Models of Matter
Models of Matter
PARTICLE
MODEL
There are three
2.1 states of matter
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has developed over thousands of years
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2.3 The particle model explains matter
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What if?
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M&Ms
The particle model can explain
2.4 the properties of matter
What you need:
M&Ms (red is best), 250 mL beaker
What to do:
1 Pour 100 mL of water into the
beaker.
2 Place one M&M in the centre of
the beaker.
3 Allow the water and the red
M&M to settle.
Increasing kinetic energy in
2.5 matter causes it to expand
4 Time how long the colour takes
to reach the walls of the beaker.
What if?
» What if the water were warm?
Would the colour move faster or
slower
» What if the water were chilled?
» What if you stirred the water?
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Solids, liquids and gases water. The ocean is liquid and the iceberg is
solid. There is also water vapour, which is a
Water is the most common substance that we
Ice = solid PL
experience in its different states of matter.
Solid water is ice. We are all familiar with
liquid water, and water as a gas is known
as water vapour. In the freezer, liquid water
solidifies into ice. On a cold night, frost (solid)
gas, in the air. Clouds are made of small liquid
water droplets. All of these different states of
water are made of the same ‘building blocks’,
or water particles.
Often substances can be described as just
one state. However, some substances seem
forms water vapour (gas) in the air. On a warm
to be made of more than one state of matter.
day, puddles (liquid) will evaporate to become
Sometimes we can see the states of a mixture,
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water vapour.
such as in honeycomb confectionary, which is a
Although the ocean and iceberg shown combination of solid, liquid and gas. But other
in Figure 2.2 may look and behave very times it is difficult to tell the state of mixtures.
differently, they are both different forms of How would you classify slime or jelly?
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Drink = liquid
Bubbles = gas
(carbon dioxide)
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Figure 2.3 Honeycomb is a combination of solid
and gas. Or is it?
Change of state
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The temperature that causes water to become a
solid is called its freezing temperature. If heat
is added back to the solid water, the ice melts.
This temperature is called the melting point.
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The process of making a gas from water is
called evaporation. The temperature at which Figure 2.5 Solid water. When heat is
the gas or vapour starts to form is called the removed from liquid water, the movement
of the water slows. The water has been
boiling point. If heat is removed from the
solidified. This is the solid form of water
steam, the gaseous water slows its movement called ice. Like all solids, ice holds its shape
until it once again forms liquid water. This
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PARTICLE MODEL 31
a b c
Melting Boiling
0°C 100°C
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Freezing Condensing
Figure 2.7 Adding or removing heat energy can change the state of water.
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what is commonly
called ‘dragon breath’.
PARTICLE MODEL 33
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Democritus
Over 2400 years ago, Democritus, a Greek
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philosopher, put forward the idea that that all
matter is made up of particles. He proposed
that if you were to cut up these particles
into smaller and smaller pieces, you would
eventually have tiny particles that could not
be cut up any more. Democritus called these
particles atomos, which is Greek for ‘indivisible’.
This is the origin of the word atom.
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John Dalton
It was not until more than 2000 years later,
in the early 1800s, that the Englishman John
Dalton developed Democritus’s idea further.
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Dalton’s ideas were based on the results Figure 2.9 Democritus (c. 460–370 BCE)
of experiments performed by many earlier proposed that all matter is made of atoms.
chemists. Dalton studied these results and
proposed a model to explain them. His model
was that matter is made of particles.
Dalton’s ideas are outlined below.
> All matter consists of tiny particles called
atoms.
> Atoms cannot be created or destroyed, and
are indivisible.
> All atoms of the same element are identical,
but different from atoms of other elements.
> When atoms combine to form compounds,
each atom keeps its identity.
> Atoms combine to form compounds called
molecules in simple whole number ratios.
For example, hydrogen and oxygen com-
bine in a ratio of 2:1 to form water, now
written as H2O. Figure 2.10 John Dalton (1766–1844) developed
Democritus’s ideas about particles.
Modern chemistry
This new understanding encouraged scientists
to find out more and more about these tiny
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particles, eventually leading to the branch of
science now called chemistry.
We can add some new ideas to Dalton’s list
to help us explain matter. H2O
> Particles are too small to be seen.
> Particles are always moving. When it is
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hotter, the particles move faster; when it is
cooler, the particles move slower.
> Particles have mass.
> Particles can join to make larger particles.
When they combine, their masses add
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together.
> There are spaces between particles.
> Forces hold particles together to stop them
from separating. Figure 2.11 A glass of water is made of
molecules. Each molecule contains two
All these ideas or rules explain how
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PARTICLE MODEL 35
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The particle model of matter is always true. The movement of people and particles is related
Every observation and every experiment can be to their kinetic (movement) energy.
explained with this model. > When people are sitting quietly, they have
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In the particle model of matter, the
particles are always moving. The word ‘kinetic’
refers to the energy of anything that is moving.
Therefore particles always have kinetic energy.
The faster they move, the more kinetic energy
they have. For this reason, the particle model
little kinetic energy. This is like a solid,
where the particles only vibrate.
> In a crowd, people are standing and moving
around and have more kinetic energy.
This is like a liquid, where the particles
jostle about. Particles in a liquid have more
can also be called the kinetic theory of matter. kinetic energy than particles in a solid.
> When people are running, they have much
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more kinetic energy. This is like a gas,
where the particles move fast and on their
own. Particles in a gas have the highest
amount of kinetic energy.
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Solid Gas
Figure 2.12 Some of the energy in storms comes from the condensation of Figure 2.13 A container of a solid has more
vapour into liquid, which we see as rain. particles than the same container of gas.
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a container of liquid nitrogen is much heavier
than the same-sized container of nitrogen gas.
This is because the liquid nitrogen has more Figure 2.16 Diffusion is slow in liquids.
particles in it than the fast moving gas particles.
A piece of lead has a much greater mass
than the same-sized piece of aluminium. Both
are metals that are made of atom particles that
are packed closely together. The difference is
the mass of each atom particle. Lead atoms
have a greater mass than aluminium atoms.
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Diffusion
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When the lid is taken off a bottle of perfume, Figure 2.17 Solids don’t diffuse.
the smell of the perfume spreads throughout the
room. This occurs without any breeze or wind
and is called diff usion. Another example of Check your learning 2.3
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PARTICLE MODEL 37
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Strength held together as strongly and can be removed
or scraped off. Therefore, plastic is not a hard
The idea of strength can be
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considered in different ways. A
rubber band is easily stretched,
but what about a piece of wire?
Different wires made of different
metals will break if stretched.
Tensile strength is a measure
substance.
There is a connection between hardness and
melting. Substances that are hard have strong
forces (bonds) between their particles. These
strong forces mean that for hard substances
to melt, a lot of heat energy is needed. These
substances usually have a high melting
of the flexibility of the links or
temperature.
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bonds between the particles. The
Viscosity
bonds between the particles in steel
are stronger than the bonds between
tin particles. Another type of strength is Viscosity is the thickness or ‘gooiness’ of a
compressional strength. Substances that can liquid. It describes how easily the particles
Figure 2.18 Reinforced withstand large forces without being crushed move around each other. Viscous liquids
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concrete combines the have a high compressional strength. are hard to pour. Water has a low viscosity,
tensile strength of steel cooking oil is more viscous and honey is very
with the compressional
strength of concrete. Hardness viscous. Engine oils used in engines have
different viscosities.
Hardness is the ability of a substance to
scratch another substance. An iron nail will
scratch a plastic ruler because the iron is harder
than plastic. However, the iron nail will not
scratch glass because the iron is softer than
glass. The order of hardness is glass, then iron,
then plastic.
Hardness is not the same as strength. A
very hard substance may shatter easily. If this
happens, the material is described as ‘brittle’.
The particle model of matter explains hardness
Figure 2.19 Glass is in terms of the forces that hold the particles
a hard, but brittle,
together. The particles in hard substances are
substance.
held together very strongly and it is difficult to Figure 2.20 Engine oils are labelled with
separate them. In plastic, the particles are not viscosities.
Normal Compressed
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can test for compressibility when substances Foam rubber 0.05
are in a plastic syringe. Wood 0.3
If you put your finger over the end of a Oil 0.75
syringe, you can compress the air inside it. 1 litre air 1 litre water 1 litre sand
Water 1.0
PARTICLE MODEL 39
Heating particles
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Gold is usually a solid at room
temperature (20°C). Like all solids,
the particles in gold are packed
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tightly together. When solid gold is
given heat energy, the gold particles
start vibrating faster and faster.
When the temperature reaches 1064°C
the particles have enough kinetic energy
to move around each other, just like the
particles in a liquid. The gold has melted.
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Figure 2.23 Vaporisation If you continue heating the gold, the
explains steam rising particles continue to gain kinetic energy, move Figure 2.25 Solidification occurs when a
from soup. faster and take up more space. Eventually, substance cools.
when the temperature reaches 2807°C, the
gold particles have enough kinetic energy to enough energy to move on their own – they
break free from the other gold particles, and become particles locked into a solid. The liquid
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a b
Figure 2.24 (a) The boiling point of water. (b) The Figure 2.26 Diffusion occurs faster in hot water
melting point of ice. (right beaker) than in cold water (left beaker).
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Cold water Hot water
particles in the liquid or gas to gain more
Figure 2.28 In a hot liquid, the particles jostle energy. The particles jostle more and speed Figure 2.30 An
around faster and take up more space than in a
up. As they move around faster, they take up expansion joint in a
cold liquid.
more space and push the other particles further suspension bridge.
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Expansion and contraction have many
important applications such as liquid-in-glass
thermometers. When an alcohol thermometer
is placed in your mouth, the heat from
your body passes to the liquid inside the
thermometer, causing it to expand and move
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up the tube. Thermometers are filled with red-
Figure 2.29 In a hot gas, the particles move or green-coloured alcohol, but not the type of
faster, and collide with each other harder, than
in a cold gas.
alcohol in alcoholic drinks.
Remember and understand Apply and analyse Figure 2.31 Train tracks
1 Draw a diagram similar to that shown 5 What precautions are taken with would buckle in the
in Figure 2.32. Add labels to show the railway tracks and bridges to ensure heat without tiny gaps
energy changes between states. that they do not buckle and bend on a between them.
Figure 2.32
PARTICLE MODEL 41
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11 Many people have ideas they think will
a strength explain observations and events in science.
b hardness For an idea to become a theory, it must be
able to explain a range of observations. The
c viscosity
idea must also be supported by evidence
e density PL
d compressibility
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You can use labelled diagrams to
improve your answers. obtaining medical-grade oxygen
and nitrogen from the air; how
a Water left in an open bottle will
the energy changes that occur
gradually evaporate and, if the
during evaporation of water and
temperature of the water increases,
the water will evaporate more
quickly.
b Mercury is a unique substance
because it is the only metal that is
liquid at room temperature, and
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of water vapour into rain affect
thunderstorms and cyclones.
both HDPE and LDPE are the same, hemispheres. Two opposing teams
suggest how the structure of the of eight horses, working like a
two substances would be different. tug-of-war, could not pull the
d When you heat a piece of polythene hemispheres apart.
it will melt. While it is liquid, it can
be formed into a different shape
and when it cools the polythene will
stay in this new shape.
e We can see steam, but we cannot
see water vapour.
PARTICLE MODEL 43
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types of atoms bonded together, e.g. water tiny particles
compressibility physical property
ability of a substance to be compressed can be measured or observed without
(squashed); gases can be compressed but changing a substance into something else,
diffusion PL
solids and liquids cannot