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Atomic Theories

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Atomic Theories

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SCIENCE

ATOMS: INSIDE OUT


WEEK 5

Denilyn B. Agripa
LEARNING OBJECTIVES

After going through this lesson, you are expected to:


1. differentiate atoms from molecules;
2. discuss the historical background of the atom and
its sub-atomic particle.
What is it? ❑ In previous lesson, you learned that matter is
made up of atoms which are too small to see
with the unaided eye.
❑ When the idea of the atoms was conceived by the
ancient Greek philosophers, they thought the atom
is indivisible, that it has no parts.
❑ Scientists have proven, however, that the atom is
composed of even smaller particles. These
components of the atom are referred to as
subatomic particles.
❑ How are these particles arranged in atoms?
Prepare yourself to turn the atoms inside out!
The History of the Atom
Democritus was a Greek philosopher who was the first person to use the term
atom (Atomos: meaning indivisible).

He thought that if you take a piece of matter and divide it and continue to divide it
you will eventually come to a point where you could not divide it anymore.

This fundamental or basic unit was what Democritus called an atom.

He called this the theory of the universe:

1. All matter consists of atoms, which are bits of matter too small to be seen.

2. There is an empty space between atoms.

3. Atoms are completely solid.

4. Atoms have no internal structure. Each atom (of a different substance) is


DEMOCRITUS different in size, weight and shape.
400 BC
The History of the Atom

▪To Democritus, atoms were small, hard particles that were all
made of the same material but were different shapes and sizes
DEMOCRITUS .
▪Atoms were infinite in number, always moving and capable of
400 BC joining together.
This theory was ignored
and forgotten for more than
2000 years!
Why?

● The eminent philosophers of the


time, Aristotle and Plato, had a more
respected, (and ultimately wrong)
theory.

Aristotle and Plato favored the earth, fire, air and


water approach to the nature of matter. Their ideas
held sway because of their eminence as
philosophers. The atomos idea was buried for
approximately 2000 years.
The History of the Atom

John Dalton was an English chemist.


His ideas form the atomic theory of matter. Here
are his ideas;

1. All matter is composed of indivisible particles


called atoms.
2. All atoms of a given element are identical in
mass and properties. Atoms of different
elements have different masses and different
properties.
3. Compounds are formed by a combination of 2
or more atoms. JOHN DALTON
4. Atoms cannot be created, destroyed, or 1800
converted into other kinds of atoms during
chemical reactions. This theory became one of the
foundations of modern chemistry.
The “Billiard Ball” Model

● proposed by John Dalton in 1804

● this theory proposed that matter was


composed of small, spherical particles

● but evidence was later gathered that


matter was composed of even smaller
bits
The History of the Atom

J.J Thomson was a physicist who is


credited for discovering the
electron. He used his research on
cathode ray tube technology in this
discovery.

J.J Thomson was an excellent physicist and thus did not stop
when he had found this negative charge. Through a series of
clever experiments he was able to predict the mass of this
charge. He then found out that this charge was 1000 times
lighter that a hydrogen atom. He made a bold statement
JOSEPH JOHN saying that this negative charge must be inside an atom. This
THOMSON negative charge (he called corpuscles) later became known as
1890 the electron.
Thomson: “Plum Pudding” or “Chocolate
Chip Cookie” Model
● using available data on the atom, J.J. Thomson came up
with the idea of having charges embedded with Dalton’s
Billiard Balls
● Also used cathode ray experiment to discover the
existance of the electron

positive negative
(evenly distributed)
“chocolate”
“dough”
part

note: this model kept Dalton’s key ideas intact


The History of the Atom THOMSON’S ATOMIC MODEL
(PLUM PUDDING MODEL)

Using what he had discovered, Thomson predicted what an


atom should look like. These are the key points to Thomson’s
Atomic Model:

1. Because of its design this model is known as the plum


pudding model
2. Each atom is a sphere filled with positively charged ‘fluid’.
This resembles the sticky jam part of a pudding.
3. Corpuscles (later called electrons), are the negatively
charged particles suspended in this ‘fluid’. This resembles
the plums in the pudding.
4. He did not predict the movement of these electrons.
ERNEST RUTHERFORD
The History of the Atom 1910’S

Ernest Rutherford was not convinced about the


model of the atom proposed by Thomson. He thus
set up his now famous Gold Foil Experiment.

1. He fired alpha particles (positively charged) at a gold foil.


2. He measured the deflection as the particles came out the
other side.
3. Most of the particles did not deflect at all. Every now and
then a particle would deflect all the way back.
4. He said that there must be a positive center of the foil. He
called this center the nucleus.
LITERATURE
REVIEW
THEORY 1 THEORY 2
Venus is terribly hot—even hotter Jupiter is a gas giant. Its name
than Mercury—and its atmosphere comes from the Roman god of the
is extremely poisonous sky and lightning

THEORY 3
Mercury is the closest planet to the
Sun and the smallest one in the
Solar System
Gold Foil Experiment

• Particles shot through thin sheet of gold


• Most shots went straight through
• A small amount were deflected
• Hence… The atoms must be made of mostly empty space with a small
dense nucleus
Further explanation of Nuclear Model
● If previous models were correct alpha particles would have
passed straight through the the gold
Rutherford’s problem:

In the following pictures, there is a target hidden by a


cloud. To figure out the shape of the target, we shot
some beams into the cloud and recorded where the
beams came out. Can you figure out the shape of the
target?

Targe Target
t #1 #2
The Answers:

Target #1 Target #2
Nuclear Model
● Rutherford found that most (99%) of the alpha particles that he shot at
the gold went straight through
● From these experiments Rutherford concluded that the atom had a
dense positive core, with the rest composed of mostly empty space with
the occasional negatively charged electron

-
-
-
+

-
-
note: this model completely changed the definition of atom
Rutherford’s Findings
* MOST of the particles passed right through
* SOME particles were deflected
* FEW were greatly deflected

Conclusions:

#1 The nucleus is small


#2 The nucleus is dense
#3 The nucleus is positively charged
Rutherford

● Rutherford reasoned that all


of an atom’s positively
charged particles were
contained in the nucleus. The
negatively charged particles
were scattered outside the
nucleus around the atom’s
edge.
RUTHERFORD’S 1. The nucleus of the atom is a dense
ATOMIC MODEL mass of positively charged
particles.
(NUCLEAR MODEL) 2. The electrons orbit the nucleus.
3. A problem raised was: Why are the
negatively charged particles not
attracted by the positively charged
nucleus.
4. Rutherford stated that the atom
was like a mini solar system and
that the electrons orbited the
nucleus in a wide orbit. That is why
it is known as the planetary model.
The History of the Atom

Niels Bohr agreed with the planetary model of the atom, but also knew
that it had a few flaws. Using his knowledge of energy and quantum
physics he was able to perfect Rutherford’s model. He was able to
answer why the electrons did not collapse into the nucleus.

According to Bohr’s atomic model,


electrons move in definite orbits
around the nucleus, much like
NEILS BOHR planets circle the sun. These orbits,
1910’S or energy levels, are located at
certain distances from the nucleus.
Bohr Model
● Niels Bohr proposed that electrons revolve around
the central positive nucleus (like planets in the solar
system)

negative electrons

3 positive protons
Bohr Model
● Bohr also suggested that the electrons can only revolve in certain
orbits, or at certain energy levels (ie, the energy levels are quantized)

no energy level in between steps


BOHR’S ATOMIC MODEL
Electrons orbit the nucleus in orbits that have a
(THE PLANETARY
1.
set size and energy.
MODEL) 2. The lower the energy of the electron, the lower
the orbit.
3. This means that as electrons fill up the orbitals,
they will fill the lower energy level first.
4. If that energy level is at fill (or at capacity), a new
energy level will begin.
5. Radiation is when an electron moves from one
level to another. However, here is the problem
with this theory: Electrons do not travel on a
specific orbit or path.
The History of the Atom

Erwin Schrödinger was a revolutionary


physicist who used Heisenberg’s
uncertainty principle to come up with
the atomic model that we still use
today.

• Found that Electrons live in fuzzy


regions or “clouds” not distinct orbits ERWIN
• Improved on Bohr’s findings SCHRÖDINGER
• Electron location can not be predicted 1920’S
Quantum Mechanical Model
electrons can be found
anywhere in these “shells”

the current understanding of the atom is


based on Quantum Mechanics

this model sees the electrons not as individual


particles, but as behaving like a cloud - the
electron can be “anywhere” in a certain
energy level note: the electrons are still
quantized
no electrons can be found
here
THE QUANTUM MECHANICAL MODEL
● According to the theory of wave mechanics, electrons do
not move about an atom in a definite path, like the
planets around the sun.

● In fact, it is impossible to determine the exact location of


an electron. The probable location of an electron is
based on how much energy the electron has.

● According to the modern atomic model, at atom has a


small positively charged nucleus surrounded by a large
region in which there are enough electrons to make an
atom neutral.
Electron Cloud:
● A space in which electrons are likely to be found.
● Electrons whirl about the nucleus billions of times in one
second
● They are not moving around in random patterns.
● Location of electrons depends upon how much energy the
electron has.
● Depending on their energy they are locked into a certain
area in the cloud.
● Electrons with the lowest energy are found in the energy
level closest to the nucleus
● Electrons with the highest energy are found in the
outermost energy levels, farther from the nucleus.
SCHRÖDINGER’S ATOMIC MODEL (THE
QUANTUM MECHANICAL MODEL)
1. An electron does not travel in an exact
orbit.
2. We can predict where it will probably
be.
3. We cannot say for certain where it is,
but only where it ought to be.
4. The type of probability orbit is
dependent on the energy level
described by Bohr.
Indivisible Electron Nucleus Orbit Electron
Cloud

Greek X

Dalton X

Thomson X

Rutherford X X

Bohr X X X

Wave X X X
TIMELINE

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