Guru Gobind Singh Public School, Chas (Bokaro)

Half-Yearly Examination (Session 2023-2024)

Date: - 20 – 9 – 2023 Time (03 Hours)

CLASS:-XI Sub.:- Chemistry (301) Marks (70)
General instructions
 There are 33 question in this question paper with internal choice
 Section A consist of 16 multiple choice question carry one marks is
 Section B consists of five short answer question carrying 2 marks each.
 Section C consists of 7 short answer question carrying 3 marks each.
 Section D consists of two Case based question carrying 4 marks each.
 Section E consist of three long answer question carrying 5 marks each.
 All question are compulsory.
Section - A
(1) Which of the following simple ratio of different element in compound
a. Molecular formula b. Empirical formula c. Chemical formula d. All of these
(2) The number of carbon atom in one mole or exactly 12 gram of carbon 12 is called
a. Faraday constant b. Aavogadro constant c. Rydberg constant d. none of these
(3) the number of d electron in Fe²+ (26)ion are
a.3. b. 4. c. 5. d6
(4) The principal quantum number is related to
a. size of orbital b. spin angular momentum
c. orbital angular momentum d. magnetic moment
(5) The value of n and l for valence electron of sodium respectively are
a.3,0. b.0,3. c.3,1. d.3,2
(6) which of the following has highest electronegativity
a. F. b. Cl. C. Br. d. I
(7) 7. Which of the following has smallest size?
a. He+. b. Li²+. c. Be²+. d. He
(8) which element is expected to have lowest ionization enthalpy
a. Sr. b. As. c. Xe. d. S
(9) Ratio of pi to sigma bond in benzene is
a.1:2. b.1:6. c.1::4. d.1:1
(10) Around which type of bond free rotation is possible.?
a. sigma bond. b. π bond c. triple bond. d. All
(11) SF6 has hybridization
a. sp³d². b. sp³d. c. dsp². d. sp³d³
(12) which of the following is liquid and has a highest boiling point
a. Hcl. b. HBr. c. HI. d. HF
In the following question (question number 13 to 16 ) statement of assertion followed by statement of
region is given.
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
(13) Assertion (A):no of atom of. He in 60u of He are15
Reason (R) Atomic mass of. He is 4U
(14) Assertion(A) no of orbital in 4th shell is 16
Reason(R) no of orbital for a value of n is equal to n²
(15) Assertion(A)IF7 has sp³d² hybridization
Reason (R) It has occtahedral structure.

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(16) Assertion(A) the molecular orbital with higher energy is called antibonding molecular orbital
Reason (R) the antibonding nature of molecular orbital is indicated by an asterisk over its
designation
Section – B

(17) Draw the Resonance structure of CO3²- and NO3 -

(18) Consider the following species
N³-, O²- , Na+, Mg³+ and Al³+
(a) what is common in them
(b) arrange them in the order of increasing ionic radii
(19) Draw the Lewis dot structures of H2SO4 and HNO3.
(20) Calculate the no of mole in each of the following
(a) 14 gm oof N2
(b) 1.12 L of CO2..
(21) (a) Write the electronic configuration of. CU²+ and Zn²+
(b) calculate the no of node in. 4d orbital.
Section – C
(22) calculate the number of electron present in 1.6 gram of methane
(23) (a) why nitrogen has higher ionization enthalpy then oxygen.
(b) what limiting reagent.
(24) calculate the wave number for the longest wavelength of transition in the balmer series of atomic
hydrogen.
(25) (a) use molecular orbital theory to predict He2 molecule does not exist.
(b) compare the stability of N2+ and N2
(26) (a)What is the number of photon of light with a wavelength of 4000 p.m. that provide 1 joule of
energy.
(b) what is the lowest value of n that allow 'g' orbital to exist.
(27) (a) distinguish between a Sigma and Pi bond.
(b) which of the species have same bond order and paramagnetic? Give reason.
N2, F2+, N2-,O2-
(28) Calculate the number of atom in each of the following
(a) 52 mole of Ar
(b) 52 u of He
(c) 52 gm of He
Section – D
(29) Read the passage given below and answer the following questions
Stoichiometry involve calculation based on chemical equation and mole concept. Mole is a counting
unit equal to 6.022 ×10²³ particle. One mole is also equal to molar mass expressed in gram. In
chemical reaction, the reactant which get used up completely is called limiting reactant and decide
the amount of product formed. The property of element depends upon their electronic configuration
and valence electron.
(a) calculate the number of atom in one mole of methane (CH4)
(b) what will be mass of residue left on heating 2.76 gram of Ag2CO3?
(c) if 50 gram of calcium carbonate is treated with 50 gram of HCl how many gram of CO2 will be
produced according to equation
CaCO3 + HCl. →. CaCl2. + H2O + CO2 [ Ca=40, C= 12, O=16,, H=1 Cl= 35.5]
OR
(c) 1 mole AB2 weight 25 gm and 1 mole of A2 B2 weight 30 gm what is atomic mass of A
(30) Modern Periodic table arrange the element in the increasing order of atomic number. It has 18
group and 7 period. Atomic number are consecutive in period and increases in a group in a
pattern. Elements are divided into four block s block p block d block and f block based on their
electronic configuration. 78% of element are metal about 20 elements are non metal and few
element like B, Si , Ge, As are metalloid. Metallic character increases down the group but decreases
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 along the period from left to right . The physical and chemical property very periodically with their
atomic number. Periodic trends are observed in atomic size, ionization enthalpy ,electron gain
enthalpy, electronegativity and valence . Oxide of metal are basic, Some are amphoteric. Non metal
form acidic oxide, some form neutral oxide. S block element are soft highly reactive do not so
variable oxidation State. P block element are metal, non metal as well as metalloid. Show variable
oxidation state exist as a solid liquid and gases. d block element are metal form coloured ion show
variable oxidation State have high melting and boiling point. Lanthanoid and actinoid are f block
element from coloured ion all actinoid are radioactive.
(a) which are representative element.
(b) which of the following belong to d block but are not transition element.
Zn, Cd, Hg, Ag
(c) write the outer electronic configuration of 'd' block element and 'f'' block element.
OR
(c) which type of compound is formed by group 14 element in third period and what is the
formula of its chloride and its oxide.
Section – E
(31) Compare the relative stability of the following species and indicate their magnetic property O2+,
O2-, O2, O2²-.
OR
What is meant by term bond order calculate the bond order of N2, O2, O2+ and O2-.
(32) A welding fuel gas contain carbon and hydrogen only . Burning a small sample of it in oxygen gives
3.38 gram of carbon dioxide and 0.690 gram of water and no other product. A volume of 10L of this
welding gas is found to weight 11.6 gram calculate empirical formula, molar mass of the gas and
molecular formula.
OR
Two metal oxide contain 27.6% and 30% of oxygen respectively if the formula of first oxide is M 2O3
find that of the second.
(33) (a) Show that the circumference of bohrs orbit for the hydrogen atom is an integral multiple of the
de broglie wavelength associated with the electron revolving around the orbit.
(b) An element with mass number 81 contain 31.7% more neutron as compared to proton. Assign
the atomic symbol.
OR
Explain giving reason, which of the following state of quantum number are not possible.
(a) n=0, l=0, m=0, S=+1/2
(b) n=1, l=0, m=0, S= -1/2
(c) n=1, l=1, m=0, S=+1//2
(d) n=2, l=1, m=0, S=-½
(e) n=3, l=3, m=-3, S=+½

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