14.NOVOCRYL S-TP NEW - v5-SDS

Safety data sheet
according to Regulation (EC) No.1907/2006

and Regulation (EC) No.1272/2008
NOVOCRYL S/TP NEW
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: NOVOCRYL S/TP NEW
Poly(ethylene-co-vinyl acetate)
CAS: 24937-78-8
EC: 607-457-0
Index:
REACH:
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Recommended use:
Aqueous dispersion of synthetic polymers.
1.3 Details of the supplier of the safety data sheet: OFFICINA +39 SRL
VIA MARCONI, 18
13900 BIELLA (BI) - ITALY
Tel. +39 015.8492913
A. Venier
[email protected]
1.4 Emergency telephone number: +39.015.8492913
(office hours)
SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:
The product is not classified as dangerous according to Regulation (EC) No.1272/2008 (CLP regulation) and Regulation (EC)
No.1907/2006 (REACH regulation).
2.1.1 CLP Regulation (EC) No.1272/2008:
2.2 Label elements
CLP Regulation (EC) No.1272/2008:

Warning:
Wng: Warning
Pictograms:
Cautionary advice:
P201: Obtain instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P264: Wash hands and face thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P501: Dispose of contents / container in accordance with the current legislation on waste treatment.
Supplementary information:
EUH208: Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
EUH208: Contains Mixture of 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one
[EC no. 220-239-6] (3:1). May produce an allergic reaction.
EUH210: Safety data sheet available on request.
2.3 Other hazards
Substance PBT: None
Substance vPvB: None
Other hazards:
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Printing date: 15/03/2021 Revised: 15/03/2021 Version: 5 Page 1/10

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 2: HAZARDS IDENTIFICATION (continue)

No other hazards.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical description
Aqueous dispersion of synthetic polymers.
3.2 Mixtures:
1,2-benzisothiazol-3(2H)-one (BIT) >= 0,025 % - < 0,05 %

CAS: 2634-33-5
EC: 220-120-9
Index: 613-088-00-6
REACH: 01-2120761540-60-XXXX
Acute Tox. 4 Skin Irrit. 2 Eye Dam. 1 Skin Sens. 1 Aquatic
Acute 1
H302 H315 H318 H317 H400
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. < 0,0015 %

247-500-7]|and 2-methyl-2H-isothiazol-3-one [EC no.
220-239-6] (3:1)
CAS: 55965-84-9
EC:
Index: 613-167-00-5
REACH:
Acute Tox. 3 Acute Tox. 2 Skin Corr. Eye Dam. 1 Skin Sens. Acute Tox. 2 Aquatic Aquatic
1C 1A Acute 1 Chronic 1
H301 H310 H314 H318 H317 H330 H400 H410
SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
Consult a doctor in case of discomfort with this Security Data Sheet.
By inhalation:
Carry away patient to outside, let him rest and keep warm.
By skin contact:
Wash with plenty of water and soap.
By eye contact:
Wash immediately with plenty of water for at least 10 minutes.
By consumption:
Do not induce vomiting. Seek medical advice, showing the safety data sheet.
4.2 Most important symptoms and effects, both acute and delayed:
No information available.
4.3 Indication of any immediate medical attention and special treatment needed:
Treatment: see section 4.1

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 5: FIREFIGHTING MEASURES (continue)
SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:
SUITABLE EXTINGUISHING EQUIPMENT
Water, carbon dioxide (CO2).
UNSUITABLE EXTINGUISHING EQUIPMENT

None in particular.
5.2 Special hazards arising from the substance or mixture:
Do not inhale explosion and combustion gases.
5.3 Advice for firefighters:
Wear the respirator.
Additional provisions:
No information.
SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2 Environmental precautions:
Limit leakages with earth or sand.
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
6.3 Methods and material for containment cleaning up:
Suitable material for taking up:
Absorbing material, organic, sand.
Wash with plenty of water.

Retain contaminated washing water and dispose it.
6.4 Reference to other sections:
See sections 8 and 13.
SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
Avoid contact with skin and eyes, inhalation of vapours and mists.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2 Conditions for safe storage, including any incompatibilities:
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:

Adequately ventilated and dry rooms.
See also section 10.

7.3 Specific end use(s):
None in particular.

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 7: HANDLING AND STORAGE (continue)

None in particular.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
DNEL (Workers):
* 1,2-benzisothiazol-3(2H)-one
Short exposure - Systemic:

Oral: Non-applicable
Dermal: Non-applicable
Inhalation: Non-applicable
Short exposure - Local:

Long exposure - Systemic:

Dermal: 0,966 mg/kg
Inhalation: 6,81 mg/m³
Long exposure - Local:

DNEL (Population):
Short exposure - Systemic:

Short exposure - Local:

Long exposure - Systemic:

Dermal: 0,345 mg/kg
Inhalation: 1,2 mg/m³
Long exposure - Local:

Inhalation: Non applicabile
PNEC:
STP: 1,03 mg/l

Soil: 3 mg/kg

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

Intermittent: 1,1 µg/l
Fresh water: 4,03 µg/l
Marine water: 0,403 µg/l
Sediment (fresh water): 49,9 µg/kg
Sediment (marine water): 4,99 µg/kg
8.2 Exposure controls:
No PPE are required under normal use conditions, we recommend the use of them in emergency situations.
To avoid getting dirty, it is recommended to use basic Personal Protection Equipment listed below, with the corresponding "CE
marking" (Regulation (EU) 2016/425).
For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection, etc...) consult the
information leaflet provided by the manufacturer.
Information contained in this point refer to pure product.
Protection measures for diluted product may vary according to its dilution degree, use, method of application, etc...
To determine the requirement of emergency showers installation and / or collyrium in warehouses will take into consideration the
rules of chemicals storage applied to each case. For more infomation see subsection 7.1 and 7.2.
* Additional emergency measures:

It is not necessary to take additional emergency measures.
Specific protection for the hands

Suitable materials for safety gloves; EN 374:
Polychloroprene - CR: thickness >=0,5 mm; breakthrough time >=480 min.
Nitrile rubber - NBR: thickness >=0,35 mm; breakthrough time >=480 min.
Butyl rubber - IIR: thickness >=0,5 mm; breakthrough time >=480 min.
Fluorinated rubber - FKM: thickness >=0,4 mm; breakthrough time >=480 min.
Ocular and facial protection

Not needed for normal use. Anyway, operate according good working practices.
Bodily protection
No special precaution must be adopted for normal use.
Respiratory protection
Not necessary.
Environmental exposure controls:
No information available.
Volatil organic compounds:
Information not available.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties:

Appearance Liquid
Colour White
Odour Characteristic
Odour threshold Not available
pH 6,50
Melting or freezing point Not available °C
Initial boiling point and boiling range 100 °C
Flammability of solids and gases Not available
Lower/upper flammability or explosion limit Not available

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

Vapour density Not available
Flash point Not available °C
Evaporation rate Not available
Vapour pressure Not available
Relative density 1,10 g/cm³
Vapour density Non-applicable
Solubility in water Dispersible
Viscosity Not available
Autoignition temperature Non-explosive °C
Decomposition temperature Not available °C
Partition coefficient n-octanol/water Not available
Explosive properties Not available
Comburent properties Not available
9.2 Other information:
Information not available
SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
Stable under normal conditions.
10.2 Chemical stability:
10.3 Possibility of hazardous reactions:
None.
10.4 Conditions to avoid:
10.5 Incompatible materials:
None in particular.
10.6 Hazardous decomposition products:
None.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects:

Acute toxicity:
LD50, inhalation: Non-applicable
LD50, oral: Non-applicable
LD50, dermal: Non-applicable
Skin corrosion/irritation:
Does not meet the classification criteria.
Serious eye damage/irritation:

Respiratory or skin sensitisation:

Germ cell mutagenicity:


Safety data sheet
NOVOCRYL S/TP NEW
SECTION 11: TOXICOLOGICAL INFORMATION (continue)
Carcinogenicity:
Reproductive toxicity:
Specific target organ toxicity (STOT) single exposure:

Specific target organ toxicity (STOT) repeated exposure:

Aspiration hazard:
Specific toxicology information on the substances:

Acute toxicity LD50 oral, rat: 1020 mg/kg

Acute toxicity LD50 dermal: Non-applicable
Acute toxicity LC50 inhalation: Non-applicable
* Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7]|and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1)
Acute toxicity LD50 oral, rat: 457 mg/kg

Acute toxicity LD50 dermal, rabbit: 660 mg/kg
Acute toxicity LC50 inhalation, rat: 2,36 mg/l (4 h)
SECTION 12: ECOLOGICAL INFORMATION

Use this product according to good working practices. Avoid littering.
12.1 Toxicity:
* 1,2-benzisothiazol-3(2H)-one (BIT)
Acute aquatic toxicity:

Endpoint: LC50 - Species: Fish 2,15 mg/l
Chronic aquatic toxicity:

Endpoint: NOEC - Species: Algae 0,04030 mg/l - Duration: 72 h
Endpoint: EC50 - Species: Algae 0,11 mg/l - Duration: 72 h
* Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7]|and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6]
(3:1)
Acute aquatic toxicity:

Endpoint: EC50 - Species: Daphnia 0,1 mg/l - Duration: 48 h
Endpoint: EC50 - Species: Algae 0,048 mg/l - Duration: 72 h
Endpoint: LC50 - Species: Fish 0,22 mg/l - Duration: 96 h
Endpoint: LC50 - Species: Fish 0,0052 mg/l - Duration: 48 h
Chronic aquatic toxicity:

Endpoint: NOEC - Species: Daphnia 0,004 mg/l - Duration: 21 d
Endpoint: NOEC - Species: Fish 0,098 mg/l - Duration: 28 d

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 12: ECOLOGICAL INFORMATION (continue)

12.2 Persistence and degradability:
Non-applicable.
12.3 Bioaccumulative potential:

Non-applicable.
12.4 Mobility in soil

Non-applicable.
12.5 Results of PBT and vPvB assessment:

vPvB Substances: None
PBT Substances: None
12.6 Other adverse effects:

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the
local and national regulations currently in force.
* Regulations related to waste management:

In accordance with Annex II of Regulation (EC) No. 1907/2006 (REACH) the community or state provisions related to waste
management are stated.
- Community legislation:
Directive 2014/955/UE, Regulation (EU) No. 1357/2014
SECTION 14: TRANSPORT INFORMATION

This product is not dangerous for transport (ADR/RID, IMDG, IATA).
SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Regulation (EC) No. 1907/2006 (REACH)
Regulation (EC) No. 1272/2008 (CLP)
Regulation (EC) No. 790/2009 (ATP 1 CLP) and (UE) N. 758/2013
Regulation (UE) No. 2015/830
Regulation (UE) No. 286/2011 (ATP 2 CLP)
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 15: REGULATORY INFORMATION (continue)

Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local
circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this
product.
Other legislation:
Regulation (EC) No. 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) No. 1907/2006.
Chemical safety assessment:
No chemical safety assessment has been processed for the mixture and the substances it contains.
SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with annex II-Guide to the compilation of safety data sheets of Regulation
(EC) No. 1907/2006 (Regulation (EC) No. 830/2015).
Modifications related to the previous security card which concerns the ways of managing risks:
Texts of the legislative phrases mentioned in sections 2 and 3:

Acute Tox. 2: Acute toxicity, category 2
Aquatic Acute 1: Hazardous to the aquatic environment, acute toxicity, category 1
Aquatic Chronic 1: Hazardous to the aquatic environment, chronic toxicity, category 1
Eye Dam. 1: Serious eye damage, category 1
Skin Corr. 1C: Skin corrosion, category 1C
Skin Irrit. 2: Skin irritation, category 2
Skin Sens. 1: Skin sensitization, category 1
Skin Sens. 1A: Skin sensitization, category 1A
H301: Toxic if swallowed.
H302: Harmful if swallowed.
H310: Fatal in contact with skin.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H330: Fatal if inhaled.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
Advice related to training:

Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://echa.europa.eu
http://eur-lex.europa.eu
Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version.
Users must verify the suitability and thoroughness of provided information according to each specific use of the product.

Safety data sheet
NOVOCRYL S/TP NEW
SECTION 16: OTHER INFORMATION (continue)

This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the
current health and safety laws and regulations.
The producer is relieved from any liability arising from improper uses.
Abbreviations and acronyms:

- ADR: European agreement concerning the international carriage of dangerous goods by road
- IMDG: International maritime dangerous goods code
- IATA: International Air Transport Association
- ICAO: International Civil Aviation Organisation
- COD: Chemical Oxygen Demand
- BOD5: 5-day biochemical oxygen demand
- BCF: Bioconcentration factor
- LD50: Lethal Dose 50
- CL50: Lethal Concentration 50
- EC50: Effective concentration 50
- Log-POW: Octanol–water partition coefficient
- Koc: Partition coefficient of organic carbon
The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its
accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and
conditions for users of this product are not within our awareness or control, and is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements
concerning the manipulation, storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs
other than those specified.
- END OF SAFETY DATA SHEET -

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Safety data sheet

according to Regulation (EC) No.1907/2006

NOVOCRYL S/TP NEW

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

SECTION 2: HAZARDS IDENTIFICATION

CLP Regulation (EC) No.1272/2008:

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Printing date: 15/03/2021 Revised: 15/03/2021 Version: 5 Page 1/10

NOVOCRYL S/TP NEW

SECTION 2: HAZARDS IDENTIFICATION (continue)

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

1,2-benzisothiazol-3(2H)-one (BIT) >= 0,025 % - < 0,05 %

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. < 0,0015 %

SECTION 4: FIRST AID MEASURES

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NOVOCRYL S/TP NEW

SECTION 5: FIREFIGHTING MEASURES (continue)

SECTION 5: FIREFIGHTING MEASURES

UNSUITABLE EXTINGUISHING EQUIPMENT

SECTION 6: ACCIDENTAL RELEASE MEASURES

Wash with plenty of water.

SECTION 7: HANDLING AND STORAGE

Instructions as regards storage premises:

See also section 10.

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NOVOCRYL S/TP NEW

SECTION 7: HANDLING AND STORAGE (continue)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Short exposure - Systemic:

Short exposure - Local:

Long exposure - Systemic:

Long exposure - Local:

Short exposure - Systemic:

Short exposure - Local:

Long exposure - Systemic:

Long exposure - Local:

STP: 1,03 mg/l

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NOVOCRYL S/TP NEW

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

* Additional emergency measures:

Specific protection for the hands

Ocular and facial protection

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:

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NOVOCRYL S/TP NEW

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

SECTION 10: STABILITY AND REACTIVITY

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:

Serious eye damage/irritation:

Respiratory or skin sensitisation:

Germ cell mutagenicity:

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