 pm
(C*) r –U;wure = 102.45, r –vf/kdre = 333.3 pm (D) r –U;wure = 98.4, r –vf/kdre = 333.3 pm

D-5. In a hypothetical solid C atoms form CCP lattice with A atoms occupying Plane
all the Tetrahedral Voids and B atoms occupying all the octahedral
voids.A and B atoms are of the appropriate size such that there is no
distortion in the CCP lattice.Now if a plane is cut (as shown) then type of
voids and their numbers whic are present at the cross section would be:
,d dkYifud Bksl esa dkcZu ijek.kq CCP tkyd cukrs gSa ftleas A ijek.kq lHkh CCP unit cell
prq"Qydh; fjfDrdkvksa ls f?kjs jgrs gS rFkk B ijek.kq lHkh v"VQydh;
fjfDrdkvksa ls f?kjk jgrk gSA A rFkk B dk vkdkj bl izdkj dk gksrk gS fd
CCP tkyd esa fdlh Hkh izdkj dh fod`fr ugha gksrh gS vc ;fn ,d lery dks
foHkkftr fd;k tkrk gS ¼tSlk fd n'kkZ;k x;k gS½ rks vuqizLFk dkV ij mifLFkr
fjfDr;ks ds izdkj rFkk budh la[;k gksxh %
(A*) O.V = 3, T.V. = 4 (B) O.V. = 2, T.V. = 4
(C) O.V. = 1, T.V. = 2 (D) O.V. = 0, T.V. = 4

D-6. Following three planes (P1, P2, P3) in an FCC unit cell are shown:

Consider the following statements and choose the correct option that follow:
(i) P1 contains no voids of three dimensions. (ii) P2 contains only octahedral voids.
(iii) P3 contains both octahedral and tetrahedral voids.
(A*) All are true (B) Only (i) & (ii) are true
(C) (i) & (iii) are true (D) Only (iii) is true.
,d FCC ,dd dksf"Bdk esa rhu lery ( P1, P2, P3) n'kkZ;s x;s gSA

fuEu dFkuksa dks voyksdu dhft, rFkk mu fodYiksa dks pqfu;s tks fd fuEu dk ikyu djrs gSA
(i) P1 f=kfoe dh dksbZ fjfDrdk ugha j[krs gSA (ii) P2 dsoy v"VQydh; fjfDrdk j[krs gSA
(iii) P3 v"VQydh; rFkk prq"Qydh; nksuksa fjfDrdk j[krs gSA
(A*) lHkh lR; gSA (B) (i) o (ii) lR; gSA (C) (i) rFkk (iii) lR; gSA (D) dsoy (iii) lR; gSA

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D-7. In an FCC unit cell a cube is formed by joining the centers of all the
tetrahedral voids to generate a new cube.Then the new cube would contain
voids as :
(A*) 1 full tetrahedral void, 1 full octahedral void
(B) 1 full tetrahedral void only
(C) 8 full tetrahedral voids and 1 full octahedral void
(D) 1 full Octahedral void only

FCC ,dd dksf"Bdk esa ,d ?ku ds lHkh prq"Qydh; fjfDrdkvksa ds dsUnz dks tksM+dj
,d u;k ?ku cuk;k tkrk gSA rc cus gq;s u;s ?ku esa fdruh fjfDrdk,¡ mifLFkr gksxhA
(A*) 1 iw.kZ prq"Qydh; fjfDrdk] rFkk 1 iw.kZ v"VQydh; fjfDrdk
(B) ek=k 1 iw.kZ prq"Qydh; fjfDrdk
(C) 8 iw.kZ prq"Qydh; fjfDrdk rFkk 1 iw.kZ v"VQydh; fjfDrdk
(D) dsoy 1 iw.kZ v"VQydh; fjfDrdk

Section (E) : Radius ratio rule and Type of ionic structures

[k.M (E) : f=kT;k vuqikr fu;e rFkk vk;fud lajpukvksa ds izdkj
E-1. The radius of Ag+ ion is 126 pm and that of – ion is 216 pm. The co-ordination number of Ag+ ion is.
Ag+ vk;u dh f=kT;k 126 pm rFkk – vk;u dh f=kT;k 216 pm gSA Ag+ vk;u dh leUo; la[;k Kkr djksA
(A) 2 (B) 4 (C*) 6 (D) 8
E-2. The tetrahedral voids formed by ccp arrangement of Cl¯ ions in rock salt structure are
(A) Occupied by Na+ ions (B) Occupied by Cl¯ ions
(C) Occupied by either Na+ or CI¯ ions (D*) Vacant
jkWd lkYV lajpuk esa Cl— vk;uksa dh fufcM+ ?kuh; ladqyu (ccp) O;oLFkk }kjk cus gq, prq"Qydh; fNnz f?kjs gksrs
gSaA
(A) Na+ vk;uksa }kjkA (B) Cl¯ vk;uksa }kjkA
(C) Na+ ;k CI¯ vk;uksa ds }kjkA (D*) [kkyhA

E-3. Antifluorite structure is derived from fluorite structure by :

(A) heating fluorite crystal lattice
(B) subjecting fluorite structure to high pressure
(C*) Inter changing the positions of positive and negative ions in the lattice
(D) none of these
,UVh¶yqjkbV lajpuk ¶yqjkbV lajpuk ls fuEu }kjk cukbZ xbZ gS %
(A) ¶yqjkbV fØLVy tkyd dks xeZ djds
(B) ¶yqjkbV lajpuk ij vf/kd nkc yxkdj
(C*) tkyd esa /kuk;u rFkk _.kk;u dh fLFkfr vUrj ifjofrZr djds
(D) buesa ls dksbZ ugha

E-4. In zinc blende structure the coordination number of Zn2+ ion is

ZnS ftad CySaM@lajpuk esa Zn2+ vk;uksa dh leUo; la[;k D;k gS
(A) 2 (B*) 4 (C) 6 (D) 8
E-5. Strontium chloride has a fluorite structure, which of the following statement is true for the structure of
strontium chloride ?
(A) the strontium ions are in a body–centered cubic arrangement
(B*) the strontium ions are in a face–centered cubic arrangement
(C) each chloride ion is at the center of a cube of 8 strontium ions
(D) each strontium ion is at the center of a tetrahedron of 4 chloride ions

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LVWªkfU'k;e DyksjkbM ,d ¶yqjkbV lajpuk j[krk gSA LVWªkfUl;e DyksjkbM dh lajpuk ds fy, fuEufyf[kr esa ls lgh
dFku gS \
(A) LVWªkfUl;e vk;u dk; dsfUnzr ?kuh; lajpuk esa O;ofLFkr gS
(B*) LVWªkfUl;e vk;u Qyd dsfUnzr ?kuh; lajpuk esa O;ofLFkr gSA
(C) DyksjkbM vk;u 8 LVWªkfUl;e vk;u ds ?ku ds dsUnz ij mifLFkr gSaA
(D) izR;sd LVWªkfUl;e vk;u 4 DyksjkbM vk;u ds prq"Qyd ds dsUnz ij mifLFkr gksrk gSaA

E-6. The spinal structure (AB2O4) consists of an fcc array of O2– ions in which the :
(A*) A cation occupies one-eighth of the tetrahedral holes and B cation occupies one-half of octahedral
holes
(B) A cation occupies one-fourth of the tetrahedral holes and the B cations the octahedral holes
(C) A cation occupies one-eighth of the octahedral hole and the B cation the tetrahedral holes
(D) A cation occupies one-fourth of the octahedral holes and the B cations the tetrahedral holes
LikbZuy lajpuk (AB2O4) esa O2– vk;u Qyd dsfUnzr ?kuh; (fcc) O;oLFkk esa gksrs gSA ftlesa %
(A*) A /kuk;u prq"Qydh; fNnz dk 1/8 rFkk B /kuk;u v"VQydh; fNnz dk 1/2 Hkkx ?ksjrs gSA
(B) A /kuk;u prq"Qydh; fNnz dk 1/4 rFkk B /kuk;u v"VQydh; fNnz dks ?ksjrk gSA
(C) A /kuk;u v"VQydh; fNnz dk 1/8 rFkk B /kuk;u prq"Qydh; fNnz dks ?ksjrk gSA
(D) A /kuk;u v"VQydh; fNnz dk 1/4 rFkk B /kuk;u prq"Qydh; fNnz dks ?ksjrk gSA

E-7. In the crystal lattice of diamond, carbon atoms adopt :

(A*) fcc arrangement along with occupancy of 50% tetrahedral holes
(B) fcc arrangement along with occupancy of 25% tetrahedral holes
(C) fcc arrangement along with occupancy of 25% octahedral hole
(D) bcc arrangement
ghjs ds fØLVy tkyd esa] dkcZu ijek.kq
(A*) 50% prq"Qydh; fNnzksa ds lkFk Qyd dsfUnzr ?ku (fcc) O;oLFkk ds vuqlkj LFkku ?ksjrs gSaA
(B) 25% prq"Qydh; fNnzksa ds lkFk Qyd dsfUnzr ?ku (fcc) O;oLFkk ds vuqlkj LFkku ?ksjrs gSaA
(C) 25% v"VQydh; fNnzksa ds lkFk Qyd dsfUnzr ?ku (fcc) O;oLFkk ds vuqlkj LFkku ?ksjrs gSaA
(D) dk; dsfUnzr ?ku (bcc) O;oLFkk esa gksrs gSA

E-8. Cesium chloride on heating to 760 K changes into

(A) CsCI(g) (B*) NaCI structure
(C) antifluorite structure (D) ZnS structure
760 K ij lhft;e DyksjkbM dks xeZ djus ij og ifjofrZr gks tkrk gSA
(A) CsCI(g) (B*) NaCI lajpuk (C) ,UVh¶yksjkbV lajpuk (D) ZnS lajpuk

Section (F) : Crystal defects and Properties of solids

[k.M (F) : fØLVy =kqfV;k¡ ¼nks"k½ rFkk Bkslksa ds xq.k
F-1. In a solid lattice the cation has left a lattice site and is located at an interstitial position, the lattice defect
is
(A) Interstitial defect (B) Valency defect (C*) Frenkel defect (D) Schottky defect
,d Bksl tkyds easa /kuk;u tkyd LFkku dks NksM+dj vUrjdk'kh LFkkuksa esa LFkku xzg.k djrk gS rc bl izdkj dk
tkyd =kqfV ;k tkyd nks"k gSA
(A) vUrjkdk'kh (B) fjfDrdk =kqfV (C*) Ýasdy =kqfV (D) 'kkW"Vdh =kqfV

F-2. Which of the following statements are correct in context of point defects in a crystal ?
(A) AgCl has anion Frenkel defect and CaF2 has Schottky defects
(B*) AgCl has cation Frenkel defects and CaF2 has anion Frenkel defects
(C) AgCl as well as CaF2 have anion Frenkel defects
(D) AgCl as well as CaF2 has Schottky defects

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fØLVy esa fcUnq nks"k ds lEcU/k esa dkSulk dFku lR; gS \
(A) AgCl esa _.kk;u Ýsady nks"k rFkk CaF2 esa 'kkWV~dh nks"k gksrk gSA
(B*) AgCl esa /kuk;u Ýsady nks"k rFkk CaF2 esa _.kk;u Ýsady nks"k gksrk gSA
(C) AgCl rFkk CaF2 nksuksa esa _.kk;u Ýsady nks"k gksrk gSA
(D) AgCl rFkk CaF2 nksuksa esa 'kkWVdh nks"k gksrk gSaA

F-3. F-centers are

(A*) the electrons trapped in anionic vacancies
(B) the electrons trapped in cation vacancies
(C) non-equivalent sites of stoichiometric compound
(D) all of the above
F-dsUnz esa
(A*) bysDVªkWu _.kk;u fjfDr;ksa esa ik;s tkrs gSaA (B) bysDVªkWu /kuk;u fjfDr;ksa esa ik;s tkrs gSaA
(C) jllehdj.kferh; ;kSfxd ds vrqY; fljs ij (D) mijksDr lHkh

F-4. Which of the following is true about the charge acquired by p-type semiconductors?
(A*) positive (B) neutral
(C) negative (D) depends on concentration of p impurity
p-izdkj ds v)Zpkydksa }kjk xzg.k fd;s x;s vkos'k ds lanHkZ esa fuEu ls dkSulk lgh gS
(A*) /kukRed (B) mnklhu
(C) _.kkRed (D) p v'kqf) dh lkanzrk ij fuHkZj djrk gSSA

PART - III : MATCH THE COLUMN

Hkkx - III : dkWye dks lqesfyr dhft, (MATCH THE COLUMN)
1. We are good at matching things let us try our hand on the following columns:
Solid Constituent particle Binding force
(a) Diamond (e) Ion (i) Metallic
(b) Sodium Chloride (f) Atom (j) Dipole dipole
(c) HCl (g) Kernel (k) Ionic
(d) Aluminium (h) Molecule (l) Covalent
fuEu LrEHkksa dks lqesfyr dhft;s \
Bksl vo;oh d.k caf/kr cy
(a) ghjk (e) vk;u (i) /kkfRod
(b) lksfM;e DyksjkbM (f) ijek.kq (j) f}/kqzo&f}/kqzo
(c) HCl (g) vf"V (k) vk;fud
(d) ,Y;qfefu;e (h) v.kq (l) lgla;kstd
Ans. (a - f,l); (b - e,k); (c - h,j); (d - g,i)
2. Match the column :
dkWye lqesfyr dhft,A
Column I (Arrangement of the atoms/ions) Column II (Planes in fcc lattice)
LrEHk I (ijek.kqvksa@vk;uksa ds foU;kl) LrEHk II (fcc tkyd esa ry)

(A) (p)

(B) (q)

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 Solid State

(C) (r)

(D) (s)

Ans. (A - r,s); (B - r,s); (C - p); (D - q)

3. Match the column :
Column-I Column-II
(A) ZnS crystal (p) fcc
(B) CaF2 crystal (q) hcp
3
(C) NaCl crystal (r) Distance between closest particles is a.
4
(D) Diamond crystal (s) Only one type of voids are occupied
dkWye lqesfyr dhft,A
LrEHk-I LrEHk-II
(A) ZnS fØLVy (p) fcc
(B) CaF2 fØLVy (q) hcp
3
(C) NaCl fØLVy (r) fudVre d.k ds chp dh nwjh a gksxh
4
(D) ghjk fØLVy (s) dsoy ,d izdkj dh fjfDr;k¡ xzg.k djsxkA
Ans. (A - p,q,r,s); (B - p,r,s); (C - p,s); (D - p,r,s)

 Marked questions are recommended for Revision.

 fpfUgr iz'u nksgjkus ;ksX; iz'u gSA
PART - I : ONLY ONE OPTION CORRECT TYPE
Hkkx-I : dsoy ,d lgh fodYi çdkj (ONLY ONE OPTION CORRECT TYPE)

1. Which of the following solids are not correctly matched with the bonds found between the constituent
particles:
(A) Solid CO2 : Vanderwaal's (B) Graphite : Covalent and Vanderwaal
(C*) Grey Cast Iron : Ionic (D) Metal alloys : Ions-delocalised electrons
fuEu esa ls dkSuls fodYi esa Bksl vo;oh d.k ds e/; cU/k ds lkFk lqesfyr ugha gSaA
(A) Bksl CO2 : okUMjokWy (B) xzsQkbV % lgla;ksth rFkk okUMjokWy
(C*) LysVh dPpk yksgk % vk;fud (D) feJ /kkrq % vk;u&foLFkkuhd`r bysDVªkWu

2. Which of the following is not correct for ionic crystals :

(A) They possess high melting point and boiling point
(B) All are electrolyte
(C) Exhibit the property of isomorphism
(D*) Exhibit directional properties of the bond
fuEu esa ls dkSuls dFku vk;fud Bkslks ds fy, lgh ugha gS&
(A) budk xyukad] DoFkukad mPp gksrk gSA (B) lHkh fo|qr vi?kV~; gksrs gSA
(C) buesa lekØfrdrk gksrh gSA (D*) buds vkcU/k fn'kkRed gksrs gSA
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 Solid State
3. An element (atomic mass = 100 g/mole) having bcc structure has unit cell edge 400 pm. The density of
the element is (no. of atoms in bcc(Z) = 2).
,d rRo (vkf.od Hkkj = 100 g/mole) ftldh lajpuk bcc gSA mldh ,dd dksf"Bdk ds fdukjsa dh yEckbZ
400 pm gSA rks ml rRo dk ?kuRo (bcc esa (Z) ijek.kq dh la[;k = 2) Kkr djks %
(A) 2.144 g/cm3 (B*) 5.2 g/cm3 (C) 7.289 g/cm3 (D) 10.376 g/cm3
4. What is the nearest distance between two different layers in ABAB arrangement (a = 2 × radius of the
particle).
ABAB O;oLFkkvksa esa nks fHkUu ijrksa ds e/; fudVre nwjh D;k gS \(a = 2 × radius of the particle).
8 4 1 2
(A) a (B) a (C) a (D*) a
3 3 6 3

5. In a CCP lattice of X and Y, X atoms are present at the corners while Y atoms are at face centers.Then
the formula of the compound would be if one of the X atoms from a corner is replaced by Z atoms (also
monovalent)?
X o Y, ds CCP tkyd esa X ijek.kq dksuksa ij rFkk Y ijek.kq Qyd ds dsUnz ij mifLFkr gaSA ;fn dksuksa ij mifLFkr
X ijek.kqvksa esa ls ,d dks Z (,dy la;ksth) ijek.kq }kjk cny fn;k tk;s] rc bl ;kSfxd dk lw=k D;k gksxk \
(A) X7Y24Z2 (B*) X7Y24Z (C) X24Y7Z (D) XY24Z
6. You are given 6 identical balls.What is the maximum number of square voids and triangular voids (in
separate arrangements) that can be created?
vkidks N% le:ih ckWy nh xbZ gS ¼i`Fkd O;oLFkk esa½ oxZ rFkk f=kHkqth; fjfDrdkvksa dh vf/kdre la[;k D;k gksxhA
¼tks fd mRiUu dh tk ldrh gSA½
(A*) 2, 4 (B) 4, 2 (C) 4, 3 (D) 3, 4
7. In a simple cubic lattice of anions, the side length of the unit cell is 2.88 Å. The diameter of the void in
the body centre is
_.kkRed ds ljy?kuh; tkyd esa ,dd dksf"Bdk dh dksj yEckbZ 2.88 Å gSA ,dd dksf"Bdk ds dsUnz ij mifLFkr
fjfDrdk O;kl crkb;sA
(A) 1.934 Å (B) 0.461 Å (C*) 2.108 Å (D) 4.988 Å
8. In a multi layered close-packed structure
(A*) there are twice as many tetrahedral holes as many close-packed atoms
(B) there are as many tetrahedral holes as many closed packed atoms
(C) there are twice as many octahedral holes as many close-packed atoms
(D) there are as many tetrahedral holes as many octahedral holes
,d cgqijrh; fufcM+ ladqyu lajpuk esa
(A*) ;gk¡ ij fufcM+ ladqyu ijek.kqvksa ls nqxqus prq"Qydh; fNnz gSA
(B) ;gk¡ ij fufcM+ ladqyu ijek.kqvksa ds cjkcj prq"Qydh; fNnz gSA
(C) ;gk¡ ij fufcM+ ladqyu ijek.kqvksa ls nqxqus v"VQydh; fNnz gSA
(D) ;gk¡ ij v"VQydh; fNnz ds cjkcj prq"Qydh; fNnz gSA

9. In a compound, oxide ions are arranged in cubic close packing arrangement. Cations A occupy one-
sixth of the tetrahedral voids and cations B occupy one-third of the octahedral voids. The formula of the
compound is
,d ;kSfxd ftlesa] vkWDlkbM vk;u ?kuh; fufcM+ ladqyu O;oLFkk esa O;ofLFkr gSA /kuk;u A prq"Qydh; fNnz dk
1/6 Hkkx rFkk _.kk;u B v"VQyd fNnz dk 1/3 Hkkx ?ksjrs gSA rks ;kSfxd dk lw=k crkvksA
(A) A2BO3 (B) AB2O3 (C) A2B2O2 (D*) ABO3

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 Solid State
10. Platinum crystallizes in a face-centered cubic crystal with a unit cell length 'a'. The distance between
nearest neighbors is :
IySfVue ,d Qyd&dsfUnzr ?kuh; fØLVy esa fØLVyhd`r gksrk gSa ftlds ,dd dksf"Bdk dh yEckbZ 'a' gSa] rks
fudVorhZ iM+kSlh ¼fcUnqvksa½ ds e/; dh nwjh D;k gksxh %
3 2 2
(A) a (B) a (C*) a (D) a
2 2 4
11. Platinum crystallises in a face centered cube crystal with a unit cell length of 3.9231 Å. The density and
atomic radius of platinum are respectively. [Atomic mass of Pt = 195]
(A) 45.25 g. cm–3, 2.516 Å (B*) 21.86 g. cm–3, 1.387 Å
(C) 29.46 g. cm–3, 1.48 Å (D) None of these
Qyd dsfUnzr ?kuh; fØLVy esa IySfVue fØLVy dh ,dd dksf"Bdk dh yEckbZ 3.9231 Å gSA IySfVue dk ?kuRo rFkk
ijekf.od f=kT;k Øe'k% gSA [Pt dk ijek.kq Hkkj = 195]
(A) 45.25 g. cm–3, 2.516 Å (B*) 21.86 g. cm–3, 1.387 Å
(C) 29.46 g. cm–3, 1.48 Å (D) buesa ls dksbZ ugha

12. Metallic gold crystallises in face centered cubic. Lattice with edge-length 4.070 Å. Closest distance
between gold atoms is :
tc /kkfRod lksuk dks 4.070 Å dh fdukjk yEckbZ ds Qyd dsfUnzr ?kuh; tkyd esa fØLVyhd`r fd;k tkrk gSa] rc
lksuk ijek.kqvksa ds e/; fudVorhZ nwjh D;k gksxh %
(A) 2.035 Å (B) 8.140 Å (C*) 2.878 Å (D) 1.357 Å
13. Which of the following statements is correct in the rock-salt structure of ionic compounds?
(A) Co-ordination number of cation is four whereas that of anion is six.
(B) Co-ordination number of cation is six whereas that of anion is four.
(C) Co-ordination number of each cation and anion is four.
(D*) Co-ordination number of each cation and anion is six.
vk;fud ;kSfxd jkWd&lkYV lajpuk ds fy, fuEufyf[kr dFku lgh gS \
(A) /kuk;u dh leUo; la[;k 4 rFkk _.kk;u dh 6 gSA
(B) /kuk;u dh leUo; la[;k 6 rFkk _.kk;u dh 4 gSA
(C) /kuk;u rFkk _.kk;u nksuksa ds fy, leUo; la[;k 4 gSA
(D*) /kuk;u rFkk _.kk;u nksuksa ds fy, leUo; la[;k 6 gSA

14. The compound AB crystallizes in a cubic lattice in which both A and B atoms have coordination
numbers of 8. To what crystal class does the unit cell belong ?
(A*) CsCI structure (B) NaCI structure (C) ZnS structure (D) AI2O3 structure
,d ;kSfxd AB ds fØLVyh; ?kuh; tkyd esa A rFkk B ijek.kq nksuksa dh leUo; la[;k 8 gSA rks mijksDr fØLVy
fdl rjg dh ,dd dksf"Bdk ls lEcfU/kr gS \
(A*) CsCI lajpuk (B) NaCI lajpuk (C) ZnS lajpuk (D) AI2O3 lajpuk

15. BaO has a rock-salt type structure. When subjected to high pressure, the ratio of the coordination
number of Ba+2 ion to O–2 changes to
BaO ,d jkWd&lkYV lajpuk j[krk gSA tc vf/kd nkc yxk;k tkrk gS rks Ba+2 vk;u rFkk O–2 vk;u dh leUo;
la[;k dk vuqikr Kkr djksA
(A) 4 : 8 (B) 8 : 4 (C*) 8 : 8 (D) 4 : 4
16. A crystal of NaCl, which has sodium ions and chloride ions missing from the lattice point, is said to
exhibit
(A) Surface defect (B) Lattice defect (C) Frenkel defect (D*) Schottky defect
tc ,d NaCl fØLVy esa tkyd fcUnq ls lksfM;e rFkk DyksjkbM vk;u nksuksa xk;c gks rks bls dgrs gSA
(A) lrgh nks"k (B) tkyd nks"k (C) Ýsady nks"k (D*) 'kkWVdh nks"k

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17. In the Schootky defect :
(A) cations are missing from the lattice sites and occupy the interstitial sites
(B*) equal number of cations and anions are missing
(C) anion are missing and electrons are present in their place
(D) equal number of extra cations and electrons are present in the interstitial sites
'kkWVdh nks"k esa
(A) /kuk;u tkyd fcUnqvksa ls xk;c gksrs gSa rFkk vUrjdk'kh fjDr LFkku esa mifLFkr gksrs gSaA
(B*) leku la[;k esa /kuk;u rFkk _.kk;u xk;c gksrs gSa
(C) _.kk;u xk;c gksrs gSa rFkk bysDVªkWu muds LFkku ij mifLFkr gksrs gSa
(D) leku la[;k esa vfrfjDr /kuk;u rFkk bysDVªkWu vUrjdk'kh fjDr LFkku esa mifLFkr gkssrs gSaA

18. NaCl shows Schottky defects and AgCl Frenkel defects. Their electrical conductivity is due to:
(A*) motion of ions and not the motion of electrons
(B) motion of electrons and not the motion of ions
(C) lower co-ordination number of NaCl
(D) higher co-ordination number of AgCl
NaCl 'kkWVdh nks"k rFkk AgCl Ýsady nks"k iznf'kZr djrk gSA budh oS|qr pkydrk dk dkj.k gS %&
(A*) vk;uksa dh xfr o bysDVªkWu dh vxfr'khyrk (B) bysDVªkWu dh xfr rFkk vk;u dh vxfr'khyrk
(C) NaCl dh de leUo; la[;k (D) AgCl dh vf/kd leUo; la[;k

19. Zinc Oxide, white in colour at room temperature, acquires yellow colour on heating due to:
(A) Zn being a transition element.
(B) paramagnetic nature of the compound.
(C*) trapping of electrons at the site vacated by Oxide ions.
(D) Both (A) & (B).
ftad vkWDlkbM tks fd dejs ds rki ij lQsn jax dk gksrk gSa] xeZ djus ij ihyk jax fuEu dkj.k ls izkIr djrk gSA
(A) Zn ,d laØe.k rRo gSA
(B) ;kSfxd dh vuqpqEcdh; izd`fÙk gksrh gSA
(C*) vkWDlkbM vk;u }kjk mRiUu fjfDr dks bySDVªkWuksa }kjk xzg.k djus ds dkj.kA
(D) (A) rFkk (B) nksuksaA

PART - II : SINGLE AND DOUBLE VALUE INTEGER TYPE

Hkkx – II : ,dy ,oa f}&iw.kk±d eku izdkj ¼SINGLE AND DOUBLE VALUE INTEGER TYPE½
1. How many of the following are Covalent network solids?
S8, Bronze, SiO2, Diamond, ZnSO4, Si, AlN, SiC, CO2.
fuEu esa ls dkSuls lgla;ksth tkyd Bksl gksxsa ?
S8, czksUt, SiO2, ghjk, ZnSO4, Si, AlN, SiC, CO2.
Ans. 5
2. How many number of atom effectively present in a cubic unit formed by arrangement of eight B.C.C unit
cell.
vkB B.C.C ,dd dksf"Bdkvksa dh O;oLFkk }kjk fufeZr ,d ?ku esa ik;s tkus okys ijek.kqvksa dh izHkkoh la[;k fdruh
gS\
Ans. 16

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 Solid State
3. How many spherical balls of radii 2 cm can be placed completely inside a cubical box of edge = 8 cm ?
,d ?kuh; ik=k ftldh Hkqtk = 8 cm gS] esa 2 cm f=kT;k ds fdrus xksys j[ks tk ldrs gS ?

Ans. 8
4. What is the co-ordination number of an atom in its own layer in ABAB type arrangement.
ABAB izdkj dh O;oLFkk esa ,d ijek.kq dh Lo;a dh ijr esa leUo; la[;k D;k gS\
Ans. 6

5. In ABAB ....... arrangement if an atom is placed in A layer then calculate the number of atoms touching
in its adjacent B layers ?
ABAB ....... O;oLFkk esa] ;fn ,d ijek.kq A ijr es fLFkr gS rc ijr B ds fdrus ijek.kq blds lEidZ esa gksxsaA
Ans. 6
6. How many number octahedral voids are effectively inside an HCP unit cell.
HCP ,dd dksf"Bd esa fdruh v"VQydh; fjfDrdk;sa izHkkoh :i ls vUnj mifLFkr gSA
Ans. 6
7. In a compound, oxide ions are arranged in cubic close packing arrangement. Cations A occupy one-
sixth of the tetrahedral voids and cations B occupy one-third of the octahedral voids. The formula of the
compound is AxByOz, then find the value of x + y + z.
,d ;kSfxd ftlesa] vkWDlkbM vk;u ?kuh; fufcM+ ladqyu O;oLFkk esa O;ofLFkr gSA /kuk;u A prq"Qydh; fNnz dk
1/6 Hkkx rFkk _.kk;u B v"VQyd fNnz dk 1/3 Hkkx ?ksjrs gSA ;kSfxd dk lw=k AxByOz gS] rks x + y + z dk eku
Kkr dhft,A
Ans. 5 = (1 + 1 + 3)
8. The coordination number of cation and anion in Fluorite CaF 2 and Zinc blende ZnS are respectively x :
y and a : b. Find (x + y + a + b).
¶yksjkbV CaF2 rFkk ftad CysUM ZnS esa /kuk;u rFkk _.kk;u dh leUo; la[;k dk vuqikr Øe'k% x : y rFkk a : b
gSA (x + y + a + b) Kkr djksA
Ans. 20 = (8 + 4 + 4 + 4)
9. In a crystalline solid having molecular formula A2B anion (B) are arranged in cubic close packed lattice
and cations (A) are equally distributed between octahedral and tetrahedral voids.
(i) What percentage of octahedral voids is occupied?
(ii) What percentage of tetrahedral voids is occupied?
Report your answer ((i) – (ii)).
,d fØLVyh; Bksl ftldk lw=k A2B _.kk;u (B) ?kuh; fufoM+ ladqyu tkyd esa O;ofLFkr gksrs gS rFkk èkuk;u (A)
v"VQydh; rFkk prq"Qydh; fjfDr;ksa esa leku :i ls foijhr gksrs gSA
(i) Hkjh tkus okyh v"BQydh; fjfDr;ksa dk izfr'kr gSA
(ii) Hkjh tkus okyh prq"Qydh; fjfDr;ksa dk izfr'kr gSA
viuk mÙkj ((i) – (ii)).
Ans. 50 = (100 – 50)

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 Solid State
PART - III : ONE OR MORE THAN ONE OPTIONS CORRECT TYPE
Hkkx - III : ,d ;k ,d ls vf/kd lgh fodYi çdkj
1. Which of the following statements is/are false.
(A*) It is the isotropic nature of amorphous solids that all the bonds are of equal strength.
(B*) Entropy of a crystalline solid is higher than that of an amorphous solid.
(C*) Amorphous solids have definite volume but not definite shape.
(D) Amorphous solids can become crystalline on slow heating (annealing).
fuEu esa ls dkSulk@dkSuls dFku vlR; gSA
(A*) vfØLVyh; Bksl dh lenSf'kd izo`fÙk gksrh gS vkSj lHkh cU/k cjkcj lkeF;Z ds gksrs gSA
(B*) vfØLVyh; Bksl dh rqyuk esa fØLVyh; Bksl dh ,UVªkWih mPp gksrh gSA
(C*) vfØLVyh; Bksl dk vk;ru fuf'pr gksrk gS ijUrq vkd`fr fuf'pr ugha gksrh gSA
(D) de rki ¼okrkuq'khru½ ij vfØLVyh; Bksl] fØLVyh; Bksl cu ldrk gSA

2. Amorphous solid can also be called ________.

(A*) pseudo solids (B) true solids
(C*) super cooled liquids (D) super cooled solids
vfØLVyh; Bksl fuEu Hkh dgykrs gSa
(A*) Nn~e Bksl (B) okLrfod Bksl (C*) vfr'khfrr nzo (D) vfr'khfrr Bksl
3. In body-centred cubic lattice given below, the three distance AB, AC and AA’ are :
fn;s x;s] ,d dki dsfUnz; ?kuh; tkyd esa AB, AC rFkk AA’ rhu nwfj;k¡ gSa %
B
C

A D
A'
E G

F
H
3a
(A*) AB = a (B*) AC = 2a (C*) AA' = (D) AA' = 3a
2
4. A metal crystallises in bcc. Find the % fraction of edge length not covered and also % fraction of edge
length covered by atom is :
,d /kkrq bcc tkyd esa fØLVyhd`r gskrh gSA ijek.kqvksa }kjk fdukjs dk vukPNkfnr % rFkk vkPNfnr % gS %
(A) 10.4% (B*) 13.4% (C*) 86.6% (D) 11.4%
5. Select the correct statements about three dimensional HCP system.
(A*) Number of atoms in HCP unit cell is six. (B*) The volume of HCP unit cell is 24 2 r3.
(C*) The empty space in HCP unit cell is 26%. (D*) The base area of HCP unit cell is 6 3 r2.
f=kfoeh; HCP ra=k ds lanHkZ esa lgh dFkuksa dk p;u dhft,A
(A*) HCP ,dd~ dksf"Bdk es ijek.kqvska dh la[;k 6 gSA
(B*) HCP ,dd~ dksf"Bdk dk vk;ru 24 2 r3 gSA
(C*) HCP ,dd~ dksf"Bdk es fjDr LFkku 26% gSA
(D*) HCP ,dd~ dksf"Bdk vk/kkj dk {ks=kQy 6 3 r2 gSA

6. Which statements is/are true about HCP and CCP lattice
(A*) Number of tetrahedral voids are twice of octahedral holes
(B*) 12 tetrahedral and 6 octahedral voids are present in one HCP unit cell
(C*) C.N. of HCP unit cell is 12
(D) If atom of tetrahedral voids displace into octahedral voids then it is Schootky defect.

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 Solid State
HCP rFkk CCP tkyd ds lanHkZ esa dkSulk@dkSuls dFku lR; gS@gSa \
(A*) lepq"Qydh; fjfDr;ksa dh la[;k] v"VQydh; fNnzksa ls nqxuh gksrh gSA
(B*) ,d HCP bdkbZ dksf"Bdk esa 12 leprq"Qydh; rFkk 6 v"VQydh; fjfDr;ka mifLFkr gksrh gSaA
(C*) HCP bdkbZ dksf"Bdk dh leUo; la[;k (C.No.) 12 gSA
(D) ;fn leprq"Qydh; fjfDr;ksa dk ijek.kq] v"VQydh; fjfDr;ksa esa izfrLFkkfir fd;k tk;s rc ;g 'kkWVZdh =kqfV
(Schootky defect) gksrh gSA

7. In which of the following arrangements octahedral voids are formed?

(A*) hcp (B) bcc (C) simple cubic (D*) fcc
fuEu esa ls dkSulh O;oLFkk v"VQydh; fjfDrdk;s cukrh gS \
(A*) hcp (B) bcc (C) ljy?kuh; (D*) fcc

8. The number of tetrahedral voids per unit cell in NaCl crystal is ________.
(A) 4 (B*) 8
(C*) twice the number of octahedral voids. (D) four times the number of octahedral voids.
NaCl fØLVy esa] izfr,dd~ dksf"Bdk] prq"Qydh; fjfDrdkvksa dh la[;k ________ gSA
(A) 4 (B*) 8
(C*) v"VQydh; fjfDrdkvksa dh nks xquh (D) v"VQydh; fjfDrdkvksa dh pkj xquh

9. Which of the following statements are correct :

(A*) The coordination number of each type of ion in CsCl crystal is 8.
(B) A metal that crystallises in bcc structure has a coordination number of 12.
(C*) A unit cell of ionic crystal shares some of its ion with other unit cells.
(D*) The length of the unit cell in NaCl is 552 pm. (  Na = 95 pm,  Cl– = 181 pm)
fuEu esa ls dkSuls dFku lgh gS@gSa \
(A*) CsCl fØLVy esa izR;sd izdkj ds vk;u dh leUo; la[;k 8 gSA
(B) ,d /kkrq tks bcc lajpuk es fØLVyhd`r gksrh gSA mldh leUo; la[;k 12 gSA
(C*) ,d vk;fud fØLVy dh ,dd dksf"Bdk] blds dqN vk;uksa dks vU; ,dd~ dksf"Bdkvksa ds lkFk lfEer djrh
gSA
(D*) NaCl esa] ,dd~ dksf"Bdk dh yEckbZ 552 pm gSA (  Na = 95 pm,  Cl = 181 pm)
 –

10. Which of the following is/are correct ?

(A*) Schottky defect lowers the density
(B*) Frenkel defect increases the dielectric constant of the crystals
(C*) Stoichiometric defects make the crystals electrical conductors
(D) In the Schoottky defect, equal number of extra cations and electrons are present in the interstitial
sites
fuEu esa ls dkSulk@dkSuls dFku lgh gS \
(A*) 'kkWV~dh nks"k esa ?kuRo de gksrk gSA
(B*) Ýsady nks"k fØLVy ds ijkoS|qrkad fLFkjkad dks c<+krk gSA
(C*) jllehdj.kferh; nks"k fØLVy dks oS|qr pkyd cukrk gSA
(D) 'kkWVdh nks"k esa leku la[;k esa vfrfjDr /kuk;u rFkk bysDVªkWu vUrjdk'kh fjDr LFkku esa mifLFkr gkssrs gSaA

11. A perfect crystal of silicon (Fig) is doped with some elements as given in the options. Which of these
options show n-type semiconductors?

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 Solid State
flfydu dk ,d ¼lEwi.kZ½ fØLVy dks dqN rRoksa ds lkFk lfEefJr (cloping) fd;k tkrk gSA fuEu esa ls dkSu ls
fodYIk n-izdkj ds v)Zpkyd ds izn'kZr djrs gS\

(A*) (B) (C*) (D)

12. Which of the following statements are true about semiconductors?

(A) Silicon doped with electron rich impurity is a p-type semiconductor.
(B*) Silicon doped with an electron rich impurity is an n-type semiconductor.
(C*) Delocalised electrons increase the conductivity of doped silicon.
(D) An electron vacancy increases the conductivity of n-type semiconductor.
v)Zpkydksa ds lUnHkZ es fuEu esa ls dkSuls dFku lgh gSa \
(A) bysDVªkWu iz;qj v'kqf);qDr ¼lafefJr½ flfydksu p-izdkj dk v)Zpkyd gksrk gSA
(B*) bysDVªkWu iz;qj v'kqf);qDr ¼lafefJr½ flfydksu n-izdkj dk v)Zpkyd gksrk gSA
(C*) foLFkkuhd`r bysDVªkWu] lfEefJr flfydkWu dh pkydrk es o`f) djrs gSA
(D) bysDVªkWu fjfDrdk] n-izdkj ds v)Zpkyd dh pkydrk es o`f) djrh gSA

PART - IV : COMPREHENSION
Hkkx - IV : vuqPNsn (COMPREHENSION)

Read the following comprehension carefully and answer the questions.

fuEu vuqPNsn dks /;kuiwoZd if<+;s rFkk iz'uksa ds mÙkj nhft,A
Comprehension # 1
Consider the figure given for solid XY. Answer the following questions
X

Figure
vuqPNsn # 1
Bksl XY dk fp=k uhps fn;k x;k gSA iz'u ds mÙkj bl fp=kkuqlkj crkvksA
X

fp=k

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 Solid State
1. The site Y represents
(A) tetrahedral void (B*) Octahedral void (C) triangular void (D) cubical void.
Y fLFkfr iznf'kZr djrk gSA
(A) prq"Qydh; fNnz (B*) v"VQydh; fNnz (C) f=kdks.kh; fNnz (D) ?kuh; fNnz
2. The number of XY units per unit cell is
çfr ,dd dksf"Bdk esa XY bdkbZ dh la[;k Kkr djksA
(A*) 4 (B) 3 (C) 3 (D) 8
3. Co-ordination number of Y is
Y dh leUo; la[;k gSA
(A) 3 (B) 4 (C*) 6 (D) 8
Comprehension # 2
When an atom or an ion is missing from its normal lattice site, a lattice vacancy (Schottky defect) is
created. In stoichiometric ionic crystals, a vacancy of one ion has to be accompanied by the vacancy of
the oppositely charged ion in order to maintain electrical neutrality.
In a Frenkel defect an ion leaves its position in the lattice and occupies an interstitial void. This is the
Frenkel defect commonly found along with the Schottky defects and interstitials. In pure alkali halides,
Frenkel defects are not found since the ions cannot get into the interstitial sites. Frenkel defects are
found in silver halides because of the small size of the Ag + ion. Unlike Schottky defects, Frenkel defects
do not change the density of the solids. In certain ionic solids (e.g. AgBr) both Schottky and Frenkel
defects occur.
The defects discussed above do not disturb the stoichiometry of the crystalline material. There is large
variety of non-stoichiomertic inorganic solids which contain an excess or deficiency of one of the
elements. Such solids showing deviations from the ideal stoichiometric composition form an important
group of solids. For example in the vanadium oxide, VOx, x can be anywhere between 0.6 and 1.3.
There are solids which are difficult to prepare in the stoichiometric composition. Thus, the ideal
composition in compounds such as FeO is difficult to obtain (normally we get a composition of Fe 0.95 O
but it may range from Fe0.93 O to Fe0.96O). Non-stoichiometric behaviour is most commonly found for
transition metal compounds though is also known for some lanthanoids and actinoids.
Zinc oxide loses oxygen reversibly at high temperatures and turns yellow in colour. The excess metal is
accommodated interstitially, giving rise to electrons trapped in the neighbourhood. The enhanced
electrical conductivity of the non-stoichiometric ZnO arises from these electrons.
Anion vacancies in alkali halides are produced by heating the alkali halide crystals in an atmosphere of
the alkali metal vapour. When the metal atoms deposit on the surface they diffuse into the crystal and
after ionisation the alkali metal ion occupies cationic vacancy whereas electron occupies anionic
vacancy. Electrons trapped in anion vacancies are referred to as F-centers (from Farbe the German
word for colour) that gives rise to interesting colour in alkali halides. Thus, the excess of potassium in
KCl makes the crystal appear violet and the excess of lithium in LiCl makes it pink.
vuqPNsn # 2
tc fdlh tkyd lrg esa ls ,d ijek.kq ;k vk;u xk;c gks tkrk gS rks ,d tkyd fjfDr ¼'kkWVdh =kqfV½ cu tkrh
gSA jllehdj.kfefr vk;fud fØLVy esa ,d vk;u }kjk mRiUu fjDrh nwljs foifjr vkosf'kr vk;u }kjk mRiUu
fjDrh }kjk bl izdkj larqfyr gksrh gS dh vkos'k mnklhurk cuh jgsA
Ýsady =kqfV esa ,d vk;u tkyd esa viuk LFkku NksM+dj ,d vUrjkdk'kh (interstitial) fjfDr xzg.k djrk gSA ;g
Ýsady =kqfV gS tks lkekU;r% 'kkWVdh =kqfV vkSj vUrjkdk'kh fjfDr;ksa (interstitials) ds lkFk ikbZ tkrh gSA 'kq)
,Ydkby gSykbM esa Ýsady =kqfV ugha ikbZ tkrh pwafd vk;u vUrjkdk'kh (interstitial) Hkkx izkIr ugha dj ikrkA Ýsady
=kqfV flYoj gSykbM esa ikbZ tkrh gS D;ksafd Ag+ vk;u dk vkdkj NksVk gksrk gSA 'kkWVdh =kqfV dh rjg Ýsady =kqfV
Bksl ds ?kuRo dks ugha cnyrhA dqN vk;fud Bksl (mnkgj.k] AgBr) esa 'kkWVdh o Ýsady =kqfV nksuksa feyrh gSaA
Åij fopkj dh xbZ =kqfV;k¡ inkFkZ dh fØLVyh; jllehdj.kfefr dks ifjofrZr ugha djrhaA cgqr ls çdkj ds
vjllehdj.kferh; çdkj ds vdkcZfud Bksl feyrs gSa tks ,d rRo dh deh ;k vf/kdrk j[krs gaSA bl rjg ds Bksl
vkn'kZ jllehdj.kfefr laxBu ls fopyu n'kkZrs gSa vkSj Bkslksa dk ,d egRoiw.kZ oxZ cukrs gSA mnkgj.k ds fy;s]
osusfM;e vkWDlkbM VOx, esa x dk eku 0.6 ls 1.3 ds chp dgha Hkh gks ldrk gSA ;s os Bksl gS ftUgs jllehdj.kfefr
laxBu esa cukuk dfBu gSA blfy, FeO dh rjg ds ;kSfxd dk vkn'kZ laxBu esa ik;k tkuk dfBu gSA ¼lkekU;r%
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 Solid State
gesa Fe0.95O dk laxBu feyrk gS ysfdu ;s Fe0.93O ls Fe0.96O ds e/; dk gks ldrk gS½ vjllehdj.kferh;
O;ogkj lkekU;r% laØe.k /kkrqvksa ds ;kSfxdksa ds fy, ik;k tkrk gS ;g dqN ySUFkSukbMksa o ,fDVukbMksa esa Hkh ik;k
tkrk gSA
ftad vkWDlkbM mPp rki ij mRØe.kh; :i ls vkWDlhtu R;kx dj ihys jax esa cny tkrk gSA /kkrq dh vf/kdrk
vUrjkdk'kh fjfDr;kas dks xzg.k dj ysrh gS vkSj lehi esa bysDVªkWu dh mifLFkfr dks c<+krh gSA bu bysDVªkWuksa ds vkus
ls vjllehdj.kferh; ZnO dh fo|qr pkydrk esa o`f) gksrh gSA
{kkjh; gSykbM esa _.kk;u fjfDr;ka] {kkjh; gSykbM fØLVy dks {kkjh; /kkrq ok"i ds okrkoj.k esa xeZ djds mRikfnr
dh tkrh gSaA tc /kkrq ijek.kq lrg ij ters gSa] os fØLVy esa pys tkrs gSa vkSj vk;uhdj.k ds ckn {kkjh; /kkrq ,d
/kuk;u fjfDr xzg.k djrs gSa vkSj bysDVªkWu _.kk;u fjfDr xzg.k djrs gaSA bysDVªkWu tks dh _.kk;u fjfDr xzg .k djrs
gSa F-dsUnz dgykrs gSa ¼teZu 'kCn Farbe = Colour jax½ og {kkjh; gSykbM dks :fpdj jax nsrk gSA ;gka KCl esa
iksVsf'k;e vf/kdrk fØLVy dks cSaxuh (violent) cukrh gS vkSj LiCl esa yhfFk;e dh vf/kdrk bls xqykch cukrh gSA
4. When LiCI is heated into the vapour of lithium, the crystal acquires pink colour. This is due to
(A) Schottkty defects (B) Frenkel defects
(C*) Metal excess defect leading to F-centers (D) Electronic defect
tc LiCI dks fyfFk;e dh ok"i esa xeZ fd;k tkrk gS] rks fØLVy xqykch jax dk gks tkrk gSA bldk dkj.k gksrk gSA
(A) 'kkWV~dh =kqfV (B) Ýasdy =kqfV
(C*) /kkrq vkf/kD; =kqfV tks fd F-dsUnz dk fuekZ.k djrh gS (D) fo|qrh; =kqfV

5. Strongly heated ZnO crystal can conduct electricity. This is due to
(A) Movement of extra Zn2+ ions present in the interstitial sites
(B*) Movement of electrons in the anion vacancies
(C) Movement of both Zn2+ ions and electrons
(D) None of these
ZnO fØLVy dks çcy :i ls xeZ djus ij fo|qrh; pkydrk n'kkZrk gSA bldk dkj.k gS&
(A) vUrjkdk'kh fjDrh esa mifLFkr vfrfjDr Zn2+ vk;u dh xfr ds dkj.k
(B*) _.kkosf'kr fjfDr;ksa esa bysDVªkWuksa dh xfr ds dkj.k
(C) Zn2+ vk;u o bysDVªkWu nksuksa dh xfr ds dkj.k
(D) buesa ls dksbZ ughaA

6. AgCl is crystallized from molten AgCl containing a little CdCl2. The solid obtained will have
(A*) cationic vacancies equal to number of Cd2+ ions incorporated
(B) cationic vacancies equal to double the number of Cd2+ ions
(C) anionic vacancies
(D) neither cationic nor anionic vacancies
xfyr AgCl tks fd de ek=kk esa CdCl2 j[krh gS ls AgCl dks fØLVyhd`r gksus ij izkIr Bksl esa gksxsA
(A*) /kukosf'kr fjfDr;k¡] Mksfir Cd2+ vk;u ds cjkcj la[;k esa gksxhA
(B) /kukosf'kr fjfDr;k¡ Cd2+ vk;u dh la[;k ds nqxus ds cjkcj gksxhA
(C) _.kk;u fjfDr;k¡
(D) u rks /kukosf'kr vkSj uk gh _.kkosf'kr fjfDr;k¡

7. Which of the following is most appropriate crystal to show Frenkel defect.

Ýsady =kqfV dks n'kkZus ds fy;s fuEu esa ls dkSulk fØLVy vuqdwy gSA
(A) CsCl (B) NaCl (C*) AgBr (D) CaCl2

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 Solid State
Comprehension # 3
Answer Question no. 8, 9 and 10 by appropriately matching the information given in the three columns
of the following table. (Z = effective number of atoms)
Column 1 Column 2 Column 3
(I) Square 2D packing (i) Z = 1 in smallest unit cell (P) edge length = 2R in smallest
unit cell
(II) Hexagonal 2D (ii) Z  3 in smallest unit cell (Q) close packing
packing of circles
(III) CCP (iii) Coordination Number = 6 (R) packing efficiency > 50%
(IV) Simple cubic (iv) Primitive unit cell possible (S) can be made by 2D hexagonal
layers of spheres
vuqPNsn # 3
fuEu dkWye esa nh xbZ lwpukvksa ds vk/kkj ij iz'u la[;k 8, 9 rFkk 10 dk lgh feyku dhft,A
(Z = izHkkoh ijek.kqvksa dh la[;k)
dkWye-1 dkWye-2 dkWye-3
(I) oxZ 2D ladqy (i) vk| ,dd dksf"Bdk esa Z = 1 (P) vk| ,dd dksf"Bdk esa dksj yEckbZ =
2R
(II) o`rksa dk "kV~dks.kh; (ii) vk| ,dd dksf"Bdk esa Z  3 (Q) fufcM+ ladqy
2D ladqyu
(III) CCP (iii) leUo; la[;k = 6 (R) ladqy n{krk > 50%
(IV) ljy ?kuh; (iv) vk| ldd dksf"Bdk lEHko gSa (S) bls 2-D "kV~dks.kh; ijrksa }kjk fufeZr
fd;k tk ldrk gSA

8.^ Identify the true combination:

lR; la;kstu igpkfu,A
(A*) (I) (i) P (B) (II) (i) Q (C) (III) (iii) R (D) (IV) (ii) S

9.^ For packing with minimum void space the true combination is:
(Consider 2D & 3D arrangements separately)
U;wure fjfDrdk vodk'k ;qDr ladqyu (space) ds fy, lR; la;kstu gS %
¼f}foeh; rFkk f=kfoeh; tkydksa dks i`Fkd ysdj½
(A) (I) (i) P (B*) (II) (i) P (C) (III) (iv) S (D) (IV) (iii) R

10.^ For the arrangement classified as ABAB type the correct combination is:
ABAB izdkj ds :i esa oxhZd`r foU;kl ds fy, lR; la;kstu gS %
(A) (I) (ii) P (B) (III) (i) Q (C*) (II) (iii) R (D) (IV) (iv) S

* Marked Questions may have more than one correct option.

* fpfUgr iz'u ,d ls vf/kd lgh fodYi okys iz'u gS -

PART - I : JEE (ADVANCED) / IIT-JEE PROBLEMS (PREVIOUS YEARS)

Hkkx - I : JEE (ADVANCED) / IIT-JEE ¼fiNys o"kksZ½ ds iz'u
1. In the figures given below show the location of atoms in three crystallographic planes in a fcc lattice.
Draw the unit cell of the corresponding structure and identify these planes in your diagram.
[JEE-2000, 3/100]
uhps nh xbZ vkd`fr esa Qyd dsfUnzr ?ku (fcc) tkyd dh rhu fØLVyh; ry esa ijek.kq dh fLFkfr;ka fn[kkbZa xbZ gSaA
lEcfUèkr lajpuk dh ,dd dksf"Bdk cukvks vkSj vius fp=k esa lrgksa dks igpkuksA [JEE-2000, 3/100]

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 Solid State

Figure ¼fp=k½

Ans.

2. In a solid 'AB' having the NaCl structure, 'A' atoms occupy the corners of the cubic unit cell. If all the
face centered atoms along one of the axes are removed, then the resultant stoichiometry of the solid is:
[JEE-2001, 1/35]
,d Bksl 'AB ' NaCl dh rjg lajpuk j[krk gSA 'A' ijek.kq ?kuh; ,dd dksf"Bdk ds dksuksa dks ?ksjrk gSA ;fn v{k ds
lgkjs fLFkr lHkh Qyd dsfUnzr ijek.kqvks dks gVk fn;k tk;s rks Bksl dh ifj.kkeh jllehdj.kfefr gksxh A
[JEE-2001, 1/35]
(A) AB2 (B) A2B (C) A4B3 (D*) A3B4
3. A substance Ax By crystallizes in a face centered cubic lattice in which atoms ‘A’ occupy each corner of
the cube and atoms ‘B’ occupy the centers of each face of the cube. Identify the correct composition of
the substance Ax By. [JEE-2002, 3/90]
(A*) AB3 (B) A4 B3
(C) A3 B (D) composition cannot be specified
,d inkFkZ AxBy dk fØLVyhdj.k Qyd dsfUnzr ?kuh; tkyd esa gksrk gSA ftlesa ijek.kqq A ?ku ds izR;sd dksus dk
LFkku o ijek.kq B ?ku ds izR;sd Qyd dsUnz dk LFkku xzg.k djrs gS rks inkFkZ AxBy ds lgh laxBu dks igpkuks \
[JEE-2002, 3/90]
(A*) AB3 (B) A4 B3
(C) A3 B (D) laxBu dks ugha crk;k tk ldrk gSA

4. Marbles of diameter 10 mm each are to be arranged on a flat surface so that their centers lie within the
area enclosed by four lines of length each 40 mm. Sketch the arrangement that will give the maximum
number of marbles per unit area, that can be enclosed in this manner and deduce the expression to
calculate it. [JEE-2003, 2/60]
lery lrg ij 10 mm O;kl ds izR;sd ekcZy ds VqdM+s dks O;ofLFkr fd;k tkrk gSA bl izdkj dsUnzd ;k e/;
fcUnq {ks=kQy pkj js[kk ls f?kjk gqvk gS] izR;sd js[kk dh yEckbZ 40 mm gSSA og O;oLFkk crkvks tgka bdkbZ {ks=kQy
esa vf/kdre la[;k esa ekcZy ds VqdM+s mifLFkr gks ldrs gSa D;k bls fdlh i)fr ls O;ofLFkr fd;k tk ldrk gS
rFkk bldh x.kuk lw=k dks Hkh Kkr djksA [JEE-2003, 2/60]
Ans. 25, 1.804 marbles/cm 2 25, 1.804 ekcZy/cm 2

5. A binary salt AB (formula weight = 6.023 Y amu, where Y is an arbitrary number) has rock salt structure
with 1 : 1 ratio of A to B. The shortest A—B distance in the unit cell is Y1/3 nm. [JEE-2004, 4/60]
(a) Calculate the density of the salt in kg m –3.
(b) Given that the measured density of the salt is 20 kg m –3, specify the type of point defect present in
the crystal.
,d ckbujh lkYV AB (lw=kHkkj = 6.023 Y amu, tgka Y dksbZ vpj la[;k gS) dh jkWd lkYV lajpuk gSA ftlesa A
rFkk B dk vuqikr 1 : 1 gSA ;fn ,dd dksf"Bdk esa A—B ds e/; dh lcls U;wure nwjh Y1/3 nm gSA
[JEE-2004, 4/60]
(a) yo.k ;k lkYV dk ?kuRo kg m–3 esa Kkr djksA
(b) ;fn yo.k dk ekfir ?kuRo 20 kg m–3 gSA rks fØLVy esa mifLFkr fcUnq nks"k ds izdkj dks le>kvksA
Ans. (a) 5 kg m–3 (b) Cancelled (Full marks given in part a)
(a) 5 kg m–3 (b) gVk fn;k x;k (Hkkx a esa iwjs uEcj fn;s x;s gS)

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 Solid State
6. In which of the following compounds the cations are present in alternate tetrahedral voids:
[JEE-2005, 3/84]
fuEufyf[kr esa ls dkSuls ;kSfxd esa /kuk;u prq"Qydh; fNnz esa ,d ds ckn ,d dh rjg ¼,dkUrfjr½ O;ofLFkr gksxsA
[JEE-2005, 3/84]
(A) NaCl (B*) ZnS (C) CaF2 (D) Na2O
7. In a FCC lattice of a metal edge length is 400 pm. Find the maximum diameter of an atom which can be
accommodated in an interstitial gap in this lattice without causing any distortion. [JEE-2005, 2/60]
/kkrq ds Qyd dsfUnzr ?ku (fcc) tkyd esa Hkqtk dh yECkkbZ 400 pm gSA ,d ijek.kq dk og vf/kdre O;kl Kkr
djks tks bl tkyd dh vUrjkdk'kh fjfDr esa fcuk fdlh =kqfV ds vk ldrs gSa \ [JEE-2005, 2/60]
Ans. 117.08 pm
8. For a unit cell edge length = 5Å, the element is of atomic mass 75, has density of 2gm/cc. Calculate
atomic radius of the element. [JEE-2006, 6/184]
,d rRo ds ,dd dksf"Bdk dh dksj yEckbZ = 5Å, ijek.kqHkkj = 75 o ?kuRo 2 gm/cc gSA rRo ds ijek.kq f=kT;k
Kkr dhft,A [JEE-2006, 6/184]
Ans. 216.5 pm.
9. Match the crystal system/unit cells mentioned in Column I with their characteristic features mentioned
in Column II. [JEE-2007, 6/162]
Column I Column II
have these cell parameters a = b = c
(A) simple cubic and face-centerd cubic (p)
and  =  = 
(B) cubic and rhombohedral (q) are two crystal systems
(C) cubic and tetragonal (r) have only two crystallographic angles of 90º
(D) hexagonal and monoclinic (s) belong to same crystal system
LrEHk I esa fn;s x;s fØLVy leqnk; @ ,dd lsy dks LrEHk II esa fn xbZ fo'ks"krkvksa ds lkFk lqesy dhft;sA
[JEE-2007, 6/162]
LrEHk-I LrEHk-II
(A) lkekU; ?kuh; vkSj Qyd (p) ds lsy izkpy (parameters) ;g gksrs gSaA a = b = c rFkk  =  = 
dsfUnz; ?kuh;
(B) ?kuh; vkSj f=kleurk{k (q) nks fØLVy leqnk; gSaA
(C) ?kuh; vkSj prq"dks.kh; (r) ds dsoy nks fØLVy lajpukRed dks.k 90º gksrs gSa
(D) "kV~dks.kh; vkSj ,durk{k (s) ,d gh fØLVy leqnk; ds gS
Ans. (A – p,s); (B–q, p); (C–q); (D–q, r).
Comprehension :
In hexagonal systems of crystals, a frequently encountered arrangement of
atoms is described as a hexagonal prism. Here, the top and bottom of the
cell are regular hexagons and three atoms are sandwiched in between them.
A space-filling model of this structure, called hexagonal close-packed (HCP),
is constituted of a sphere on a flat surface surrounded in the same plane by
six identical spheres as closely as possible. There spheres are then placed
over the first layer so that they touch each other and represent the second
layer. Each one of these three spheres touches three spheres of the bottom
layer. Finally, the second layer is covered with third layer that is identical to
the bottom layer in relative position. Assume radius of every sphere to be 'r'.

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 Solid State
vuqPNsn :
"kV~dks.kh; fØLVy leqnk; esa ijek.kq foU;kl vf/kdrj "kV~dks.kh; fizTe ds vkdkj esa
of.kZr fd;s tkrs gSaA blesa lsy ds Åij vkSj uhps fu;fer "kV~dks.k gksrs gSa rFkk rhu
ijek.kq muds chp vUrfuZfo"V (sandwiched) gksrs gSaA bl lajpuk ds ,d LFkku&Hkj.k
izfr:i (space-filling model), tks "kV~dks.kh; fufcM+ ladqyu (HCP) dgykrk gSa] bleas
lery ij ,d xksyk mlh ry esa vius tSls N% (6) xksyksa ls fudVre :i ls f?kjk
gksrk gSA mlds mijkUr rhu xksys ,d nwljs dks Li'kZ djrs gq, igyh ijr ij j[ks gSa
tks nwljh ijr cukrs gSaA bu rhuksa xksyksa esa izR;sd xksyk uhps okyh ijr ds rhu xksyksa
dks Li'kZ djrk gSA vUrr% nwljh ijr dks ,d rhljh ijr <drh gS ftldh lkis{k
fLFkfr lcls fupyh ijr ds leku gSA izR;sd xksys dh f=kT;k 'r' ekusaA
10. The number of atoms in the HCP unit cell is [JEE-2008, 4/163]
,d "kV~dks.kh; fufcM+ ladqyu (HCP) ,dd dksf"Bdk (unit cell) esa ijek.kqvksa dh la[;k gS [JEE-2008, 4/163]
(A) 4 (B*) 6 (C) 12 (D) 17
11. The volume of this HCP unit cell is [JEE-2008, 4/163]
bl HCP ,dd dksf"Bdk dk vk;ru gS [JEE-2008, 4/163]
64 3
(A*) 24 2 r 3 (B) 16 2 r 3 (C) 12 2 r 3 (D) r
3 3
12. The empty space in this HCP unit cell is [JEE-2008, 4/163]
bl HCP ,dd dksf"Bdk esa fjä LFkku gS [JEE-2008, 4/163]
(A) 74% (B) 47.6% (C) 32% (D*) 26%
13.* The correct statement(s) regarding defects in solids is(are) : [JEE-2009, 4/160]
(A) Frenkel defect is usually favoured by a very small difference in the sizes of cation and anion.
(B*) Frenkel defect is a dislocation defect.
(C*) Trapping of an electron in the lattice leads to the formation of F-center.
(D) Schottky defects have no effect on the physical properties of solids.
Bksl inkFkksZ esa nks"kksa (defects in solids) ls lEcfU/kr dkSulk (ls) oäO; lgh gS (gSa) ? [JEE-2009, 4/160]
(A) /kuk;u ,oa _.kk;u ds lkbtksa dk fuEuvUrj Ýsadsy nks"k (Frenkel defect) ds cuus esa lgk;d gksrk gSA
(B*) Ýsadsy nks"k (Frenkel defect) ,d izHka'k nks"k (dislocation defect) gSA
(C*) ySfVl esa bysDVªkWu idM+ (electron trapping) ds dkj.k F-dsUnz mRiUu gksrs gSaA
(D) Bksl inkFkks± ds HkkSfrd xq.k 'kkWV~dh nks"k (Schottky defects) ij fuHkZj ugha gksrs gaSA

14. The packing efficiency of the two dimensional square unit cell shown below is : [JEE-2010, 5/163]
uhps n'kkZ;s x;s f}Hkh; oxZ ,dd dksf"Bdk dh ladqyu {kerk gSA [JEE-2010, 5/163]

Figure ¼fp=k½
(A) 39.27% (B) 68.02% (C) 74.05% (D*) 78.54%
15. The number of hexagonal faces that are present in a truncated octahedron is
:afMr v"VQyd (truncated octahedron) esa mifLFkr "kVdks.kh; Qydksa dh la[;k gSA [JEE-2011, 3/160]
Ans. 8

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 Solid State
16. A compound MP Xq has cubic close packing (ccp) arrangement of X. Its unit cell structure is shown
below. The empirical formula of the compound is : [IIT-JEE-2012, 3/136]
;kSfxd MP Xq esa X ds lanHkZ esa ?kuh; fufcM+ ladqfyr lajpuk (ccp) dh O;oLFkk gSA bldh ,dd dksf"Bdk lajpuk
(unit cell structure) fp=k esa fn[kk;h xbZ gS bldk ewykuqikrh lw=k (empirical formula) gSA
[IIT-JEE-2012, 3/136]

(A) MX (B*) MX2 (C) M2X (D) M5X14

–
17. The arrangement of X ions around A ion in solid AX is given in the figure (not drawn to scale). If the
+

radius of X– is 250 pm, the radius of A+ is : [JEE(Advanced) 2013, 2/120]

,d Bksl AX esa A+ vk;u ij X– vk;uksa dh O;oLFkk ¼lgh ekilwpd esa ugha½ fp=k esa nh xbZ gSA ;fn X– dk v)ZO;kl
250 pm gS] rc A+ dk v)ZO;kl gksxk % [JEE(Advanced) 2013, 2/120]

(A*) 104 pm (B) 125 pm (C) 183 pm (D) 57 pm

18. If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of
octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by
magnesium ions, m and n, respectively, are [JEE(Advanced) 2015, 4/168]
;fn ,d [kfut dh ,dd lsy esa vkWDlhtu ijek.kq ?kuh; lad qfyr (cubic close packing) O;wg (array) esa gksa tgk¡
m fHkUu (fraction) v"VQydh; (octahedral) fjfDrdkvksa (holes) esa ,syqfefu;e vk;u rFkk n fHkUu prq"Qydh;
(tetrahedral) fjfDrdkvksa esa eSaXuhf'k;e vk;u mifLFkr gksa] rc m rFkk n Øe'k% gSa %
[JEE(Advanced) 2015, 4/168]
1 1 1 1 1 1 1
(A*) , (B) 1, (C) , (D) ,
2 8 4 2 2 4 8
19.* The CORRECT statement(s) for cubic close packed (ccp) three dimensional structure is(are)
[JEE(Advanced) 2016, 4/124]
(A) The number of the neighbours of an atom present in the topmost layer is 12 (SST-CCP_M(P))
(B*) The efficiency of atom packing is 74%
(C*) The number of octahedral and tetrahedral voids per atom are 1 and 2, respectively
(D*) The unit cell edge length is 2 2 times the radius of the atom
?kuh; fufoM ladqfyr (cubic close packed) (ccp) f=kfoeh; lajpuk ds fy;s lgh dFku gS@gSa
[JEE(Advanced) 2016, 4/124]
(A) ,d ijek.kq tks lokZsPp ijr (topmost layer) esa mifLFkr gS mlds fudVre izfrosf’k;ksa ¼iM+ksfl;ksa½ dh la[;k 12
gSA
(B*) ijek.kq dh ladqyu {kerk 74% gS
(C*) v”VQydh; rFkk prq”Qydh; fjfä;ksa dh la[;k izfr ijek.kq Øe’k% 1 rFkk 2 gSa
(D*) ,d dksf”Bdk ds dksj (unit cell edge) dh yEckbZ ijek.kq dh f=kT;k dk 2 2 xquk gSA
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 Solid State
20. A crystalline solid of a pure substance has a face-centred cubic structure with a cell edge of 400 pm. If
the density of the substance in the crystal is 8 g cm–3, then the number of atoms present in 256 g of the
crystal is N×1024. The value of N is [JEE(Advanced) 2017, 2/122]
,d 'kq) inkFkZ ds ,d fØLVyh; Bksl dh Qyd&dsfUnzr ?ku (face-centred cubic) lajpuk ds lkFk dksf"Bdk dksj
(cell edge) dh yEckbZ 400 pm gSA ;fn fØLVy ds inkFkZ dk ?kuRo 8 g cm–3 gS] rks fØLVy ds 256 g esa mifLFkr
ijek.kqvksa dh dqy la[;k N×1024 gSA N dk eku gSA [JEE(Advanced) 2017, 2/122]
Ans. 2
21. Consider an ionic solid MX with NaCl structure. Construct a new structure (Z) whose unit cell is
constructed from the unit cell of MX following the sequential instructions given below. Neglect the
charge balance.
(i) Remove all the anions (X) except the central one
(ii) Replace all the face centered cations (M) by anions (X)
(iii) Remove all the corner cations (M)
(iv) Replace the central anion (X) with cation (M)
 number of anions 
The value of   in Z is ______. [JEE(Advanced) 2018, 3/120]
 number of catons 
NaCl lajpuk ds ,d vk;fud Bksl MX ij fopkj djsaA ,d u;h lajpuk (Z) dk fuekZ.k djsa ftldh ,dd dksf"Bdk
(unit cell) dk fuekZ.k (MX) dh ,dd dksf"Bdk ls uhps nh x;ha vuqØfed vuqns'kksa ds vuqlj.k }kjk fd;k x;k gSA
pktZ (charge) larqyu dh mis{kk djsaA
(i) dsUæ okys dks NksMdj lHkh _.kk;uksa (X) dks gVk;saA
(ii) lHkh Qyd–&dsfUær (face centered) /kuk;uksa (M) dks _.kk;uksa (X) ls cnysaA
(iii) lHkh dksuksa ls /kuk;uksa (M) dks gVk;saA
(iv) dsUæh; _.kk;u (X) dks /kuk;u (M) ls cnysaA
 _.kk;uksa dh la[ ;k 
Z esa   dk eku ______gSA [JEE(Advanced) 2018, 3/120]
 /kuk;uksa dh la[ ;k 
Ans. 3

PART - II : JEE (MAIN) / AIEEE PROBLEMS (PREVIOUS YEARS)

Hkkx - II : JEE (MAIN) / AIEEE ¼fiNys o"kksZ½ ds iz'u
OFFLINE JEE-MAIN

1. Na and Mg crystallize in BCC and FCC type crystals respectively, then the number of atoms of Na and
Mg present in the unit cell of their respective crystal is [AIEEE-2002, 3/225]
(1) 4 and 2 (2) 9 and 14 (3) 14 and 9 (4*) 2 and 4
Na (BCC izdkj dk fØLVy) rFkk Mg (FCC izdkj dk fØLVy) dh ,dkad dksf"Bdk esa ijek.kqvksa dh la[;k Øe'k%
gksxh % [AIEEE-2002, 3/225]
(1) 4 rFkk 2 (2) 9 rFkk 14 (3) 14 rFkk 9 (4*) 2 rFkk 4

2. How many unit cells are present in a cube-shaped ideal crystal of NaCl of mass 1.00g?
[Atomic masses : Na = 23, Cl = 35.5] [AIEEE-2003, 3/225]
nzO;eku 1.00 xzke ds NaCl ds /kuh; vkd`fr ds vkn'kZ fØLVy esa mifLFkr fdruh ,dd dksf"Bdk gksrh gS\
[ijek.oh; nzO;eku : Na = 23, Cl = 35.5] [AIEEE-2003, 3/225]
(1*) 2.57 × 1021 (2) 5.14 × 1021 (3) 1.28 × 1021 (4) 1.71 × 1021.
3. What type of crystal defect is indicated in the diagram below? [AIEEE-2004, 3/225]
Na+ Cl– Na+ Cl– Na+ Cl– 
  Cl–  Cl– Na+   Na+
Na+ Cl–  Cl– Na+ Cl–
Cl– Na+ Cl– Na+   Na+
(1) Frenkel defect (2*) Schottky defect
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 Solid State
(3) interstitial defect (4) Frenkel and Schottky defects
uhps fn;s x;s vkjs[k esa fdl çdkj dh fØLVy =kqfV bafxr dh xbZ gSa\ [AIEEE-2004, 3/225]
Na+ Cl– Na+ Cl– Na+ Cl– 
  Cl–  Cl– Na+   Na+
Na+ Cl–  Cl– Na+ Cl–
Cl– Na+ Cl– Na+   Na+
(1) Ýsady =kqfV (2*) 'kksV~dh =kqfV
(3) vUrjdk'kh =kqfV (4) Ýsady rFkk 'kksV~dh =kqfV
4. An ionic compound has a unit cell consisting of A ions at the corners of a cube and B ions on the
centers of the faces of the cube. The empirical formula for this compound would be
[AIEEE-2005, 1½/225]
,d vk;fud ;kSfxd ,d ,dd dksf"Bdk j[krk gSa tks ,d /ku ds fdukjksa ij A vk;u j[krk gSa rFkk /ku ds Qyd
ds dsUnz ij B vk;u j[krk gSAa bl ;kSfxd ds fy, ewykuwikrh lw=k fuEu gkssxk % [AIEEE-2005, 1½/225]
(1) AB (2) A2B (3*) AB3 (4) A3B
5. Total volume of atoms present in a face-center cubic unit cell of a metals (r is atomic radius).
[AIEEE-2006, 3/165]
,d /kkrq ds Qyd&dsfUnzr ?kuh; ,dd dksf"Bdk esa mifLFkr ijek.kqvksa dk dqy vk;ru gksxk (r ijek.kq dh f=kT;k
gS): [AIEEE-2006, 3/165]
20 3 24 3 12 3 16 3
(1) r (2) r (3) r (4*) r
3 3 3 3
6. In a compound, atoms of element Y form ccp lattice and those of element X occupy 2/3 rd of tetrahedral
voids. The formula of the compound will be [AIEEE - 2008, 3/105]
,d ;kSfxd esa rRo Y ds ijek.kq lh- lh- ih- (ccp) tkyd fuekZ.k djrs gSa rFkk rRo X ds ijek.kq prq"Qydh;
fjfDr;ksa 2/3rd esa mifLFkr gSaA ;kSfxd dk lw=k gksxkA [AIEEE - 2008, 3/105]
(1) X2Y3 (2) X2Y (3) X3Y4 (4*) X4Y3
7. Copper crystallises in fcc with a unit cell length of 361 pm. What is the radius of copper atom ?
[AIEEE - 2009, 8/144]
361 pm ,dd dksf"Bdk dh yEckbZ ds lkFk dkWij (rk¡ck) fcc esa fØLVfyr gksrk gSA dkWij ijek.kq dh f=kT;k D;k gS\
[AIEEE - 2009, 8/144]
(1*) 127 pm (2) 157 pm (3) 181 pm (4) 108 pm
8. The edge length of a face centred cubic cell of an ionic substance is 508 pm. If the radius of the cation
is 110 pm, the radius of the anion is [AIEEE - 2010, 4/144]
,d vk;fud inkFkZ ds ,d Qyd dsfUnzr ?kuh; lsy ds dksj dh yEckbZ 508 pm gSA ;fn /kuk;u dh f=kT;k 110
pm gks, rks _.kk;u dh f=kT;k gS % [AIEEE - 2010, 4/144]
(1) 288 pm (2) 398 pm (3) 618 pm (4*) 144 pm
9. Percentages of free space in cubic close packed structure and in body centered packed structure are
respectively. [AIEEE - 2010, 4/144]
(1) 30% and 26% (2*) 26% and 32% (3) 32% and 48% (4) 48% and 26%
?kuh; lqladqfyr lajpuk vkSj dk; dsfUnzr lqladqfyr lajpuk esa fjDr LFkku dh izfr'kÙrk Øe'k% gSA
[AIEEE - 2010, 4/144]
(1) 30% vkSj 26% (2*) 26% vkSj 32% (3) 32% vkSj 48% (4) 48% vkSj 26%

10. In a face centred cubic lattice, atom A occupies the corner positions and atom B occupies the face
centre positions. If one atom of B is missing from one of the face centred points, the formula of the
compound is: [AIEEE-2011, 4/120]
,d Qyd dsfUnzr D;wfcd ySfVl esa ijek.kq dksuksa ij fLFkr gS rFkk B ijek.kq Qyu ds dsUnzksa esa fLFkr gSA ;fn B dk
,d ijek.kq fdlh ,d Qyd dsUnz fcUnq ls gVk gks rks ;kSfxd dk QkewZyk gS % [AIEEE-2011, 4/120]
(1) A2B (2) AB2 (3) A2B3 (4*) A2B5

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11. Copper crystallises in fcc lattice with a unit cell edge of 361 pm. The radius of copper atom is:
[AIEEE-2011, 4/120]
361 pm ;wfuV lsy dksj ds lkFk dkij fcc tkyd esa fØLVfyr gksrk gSA dkij ijek.kq dh f=kT;k gS %
[AIEEE-2011, 4/120]
(1) 108 pm (2*) 128 pm (3) 157 pm (4) 181 pm
12. Lithium forms body centred cubic structure. The length of the side of its unit cell is 351 pm. Atomic
radius of the lithium will be : [AIEEE-2012, 4/120]
yhfFk;e dk; dsfUær ?ku lajpuk cukrk gSA ;fn yhfFk;e ds ;wfuV lsy ds lkbM dh yEckbZ 351 pm gS rks yhfFk;e
dh ijek.kq f=kT;k gksxh % [AIEEE-2012, 4/120]
(1) 75 pm (2) 300 pm (3) 240 pm (4*) 152 pm
13. Experimentally it was found that a metal oxide has formula M0.98O. Metal M, present as M2+ and M3+ in
its oxide. Fraction of the metal which exists as M3+ would be : [JEE(Main) 2013, 3/120]
iz;ksx ds vk/kkj ij ,d /kkrq vkWDlkbM dk lw=k M0.98O ik;k x;kA ;fn /kkrq M bl vkWDlkbM esa M2+ vkSj M3+ ds
:i esa fo|eku gks rks /kkrq dk tks izHkka'k M3+ ds :i esa gksxk] og gS% [JEE(Main) 2013, 3/120]
(1) 7.01% (2*) 4.08% (3) 6.05% (4) 5.08%
14. CsCl crystallises in body centred cubic lattice. If 'a' its edge length then which of the following
expressions is correct ? [JEE(Main) 2014, 4/120]
CsCl dk; dsfUnzr ?kukdj tkyd esa fØLVfyr gksrk gSA ;fn fdukjs dh yEckbZ 'a' gks rks fuEu lw=kksa esa ls dkSu&lk
Bhd gksxk\ [JEE(Main) 2014, 4/120]
3a 3
(1) rCs  rCl–  3a (2) rCs  rCl–  (3*) rCs  rCl–  a (4) rCs  rCl–  3a
2 2
15. Sodium metal crystallizes in a body centred cubic lattice with a unit cell edge of 4.29Å. The radius of
sodium atom is approximately: [JEE(Main) 2015, 4/120]
lksfM;e /kkrq ,d var% dsfUnzr ?kuh; tkyd esa fØLVfyr gksrk gS ftlds dksj dh yackbZ 4.29Å gSA lksfM;e ijek.kq
dh f=kT;k yxHkx gS % [JEE(Main) 2015, 4/120]
(1*) 1.86Å (2) 3.22Å (3) 5.72Å (4) 0.93Å
16. Which of the following compounds is metallic and ferromagnetic ? [JEE(Main) 2016, 4/120]
fuEu esa ls dkSulk ;kSfxd /kkfRod rFkk QsjkeSxusfVd ¼ykSg pqEcdh;½ gS\ [JEE(Main) 2016, 4/120]
(1*) CrO2 (2) VO2 (3) MnO2 (4) TiO2
17. A metal crystallises in a face centred cubic structure. If the edge length of its unit cell is 'a', the closest
approach between two atoms in metallic crystal will be : [JEE(Main) 2017, 4/120]
,d /kkrq Qyd dsfUnzr ?ku lajpuk esa fØLVyh; gksrk gSA ;fn blds ,dd lsy dh dksj yEckbZ 'a' gS] rks /kkfRod
fØLVy esa nks ijek.kqvks ds chp lfUUkdVre nwjh gksxhA [JEE(Main) 2017, 4/120]
a
(1) 2 2 a (2) 2 a (3*) (4) 2ª
2
18. Which type of 'defect' has the presence of cations in the interstitial sites ? [JEE(Main)-2018, 4/120]
(1*) Frenkel defect (2) Metal deficiency defect
(3) Schottky defect (4) Vacancy defect
fdl rjg dh ^=kqfV* esa varjdk'kh LFkku esa /kuk;u ¼dSVk;u½ dh mifLFkfr gksrh gS\ [JEE(Main)-2018, 4/120]
(1*) Ýsady =kqfV (2) /kkrq ghurk =kqfV (3) lkV~dh =kqfV (4) fjfDrdk =kqfV

ONLINE JEE-MAIN

1. In a face centered cubic lattice atoms A are at the corner points and atoms B at the face centered
points. If atom B is missing from one of the face centered points, the formula of the ionic compound is :
[JEE(Main) 2014 Online (09-04-14), 4/120]
,d Qyd dsfUnzr ?kukdkj tkyd esa A ds ijek.kq dksuksa ds fcUnqvksa ij gS vkSj B ds ijek.kq Qyd dsUnzksa ij gSA ;fn
B ijek.kq ,d Qyd dsUnz ij u gks rks vk;fud ;kSfxd dk lw=k gksxk&
[JEE(Main) 2014 Online (09-04-14), 4/120]
(1) AB2 (2) A5B2 (3) A2B3 (4*) A2B5
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 Solid State
2. The appearance of colour in solid alkali metal halides is generally due to :
[JEE(Main) 2014 Online (11-04-14), 4/120]
(1) Schottky defect (2) Frenkel defect (3) Interstitial position (4*) F-centres
Bksl {kkj /kkrq gsykbMksa esa jax ds ns[ks tkus dk dkj.k izk;% gksrk gS&
[JEE(Main) 2014 Online (11-04-14), 4/120]
(1) 'kkWVdh nks"k (2) ÝSady nks"k (3) vUrjkyh LFkku (4*) F-dsUnz

3. In a monoclinic unit cell the relation of sides and angles are respectively :
[JEE(Main) 2014 Online (12-04-14), 4/120]
(1) a = b  c and  =  =  = 90º (2) a  b  c and  =  =  = 90º
(3*) a  b  c and  = = 90º  (4) a  b  c and       90º
,d eksuksfDyfud ,dd lSy esa i{kksa ds dksuls fcUnqvksa ls lEcU/k Øekuqlkj gksrs gS&
[JEE(Main) 2014 Online (12-04-14), 4/120]
(1) a = b  c vkSj  =  =  = 90º (2) a  b  c vkSj  =  =  = 90º
(3*) a  b  c vkSj  =  = 90º  (4) a  b  c vkSj       90º

4. The total number of octahedral void (s) per atom present in a cubic close packed structure is :
[JEE(Main) 2014 Online (19-04-14), 4/120]
?kukdkj lqladqfyr ¼fufcM+½ lajpuk esa mifLFkr izfr ijek.kq v"VQydh; fjfDr;ksa dh ldy la[;k gksxh&
[JEE(Main) 2014 Online (19-04-14), 4/120]
(1) 2 (2) 4 (3*) 1 (4) 3
5. Which of the following arrangements shows the schematic alignment of magnetic moments of
antiferromagnetic substance ? [JEE(Main) 2018 Online (15-04-18), 4/120]
fuEu esa ls dkSu lh O;oLFkk izfryksg pqEcdh; inkFkZ ds pqEcdh; vk?kw.kZ ds ;kstukc) lajs[k.k dks iznf'kZr djrh gS \
[JEE(Main) 2018 Online (15-04-18), 4/120]
(1) (2)

(3) (4*)

6. All of the following share the same crystal structure except :

fuEUk esa ls ,d ds vfrfjDr lcdh fØLVy lajpuk ,d tSlh gS] og ,d dkSu gS \
[JEE(Main) 2018 Online (15-04-18), 4/120]
(1) LiCl (2) NaCl (3) RbCl (4*) CsCl
7. The one that is extensively used as a piezoelectric material is :
[JEE(Main) 2019 Online (09-01-19), 4/120]
(1) tridymite (2) amorphous silica
(3*) quartz (4) mica
nkc&fo|qr inkFkZ dh rjg foLrh.kZ mi;ksx esa vkus okyk v;Ld gS %
[JEE(Main) 2019 Online (09-01-19), 4/120]
(1) VªkbMkbekbV (2) vfØLVyh; flfydk
(3*) DokV~tZ (4) ekbdk

8. At 100ºC, copper (Cu) has FCC unit cell structure with cell edge length of x Å. What is the approximate
density of Cu (in g cm –3) at this temperature? [Atomic mass of Cu = 63.55 u]
100ºC ij dkij (Cu), x Å dksf"Bdk dksj dh yEckbZ okys FCC ,dd dksf"Bdk lajpuk j[krk gSA bl rki ij Cu dk
?kuRo (g cm–3 esa) yxHkx gksxk% [Cu dk ijek.kq Hkkj = 63.55 u] [JEE(Main) 2019 Online (09-01-19), 4/120]
205 105 422 211
(1) 3 (2) 3 (3*) 3 (4) 3
x x x x
9. Which premitive unit cell has unequal edge lengths (a  b c) and all axial angles different from 90º ?
[JEE(Main) 2019 Online (10-01-19), 4/120]
(1) Monoclinic (2*) Triclinic (3) Hexagonal (4) Tetragonal

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 Solid State
fdl vHkkT; ,dd dksf"Bdk esa vleku dksj yEckbZ (a  b c) gksrh gS rFkk lHkh v{kh; dks.k 90º ls fHkUu gksrs gS?
[JEE(Main) 2019 Online (10-01-19), 4/120]
(1) f}leyEck{k (2*) f=kurk{k (3) "kVdks.kh; (4) ,durk{k

10. A compounds of formula A2B3 has the hcp lattice. Which atom forms the hcp lattice and what fraction of
tetrahedral voids is occupied by the other atoms;
[JEE(Main) 2019 Online (10-01-19), 4/120]
2 1
(1) hcp lattice –A, Tetrahedral voids-B (2*) hcp lattice –B, Tetrahedral voids-A
3 3
2 1
(3) hcp lattice –B, Tetrahedral voids-A (4) hcp lattice –A, Tetrahedral voids-B
3 3
A2B3 lw=k okys ,d ;kSfxd esa hcp tkyd gSA dkSu lk ijek.kq hcp tkyd cukrk gS rFkk prq"Qydh; fjfDr;ksa dk
dkSu lk va'k nwljs ijek.kq }kjk v/;kflr gksrk gS;
[JEE(Main) 2019 Online (10-01-19), 4/120]
2 1
(1) hcp tkyd –A, prq"Qydh; fjfDr;k¡ -B (2*) hcp tkyd –B, prq"Qydh; fjfDr;k¡-A
3 3
2 1
(3) hcp tkyd –B, prq"Qydh; fjfDr;k¡-A (4) hcp tkyd –A, prq"Qydh; fjfDr;k¡-B
3 3
11. A solid having density of 9 × 103 kg m–3 forms face centred cubic crystals of edge length 200 2 pm.
What is the molar mass of the solid? [Avogadro constant  6 × 1023 mol–1,   3]
,d Bksl] ftldk ?kuRo 9 × 103 kg m–3 gS] Qyd dsfUnzr ?kuh; fØLVy cukrk gS ftlds dksj dh yEckbZ
200 2 pm gSA Bksl dk eksyj nzO;eku D;k gS \ [vokxknzks fu;rkad  6 × 1023 mol–1,   3]
[JEE(Main) 2019 Online (11-01-19), 4/120]
(1) 0.0432 kg mol–1 (2*) 0.0305 kg mol–1 (3) 0.4320 kg mol–1 (4) 0.0216 kg mol–1
12. The radius of the largest sphere which fits properly at the centre of the edge of a body centred cubic
unit cell is : (Edge length is represented by 'a') [JEE(Main) 2019 Online (11-01-19), 4/120]
dk; dsfUnzr ?ku ,dy lsy ds dksj ds dsUnz esa cSBus okys ¼fQV gksus okys½ lcls cM+s xksys dh f=kT;k gksxh :
(dksj yEckbZ dks 'a' }kjk O;Dr fd;k x;k gS) : [JEE(Main) 2019 Online (11-01-19), 4/120]
(1) 0.047 a (2) 0.027 a (3) 0.134 a (4*) 0.067 a

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 Solid State

 Marked questions are recommended for Revision.

 fpfUgr iz'u nksgjkus ;ksX; iz'u gSA
This Section is not meant for classroom discussion. It is being given to promote self-
study and self testing amongst the Resonance students.

PART - I : PRACTICE TEST-1 (IIT-JEE (MAIN Pattern))

Hkkx - I : PRACTICE TEST-1 (IIT-JEE (MAIN Pattern))
Max. Time : 1 Hr. Max. Marks : 120
Important Instructions
egÙoiw.kZ funsZ'k %
1. The test is of 1 hour duration.
ijh{kk dh vof/k 1 ?kaVs gSA
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
bl ijh{kk iqfLrdk esa 30 iz'u gSA vf/kdre vad 120 gSA
3. Each question is allotted 4 (four) marks for correct response.
lHkh iz'uksa ds vad leku gSA izR;sd iz'u ds lgh mÙkj ds fy, 4 ¼pkj½ vad fu/kkZfjr fd;s x;s gSA
4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of each
question.
¼ (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction
from the total score will be made if no response is indicated for an item in the answer sheet.
vH;kfFkZ;ksa dks izR;sd lgh mÙkj ds fy, mijksDr funsZ'ku la[;k 3 ds funsZ'kkuqlkj ekDlZ fn;s tk,axsA izR;sd iz'u ds
xyr mÙkj ds fy;s ¼ oka Hkkx fy;k tk;sxkA ;fn mÙkj iqfLrdk esa fdlh iz'u dk mÙkj ugha fn;k x;k gks rks dqy
izkIrkad ls dksbZ dVkSrh ugha fd tk;sxhA
5. There is only one correct response for each question. Filling up more than one response in any question
will be treated as wrong response and marks for wrong response will be deducted accordingly as per
instructions 4 above.
çR;sd iz'u dk dsoy ,d gh lgh mÙkj gSA ,d ls vf/kd mÙkj nsus ij mls xyr mÙkj ekuk tk;sxk vkSj mijksDr
funsZ'k 4 ds vuqlkj vad dkV fy;s tk;saxsA
1. In a lattice of X and Y atoms, if X atoms are present at corners and Y atoms at the body centre & one X
atom is removed from a corner from each unit cell, then the formula of the compound will be :
X o Y ijek.kqvksa ds tkyd esa ;fn dksus ij X ijek.kq mifLFkr gksa rFkk dk; dsUnz ij Y ijek.kq mifLFkr gksa rFkk
izR;sd bdkbZ lSy ls dksus ls ,d X ijek.kq dks gVk;k tkrk gS rks ;kSfxd dk lw=k fuEu gksxk :
(1) X7Y (2) X8Y7 (3*) X7Y8 (4) X7Y7
2. The vacant space in B.C.C. unit cell is :
B.C.C. bdkbZ dksf"Bdk esa fjfDrdk gS %
(1*) 32% (2) 10% (3) 23% (4) 46%
3. When NaCl crystal is heated in sodium vapors, then it attains yellow colour. It is due to :
(1) electrons trapped in cation vacancies.
(2*) F-centres, which is electron trapped in anion vacancy created by Cl –.
(3) F-centres, which is cation trapped in cation vacancy created by Na+.
(4) interstitial defect caused by external impurity.
tc NaCl fØLVy dks lksfM;e ok"i esa xeZ fd; tkrk gS rks ;g ihyk jax iznku djrk gSA ;g :
(1) /kuk;u fjfDrdk esa bySDVªkWu dks j[kus ds dkj.k gSA
(2*) F dsUnz ds dkj.k tks Cl– }kjk mRiUu dh xbZ _.kk;u fjfDrdk esa bySDVªkWu dks j[kk tkrk gSA
(3) F dsUnz ds dkj.k] tks Na+ }kjk mRiUu dh xbZ /kuk;u fjfDrdk esa bySDVªkWu dks j[kk tkrk gSA
(4) ckâ; v'kq)rk }kjk gksus okys vUrjkdk'kh nks"k ds dkj.k gksrk gSA
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 Solid State
4. 1 g of X has atoms arranged in cubic packing so as to give best packing efficiency. The possible
arrangement is :
(1) simple cubic (2*) face centred cubic
(3) body certred cubic (4) hexagonal close packing
1 xzke X esa jgus okys ijek.kqvksa dks bl izdkj ls fufcM ladqy esa j[kk tkrk gS fd ladqy n{krk vf/kdre gksA laHko
O;oLFkk fuEu gS %
(1) ljy /kuh; (2*) Qyd dsfUnzr ?kuh;
(3) dk; dsfUnzr ?kuh; (4) "kV~Qydh; fufcM ladqy

5. In 3D close packed structures, for every 100 atoms, it contain :

(1) 50 octahedral voids (2) 100 tetrohedral voids
(3) 200 octohedral voids (4*) 100 octahedral voids
3D fufcM ladqy lajpuk esa izR;sd 100 ijek.kqvksa ds fy, ;g :
(1) 50 v"VQydh; fjfDrdk j[krk gSA (2) 100 prq"Qydh; fjfDrdk j[krk gSA
(3) 200 v"VQydh; fjfDrdk j[krk gSA (4*) 100 v"VQydh; fjfDrdk j[krk gSA
6. If x = radius of Na+ & y = radius of Cl– & a is the unit cell edge length for NaCl crystal, then which of the
given relation is correct ?
;fn x = Na+ dh f=kT;k rFkk y = Cl– dh f=kT;k rFkk NaCl fØLVy ds fy, a bdkbZ lSy dksj yECkkbZ gksa rks fn;s
x;s lEcU/k esa ls dkSulk lgh gS?
(1) x + y = a (2*) 2x + 2y = a (3) x + y = 2a (4) x + y = 2a
7. The co-ordination number of calcium fluoride (CaF2) type structure is
dSfY'k;e ¶yksjkbM (CaF2) izdkj dh lajpuk ds fy, leUo; la[;k fuEu gS
(1) 1 : 2 (2) 4 : 4 (3*) 4 : 8 (4) 8 : 4
8. The lattice of CaF2 is called fluorite structure. SrCl2 has fluorite structure. Which of the following
statements is true for SrCl2 ?
(1*) Sr2+ are at the corners and face centres of the cubic arrangment
(2) Sr2+ are arranged in bcc lattice
(3) a– are arranged in fcc lattice
(4) Cl– occupy octahedral holes in the lattice.
CaF2 dk tkyd ¶yksjkbV lajpuk dgykrk gSA SrCl2 ¶yksjkbV lajpuk j[krk gSA SrCl2 ds fy, fuEu esa ls dkSulk
dFku lR; gS ?
(1*) ?kuh; O;oLFkk ds dksus o Qyd dsUnz ij Sr2+ mifLFkr jgrk gSA
(2) bcc tkyd esa Sr2+ O;ofLFkr jgrk gSA
(3) fcc tkyd esa a– O;ofLFkr jgrk gSA
(4) Cl– tkyd esa v"VQydh; fjfDrdk dks ?ksjrk gSA

9. The most unsymmetrical system is :

(1) Cubic (2) Hexagonal (3*) Triclinic (4) Orthorhombic
lcls vf/kd vlefer rU=k fuEu gS :
(1) ?kuh; (2) "kV~dks.kh; (3*) f=kurk{k (4) fo"keyEck{k

10. Schottky defect occurs mainly in electrovalent compounds where :

(1) positive ions and negative ions are of different size
(2*) positive ions and negative ions are of same size
(3) positive ions are small and negative ions are big
(4) posiive ions are big and negative ions are small.
'kksV~dh nks"k eq[; :i ls oS|qr la;ksth ;kSfxd esa izkIr gksrk gS tgk¡ :
(1) /kukRed vk;u o _.kkRed vk;u fHkUu vkdkj ds gSA
(2*) /kukRed vk;u o _.kkRed vk;u leku vkdkj ds gSA
(3) /kukRed vk;u NksVk o _.kkRed vk;u cM+k gksrk gSA
(4) /kukRed vk;u cM+k o _.kkRed vk;u NksVk gksrk gSA
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 Solid State
11. An ionic compound is expected to have tetrahedral structure if r +/r– lies in the range of :
(1) 0.155 to 0.225 (2) 0.732 to 0.414 (3) 0.414 to 0.732 (4*) 0.225 to 0.414
,d vk;fud ;kSfxd dh prq"Qydh; lajpuk gksrh gS ;fn r+/r– dh ijkl fuEu gks :
(1) 0.155 ls 0.225 rd (2) 0.732 ls 0.414 rd (3) 0.414 ls 0.732 rd (4*) 0.225 ls 0.414 rd

12. Malleability and ductility of metals can be acounted due to :

(1*) the capacity of layers of metal ions to slide over the other
(2) the interaction of electrons with metal ions in the other
(3) the presence of electrostatic forces
(4) the crystalline structure of metal
/kkrqvksa dh v?kkro/kZrk rFkk rU;rk fuEu ds dkj.k gksrh gS:
(1*) /kkrq vk;uksa dh ijrksa dh vU;ksa ij fQlyus dk lkeF;Z ds dkj.k
(2) vU;ksa esa /kkrq vk;u ds lkFk bysDVªksuksa dh vUrZfØ;k ds dkj.k
(3) oS|qr LFkSfrdh cyksa dh mifLFkfr ds dkj.k
(4) /kkrq dh fØLVyh; lajpuk

13. KCI crystallises in the same type of lattice as does NaCl. Given that rNa / rCl = 0.55 and rK  / rCl =
0.74. Calculate the ratio of the side of the unit cell of KCI to that of NaCl :
KCI o NaCl leku izdkj ds tkyd esa fØLVyhd`r gksrs gSA fn;k x;k gS rNa / rCl = 0.55 rFkk rK  / rCl = 0.74.
KCI o NaCl ds ,dd~ dksf"Bdk dh lrg dk vuqikr ifjdfyr dhft, :
(1*) 1.123 (2) 0.891 (3) 1.414 (4) 0.414
14. A solid compound contains X, Y and Z atoms in a cubic lattice with X atom occupying the corners, Y
atoms in the body centred positions and Z atoms at the centres of faces of the unit cell. What is the
empirical formula of the compound :
,d Bksl ;kSfxd ?kuh; tkyd esa X, Y o Z ijek.kq ;qDr gS rFkk bl tkyd esa ,dd~ dksf"Bdk ds dksus ij X ijek.kq]
dk; dsfUnz; fLFkfr esa Y ijek.kq o Qyd ds dsUnz ij Z ijek.kq fLFkr gksrs gSA ;kSfxd dk eqykuqikrh lw=k D;k gS
(1) XY2Z3 (2*) XYZ3 (3) X2Y2Z3 (4) X8YZ6
15. An example of a face centred cubic lattice is :
(1) Zinc (2) Sodium (3*) Copper (4) Caesium chloride
Qyd dsfUnz; ?kuh; tkyd dk ,d mnkgj.k gS :
(1) ftad (2) lksfM;e (3*) dkWij (4) lhth;e DyksjkbM
16. Which of the following is NOT ferromagnetic ?
(1) Cobalt (2) Iron (3*) Manganese (4) Nickel
fuEu esa ls dkSu ykSg pqEcdh; ugha gS \
(1) dksckYV (2) vk;ju (3*) eSXuht (4) fudy

17. In AgBr, there can occur

(1) only schottky defect (2) only Frenkel defect (3*) both (1) and (2) (4) None of these
AgBr esa ;gk¡ dsoy
(1) 'kksV~dh nks"k gksrk gSA (2) Ýsady nks"k gksrk gSA (3*) (1) o (2) nksuksa (4) buesa ls dksbZ ugha
18. In face-centred cubic unit cell, edge length is :
Qyd dsfUnz; ?kuh; bdkbZ dksf"Bdk esa dksj yEckbZ fuEu gS:
4 4 3
(1) r (2*) r (3) 2r (4) r
3 2 2

19. In an antifluorite structure, cations occupy :

(1) octahedral voids (2) centre of the cube (3*) tetrahedral voids (4) corners of the cube
,d ,UVh ¶yksjkbV lajpuk esa /kuk;u :
(1) v"VQydh; fjfDrdkvksa dks ?ksjrs gSA (2) ?ku ds dsUnz dks ?ksjrs gS
(3*) prq"Qydh; fjfDrdkvksa dks ?ksjrs gSA (4) ?ku ds dksuksa dks ?ksjrs gSA
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 Solid State
20. The number of tetrahedral voids in the unit cell of a face-centred cubic lattice of similar atoms is :
leku ijek.kqvksa ds ,d Qyd dsfUnzr ?kuh; tkyd dh ,dd~ dksf"Bdk esa prq"Qydh; fjfDrdkvksa dh la[;k fuEu
gS %
(1) 4 (2) 6 (3*) 8 (4) 10
21. A p-type material is electrically .......
(1) positive (2) negative (3*) neutral
(4) depends upon the concentration of p impurities.
,d p-izdkj dk inkFkZ oS|qrh; :i ls .......
(1) /kukRed gS (2) _.kkRed gS (3*) mnklhu gS
(4) p v'kq)rk dh lkUnzrk ij fuHkZj djrk gSA

22. The interionic distance for cesium chloride crystal will be :

lhth;e DyksjkbM fØLVy ds fy, vUrkZ;fud nwjh fuEu gksxh :
(1) a (2) a/2 (3*) 3 a/2 (4) 2a / 3
23. Superconductors are derived from the compounds of :
(1*) p-block elements (2) lanthanides (3) actinides (4) transition elements
fuEu ;kSfxdks ls vfrpkyd dks O;qRiUu fd;k tk ldrk gS :
(1*) p-CykWd rRo (2) ySUFksukbM (3) ,fDVukbM (4) laØe.k rRo
24. A substance AxBy crystallizes in a face centred cubic (FCC) lattice in which atoms ‘A’ occupy each
corner of the cube and atoms ‘B’ occupy the centres of each face of the cube. Identify the correct
composition of the substance AxBy.
(1*) AB3 (2) A4B3
(3) A3B (4) Composition cannot be specified
,d Qyd dsfUnzr ?kuh; FCC tkyd esa inkFkZ AxBy fØLVyhd`r gksrk gSa ftlesa ‘A’ ijek.kq izR;sd ?ku ds dksus dks
o ijek.kq ‘B’ izR;sd ?ku ds Qyd dsUnz dks ?ksjrk gSA inkFkZ AxBy ds lgh laxBu dks igpkfu;s:
(1*) AB3 (2) A4B3
(3) A3B (4) laxBu dks O;Dr ugha fd;k tk ldrk gSA

25. The number of atoms in 100 g of a fcc crystal with density = 10.0 g/cm 3 and cell edge equal to 200 pm
is equal to :
100 g fcc fØLVy ¼?kuRo = 10.0 g/cm3½ o dksf"Bdk dh dksj yEckbZ 200 pm gSa rks bl fØLVy esa ijek.kqvksa dh
la[;k fuEu gS :
(1*) 5  1024 (2) 5  1025 (3) 6  1023 (4) 2  1025
26. In the sphalerite (ZnS) structure, S 2– ions form a face-centred cubic lattice. Then Zn2+ ions are present
on the body diagonals at
1 1
(1) rd of the distance (2*) th of the distance
3 4
1 1
(3) th of the distance (4) th of the distance
6 8
LisysjkbV (ZnS) lajpuk esa S2– vk;u ,d Qyd dsfUnz; ?kuh; tkyd cukrk gSA rc fuEu dk; fod.kZ ij mifLFkr
Zn2+ dh nwjh gS
1 1 1 1
(1) rd (2*) th (3) th (4) th
3 4 6 8
27. In a solid, S2– ions are packed in fcc lattice. Zn2+ occupy half of the tetrahedral voids in an alternating
arrangement. Now if a plane is cut (as shown) then the cross-section would be :
,d Bksl esa] S2– vk;u fcc tkyd esas ladqfyr fd;k tkrk gSA ,d ,dkUrfjr O;oLFkk esa Zn2+ prq"Qydh; fjfDrdk
dk vk/kk Hkkx ?ksjrk gSA vc ;fn ,d lery dks dkVrs gS ¼tSlk fd n'kkZ;k x;k gS½ rks vuqizLFk Hkkx fuEu gksxk :

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(1) (2*) (3) (4)

28. In a bcc- arrangement which of the marked planes have maximum spatial density of atoms ?
,d bcc- foU;kl esa fdl vafdr ry esa ijek.kqvksa dk vkdk'kh ?kuRo vf/kdre jgrk gS ?

(1*) 1 (2) 2 (3) 3 (4) 4

29. S1 : Cubic system have four possible type of unit cells.
S1 : ?kuh; fudk; ds fy, pkj izdkj ds bdkbZ lSy laHko gSA
S2 : H2O is diamagnetic substance and it is weakly attracted in magnetic field.
S2 : H2O izfrpqEcdh; inkFkZ gS rFkk bldh pqEcdh; {kS=k esa vkdf"kZr gksus dh izo`fÙk nqcZy gksrh gSA
S3 : Graphite is a covalent solid with vanderwaal’s forces as well.
S3 : xzsQkbV okUMjokWYl~ cy ds lkFk ,d lgla;ksth Bksl gksrk gSA
(1*) F F T (2) F T F (3) T F F (4) F F F
30. S1 : Distance between Na+ & Cl– in NaCl crystal is more than half of edge length.
S2 : The no. of triagular viods in the given arrangement in the enclosed region is 3.

S3 : In ZnS structure, 2Zn2+ & 2S2– ions are present in each unit cell.
S1 : NaCl fØLVy esa Na+ o Cl– ds chp vUrjky dksj yEckbZ ds vk/ks ls vf/kd gksrk gSA
S2 ifjc) {ks=k esa fn;s x;s foU;kl esa f=kdks.kh; fjfDrdkvksa dh la[;k 3 gksrh gSA

S3 : ZnS lajpuk esa izR;sd bdkbZ lSy esa 2Zn2+ o 2S2– vk;u mifLFkr jgrs gSA
(1) F F T (2) F T F (3) T F F (4*) F F F

PART - II : NATIONAL STANDARD EXAMINATION IN CHEMISTRY (NSEC) STAGE-I

Hkkx - II : NATIONAL STANDARD EXAMINATION IN CHEMISTRY (NSEC) STAGE-I
1. Number of atoms per unit cell for Body Centered Cubic system is : [NSEC-2001]
(A) six (B) four (C*) two (D) one
dk; dsfUnzr /kuh; fudk; ds fy, izfr ,dd dksf"Bdk ijek.kqvksa dh la[;k gksxh&
(A) N% (B) pkj (C*) nks (D) ,d

2. Co-ordination number for sodium metal is : [NSEC-2001]

lksfM;e /kkrq dh leUo; la[;k gksrh gS&
(A) 11 (B) 12 (C*) 8 (D) 10

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3. Sodium chloride crystallises in a face centred cubic lattice in which each [NSEC-2003]
(A) sodium ion is tetrahedrally surrounded by 4 chloride ions and each chloride ion is tetrahedrally
surrounded by 4 sodium ions
(B) sodium ion is tetrahedrally by 4 chloride ions and each chloride ion is octahedrally surrounded by 6
sodium ions
(C) sodium ion is octahedrally surrounded by 6 chloride ions and each chloride ion is surrounded by 4
sodium ions
(D*) sodium ion is octahedrally surrounded by 6 chloride ions and each chloride ion is octahedrally
surrounded by 6 sodium ions.
lksfM;e DyksjkbM Qyd dsfUnzr ?kuh; tkyd esa fØLVyhd`r gksrk gS ftlesa izR;sd
(A) lksfM;e vk;u 4 DyksjkbM+ vk;u ls prq"Qyfd; :i ls f?kjk gksrk gS rFkk izR;sd DyksjkbM vk;u prq"Qyfd;
:i ls pkj lksfM;e vk;u ls f?kjk gksrk gS
(B) lksfM;e vk;u 4 DyksjkbM+ vk;u ls prq"Qyfd; :i ls f?kjk gksrk gS rFkk izR;sd DyksjkbM vk;u v"BQyfd;
:i ls N% lksfM;e vk;u ls f?kjk gksrk gS
(C) lksfM;e vk;u v"BQyfd; :i ls N% DyksjkbM+ vk;u ls rFkk izR;sd DyksjkbM+ vk;u 4 lksfM;e vk;u ls f?kjk
gksrk gSA
(D*) lksfM;e vk;u v"BQyfd; :i ls N% DyksjkbM+ vk;u ls rFkk izR;sd DyksjkbM+ vk;u 6 lksfM;e vk;u ls
v"BQyfd; :i ls f?kjk gksrk gSA
4. An element crystallises in a face centered cubic lattice. Hence, its unit cell contains [NSEC-2004]
(A) 14 atoms of the element and 8 of them belong to the unit cell
(B*) 14 atoms of the element and 4 of them belong to the unit cell
(C) 8 atoms of the unit cell and only 1 of them belongs to the cell
(D) 8 atoms of the unit cell and only 2 of them belong to the cell
,d0 rRo Qyd dsfUnz; ?kuh; tkyd esa fØLVyhd`r gSA vr% bldh bZdkbZ dksf"Bdk esa gksaxs&
(A) rRo ds 14 ijek.kq gksrs gS rFkk buesa ls 8 ,dd dksf"Bdk ls lEcfU/kr gksrs gSA
(B*) rRo ds 14 ijek.kq gksrs gS rFkk buesa ls 4 ,dd dksf"Bdk ls lEcfU/kr gksrs gSA
(C) ,dd dksf"Bdk ds 8 ijek.kq gksrs gS rks buesa ls dsoy 1 ,dd dksf"Bdk ls lEcfU/kr gksrs gSA
(D) ,dd 8 dksf"Bdk ds ijek.kq gksrs gS rFkk buesa ls dsoy 2 ,dd dksf"Bdk ls lEcfU/kr gksrs gSA

5. Arsenic is used to dope germanium to obtain [NSEC-2005]

(A) intrinsic semiconductors (B) p-type semiconductors
(C*) n-type semiconductors (D) non-conducting germanium.
vklsZfud dks tesZfu;e ds lkFk lfefJr djds D;k izkIr fd;k tkrk gS& [NSEC-2005]
(A) vkarfjd v/kZpkyd (B) p-izdkj dk v/kZpkyd
(C*) n-izdkj dk v/kZpkyd (D) vpkyd tesfZ u;e

6. Carborundum is a [NSEC-2005]
(A) molecular solid (B*) covalent solid (C) ionic solid (D) amorphous solid.
dkcksZj.Me gS& [NSEC-2005]
(A) vkf.od Bksl (B*) lgla;kstd Bksl (C) vk;fud Bksl (D) vfØLVyh; Bksl

7. If a  b  c and  =  = 90o ,   90o , the crystal system is called [NSEC-2005]

(A*) monoclinic (B) triclinic (C) hexagonal (D) orthorhombic.
;fn a  b  c rFkk  =  = 90 ,   90 rks fØLVy fudk; dgykrk gS&
o o [NSEC-2005]
(A*) ,durk{k (B) f=kurk{k (C) "kB~Hkqth; (D) fo"keyEck{k

8. The number of units cells in 117.0 grams of NaCI is approximately [NSEC-2006]

117.0 g NaCI esa ,dd dks"Bhdkvksa dh la[;k yxHkx gksrh gS& [NSEC-2006]
(A) 12 × 1020 (B*) 3 × 1023 (C) 6 × 1023 (D) 1 × 1024

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9. In the unit cell of the crystal formed by the ionic compound of X and Y, the corners are occupied by X
and the centers of the faces by Y. The empirical formula of the compound is : [NSEC-2007]
X rFkk Y ds vk;fud ;kSfxd ls fufeZr fØLVy dh ,dd dksf"Bdk esa X dksus ij rFkk Y Qyd ds dsUnz dks ?ksjrk
gSA ;kSfxd dk ewykuqikrh lw=k gS& [NSEC-2007]
(A) XY (B) X2Y (C*) XY3 (D) X8Y6
10. How many nearest neighbours surround each ion in a face-centered cubic lattice of an ionic crystal ?
,d vk;fud fØLVy dh ,d Qyd&dsfUnzr ?kuh; lajpuk esa izR;sd vk;u vU; fdrus vk;uksa ls f?kjk gqvk gksrk gS\
[NSEC-2008]
(A) 4 (B) 6 (C) 8 (D*) 12
11. A match box exhibits [NSEC-2008]
(A) Cubic geometry (B) Monoclinic geometry
(C) Tetragonal geometry (D*) Orthorhombic geometry
,d ekfpl dh fMfc;k iznf'kZr djrk gS&
(A) ?kuh; T;kferh (B) ,durk{k T;kferh (C) f}leyEck{k T;kferh (D) fo"ke yEck{k T;kferh
12. The simplest formula of a compound containing 50% of element ‘A’ (Atomic weight = 10) and 50% of
element ‘B’ (Atomic weight = 20) is [NSEC-2008]
rRo ‘A’ (ijek.kq Hkkj = 10) ds 50% rFkk rRo ‘B’ (ijek.kq Hkkj = 20) ds 50% ;qDr ,d ;kSfxd dk ljyre lw=k gS&
(A) AB (B*) A 2B (C) A2B2 (D) A2B3
13. For a face centered cubic lattice, the unit cell content is – [NSEC-2009]
,d Qyd dsfUnzr ?kuh; tkyd ds fy, bdkbZ dksf'kdk esa fufgr vo;oksa dh la[;k gS % [NSEC-2009]
(A) 1 (B) 2 (C) 3 (D*) 4
14. Body-centred cubic lattice has a coordination number of : [NSEC-2010]
dk; dsfUnzr ?kuh; tkyd dh leUo; la[;k gksrh gS& [NSEC-2010]
(A*) 8 (B) 10 (C) 6 (D) 4
15. If a  b  c and  =  =  = 90º, the crystal system is [NSEC-2011]
(A) monoclinic (B) triclinic (C) hexagonal (D*) orthorhombic
;fn a  b  c rFkk  =  =  = 90º gS] rks fØLVy fudk; gksxk [NSEC-2011]
(A) ,durk{k (B) f=kurkd{k (C) "kV~dks.kh; (D*) fo"keyEck{k

16. The number of atoms per unit cell and number of the nearest neighbour in a body centred cubic
structure are : [NSEC-2011]
dk; dsfUnzr ?kuh; lajpuk esa izfr ,dd dksf"Bdk ijek.kqvksa dh la[;k rFkk lehiLFk iM+ksfl;ks a dh la[;k gksxh&
[NSEC-2011]
(A) 4, 12 (B) 2, 6 (C) 9, 6 (D*) 2, 8

17. Ionic salt AX grows in face centered cubic lattice with cell length ‘a’. The ratio rA / rx  for this salt will be
vk;fud yo.k AX Qyd dsfUnzr ?kuh; lajpuk j[krk gS ftldh dksj yEckbZ ‘a’ gSA bl yo.k ds fy, rA / rx 
vuqikr gksxk\ [NSEC-2014]
(A) 0.155 (B) 0.225 (C*) 0.414 (D) 0.732
18. The unit cell of a compound made up of the three elements X, Y and Z is given below.
fuEu fn[kk;s vuqlkj ,d ;kSfxd dh bdkbZ dksf’'kdk rhu rRoks X, Y rFkk Z ls feydj cuh gSA

The formula of this compound is : [NSEC-2014]

bl ;kSfxd dk lw=k gSA [NSEC-2014]
(A) X2YZ3 (B) XY3 Z (C*) XYZ3 (D) X3YZ2
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 Solid State
19. The metal M crystallizes in a body centered lattice with cell edge 400 pm. The atomic radius of M is.
[NSEC-2015]
/kkrq M dksf”"Bdk dksj 400 pm ds lkFk ,d dk; dsfUnzr tkyd esa fØLVyhd`‘r gksrh gSA M dh ijek.oh; f=kT;k gS&
[NSEC-2015]
(A) 200pm (B) 100pm (C*) 173pm (D) 141pm
20. Ice crystallizes in a hexagonal lattice. At ascertain low temperature, the lattice constants are a = 4.53 Å
and c = 7.41 Å. The number of H2O molecules contained in a unit cell (d  0.92 g cm–3 at the given
temperature) is [NSEC-2015]
cQZ “"kVdks.kh; tkyd esa fØLVyhd`r gksrh gSA fuf'’pr fuEu rki ij tkyd fu;rkad a = 4.53 Å rFkk c = 7.41 Å
gSA ,d ,dd dksf”"Bdk esa fufgr H2O v.kqvksa dh la[;k gSA (fn;s x;s rki ij d  0.92 g cm–3) [NSEC-2015]
(A*) 4 (B) 8 (C) 12 (D) 24
21. One mole crystal of a metal halide of the type MX with molecular weight 119 g having face centered
cubic structure with unit cell length 6.58 Å was recrystallized. The density of the recrystallized crystal
was found to be 2.44 g cm –3. The type of defect introduced during the recrystalization is [NSEC-2015]
(A) a ditional M+ and X– ions at interstitial sites (B*) Schottky defect
(C) F-centre (D) Frenkel defect
,dd dksf"”Bdk yEckbZ 6.58 Å ;qDr Qyd dsfUnzr ?kuh; lajpuk j[kus okys v.kqHkkj 119 xzke ds lkFk MX izdkj ds
/kkrq gSykbM ds ,d eksy fØLVy dks iqu% fØLVyhd`‘r fd;k x;kA iqu% fØLVyhd`‘r fØLVy dk ?kuRo 2.44 g cm–3
izkIr gqvkA iqu% fØLVyhdj.k ds nkSjku dkSuls izdkj dh =kqfV izkIr gksrh gSA [NSEC-2015]
+ –
(A) vUrjkdk’'kh LFkyksa ij ;ksxt M rFkk X vk;u (B*) '‘kkWVdh =kqfV
(C) F-dsUnz (D) Ýsady =kqfV

22. An ionic solid LaI2 shows electrical conduction due to presence of : [NSEC-2016]
(A) La2+ and 2I– (B*) La3+, 2I– and e– (C) La2+, I2 and 2e– (D) La3+, I2 and 3e–
,d vk;fud Bksl LaI2 fuEu dh mifLFkfr ds dkj.k oS|qr pkydrk n’kkZrk gS% [NSEC-2016]
(A) La2+ rFkk 2I– (B*) La3+, 2I– rFkk e– (C) La2+, I2 rFkk 2e– (D) La3+, I2 rFkk 3e–

23. In a cubic crystal structure, divalent metal-ion is located at the body-centered position, the smaller
tetravalent metal ions are located at each corner and the O 2– ions are located half way along each of
the edges of the cube. The number of nearest neighbour for oxygen is : [NSEC-2016]
,d ?kuh; fØLVy lajpuk esa] f}la;ksth /kkrq vk;u dk; dsfUnzr fLFkfr ij fLFkr gksrk gS] NksVs prq”"la;ksth /kkrq
vk;u izR;sd fdukjs ij fLFkr gksrs gSa rFkk O2– vk;u ?ku ds izR;sd dksj ds vuqfn’'k vk/kk jkLrs ij fLFkr gksrs gSaA
vkWDlhtu ds fy, fudVre iM+kSfl;ksa dh la[;k gS% [NSEC-2016]
(A) 4 (B) 6 (C*) 2 (D) 8
24. HgO is prepared by two different methods : one shows yellow colour while the other shows red colour.
The difference in colour is due to difference in [NSEC-2016]
(A) electronic d-d transitions (B*) particle size
(C) Frenkel defect (D) Schottkey defect
HgO dks nks fofHkUu fof/k;ksa }kjk cuk;k tkrk gS % ,d ihyk jax n'’kkZrh gS tcfd vU; ykyk jax n'’kkZrh gSA jax esa
vUrj fuEu esa vUrj ds dkj.k gksrk gS% [NSEC-2016]
(A) bysDVªkWfud d-d ladj.k (B*) d.k vkdkj
(C) Ýsady =kqfV (D) ‘'kkWV~dh =kqfV

25. When NiO is doped with a small quantity of Li2O [NSEC-2017]

(A) both cation and anion vacancies are generated
(B) Shottky defects are generated
(C) NiO becomes an n-type semiconductor
(D*) NiO becomes a p-type semiconductor
tc NiO esa Li2O dh lw{e ek=kk feyk;h tkrh gSA rc [NSEC-2017]
(A) /kuk;u rFkk _.kk;u fjfDr;k¡ fufeZr gksrh gSaA (B) 'kkWVdh =kqfV mRiUu gksrh gSA
(C) NiO, n-izdkj dk pkyd curk gSA (D*) NiO, p-izdkj dk pkyd curk gSA
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 Solid State
26. A crystal of KCl containing a small amount of CaCl2 will have [NSEC-2018]
(A) vacant Cl– sites
(B) vacant K+ sites and a higher density as compared to pure KCl
(C*) vacant K+ sites and a lower density as compared to pure KCl
(D) K+ ions in the interstitial sites
CaCl2 dh lw{e ek=kk ;qDr KCl dk ,d fØLVy j[ksxk& [NSEC-2018]
(A) fjDr Cl– LFky
(B) fjDr K+ LFky rFkk 'kq) KCl dh rqyuk esa mPp ?kuRo
(C*) fjDr K+ LFky rFkk 'kq) KCl dh rqyuk esa U;wu ?kuRo
(D) vUrjdk'kh LFkyks esa K+ vk;u

27. A scientist attempts to replace a few carbon atoms in 1.0 g of diamond with boron atoms or nitrogen
atoms in separate experiments. Which of the following is correct ? [NSEC-2018]
(A) The resulting material with B doping will be an n-type semiconductor
(B*) The resulting material with B doping will be an p-type semiconductor
(C) B doping is NOT possible as B cannot from multiple bonds
(D) The resulting material with N doping will be a p-type semiconductor
,d oSKkfud 1.0 g ghjs esa dqN dkcZu ijek.kqvksa dks i`Fkd iz;ksxksa esa cksjkWu ijek.kqvksa ;k ukbVªkstu ijek.kqvksa ls
izfrLFkkfir djus dk iz;kl djrk gSA fuEu esa ls dkSulk lgh gS\ [NSEC-2018]
(A) B ds lkFk ifj.kkeh inkFkZ dk vifeJ.k n-izdkj dk v)Zpkyd gksxkA
(B*) B ds lkFk ifj.kkeh inkFkZ dk vifeJ.k p-izdkj dk v)Zpkyd gksxkA
(C) B dk vifeJ.k lEHko ugha gS D;ksafd B cgqcU/k ugha cuk ldrk gSA
(D) N ds lkFk ifj.kkeh inkFkZ dk vifeJ.k p-izdkj dk v)Zpkyd gksxkA

PART - III : HIGH LEVEL PROBLEMS (HLP)

Hkkx - III : mPpLrjh; iz'u (HIGH LEVEL PROBLEMS (HLP)
ONLY ONE OPTION CORRECT TYPE
dsoy ,d lgh fodYi çdkj (ONLY ONE OPTION CORRECT TYPE)

1. Consider a cube 1 of Body Centered Cubic unit cell of edge length a now atom at the body center can
be viewed to be lying on the corner of another cube 2.Find the volume common to cube 1 and cube 2.
a yEckbZ okys dk; dsfUnzr ,dd dksf"Bdk dks ?ku&1 ekusA vc blds dk; dsUnz ds ijek.kq dks nwljs ?ku&2 ds dksus
ij mifLFkr ekuk tkrk gS rks ?ku 1 rFkk 2 dk la;qDr (common) vk;ru Kkr djksA
a3 a3 a3 a3
(A) (B) (C) (D*)
27 64 2 2 8

2. In an arrangement of type ABABA... identical atoms of I layer A and III layer A are joined by a line
passing through their centers. Suggest the correct statement.
(A) No void is found on the line
(B*) Only Tetrahedral voids are found on the line
(C) Only octahedral voids are found on the line
(D) Equal number of tetrahedral and octahedral voids are found on the line
ABABA... izdkj ds foU;kl esa I ijr A rFkk III ijr A ds le:i ijek.kqvksa ds dsUnz ls ,d js[kk dks ikl fd;k
tkrk gSA rc lgh dFku dk pquko dhft;ssA
(A) js[kk ij dksbZ fjfDrdk ugha izkIr gksrh gSA
(B*) js[kk ij dsoy prq"Qydh; fjfDrdk,¡ izkIr gksrh gSA
(C) js[kk ij dsoy v"VQydh; fjfDrdk,¡ izkIr gksrh gSA
(D) js[kk ij prq"Qydh; rFkk v"VQydh; fjfDrdkvksa dh leku la[;k izkIr gksrh gSA

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3. Square packed sheets are arranged on the top of other such that a sphere in the next layer rests on the
center of a square in the previous layer. Identify the type of arrangement and find the the coordination
number.
(A) Simple Cubic, 6 (B) Face Centered Cubic, 8
(C*) Face Centered Cubic, 12 (D) Body Centered Cubic, 8
oxZ ladqylhV dks vU; ds Åij bl izdkj ls O;ofLFkr fd;k tk ldrk gS fd vxyh ijr esa ,d xksyk fiNyh ijr
esa ,d oxZ ds dsUnz ij j[kk gksrk gSA
bl izdkj dh O;oLFkk dks igpkfu, rFkk leUo; la[;k Kkr dhft,A
(A) lk/kkj.k ?ku, 6 (B) Qyd dsfUnzr ?ku, rFkk 8
(C*) Qyd dsfUnzr ?ku rFkk 12 (D) dk; dsfUnzr ?ku rFkk 8

4. Given an alloy of Cu, Ag and Au in which Cu atoms constitute the CCP arrangement.If the hypothetical
formula of the alloy is Cu4Ag3Au. What are the probable locations of Ag and Au atoms.
(A) Ag - All tetrahedral voids; Au - all octahedral voids
(B*) Ag - 3/8th tetrahedral voids; Au - 1/4th octahedral voids
(C) Ag - 1/2 octahedral voids; Au - 1/2 tetrahedral voids
(D) Ag - all octahedral voids; Au - all tetrahedral voids
Cu, Ag rFkk Au dh ,d feJ/kkrq nh xbZ gS ftlesa Cu ijek.kq CCP O;oLFkk cukrs gSaA ;fn feJ /kkrq dk dkYifud
lw=k Cu4Ag3Au gS rks Ag rFkk Au ijek.kq dh fLFkfr dh lEHkkouk D;k gSA
(A) Ag - lHkh prq"Qydh; fjfDrdk esa Au - lHkh v"VQydh; fjfDrdk esaA
(B*) Ag - 3/8th prq"Qydh; fjfDrdk; Au - 1/4th v"VQydh; fjfDrdk esaA
(C) Ag - 1/2 v"VQydh; fjfDrdk,; Au - 1/2 prq"Qydh; fjfDrdk esaA
(D) Ag - lHkh v"VQydh; fjfDr;k¡; Au - lHkh prq"Qdh; fjfDrdk esaA

5. The distance between adjacent, oppositely charged ions in rubidium chloride is 3.285 Å; in potassium
chloride is 3.139Å; in sodium bromide is 2.981 Å and in potassium bromide is 3.293 Å. The distance
between adjacent oppositely charged ions in rubidium bromide is :
:fcfM;e DyksjkbM esa fudVorhZ foijhr vkosf'kr vk;uksa ds e/; dh nwjh 3.285 Å gS rFkk ikSVsf'k;e DyksjkbM esa
3.139 Å, lksfM;e czksekbM esa 2.981 Å, rFkk ikSVsf'k;e czksekbM esa 3.293 Å gSA rks :fcfM;e czksekbM esa fudVorhZ
foijhr vkosf'kr vk;uksa ds e/; dh nwjh Kkr djksA
(A) 3.147 Å (B) 3.385 Å (C) 3.393 Å (D*) 3.439 Å
6. Zinc sulphide exists in two different forms-zinc blende and wurtzite. Both occur as 4:4 co-ordination
compounds. Choose the correct option from among the following :
(A) zinc blende has a bcc structure and wurtzite an fcc structure
(B*) zinc blende has an fcc structure and wurtzite an hcp structure
(C) zinc blende as well as wurtzite have a hcp structure
(D) zinc blende as well as wurtzite have a cpp structure
ftad lYQkbM nks vyx :iks ftad CyS.M rFkk oqVZtkbV (wurtzite) esa ik;k tkrk gSA nksuksa gh ;kSfxdksa dh leUo;
la[;k dk vuqikr 4 : 4 gksrk gSA rks fuEu esa ls lgh dFku dks pqfu,s %
(A) ftad CyS.M bcc lajpuk rFkk oqVZtkbV Qyd dsfUnzr ?ku (fcc) lajpuk j[krh gSA
(B*) ftad cyS.M Qyd dsfUnzr ?ku (fcc) lajpuk rFkk oqVZtkbV "kV~dks.kh; fufcM+ ladqy (hcp) lajpuk j[krh gSA
(C) ftad cyS.M rFkk oqVZtkbV nksuksa "kV~dks.kh; fufcM+ ladqy (hcp) lajpuk j[krh gSA
(D) ftd cyS.M rFkk oqVZtkbV nksuksa ?kuh; fufcM+ ladqy (cpp) lajpuk j[krh gSA

SINGLE AND DOUBLE VALUE INTEGER TYPE

,dy ,oa f}&iw.kk±d eku izdkj ¼SINGLE AND DOUBLE VALUE INTEGER TYPE½
7. The 2 D unit cell of an element is shown. The two layers are placed one over the other and touching
each other. Find the effective number of atoms in the unit cell :

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 Solid State

,d rRo dh 2 D ,dd dksf"Bdk n'kkZ;h x;h gS nks ijrsa ijLij ,d ds Åij ,d izdkj ls lEidZ eas j[kh gqbZ gS rc
,dd dksf"Bdk esa ijek.kqvksa dh izHkkoh la[;k dh x.kuk dhft,

Ans. 3
8. The density of solid argon is 1.65 g/mL at – 233ºC. If the argon atom is assumed to be sphere of radius
1.54 × 10–8 cm, what percentage of solid argon is apparently empty space ? (At. wt. of Ar = 40)
– 233ºC ij Bksl vkxZu dk ?kuRo 1.65 g/mL gSA ;fn vkxZu ijek.kq ds xksys dh f=kT;k 1.54 × 10–8 cm gS] rks
izR;{k :i ls fjDr LFkku ij vkxZu Bksl dk izfr'kr D;k gksxk \ (Ar dk ijek.kq Hkkj = 40)
Ans. 62
9. How many number of tetrahedral voids are completely inside the HCP unit cell.
HCP ,dd dksf"Bdk esa fdruh prq"Qydh; fjfDrdk;sa iw.kZr% vUnj mifLFkr gSA
Ans. 8
10. How many number of atoms present in half of HCP unit cell.
vk/kh HCP ,dd dksf"Bdk esa fdrus ijek.kq mifLFkr gSA
Ans. 3
11. Let MgTiO3 exists in pervoskite structure. In this lattice, all the atoms of one of the face diagonals are
removed. Calculate the density of unit cell if the radius of Mg 2+ is 0.7 Å and the corner ions are touching
each other. [Given atomic mass of Mg = 24, Ti = 48]
ekuk fd MgTiO3 ,d izoksfLVd lajpuk essa gSA tkyd esa ,d Qyd fod.kZ ds lHkh ijek.kqvksa dks gVk fn;k tk;s rks
,dd dksf"Bdk dk ?kuRo Kkr dhft, ;fn Mg2+ vk;u dh f=kT;k 0.7 Å rFkk lHkh fdukjs vk;u ,d nwljs dks
lEidZ djrs gSaA [Mg dk ijek.oh; Hkkj = 24, Ti = 48]
Ans.  65 g/cm3
12. A mineral having the formula AB2, crystallises in the cubic close - packed lattice, with the A atoms
occupying the lattice points. The co-ordination number of the A atoms is x, that of B atoms is y. Report
your answer (x – y).
,d [kfut yo.k AB2,lw=k j[krk gS rFkk ?kuh; fufcM+ ladqyu tkyd ds :i esa ik;k tkrk gSA A ijek.kqvksa }kjk
tkyd fcUnqvksa dks ?ksjk tkrk gSA A ijek.kqvksa dh leUo; la[;k] B ijek.kqvksa dh leUo; la[;kA viuk mÙkj (x –
y) esa nhft,A
Ans. 4 (8 – 4)

ONE OR MORE THAN ONE OPTIONS CORRECT TYPE

,d ;k ,d ls vf/kd lgh fodYi çdkj
13. Which of the following is not true about the voids formed in 3 dimensional hexagonal close packed
structure?
(A) A tetrahedral void is formed when a sphere of the second layer is present above triangular void in
the first layer.
(B) All the triangular voids are not covered by the spheres of the second layer.
(C*) Tetrahedral voids are formed when the triangular voids in the second layer lie above the triangular
voids in the first layer and the triangular shapes of these voids do not overlap.
(D*) Octahedral voids are formed when the triangular voids in the second layer exactly overlap with
similar voids in the first layer.
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 Solid State
f=kfofe; "kV~dks.kh; fufcM+ ladqyu lajpuk es fufeZr fjfDrdkvksa ds lanHkZ es] fuEu esa ls dkSuls dFku lR; ugha gS \
(A) tc f}rh; ijr dks] ,d xksyk ¼ijek.kq½] izFke ijr ds f=kdks.kh; fjfDrdk ds Åij mifLFkr gskrk gS rc] ,d
prq"Qydh; fjfDrdk curh gSA
(B) lHkh f=kdks.kh; fjfDrdk;sa] f}rh; ijr ds xksyksa }kjk vkPNfnr ugha gksrs gS A
(C*) tc f}rh; ijr esa mifLFkr f=kdks.kh; fjfDrdk;sa] izFke ijr es mifLFkr f=kdks.kh; fjfDrdkvksa ds Åij mifLFkr
gksa] rc prq"Qydh; fjfDrdkvksa dk fuekZ.k gksrk gS rFkk bu fjfDrdkvksa ds f=kdks.kh; vkdkj] vkPNfnr ugha gksrs gSaA
(D*) tc f}rh; ijr es mifLFkr f=kdks.kh; fjfDrdk;sa izFke ijr esa mifLFkr f=kdks.kh; fjfDrdkvks ds Bhd Åij]
vfrO;kfir gksa] tc v"VQydh; fjfDdkvksa dk fuekZ.k gksrk gSA
14. The co-ordination number of FCC structure for metals is 12, since
(A) each atom touches 4 others in same layer, 3 in layer above and 3 in layer below.
(B*) each atom touches 4 others in same layer, 4 in layer above and 4 in layer below.
(C*) each atom touches 6 others in same layer, 3 in layer above and 3 in layer below.
(D) each atom touches 3 others in same layer, 6 in layer above and 6 in layer below.
fdlh FCC fØLVy lajpuk okys /kkrq ds fy, leUo; la[;k 12 gS] pawfd
(A) izR;sd ijek.kq leku ijr ds 4 vU; ijek.kqvksa dks, Åijh ijr ds 3 o fupyh ijr ds 3 ijek.kqvksa dks Li'kZ
djrk gSA
(B*) izR;sd ijek.kq leku ijr ds 4 vU; ijek.kqvksa dks, Åijh ijr ds 4 o fupyh ijr ds 4 ijek.kqvksa dks Li'kZ
djrk gSA
(C*) izR;sd ijek.kq leku ijr ds 6 vU; ijek.kqvksa dks] Åijh ijr ds 3 o fupyh ijr ds 3 ijek.kqvksa dks Li'kZ
djrk gSA
(D) izR;sd ijek.kq leku ijr ds 3 vU; ijek.kqvksa dks] Åijh ijr ds 6 o fupyh ijr ds 6 ijek.kqvksa dks Li'kZ
djrk gSA
15. Three lines are drawn from a single corner of an FCC unit cell to meet the other corner such that they
are found to pass through exactly only 1 octahedral void, no voids of any type and exactly 2 tetrahedral
voids with 1 octahedral void. Identify the line?
(A*) Edge length (B*) Body diagonal (C*) Face diagonal
(D*) A line which passes through only two face centres of opposite faces
,d FCC ,dd dksf"Bdk ds fdlh ,d fdukjs dks ,dd dksf"Bdk ds vU; fdukjks ls feykdj rhu js[kkvksa dks bl
izdkj [khapk tkrk gSa fd os dsoy 1 v"VQydh; fjfDrdk] fdlh izdkj dh dksbZ fjfDrdk ls ugha rFkk Bhd 2
prq"Qydh; fjfDrdkvksa ds lkFk ,d v"VQydh; fjfDrdkvksa esa ls ikl dh tkrh gSaA blh leku Øe esa js[kkvksa ds
izdkj dks crkb;sA
(A*) fdukjk (B*) dk; fod.kZ (C*) Qyd fod.kZ
(D*) nks foifjr Qydksa ds dsUnzks ls xqtjus okyh js[kk

PART - IV : PRACTICE TEST-2 (IIT-JEE (ADVANCED Pattern))

Hkkx - IV : PRACTICE TEST-2 (IIT-JEE (ADVANCED Pattern))
Max. Time : 1 Hr. Max. Marks : 66
Important Instructions
egÙoiw.kZ funsZ'k %
A. General lkekU; %
1. The test is of 1 hour duration.
ijh{kk dh vof/k 1 ?kaVs gSA
2. The Test Booklet consists of 22 questions. The maximum marks are 66.
bl ijh{kk iqfLrdk esa 22 iz'u gSA vf/kdre vad 66 gSA
B. Question Paper Format
iz'u&i=k dk izk:i

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 Solid State
3. Each part consists of five sections.
bl iz'u&i=k esa ik¡p [kaM gSaA
4. Section-1 contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE is correct.
[kaM 1 esa 7 cgqfodYi iz'u gSaA gj iz'u esa pkj fodYi (A), (B), (C) vkSj (D) gSa ftuesa ls ,d lgh gSaA
5. Section-2 contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE THAN ONE are correct.
[kaM-2 esa 5 cgqfodYi iz'u gSaA gj iz'u esa pkj fodYi (A), (B), (C) vkSj (D) gSa ftuesa ls ,d ;k ,d ls vf/kd lgh
gSaA
6. Section-3 contains 6 questions. The answer to each of the questions is a single-digit integer, ranging from
0 to 9 (both inclusive).
[kaM-3 esa 6 iz'u gSaA izR;sd iz'u dk mÙkj 0 ls 9 rd ¼nksuksa 'kkfey½ ds chp dk ,dy vadh; iw.kkZad gSA
7. Section-4 contains 1 paragraphs each describing theory, experiment and data etc. 3 questions relate to
paragraph. Each question pertaining to a partcular passage should have only one correct answer among
the four given choices (A), (B), (C) and (D).
[k.M-4 esa fl)kUrksa] iz;ksxksa vkSj vk¡dM+ksa vkfn dks n'kkZus okys 1 vuqPNsn gSaA vuqPNsn ls lacaf/kr rhu iz'u gSaA fdlh Hkh
vuqPNsn esa gj iz'u ds pkj fodYi (A), (B), (C) vkSj (D) gSa ftuesa ls dsoy ,d gh lgh gSA
8. Section-5 contains 1 multiple choice questions. Question has two lists (list-1 : P, Q, R and S; List-2 : 1, 2,
3 and 4). The options for the correct match are provided as (A), (B), (C) and (D) out of which ONLY ONE
is correct.
[kaM-5 esa 1 cgqfodYi iz'u gSaA iz'u esa nks lwfp;k¡ (lwph-1 : P, Q, R vkSj S; lwph-2 : 1, 2, 3 vkSj 4) gSA lgh feyku ds
fy, fodYi (A), (B), (C) vkSj (D) gSa ftuesa ls dsoy ,d lgh gSA
C. Marking Scheme vadu ;kstuk
9. For each question in Section 1, 4 and 5 you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one
(– 1) mark will be awarded.
[k.M 1, 4 vkSj 6 ds gj iz'u esa dsoy lgh mÙkj okys cqycqys dks dkyk djus ij 3 vad vkSj dksbZ Hkh cqycqyk dkyk
ugha djus ij 'kwU; (0) vad iznku fd, tk;sxsaA vU; lHkh fLFkfr;ksa esa _.kkRed ,d (– 1) vad iznku fd;k tk;sxkA
10. For each question in Section 2, you will be awarded 3 marks. If you darken all the bubble(s)
corresponding to the correct answer(s) and zero mark. If no bubbles are darkened. No negative marks will
be answered for incorrect answer in this section.
[kaM 2 esa gj iz'u esa lHkh lgh mÙkj ¼mÙkjksa½ okys cqycqys ¼cqycqyksa½ dks dkyk djus ij 3 vad iznku fd;s tk;sxsa vkSj
dksbZ Hkh cqycqyk dkyk ugha djus ij 'kwU; vad iznku fd; tk;sxsaA bl [kaM ds iz'uksa esa xyr mÙkj nsus ij dksbZ
_.kkRed vad ugha fn;s tk;sxsaA
11. For each question in Section 3, you will be awarded 3 marks if you darken only the bubble corresponding
to the correct answer and zero mark if no bubble is darkened. No negative marks will be awarded for
incorrect answer in this section.
[kaM 3 esa gj iz'u esa lHkh lgh mÙkj okys cqycqys dks dkyk djus ij 3 vad iznku fd;s tk;sxsa vkSj dksbZ Hkh cqycqyk
dkyk ugha djus ij 'kwU; vad iznku fd; tk;sxsaA bl [kaM ds iz'uksa esa xyr mÙkj nsus ij dksbZ _.kkRed vad ugha
fn;s tk;sxsaA
SECTION-1 : (Only One option correct Type)
This section contains 7 multiple choice questions. Each questions has four choices (A), (B), (C)
and (D) out of which Only ONE option is correct.
[k.M-1 : (dsoy ,zd lgh fodYi çdkj)
bl [k.M esa 7 cgqfodYi ç'u gSaA çR;sd ç'u esa pkj fodYi (A),(B),(C) vkSj (D) gSa] ftuesa ls dsoy ,d lgh gSA
1. In a square close packing pattern, one atom is in contact with how many atoms in the 2-D plane base?
,d oxkZdkj ladqfyr O;oLFkk esa 2-D ry esa ,d ijekk.kq fdrus ijek.kq ds lEidZ esa jgrk gSA
(A) 2 (B*) 4 (C) 6 (D) 8

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 Solid State
2. In a face centerd lattice of X and Y, X atoms are present at the corners while Y atoms are at face
centers. Then the formula of the compound would be if one of the X atoms is missing from a corner in
each unit cell
X rFkk Y ds Qyd dsfUnzr tkyd esa X ijek.kq dksus ij rFkk Y ijek.kq Qyd ds dsUnz ij mifLFkr gSA ;fn ,d X
ijek.kq dks çR;sd ,dd dksf"Bdk esa ,d dksus ls xk;c dj fn;k tk;s rks ;kSfxd dk lw=k Kkr djksA
(A*) X7Y24 (B) X24Y7 (C) XY24 (D) X24Y
3. In a ccp structure of X atoms, Y atoms occupy all the octahedral holes. If 2X atom are removed from
corners and replaced by Z, then the formula of the compound will be :
X ijek.kqvksa dh ,d ccp lajpuk esa Y ijek.kq lHkh v"VQydh; fjfDrdkvka dks ?ksjrk gSA ;fn dksus ls 2X ijek.kqvksa
dks gVk;k tkrk gS rFkk Z }kjk foLFkkfir fd;k tkrk gS rks ;kSfxd dk lw=k fuEu gksxk :
(A*) X15Y16Z (B) X7Y8Z (C) X7.5 Y8Z (D) X8Y8Z3
4. The following diagram shows arrangement of lattice point with a = b = c and  =  =  = 90º.
Choose the correct options.

(A*) The arrangement is SC with each lattice point surrounded by 6 nearest neighbours.
(B) The arrangement is SC with each lattice point surrounded by 8 nearest neighbours.
(C) The arrangement is FCC with each lattice point surrounded by 12 nearest neighbours.
(D) The arrangement in BCC with each lattice point surrounded by 8 nearest neighbours
fuEu vkjs[k tkyd fcUnq dh O;oLFkk n'kkZrk gS ftlds a = b = c vkSj  =  =  = 90º gaSA lgh oDrO; igpkuksA

(A*) O;oLFkk ljy ?kuh; gS ftlesa izR;sd tkyd fcUnq 6 fudVre d.kksa ls f?kjk jgrk gSA
(B) O;oLFkk ljy ?kuh; gS ftlesa izR;sd tkyd fcUnq 8 fudVre d.kksa ls f?kjk jgrk gSA
(C) O;oLFkk FCC gS ftlesa izR;sd tkyd fcUnq 12 fudVre d.kksa ls f?kjk jgrk gSA
(D) O;oLFkk BCC gS ftlesa izR;sd tkyd fcUnq fudVre 8 d.kksa ls f?kjk jgrk gSA

5. A crystal is made of particles A and B. A forms FCC packing and B occupies all the octahedral voids. If
all the particles along the plane as shown in figure are removed, then, the formula of the crystal would
be :

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 Solid State

(A*) AB (B) A5B7 (C) A7B5 (D) None of these.

,d fØLVy A rFkk B d.kksa ls cuk gSA A Qyd dsUnzh; (FCC) ladqyu djrk gS ,oa B lHkh v"VQydh; fjfDr;ksa esa
jgrk gSA ;fn fp=k esa fn[kk;s x;s ry ds lHkh d.k gVk fy;s tk;as rc fØLVy dk lw=k gksxkA

(A*) AB (B) A5B7 (C) A7B5 (D) buesa ls dksbZ ugha

6. Calculate the perimeter of given plane in HCP unit cell (Given that radius of atoms = R Å).
HCP ,dd dksf"Bkdk esa fn;s x, lery ds ifjeki dh x.kuk djksA (fn;k x;k gS ijek.kq dh f=kT;k = R Å).

(A*) 6.437 R (B) 15.32 R (C) 16 R (D) 8 R

7. MgAl2O4, is found in the Spinal structure in which O2– ions constitute CCP lattice, Mg2+ ions occupy
1/8th of the Tetrahedral voids and Al3+ ions occupy 1/2 of the Octahedral voids.
Find the total +ve charge contained in one unit cell.
(A) +7/4 electronic charge (B) +6 electronic charge
(C) +2 electronic charge (D*) +8 electronic charge
MgAl2O4, Likbuy (Spinal) lajpuk esa izkIr gksrk gSa ftlesa O2– vk;u ds fy, CCP tkyd] Mg2+ vk;u
prq"Qydh; fjfDrdkvksa dk 1/8th Hkkx esa fLFkr gksrk gS rFkk Al3+ vk;u v"VQydh; fjfDrdkvksa dk 1/2 Hkkx ?ksjrk
gSaA ,d ,dd dksf"Bdk esa fLFkr dqy +ve vkos'k Kkr dhft,A
(A) +7/4 bysDVªkWfud vkos'k (B) +6 bysDVªkWfud vkos'k
(C) +2 bysDVªkWfud vkos'k (D*) +8 bysDVªkWfud vkos'k

Section-2 : (One or More than one options correct Type)

This section contains 6 multipole choice questions. Each questions has four choices (A), (B),
(C) and (D) out of which ONE or MORE THAN ONE are correct.

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 Solid State
[k.M+-2 : (,d ;k ,d ls vf/kd lgh fodYi izdkj)
bl [k.M esa 6 cgqfodYi iz'u gSA izR;sd iz'u esa pkj fodYi (A), (B), (C) vkSj (D) gSa] ftuesa ls ,d ;k ,d ls
vfèkd lgh gSA
8. Lead metal has a density of 11.34 g/cm 3 and crystallizes in a face–centered lattice. Choose the correct
alternatives
(A*) the volume of one unit cell is 1.214 × 10–22 cm3
(B) the volume of one unit cell is 1.214 × 10–19 cm3
(C*) the atomic radius of lead is 175 pm
(D) the atomic radius of lead is 155.1 pm
ySM /kkrq dk ?kuRo 11.34 g/cm3 gS rFkk ;g Qyd dsfUnzr tkyd esa fØLVyhd`r gksrk gSa] rks lgh fodYi pqfu;s &
(A*) çR;sd ,dd dksf"Bdk dk vk;ru 1.214 × 10–22 cm3 gSA
(B) çR;sd ,dd dksf"Bdk dk vk;ru 1.214 × 10–19 cm3 gSA
(C*) ySM dh ijek.kq f=kT;k 175 pm gSA
(D) ySM dh ijek.kq f=kT;k 155.1 pm gSA

9. Given that interionic distance in Na+, F– crystal is 2.31Å and rF = 1.36Å, which of the following
predictions will be right
(A*) rNa rF  0.7
(B*) coordination number of Na+ = coordination nunber of F– = 6
(C*) Na+, F– will have rock salt type crystal structure
(D) effective nuclear charge for Na+ and F– are equal
Na+, F– fØLVy esa vUrj vk;fud nwjh dk eku 2.31Å rFkk rF = 1.36Å, fn;k gqvk gS rks fuEu es ls dkSu&lk
vuqeku lgh gSA
(A*) rNa rF  0.7
(B*) Na+ rFkk F– nksuks dh leUo;h la[;k dk eku 6 gSA
(C*) Na+ F– dh fØLVyh; lajpuk jkWd yo.k izdkj dh gksxhA
(D) Na+ rFkk F– ds fy, izHkkoh ukfHkdh; vkos'k dk eku leku gksxkA
10. Which of the following statement(s) for crystal having schottky defect is/are correct.
(A*) Schottky defect arises due to absence of cations & anion from positions which they are expected to
occupy.
(B*) The density of crystal having shottky defect is smaller than that of perfect crystal.
(C) Schottky defect are more common in co-valent compound with higher co-ordination number.
(D*) The crystal having shottky defect is electrically neutral as a whole.
'kkWVdh =kqfV ;qDr fØLVy ds fy,] fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A*) 'kkWVdh =kqfV] /kuk;u rFkk _.kk;u dh vuqekfur fLFkfr;ksa ls vuqifLFkfr ds dkj.k mRiUu gksrh gSA
(B*) 'kkWVdh =kqfV ;qDr fØLVy dk ?kuRo] iw.kZ fØLVy dh rqyuk esa de gksrk gSA
(C) 'kkWVdh =kqfV lkekU;r% mPp milgla;kstd la[;k ;qDr lgla;kstd ;kSfxdksa esa ik;h tkrh gSA
(D*) 'kkWVdh =kqfV ;qDr fØLVy dk lEiw.kZ Hkkx] oS|qr mnklhu gksrk gSA

11. For each of the following substances, identify the intermolecular force or forces that predominate. Using
your knowledge of the relative strengths of the various forces, rank the substances in order of their
normal boiling points. A2O3, F2, H2O, Br2, Cl, NaCl
fuEufyf[kr izR;sd Lih'kht esa yxus okyk vUrjkf.od cy ;k izHkkoh cy igpkuksaA fofHkUu cyksa ds lkeF;Z dh
tkudkjh dk mi;ksx djrs gq, Lih'kht dks muds lk/kkj.k DoFkukad fcUnq ds c<+rs gq, Øe esa O;ofLFkr djksA
A2O3, F2, H2O, Br2, Cl, NaCl
 (A*) F2 < Br2 < Cl    (B*) H2O < NaCl < Al2O3
(C*) Cl < H2O (D) H2O < Cl

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12. The ZnS zinc blende structure is cubic. The unit cell may be described as a face-centered sulfide ion
sublattice with zinc ions in the centers of alternating minicubes made by partitioning the main cube into
8 equal parts (as shown in fig.)

(a) How many nearest neighbors does each Zn2+ have?

(b) How many nearest neighbors does each S2– have?
(c) What angle is made by the lines connecting any Zn 2+ to any two of its nearest neighbors?
(d) What minimum r+/r– ratio is needed to avoid anion-anion contact, if closest cation-anion pairs are
assumed to touch ?
(A*) C.N. of Zn2+ & S2– = 4 & 4 (B) C.N. of Zn2+ & S2– = 6 & 6
r 2
(C*) 109°28’ (D*) Zn = 0.225
rS2
ZnS (ftad CyS.M) ?kuh; lajpuk esa gksrk gSA ftlesa lYQkbM vk;u Qyd dsfUnz; ?kuh; lajpuk esa gksrs gS tcfd
eq[; ?ku dks 8 leku Hkkxksa ds NksVs ?ku esa foHkkftr djus ij ,dkUrj NksVs ?ku ds dsUnz ij Zn2+ vk;u gksrk gSA
(a) çR;sd Zn2+ vk;u ds fudVre iM+kSfl;ksa dh la[;k fdruh gksxh\
(b) çR;sd S2– ds fudVre iMkSfl;ksa dh la[;k fdruh gksrh gS\
(c) fdlh Zn2+ vk;u dks mlds fdUgh nks fudVre iM+kSfl;ksa dks tksM+us okyh nks js[kkvksa ds e/; dks.k fdruk gksrk
gS\
(d) _.kk;u&_.kk;u lEidZ dks nwj djus ds fy, r+/r– ds e/; U;wure f=kT;k dk vuqikr Kkr djksA ;fn lcls
ikl /kuk;u rFkk _.kk;u dk lEidZ ekuk tk;s?

(A*) Zn2+ & S2– dh leUo; la[;k = 4 & 4 (B) Zn2+ & S2– dh leUo; la[;k = 6 & 6
r 2
(C*) 109°28’ (D*) Zn = 0.225
rS2

13. A metal (M), shows ABAB arrangement of atoms in solid state, then what is the relation between radius
of atom (r) and edge length (a) and height (c) of HCP unit cell.
,d /kkrq (M), Bksl voLFkk esa ijek.kqvksa dh ABAB izdkj dh O;oLFkk iznf'kZr djrh gS rc ijek.kq dh f=kT;k (r)]
dksj yEckbZ (a) rFkk HCP ,dd dksf"Bdk dh Åpk¡bZ (c) ds e/; lEcU/k crkb,A
 2  3
(A*) a = 2R (B*) c =   4r
 3
(C) c =   4r
 2

(D) a  2 2 r 
Section-3 : (One Integer Value Correct Type.)
This section contains 5 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive)

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[k.M+-3: (,d iw.kkZad eku lgh izdkj)
bl [k.M esa 5 iz'u gSA izR;sd iz'u dks gy djus ij ifjek.k 0 ls 9 (nksuksa 'kkfey) ds chp dk ,d iw.kk±d eku
gksxkA

14. A mineral of iron contains an oxide containing 72.36% iron by mass and has a density of 5.2 g/cc. Its
unit cell is cubic with edge length of 839 pm. What is the total number of atoms (ions) present in each
unit cell ? (Fe - 56, O-16)
,d vk;ju ds [kfut esa eq[;r% bldk vkWDlkbM ik;k tkrk gS] ftlesa vk;ju Hkkj vuqlkj 72.36% gS] rFkk ftldk
?kuRo 5.2 g/cc. gSaA bldh bdkbZ dksf"Bdk ?kuh; gS rFkk blds dksj dh yEckbZ 839 pm. gSA izR;sd bdkbZ dksf"Bdk
esa mifLFkr ijek.kqvksa ¼vk;uksa½ dh dqy la[;k D;k gS \ (Fe - 56, O-16)
Ans. 56
r 1
15. Percentage of void space in AB solid having rock salt structure if = having cation anion contact.
r– 2
Given  = 3.15.
r 1
Bksl AB tks fd] jkWd lkWYV lajpuk j[krk gS] esa fjfDr;ksa ds LFkku dk % Kkr dhft;s \ ;fn = rFkk
r– 2
èkuk;u&_.kk;u lEidZ esa jgrs gSA fn;k gS %  = 3.15
Ans. 30%
16. In an ionic solid r(+) = 1.6 Å and r(–) = 1.864 Å. Use the radius ratio rule to determine the edge length of
the cubic unit cell in Å.
,d vk;fud Bksl esa r(+) = 1.6 Å rFkk r(–) = 1.864 Å gSaA rks f=kT;k vuqikr fu;e dk mi;ksx djrs gq;s ?kuh; ,dd
dksf"Bdk ds dksj dh yEckbZ Å esa Kkr dhft,A
Ans. 4
17. Ice crystallizes in a hexagonal lattice. At the low temperature at which the structure was determined, the
lattice constants were a = 4.53 Å and c = 7.41 Å (as shown in fig.). How many H 2O molecules are
contained in a unit cell? (Density of ice = 0.92 gm/cc)
,d cQZ fØLVy tks "k"V~dks.kh; tkyd esa gSA de rki ij fp=kkuqlkj lajpuk ns[kh xbZ gSA tgk¡ tkyd fu;rkad
a = 4.53 Å rFkk c = 7.41 Å FkhA ,dd dksf"Bdk esa mifLFkr H2O v.kqvksa dh la[;k Kkr djksA (cQZ dk ?kuRo =
0.92 gm/cc)

Ans. 4 water molecules, (4 ty v.kq½

18. A spinal is an important class of oxides consisting of two types of metal ions with the oxides ions
arranged in CCP layers. The normal spinal has one-eighth of the tetrahedral holes occupied by one
type of metal ion and one-half of the octahedral holes occupied by another type of metal ion. Such a
spinal is formed by Zn2+, Al3+ and O2– with Zn2+ in the tetrahedral holes. If formula of the compound is
ZnxAlyOz, then find the value of (x + y + z) ?
,d Likbfuy tks vkWDlkbM dh ,d egÙoiw.kZ Js.kh gS ftlesa nks rjg ds /kkrq vk;u ds lkFk vkWDlkbM vk;u CCP
ijr dh O;oLFkk esa O;ofLFkr gksrs gaSA lkekU; Likbfuy esa prq"Qydh; fNnzksa dk 1/8 Hkkx ,d /kkrq vk;u }kjk rFkk
v"VQydh; fNnzksa dk 1/2 Hkkx nwljs /kkrq vk;u }kjk ?ksjk tkrk gSA bl çdkj Likbfuy tks fd Zn2+, Al3+ rFkk O2–
ls curk gSA mlesa Zn2+ vk;u prq"Qydh; fNnzksa esa mifLFkr gSA ;fn Likbfuy dk lw=k ZnxAlyOz gksxk] rc (x +
y + z) dk eku Kkr djsaA
Ans. 7 = (1 + 2 + 4)

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SECTION-4 : Comprehension Type (Only One options correct)
This section contains 1 paragraphs, each describing theory, experiments, data etc. 3 questions
relate to the paragraph. Each question has only one correct answer among the four given
options (A), (B), (C) and (D)
[k.M-4 : vuqPNsn çdkj (dsoy ,d fodYi lgh)
bl [k.M esa fl)karksa] ç;ksxksa vkSj vk¡dM+ksa vkfn dks n'kkZus okys 1 vuqPNsn gSA vuqPNsn ls lacaf/kr rhu ç'u gSaA
vuqPNsn esa gj ç'u ds pkj fodYi (A), (B), (C) vkSj (D) gSa] ftuesa ls dsoy ,d gh lgh gSA
Paragraph for Questions 19 to 21
Two dimensional close packed structure can be generated by stacking the rows of close packed
spheres. This can be done in two different ways.
(I) The second row may be placed in contact with the first one, such that the spheres of the second row
are exactly above those of first row. The spheres of the two rows are aligned vertically as well as
horizontally.
If we call the first row as ‘A’ type of row, the second row being exactly same as the first one is also of ‘A’
type. Similarly, we may place more rows to obtain AAAA.... type arrangement.
(II) In this type, the second row may be placed above the first one in a staggered manner such that its
spheres. fit in depressions of first row. If the arrangement of spheres in the first row is called ‘A’ type,
the one in the second row is different and may be called ‘B’ type. When the third row is placed adjacent
to the second in staggered manner, its spheres are aligned with those of first layer. Hence this layer is
also ‘A’ type. The spheres of similarly placed fourth row will be aligned with those of the second row (‘B’
type). Hence this arrangement is of ABAB.......type.

iz'u la[;k 19 ls 21 ds fy, vuqPNsn

fufcM ladqy xksyh; iafDr ds <sj dks ysdj f}foeh; fufcM ladqy lajpuk dks cuk;k tk ldrk gSA bls nks fofHkUu
rjhds ls crk;k tk ldrk gSA
(I) f}rh; iafDr dks izFke iafDr ds lEidZ esa bl izdkj ls j[kk tkrk gS fd f}rh; iafDr ds xksys dks Bhd izFke iafDr ds
Åij j[kk tkrk gksaA nksuksa iafDr;ksa ds xksyks dks m/okZ/kj ds lkFk {kSfrt esa lajsf[kr fd;k tkrk gSA ;fn izFke iafDr
dks ‘A’ izdkj dh iafDr dgsa rks f}rh; iafDr] tks izFke iafDr ds leku gh gS dks Hkh ‘A’ izdkj dh dg ldrs gSA blh
izdkj ge cgqr lkjh ifDr;k¡ ysdj AAAA.... izdkj dk foU;kl izkIr dj ldrs gSA
(II) bl izdkj esa f}rh; iafDr dks lkUrfjr :i ls izFke iafDr eas bl izdkj ls j[kk tkrk gS fd bldk xksyk izF ke iafDr
ds xrZ esa lek tkrk gSA ;fn izFke iafDr esa xksys dk foU;kl ‘A’ izdkj dk dgykrk gS] f}rh; iafDr esa fHkUu izdkj
dk gksrk gS rFkk bls ‘B’ izdkj dk dg ldrs gSA tc r`rh; ijr dks lkUrfjr :i ls f}rh; ds lkFk la;qXeh :i ls
j[kk tkrk gS] rks bldk xksyk izFke ijr ds lkFk lajs[k.k gksrk gSA vr% ;g ‘A’ izdkj dh ijr gksrh gSA blh izdkj
j[kh x;h prqFkZ iafDr dks xksyk f}rh; ijr (‘B’ izdkj) ds lkFk lajsf[kr gksrk gSA vr% ;g ABAB....... izdkj dk
foU;kl gksrk gSA
19. The type of packing generated by type (I) is :
(A) hexagonal close packing (B*) square close packing
(C) cubic close packing (D) body centered packing
(I) izdkj }kjk cuk;s x;s ladqyu dk izdkj fuEu gS :
(A) "kV~dks.kh; fufcM ladqyu (B*) oxZ fufcM ladqyu
(C) ?kuh; fufcM ladqyu (D) dk; dsfUnz; ladqyu

20. Of type (I) & type (II), the packing efficiency :

(A) is better in type I (B*) is better in type II
(C) is same in both (D) can’t be compared
(I) izdkj o (II) izdkj esa ladqyu n{krk :
(A) I izdkj esa T;knk vPNk gSA (B*) II izdkj esa T;knk vPNk gSA
(C) nksuksa esa leku gSA (D) dgk ugh tk ldrkA

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21. The types of voids generated in type (I) & (II) respectively are
(A) tetrahedral, octahedral (B) octahedral, tetrahedral
(C) triangular, square (C*) square, triangular
(I) izdkj o (II) izdkj esa cuk;s x;s fjfDrdkvksa ds izdkj Øe'k% fuEu gaS &
(A) prq"Qydh;] v"VQydh; (B) v"VQydh;] prq"Qydh;
(C) f=kdks.kh;] oxZ (D*) oxZ] f=kdks.kh;

SECTION-5 : Matching List Type (Only One options correct)

This section contains 1 questions, each having two matching lists. Choices for the correct
combination of elements from List-I and List-II are given as options (A), (B), (C) and (D) out of
which one is correct
[k.M-5 : lqesyu lwph izdkj ¼dsoy ,d fodYi lgh½
bl [k.M esa 1 cgqfodYi iz'u gSA izR;sd iz'u esa nks lqesyu lwfp;k¡ gSA lwfp;ksa ds fy, dwV ds fodYi (A), (B),
(C) vkSj (D) gSa ftuesa ls dsoy ,d lgh gSA

22. Match list- with list- and select the correct answer by using the codes given below:
List- List-
(Shapes) (Radius ratio)
P. Planar triangle 1. 0.732
Q. Square planar 2. 0.225
R. Body centered cubic 3. 0.155
S. Tetrahedral 4. 0.414
lwph- dk lwph- ds lkFk feyku dhft, rFkk uhps fy[ks dksM dk mi;ksx djrs gq, lgh mÙkj dk p;u dhft,A
lwph- lwph-
¼vkd`fr½ ¼f=kT;k vuqikr½
P. leryh; f=kHkqt 1. 0.732
Q. leryh; oxkZdkj 2. 0.225
R. dk; dsfUnzr ?kuh; lajpuk 3. 0.155
S. prq"Qydh; 4. 0.414
Code dksM
P Q R S P Q R S
(A*) 3 4 1 2 (B) 3 2 1 4
(C) 2 1 4 3 (D) 1 3 4 2

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