Smart Guess & Test Papers

Student Name ______________________ Father Name ______________________ Roll Number _______

Class: 1st /year - Chemistry Marks : ___________ Exam Format : www.notespk.com_Nauman Sadaf
Time : Practice MCQs | Date _________________ Examiner Sig __________ Chapter#: 1, 2, 3, 4, 5, 6, 7, 8,
9, 10, 11

MCQ's S/Q L/Q Total

Objective Type

1. Encircle the Correct Option.

1) Isotopes differ in

a) Properties Which b) Arrangement of electrons in c) Chemical properties d) The extent to which they may be
depends upon mass orbitals effected in electromagnetic field

2) 27 g of A1 will react completely with how much mass of O2 to produce Al2O3.

a) 8 g of oxygen b) 16 g of oxygen c) 32 g of oxygen d) 24 g of oxygen
3) A limiting reactant is the one which
a) Is taken in lesser quantity in b) Is taken in lesser quantity in c) Gives the maximum amount d) Gives the minimum amount
grams as compared to other volume as compared to the of the product which is of the product under consideration.
reactants. other reactants. required.

4) Isotopes differ in

a) Properties which depend b) Arrangement of electrons in c) Chemical properties d) The extent to which they may be
upon mass orbitals affected in electromagnetic field

5) The number of Isotopes of Gold ( Au ) is

a) 1 b) 3 c) 7 d) 11

6) The number of natural Isotopes is

a) 280 b) 150 c) 300 d) 400

7) Isotopes differ in
a) Number of atoms b) Number of Ptoton c) Number of electron d) Number of neutron
8) Which of the following statement is not true.
a) Isotopes with even atomic b) Isotopes with odd atomic c) Isotopes with even atomic d) Isotopes with even atomic
masses are comparatively masses are comparatively masses and even atomic masses and oss atomic numbers
abundaat abundant numbers are comparatively are comparatively abundant
abundant

9) Solvent extraction is an equilibrium process and it is controlled by.

a) Law of mass action b) Distribution law c) The amount of solute d) The amount of solvent used

10) Solvent extraction method is a particularly useful technique for separation when the product to be separated is:
a) Non-volatile or thermally b) Non-volatile or thermally c) Volatile or thermally stable d) Volatile or thermally
unstable stable unstable

11) The comparative rates at which the solutes move in paper chromatography, depend on:
a) The size of paper b) Temperature of the experiment c) R values Of solutes d) Size of the chromatographic tank
used

12) The number of isotopes of calcium is

a) Six b) Seven c) Five d) Nine

13) Silver has ________ natural isotopes.

a) Nine b) Two c) Eleven d) Sixteen

14) Silver has _______ isotopes.

a) Nine b) Ten c) Eleven d) Sixteen
15) What is the maximum mass of chromium that can be extracted from 76g of Cr2O3 ?
a) 48g b) 52g c) 104g d) 152g

16) Which of the following has highest mass at S.T.P ?

a) 6.02 × 1022 molecules of CO2 b) 2 moles of CH4 c) 0.1 g mole of N2O d) 22.4 dm3 of CO2 at .
S.T.P.

17) The number of atoms present in 0.5 moles of Na is

 a) 1.0 × 1023 b) 6.02 × 1023 c) 2.04 × 1023 d) 3.01 × 1023
18) The volume occupied by 16g of CH4 at S.T.P.
a) 224.14 dm3 b) 22.414 dm3 c) 1.12 dm3 d) 2.24 dm3

19) The volume occupied by 1.6 g of O2 at S.T.P.

a) 24.4 dm3 b) 2.24 dm3 c) 1.12 dm3 d) 112 dm3

20) The volume occupied by 1.4g of N2 at S.T.P is

a) 24.4 dm3 b) 22.4 dm3 c) 1.12 dm3 d) 112 dm3

21) What are the number of moles of hydrogen atom in 3.2g of CH4 ? ( Relative atomic mass C = 12 )
a) 0.2 b) 0.4 c) 0.6 d) 0.8
22) One mole of water contains .
a) 81 g water b) 6.02 × 1023 atoms c) 6.02 × 1023 inons d) 6.02 × 1023 molecules
23) What is the ratio of volume of 2g of H2 to the volume of 16g CH4 both volumes are at STP
a) 1:8 b) 1:2 c) 1:1 d) 2:1

24) Number of moles in 100g of KClO3 .

a) 0.76 b) 0.56 c) 0.014 d) 0.816
25) Stoichiometry is a branch of ______
a) Physics b) Chemistry c) Biology d) English

26) Stoichiometry tells us the ______ relationship between reactants and products .
a) Qualitative b) Quantitative c) Both A & B d) None of these

27) In mass mole relationship if we are given with mass of substance the we can calculate _________ of other substance .
a) Mass b) No. of electron c) Moles d) None of these

28) In Mass-volume relationship if we are given with mass of one substance we can calculate ________ of other substance .
a) Mole b) Volume c) Both A & B d) None of these

29) In stoichiometric calculate all the reactants must converted into

a) Products b) Reactants c) Both A & B d) Molar mass

30) The reactant which consumes earlier and gives least quantity of product is called.
a) Reactant b) Limiting reactant c) Stoichiometryd d) Stoichiometric amount

31) A limiting reactant is the one which

a) Is taken is lesser quantity to b) Is taken is lesser quantity in c) Gives the maximum amount of d) Gives the minimum
the amount in gram required volume as per its required the product required amount of the required product

32) The amount of products obtained in a chemical reaction is called _______ yield of that reaction .
a) Required b) Low c) High d) Actual
33) The amount of products calculated from balanced chemical equation represents .
a) Actual yield b) Theoretical yield c) Both A & B d) None of these

34) In most of the reactions the actual yield is ________ than theoretical yield .
a) More b) Less c) None d) Expected yield

35) One of the following substances does not undergo sublimation .

a) KMnO4 b) Naphthalene c) NH4Cl d) Iodine

36) Which one of the following compound is purified by sublimation.

a) Benzoic acid b) SiO2 c) CS2 d) Nal

37) Direct conversion of solid into its vapour is called

a) Crystallization b) Sublimation c) Vapourization d) Distribution

38) Which of the following pairs can be separated by sublimation?

a) Sand and NaCl b) Sand and broken pieces of c) Sand and naphthalene d) NaCl and KCl
glass

39) Which of the following substances is a sublime material ?

a) Potash alum b) NaCl c) Acetic acid d) Benzoic acid
40) Which one is not sublimable in laborarory ?
a) NH4Cl b) Benzonic Acid c) Naphthalene d) AlCl3
41) In _______ technique a solute distribute between two immiscible liquids .
a) Crystallizzation b) Solvent extraction c) Filtration d) Distillation
42) Solvent extraction is an equilibrium process and it is controlled by
a) Law of mass action b) Distribution law c) The amount of solvent used d) The amount of solute

43) Solvent extraction method is particularly useful technique for separation when the product to be separated is
a) Non-volatile or thermally b) Non-volatile or thermally c) Volatile or thermally stable d) Volatile or thermally
unstabel stable unstable

44) Equilibrium is established during the process of solvent extraction and the phenomenon obeys

a) Distribution law b) Law of mass action c) Le-chatelier's principle d) Law of chemical equilibrium

45) The iodine present in water can be separated by which one of the following techniques ?
a) Sublimation b) Chromatography c) Filtration d) Solvent extraction
46) If Solvent front is 10 cm and distance travelled by solute is 1.2 cm , what is its Rf value ?
a) 0.83 b) 0.12 c) 1.2 d) 8.3

47) The most common Solvent used for solvent extraction is

a) Water b) Ethanol c) Ether d) Carbon tetrachloride

48) Iodine is soluble in

a) Water b) CCl4 c) Water and CCl4 d) NaCl

49) Which of the following techniques can separate organic compound from aqueous solution ?
a) Distillation b) Chromatograph c) Filtration d) Solvent extraction
50) Solvent extraction is a process.
a) Exothermic b) Endothermic c) Equilibrium d) Non-equilibrium

51) Chromatography in which the stationary phase is a solid is classified as.

a) Partition Chromatography b) Adsorption Chromatography c) Gas Chromatography d) Thin layer

52) The rate at which the solute moves in paper Chromatography depends upon
a) Distribution coefficient b) Boiling point of the solvent c) Distribution law d) Low partial pressures

53) In paper Chromatography the point at which the solvent rises the maximum extent is called
a) Eluent b) Chromatogram c) Solvent front d) Base line

54) Chromatography is the process which involves the distribution of a solute between
a) Two mobile phases b) Two stationary phases and c) Two stationary phases d) A stationary phase and
two mobile phases mobile phase

55) In paper Chromatography mobile phase is

a) Gas b) Liquid c) Solid d) Gas + Liquid

56) Which of the following technique is useful in organic synthesis for separation , purification and identification of products ?
a) Sublimation b) Filtration c) Chromatography d) Solvent extraction

57) The pattern of inks formed on paper in Chromatography is called

a) Chromatophore b) Chromatogram c) Chromatograph d) Chromatograph
and Chromatogram

58) The locating agent which can not be used to identify colorless components in Chromatography is
a) H2S b) Rubeanic Acid c) Ninhydrim d) HCl

59) The natural plasma is extremely hot and it has minimum temperature.
a) 20000C b) 20,0000C c) 30000C d) 30,0000C

60) The temperature of natural plasma is about

a) 20,0000C b) 10,0000C c) 50,0000C d) 10000C

61) At high temperature the gas ionizes and generates free electrons giving a mixture of gas molecules , ions and free electrons . This collection
is called
a) Mixture of gas b) Highly discordered collection of c) Gaseous phase substance d) Plasma
particles

62) Plasma consists of mixture of neutral particles , positive ions and

a) Protons b) Electrons c) Neutrons d) Positron

63) The free expansion of the gas from high pressure towards the low pressure causes.
a) Increase of temperature b) Greater number of collisions c) Decrease of temperature d) Decrease of velocities of gas
among the molecules molecules

64) Air is a mixture of gases . The molecules of the air are not settled down due to
a) Different molar masses b) Pressure of dust particles in c) Non-polar nature of gases d) Collision of gas molecules
the air
65) The highest temperature above which a gas cannot be liquefied , no matter how much the pressure is applied is known as
a) Boiling temperature b) Absolute zero c) Consulate temeprature d) Critical temperature
66) The relation used to calculate root mean square velocity of gases is

a) b) c)
d)

67) Behaviour of gas molecules can be understood from the kinetic equation of gases . This equation was given by clausius and equation is :
c)
b) d)
a)

68) According to Kinetic Molecular Theory , Kinetic energy of molecules increase when they are
a) Mixed with other melecules at b) Frozen to solid c) Melted from solid to d) Condensed to liquid
low temperature liquid

69) Kinetic theory was proposed by

a) Bernoulli b) Coulomb c) Maxwell d) Newton

70) Feeling uncomfortable breathing in un-pressurized cabin is due to

a) High pressure of CO2 b) Low pressure of O2 c) Low pressure of CO2 d) High pressure of O2

71) Partial pressure of O2 in the air is

a) 156 torr b) 157 torr c) 158 torr d) 159 torr
72) Partial pressure of oxygen in the lung is
a) 760 torr b) 320 torr c) 159 torr d) 116 torr
73) If 10g of a gas at one atmospheric pressure is cooled from 2730C to 00C at constant volume , its pressure would become .
a) 1 atm b) 273 atm
c) atm d) atm

74) Which pair of gases do not obey Dalton's law of partial pressure ?
a) H2 and O2 b) N2 and O2 c) H2 and O2 d) NH3 and HCl
75) The respiration process in the animals depends on the difference of
a) Osmotic pressure b) Partial pressure c) Vapour pressure d) Atmospheric pressure

76) 4 gm of H2 gas at STP occupies volume of

a) 60 lit b) 44.8 lit c) 35.5 lit d) 22.4 lit

77) Volume occupied by one mole of a gas at STP is called

a) Normal volume b) Molar volume c) Standard volume d) Mean volume

78) A certain mass of a gas occupies a volume of 2 dm3 at STP . Keeping the pressure constant , at what temperature would the gas occupies a
volume of 4 dm3 ?
a) 3000C b) 546 K c) 500K d) 1000C

79) 1 dm3 of O2 at STP contains

a) 6.02 × 1023 molecules b) 0.602 × 1023 molecules c) 0.602 × 1022 molecules d)

80) Normal temperature and pressure ( STP ) of gas refers to

a) 273 K and 76 mm of Hg b) 273 K and 760 mm of Hg c) 2730 C and 760 mm of Hg d) 2730 C and 76 mm of Hg

81) The molar volume of CO2 is maximum at

a) STP ( 00C and 1 atm ) b) 00C and 1 atm c) 1270C and 1 atm d) 2730C and 2 atm

82) Which of the following will have the same number of molecules at STP ?

a) 280 cm3 of CO2 and 280 b) 44 g of CO2 and 11.2 dm3 of c) 1 dm3 of O2 and 32 g of O2 d) 28 g of N2 and 5 dm3 of O2
cm3 of N2O CO

83) At 1000C a gas has 1 atm . Pressure and 10 dm3 volume . Its volume at S.T.P would be
a) 10 dm3 b) less then 10 dm3 c) More than dm3 d) Cannot be predicted

84) The number of molecules in one dm3 of water is close to

a) 55.6 × 6.02 × 1023
b) c) d)

85) One dm3 of H2 and one dm3 have same number of molecules at STP , their respective masses are
a) 0.1 g and 4.3 g b) 2 g and 32 g c) 0.0899 g and 1.4384 g d) 4 g and 16 g
86) For an ideal gas at a constant T at which pressure its volume doubles , when the initial pressure is 2 atm.
a) 4 atm b) 101325 Nm-2 c) 1 torr d) 101325 torr

87) The value of the general gas constant R in SI units is

a) 8.3143 kj.K-1 .mol-1 b) 0.0821 dm3 .torr.K-1 .mol-1 c) 62.4 dm3 .torr.K-1 .mol-1 d) 8.3143 Nm.K-1 .mol-1
88) An ideal gas is one which
a) Shows deviation from gas b) Has attraction between c) Has significant volume of the d) Obeys gas laws at all
laws molecules molecules conditions

89) The value of the general gas constant R in SI units is

a) 8.3143 kj.K-1 .mole-1 b) 0.00821 dm3.atmK-1 .mole-1 c) 8.3143 JK-1 .mole-1 d) 62.4 dm3torrK-1 .mole-1

90) More ideal gas at room temperature is

a) CO2 b) NH3 c) SO2 d) N2
91) For an ideal gas , the compressibility factor is equal to
a) 0.5 b) 1 c) 1.5 d) 2

92) A real gas obeying Van der Wall's equation will resemble ideal gas if
a) Both " a " and " b " are large b) " a " is small and " b " is large c) Both " a " and " b " are d) " a " is large and " b " is small
small

93) CH4 gas is maintained at 00C and 1 atm pressure . Its density is 0.714 g/dm3 . What is its density at 0.5 atm and 00C ?
a) 0.714 dm-3 b) 1.428 dm-3 c) 0.35 dm-3 d) 7.14 dm-3

94) Gas equation is derived by combining .

a) Avogadro's and Charls' law b) Avogadro's and Boyle's law c) Avogadro's , Charls' and d) Charls' law and Boyle's
Boyle's law law

95) The formula for density of a gas at a given temperature and pressure is

a) b) c) d)

96) The density of CH4 at 2 atm pressure at 270C is

a) 26 g dm3 b) 0.26 g dm3 c) 1.3 g dm-3 d) 0.13 g dm-3

97) Mathematical expression of compressibility factor is

a) b) c) d)

98) Body temperature of a normal person is

a) 97.60F b) 96.80F c) 98.40F d) 98.60F
99) The product PV of a gas is a unit of
a) Force b) Entropy c) Work d) Impulse

100) Which of the following relationships is incorrect ?

a) K = C0 + 273
b) c) d)

101) The highest temperature at which a substance can exist as liquid state at its critical pressure is
a) Absolute zero b) Critical temperature c) Consulate temperature d) Tranisition temperature

102) A graph obtained from Boyle's law by plotting P versus V at constant T is.
a) A straight line b) A curve with minimum c) A curve with maximum d) A parabolic curve called
isotherm

103) The gas law giving relationship between volume and temperature of gas is
a) Dalton's law b) Charl's law c) Graham's law d) Boyle's law

104) Pressure remaining constant , at which temperature the volume of a gas will becomes twice of what it is at 00C ?
a) 5460 C b) 2000 C c) 546 K d) 273 K

105) Equal masses of methane and oxygen are mixed in an empty container at 250C. The fraction of total pressure exerted by oxygen is.

a) b) c) d)

106) The isotherm of CO2 changes the position in the graph by changing the temperature in such a way that
a) The curve comes closer to b) The curve goes from the c) The curve are converted into d) The curve becomes
the axis by increasing pressure axis by increasing the straight line at high temperature discontinuous at 31.50C
temperature

107) The graph between pressure and inverse of volume for a given mass of a gas at constant temperature is
 a) Straight line parallel to x-axis b) Straight line passing c) Straight line parallel to y-axis d) The curve showing the
through the origin maximum

108) If a graph is plotted between temperature on x-axis and volume of the one mole of the gas on y-axis at constant pressure then a straight line
is obtained which hypothetically cuts the temperature axis at
a) 00C b) -273.160C c) -273.16 K d) 300 K

109) Dipole-dipole interaction are present in the

a) Atoms of the He gas b) Molecules of solid iodine c) Molecules of CCl4 d) Molecules of NH3

110) Which of the given has hydrogen bonding

a) CH3 b) CCl4 c) NH3 d) NaCl

111) Which of the following liquid has highest boiling point.

a) HCl b) HBr c) H2O d) Br2

112) Dipole-induced dipole forces are also called

a) London Dispersion Forces b) Hydrogen boinding c) Debye Forces d) Huckel Forces

113) The strongest acid among Halogen acids is

a) HCl b) HBr c) Hl d) HF

114) Which of the hydrogen halides has the highest percentage of ionic character ?
a) HCl b) HBr c) HF d) Hl

115) H-bonding is maximum

a) Ethanol b) Benzene c) Diethyl ether d) Water
116) Density of ice is maximum at 40C due to

a) Empty spaces in structure b) Lage bond lengths c) Tetrahedral shape of crystal if d) Large bond angles
of ice ice

117) London dispersion forces are the only forces present among the
a) Molecules of water in liquid b) Atoms of helium in gaseous c) Molecules of solid iodine d) Molecules of hydrogen
state state at high temperature chloride gas

118) Acetone and chloroform are soluble in each other due to

a) Intermolecular hydrogen b) Instantaneous dipoles c) Dipole-dipole interaction d) Ion dipole forces
bonding

119) When water freezes at 00C , its density decreases due to

a) Cubic structure of ice b) Empty spaces present in c) Change of bond length d) Change of bond angles
the structure of ice

120) The repulsions of electronic clouds of molecules are responsible for the attractive forces among the molecules . These forces are
a) Dipole-induced dipole forces b) Instantaneous dipole-induced c) Ion-dipole forces d) Dipole-dipole forces
dipole force

121) The force which are present between the ions and the polar molecular of the solvent are
a) Dipole-induced dipole forces b) Ion-dipole forces c) Dipole-dipole forces d) London dispersion forces

122) Hydrogen bonding is extensively present in proteins between

a) Nitrogen and hydrogen atoms b) Carbon and hydrogen atoms c) Oxygen and hydrogen d) Nitrogen and oxygen
atoms

123) Ice floats on water because

a) The hydrogen bonding in ice b) Empty spaces are present c) Not empty spaces in ice d) Ice has two-dimensional
is stronger than that in water in ice structure

124) The long chains of amino acids are coiled about one another into a spiral by
a) Ionic bond b) Hydrogen bonding c) Van der Waal's forces d) Overlapping of orbitals

125) The weakest intermolecular forces present in a liquid may be

a) Dipole-induced dipole force b) Dipole-dipole forces c) London Dispersion forces d) Electrostatic forces between
ions in ionic solid

126) Polarizability is responsible for the intermolecular forces and it

a) Increases down the group b) Decrease down the group c) Almost remains the same d) Increases along a period

127) Van-der Waal's forces are weak intermolecular forces , they include
a) Dipole-Dipole forces only b) Ion-Dipole forces only c) Dipole-induced dipole forces d) All of the above
only

128) The London forces becomes stronger if

 a) Size of atom is smaller b) Density of molecules is large c) Number of atoms in a d) Molecules are homo-atomic
molecule are large

129) Which of the following forces exist in noble gases ?

a) Dipole-dipole forces b) Dipole-induced Dipole c) Iondon dispersion d) Hydrogen bonding
forces

130) Which of the following is not a type of liquid crystal ?

a) Enteric b) Cholesteric c) Smectic d) Nematic

131) Liquid crystals are used to find the point of _______ in electrical circuits.
a) Potential difference b) Potential failure c) Both A & B d) None of these

132) Liquid crystals can diffract _________

a) Light b) Heat c) Both A & B d) None of these

133) In chromatography liquid crystal are used as_______

a) Solute b) Solvent c) Substrate d) None of these

134) The transition temperature of KNO3 is

a) 13.20C b) 95.50C c) 1280C d) 32.020C

135) The solid which has no definite crystalline shape

a) Sugar b) Salt c) Glass d) Dry ice

136) Amorphous solids

a) Have sharp points b) Undergo clean cleavage c) Have perfect arrangement of d) Can possess small regions of
when cut with knife atoms orderly arrangement of atoms

137) Isomorphism is present in K2 SO4 and K2CrO4 . These two compounds

a) Show same physical and b) 100% equal ionic character c) Have difference ration of the d) The shapes of both So2-
chemical properties atoms in them 4 and CrO-2 4

138) The allotropes are those solids , which have

a) Same physical properties b) Same physical but different c) Same chemical properties d) Same physical & chemical
chemical properties properties

139) Which of the following substances is amorphous in nature ?

a) Sugar b) Graphite c) KCl d) Plastic
140) Plastics are amorphous solids and
a) Have sharp melting point b) Undergo clean cleavage c) Do not undergo clean d) Possess orderly arrangement
when cut with knife cleavage over long distances

141) Which among the following will show anisotropy ?

a) Wood b) Paper c) Glass d) BaCl2
142) The existence of an element in more than one form is called
a) Isomorphism b) Allotropy c) Polymorphism d) Symmetry

143) Variation of a physical property in a crystal in different directions is called

a) Absence of symmetry b) Anisotropy c) Isomorphism d) Polymorphism

144) The crystals of Na2SO4 and Na2SeO4 should be

a) Isomorphs of each other b) Allotropes c) Polymorphs of each other d) Isomorphs and allotropes of
each other

145) The pure Crystalline substance on heating become turbid liquid. On further heating turbidity disappears . The substance is
a) Allotropic ctystal b) Isomeric crystal c) Liquid crystal d) Isomorphic crystal

146) The crystals which show different physical properties from different directions is called
a) Symmetry b) Polymorphism c) Habit of crystal d) Anisotropy
147) Crystals can be classified into

a) 7 crystal systems b) 4 crystal systems c) 3 crystal systems d) 14 crystal systems

148) Most crystals show good cleavage because their atoms , ions and molecules are
a) Arranged in planes b) Spherically symmetrical c) Weakly bounded together d) Strongly bounded together

149) The number of Cl- ions per unit cell of NaCl are
a) 6 b) 4 c) 2 d) 8

150) The Cl- ions present at the corner of the unit cell and NaCl crystal , contributes
a) 1
b) c) d)
151) NaCl has face centered cubic structure . The Na + ion at the faces of the unit cell is shared by

a) 2 unit cells b) 4 unit cells c) 8 unit cells d) Only one unit cell

152) The number of Na+ ions which surround each Cl- ion in the NaCl crystal lattice is
a) 8 b) 12 c) 6 d) 4

153) Transition temperature of S8 ( monoclinic ) S8 ( Rhomic ) is

a) 13.20C b) 95.50C c) 1280C d) 1100C

154) Which of the following metals shows hexagonal geometry ?

a) Cu b) Ag c) Zn d) Na

155) Graphite belongs to the crystal system ?

a) Hexagonal b) Monoclinic c) Cubic d) Tetragonal

156) Which of the following crystal systems represent the structure of sugar.
a) Triclinic b) Monoclinic c) Cubic d) Tetragonal

157) Which crystal system is found in AgNO3 ?

a) Orthorhombic and b) Cubic and tetragonal c) Cubic and orthorhombic d) Monoclinic and hexagonal
rhombohedral

158) The structure of NaCl crystal is

a) Body centered cubic lattice b) Square planar c) Face centered cubic lattice d) Octahedral

159) Mass of electron is

a) 9.1095 × 1031 kg b) 9.1095 × 10-31 kg c) 9.1095 × 10-27 kg d) 9.1095 × 10-31 g

160) The e/m value for the positive rays is maximum for

a) Hydrogen b) Helium c) Oxygen d) Nitrogen

161) Positive rays were discovered by

a) Goldstein b) Rutherford c) J.J Thomson d) William Crookes

162) Name the electrons is given by

a) William Crooks b) J.J Thomson c) Stoney d) Chadwick

163) The maximum number of unpaired electrons are present in

a) Fe = 26 b) Ni = 28 c) Cr = 24 d) Na = 11

164) Neutron was discovered by

a) Rutherford b) Bohr c) Goldstein d) James Chadwick
165) The mass of neutron is greater than electron by
a) 2000 times b) 300 times c) 1840 times d) 1580 times

166) The nature of positive rays depends upon

a) Nature of electrode b) Nature of residual gas c) Nature of discharge tube d) None of Above

167) Cathode rays are material particles having definite

a) Time period & amplitude b) Wavelength c) Frequency & amplitude d) Mass
168) Charge on an electron is

a) 1.602 × 10-19C b) 9.1 × 10-34C c) 1.7588 × 1011C d) 6.625 × 10-34C

169) In the nuclear reaction Cu29 66 66 30Zn + x . The " x " is

a) Electron b) Proton c) Neutron d) -radiation

170) The mass of neutron is

a) 9.1095 × 10-31 kg b) 1.675 × 10-27 kg c) 2.67 × 10-27 kg d) 5.35 × 10-27 kg

171) When - particles is bombarded over beryllium _______ is produced.

a) Positron b) Proton c) Electron d) Neutron
172) The e / m ratio of cathode rays is ________ to e / m ratio of positive rays .
a) Smaller b) Greater c) Equal d) Opposite

173) Particle having the longest wavelength

a) Electron b) Proton c) Neutron d) -particle

174) Rutherford's experiment of scattering particles showed for 1st time that an atom has
a) Electron b) Proton c) Nucleus d) Neutrons

175) Rutherford's alpha particle scattering experiment eventually led to the conclusion that
 a) Mass and Energy are related b) Electrons occupy space c) Neutrons are buried deep in d) The electrons are present in
around the nucleus the nucleus the nucleus

176) The average distance of an electron from the nucleus of an atom is

a) 10-20 cm b) 10-12 cm c) 10-8 cm d) 10-4 cm

177) Rutherford's model of atom failed because

a) The atom did not have a b) It did not account for the c) It did not account for the d) There is actually no space
nucleus and electron attraction between proton and stability of the atom between the nucleus and the
neutrons electrons

178) The probability of finding the electron outside the nucleus is at a distance of
a) 0.83 m b) 0.053 m c) 0.053 nm d) 0.083 m

179) In the ground state of an atom , the electron is present

a) In the nucleus b) Nearest to the nucleus c) In the second shell d) Farthest from the nucleus

180) 10A = __________ m

a) 10-10 b) 10-11 c) 10-12 d) 10-13

181) A quantum of light energy is called as

a) Proton b) Electron c) Neutron d) Photon
182) Which of the following gives correct relation.

a) b) c) d)

183) Who proposed the quantum theory

a) J.J. Thomson b) Max planck c) Rutherford d) Bohar

184) According to Bohr's model , the radius of the second orbit is

a) 2 0A b) 2.1 0A c) 2.11 × 10-11 m d) 2.11 × 10-12 m

185) The value of radius of first Bohr's orbit of Hydrogen atom is

a) 0.229 × 10-10m b) 0.32 × 10-10m c) 0.429 × 10-10m d) 0.529 × 10-10m
186) Velocity of proton is
a) Dependent on its wavelength b) Dependent on its source c) Independent of its d) Equal to square of amplitude
wavelength

187) The correct expression derived for the energy of an electron in the nth energy level is

a) b) c) d)

188) Bohr's model can explain

a) Spectrum of " H " atom only b) Spectrum of atom or ion c) Spectrum of H2 molecule d) Spectrum of multi electronic
containing one e- only atoms

189) Bohr's model of atom is contradicted by

a) Planck quantum theory b) Heisenberg's uncertainty c) Pauli's exclusion principle d) Hund's rule
principle

190) The energy of an electron at infinite orbital is

a) Positive b) Zero c) Negative d) Very high

191) Which of the following is correct for energy when we go from lower to higher orbits in case of Bohr's atomic model
a) E2 - E1 < E3 - E2 > E3 - E4 > b) E3 - E2 < E2 - E1 > E4 - E3 > c) E2 - E1 < E3 - E2 > E4 - E3 d) E3 - E4 < E3 - E2 > E4 - E3 >
.............. .............. > .............. ..............

192) The lines of the Balmer series lie in the visible region of the spectrum , but the limiting line , in the series lies in
a) Visible region b) I.R region c) X-Ray region d) U.V. region
193) Spectrum of lines of pfund series of H-atom are produced when electron jumps down to
a) Fifth orbit b) Third orbit c) Second orbit d) First orbit

194) The range of visible region of spectrum is form

a) 300 - 750 nm b) 400 - 750 nm c) 300 - 650 nm d) 400 - 850 nm

195) The spectral line obtained when an e- jumps from n = 6 to n = 3 belongs to which series ?
a) Lyman series b) Paschen series c) Balmer series d) Pfund series

196) Splitting of spectral line when atoms are subjected to strong electric field is
a) Zeeman effect b) Stark effect c) Photoelectric effct d) Compton effect

197) Lyman series is obtained when electron in an atom jumps from higher energy level to
 a) Ground level b) 2nd level c) 3rd level d) 4th level

198) Splitting of specteal line of hydrogen atom under the influence of magnetic field is called
a) Photoelectric effect b) Zeeman effect c) Compton effect d) Stark effect

199) The spectrum of radiation from which particular radiation has been absorbed after passing through absorbing substance is called
a) Continuous spectrum b) Line absorption spectrum c) Line emission spectrum d) Band spectrum

200) Spectrum of sodium contains two lines in the region

a) Violet region b) Red region c) Greed region d) Yellow region
201) De-Broglie equation is represented by

a) b) c) d)

202) Which is correct relation ?

a) b) d)
c)

203) Wave number has the unit

a) m b) cm c) m-1 d) No unit

204) When 5th orbital is completed then entering electron goes into
a) 6s b) 6p c) 6d d) 6f

205) An orbital which is spherically symmetrical is

a) s-orbital b) p-orbital c) d-orbital d) f-orbital

206) The sub-shell which has highest energy is

a) 4d b) 5d c) 6s d) 6p
207) What is the value of ( n + l ) for the 3d sub-shell ?
a) 2 b) 1 c) 5 d) 3

208) Azimuthal quantum number gives us the information about

a) Size of orbital b) Shape of orbital c) Structure of orbital d) Spin of electron

209) The number of f-orbitals associated with n = 5

a) 5 b) 6 c) 7 d) 8

210) Concept of Elliptical orbits in an atom was proposed by

a) Bohr b) Heisenberg c) Schrodinger d) Sommerfeld
211) Formula for calculating the number of electrons in a sub-shell is
a) 2n2 b) 2 ( 2l + 1 ) c) 2n2+1 d) 2 ( 2l + 2 )

212) Which orbital lies upon the axis?

a) dz2 b) dxy c) dyz d) dxz

213) Which pair of orbitals is degenerate pair ?

a) sp3 . sp3 b) sp3 . sp2 c) sp . sp2 d) sp3 . sp

214) If value of Azimuthal quantum number is 3 , the value of " m " will be
a) +3, +2, +1, 0 , -1, -2, -3 b) +2, +1, 0 , -1, -2 c) 0, 1, 2, 3 d) -1 , 0 , + 1

215) Heisenberg's uncertainty principle is not applicable to

a) Electron b) Proton c) Neutron d) A dust particle
216) Which atomic orbital has lowest energy ?

a) 4f b) 5d c) 6p d) 7s

217) The H-H bond energy in kJ mol-1 is

a) 346 b) 436 c) 463 d) 336

218) Force of attraction between the atoms are

a) Hydrogen bonding b) London forces c) Debye forces d) Ion dipole forces

219) An ionic compound will dissolve in water only if

a) Hydration Energy < Lattice b) Lattice energy < Hydration c) Bond energy in low d) Bond energy in high
energy Energy

220) The number of lone pair of electrons in ammonium ion is

a) One b) Three c) Two d) Zero

221) The bond distance between H - H is

 a) 436.45 pm b) 75.4 pm c) 154 pm d) 133 pm

222) The bond formation energy of a compound is

a) Less than bond dissociation b) Equal to bond dissociation c) Greater than bond d) Inversely proportional to bond
energy energy dissociation energy dissociation energy

223) Formation of a chemical bond takes place when

a) Energy is absorbed b) Forces of repulsion overcome c) Force of attraction are d) Forces of attraction overcome
forces of attraction equal to force of repulsion forces of repulsion

224) Bond formed by mutual sharing of electrons is called

a) Ionic bond b) Co-ordinate covalent bond c) Covalent bond d) Metallic bond

225) The geometry of ethane is

a) Trigonal planar b) Linear c) V-shaped d) Tetrahedral
226) Which of the following has smallest size ?
a) Be b) B c) O d) F
227) One of the best technique used to measure atomic radii is
a) Spectrometry b) Chromatography c) Potentiometry d) X-ray diffraction
228) The atomic radii decrease along the period due to
a) Increase in nuclear b) Increase in electropositivity c) Increase in atomic mass d) Increase in electron affinity
charge

229) The Increase in atomic radii in a group is due to

a) Increase in atomic mass b) Increase in electropositivity c) Increase in number of d) Increase in polarizability
shells

230) An Angstrom is the unit of

a) Time b) Length c) Mass d) Frequency

231) An ionic compound A+B- is most likely to be formed when

a) The ionization energy A is b) The ionization energy A is c) Both The ionization energy A d) Both The ionization energy A
high and electron affinity of B is low and electron affinity of B is is high and electron affinity of B is high and electron affinity of B
low high is high is low

232) Which element has highest ionization potential ?

a) Li b) Be c) B d) C

233) _______ element has highest value of electron affinity .

a) Fluorine b) Chlorine c) Bromine d) Iodine

234) The amount of energy released by absorbing electron in the valence shell is
a) Ionization energy b) Electronegativity c) Electron affinity d) Atomic radius

235) The most electronegativity atom is

a) N b) Cl c) O d) F
236) Tendency of an atom to attract the shared pair of electrons is called
a) Ionization Energy b) Electronegativity c) Electron Affinity d) Electropositivity

237) If the electronegativity difference between bonded atom is more than 0.5 but less than 1.7 , the bond will be
a) Ionic b) Non Polar covalent c) Polar covalent d) Co-ordinate covalnet

238) Shielding effect of the inner electrons is responsible for

a) Increasing electron affinity b) Increasing Ionization energy c) Decreasing Ionization d) Electro Negativity
energy

239) Which one of the following is a vector quantity ?

a) Ionization energy b) Electron affinity c) Dipole moment d) Electronegativity

240) Which molecule has Sp2 hydridization ?

a) CH4 b) C2H4 c) C2H2 d) C2H6

241) Which of the following has linear structure ?

a) CO2 b) NH3 c) CH4 d) H2O

242) The shape of SnCl2 molecule is

a) Linear b) Angular c) Trigonal planar d) Tetrahedral

243) Which of the following has bond angle of 1200 ?

a) BF3 b) NH3 c) CH4 d) BeCl3

244) The carbon atom in C2H4 is

 a) Sp3-hydridized b) Sp2-hydridized c) Sp-hydridized d) Not -hydridized

245) Geometry of SO2 molecule is

a) Linear b) Angular c) Tetrahedral d) Trigonal pyramidla

246) ______ is not paramagnetic

a) O2 -2 b) O2 c) N2 -2 d) None of these

247) In ethyne molecule the number and nature of bonds are

a) One sigma two pi b) Two sigma one pi c) Three sigma two pi d) Two sigma two pi

248) The bond order of N2 molecule is

a) 1 b) 2 c) 3 d) 4

249) The type of hydridization in BeCl2

a) sp3 b) sp2 c) sp d) dsp2

250) The strongest bond is

a) C-C b) C=C c) C C d) All are equally strong

251) sp3 Hydridization is associated with structure

a) Linear b) Trigonal c) Tetrahedral d) Octahedral

252) Highest bond order is found in

a) O2 b) O2 -1 c) O2 -2 d) O2 +2
253) Covalent bonds are
a) Rigid and directional b) Rigid and non directional c) Non Rigid and directional d) Non Rigid and non
directional

254) What is molecular geometry of SO4 -2 ion ?

a) Tetrahedral b) Trigonal planer c) Trigonal pyramidal d) Linear

255) Which one is not AB4 type molecule according to VSEPR theory ?
a) SO2 b) SO4 2- c) PH3 d) H2S

256) The structure of Ammonia is

a) Linear b) Bipyramidal c) Tetragonal d) Triangular pyramidal
257) The number of fundamental ways of transferring energy into or out of system is
a) One b) Two c) Three d) Four

258) _______ is not state function.

a) Pressure b) Volume c) Temperature d) Heat

259) If an endothermic reaction is allowed to take place very rapidly in the air , the temperature of the surrounding air .
a) First increases then decreases b) Decrease c) Increases d) Remains unchanged

260) The condition of standard state of a substance can be represented as

a) 700 mm of Hg and 00C b) 1 atm and 00C c) 2 atm and 00C d) 1 atm and 298 K
261) The internal energy of a system is equal to
a) P.E. of the particles b) Kinetic energy of the particles c) Enthalpy d) Sum of K.E and P.E
262) Which of the following statement is contray to the first law of thermodynamics ?
a) Energy can neither be b) One from of energy can be c) Continuous production of d) In an adiabatic process , the
created nor be destroyed transferred into an equivalent mechanical work without work done is independent of its
amount of other kind of energy supplying an equivalent amount path
of heat is possible

263) Which of the following is the mathematical expression of First Law of Thermodynamics ?
a) q = m.S. T b) E = q - PVV c) H= E+P V d) H= E

264) Which of the following is the application of Law of conservation of energy ?

a) 1st Law of Thermodynamics b) Born Haber cycle c) Hess's Law d) All of the above
265) The measurement of enthalpy change at standard condition means that we should manage the measurement at.
a) 240C at 1 atm b) 250C at 1 atm c) 00C at 1 atm d) 1000C at 1 atm

266) The amount of heat absorbed when one mole of gaseous atoms are formed from the element is called enthalpy of

a) Formation b) Reaction c) Combustion d) Atomization

267) The change in heat energy of a chemical reaction at constant temperature and pressure is called

a) Enthalpy change b) Heat of sublimation c) Bond energy d) Internal energy change

268) For the reaction NaOH + HCl NaCl + H2O , the change in enthalpy is called
 a) Heat of reaction b) Heat of neutralizaion c) Heat of formation d) Heat of combustion

269) Heat of combustion can be determined by

a) Glass calorimeter b) Copper calorimeter c) Bomb calorimeter d) Heat calorimeter

270) In bomb calorimeter the reactions are carried out at

a) Constant pressure b) Constant temperature c) Constant volume d) Constant enthalpy

271) Which of the following formulas is used to calculate the amount of heat change in a chemical reaction .
a) H= E+P V b) E= H+W c) q = m.S . T d) H= E

272) For a given reaction which description is correct ?

CH4 + 2O2 CO2 + 2H2O
a) Heat of oxidation b) Heat of combustion of c) Endothermic reaction d) Heat of Atomization
CH4

273) The heat of neutralization for a strong acid and a strong base is 57.kJ / mole . The heat of neutralization for the reaction of NaOH and
CH3COOH is
a) 5.7.kJ / mole b) Less than 57.kJ / mole c) 57.kJ / mole d) More than 57.kJ / mole

274) Standard enthalpies are measured at

a) 2730C b) 3730C c) 00C d) 298K
275) The Born-Haber cycle is the best application of law
a) Boyle's law b) Hess's law c) Dalton's law d) Graham law

276) The subject matter of thermochemistry is based upon

a) Hess's Law b) Law of sonseervation of energy c) Born Haber's cycle d) Law of mass action

277) Born Haber cycle is used to calculate the

a) Lattice energy b) Heat of reaction c) Enthalpy change d) Heat of Atomization

278) Catalyst used in preparation of NH3 from N2 and H2 is

a) Fe b) Ni c) Pt d) V2O5

279) The unit of equilibrium constant Kc for the reaction N2 + 3H2 2NH3
a) dm+6 mole-2 b) mole2 dm-6 c) mole dm-3 d) having no units

280) The unit of equilibrium constant Kc for the reaction H2 + I2 2Hl is

a) mole-1 dm3 b) mole-2 dm3 c) mole dm-1 d) None of these
281) Law of mass action was given by Guldberg and Waag in
a) 1909 b) 1906 c) 1846 d) 1864
282) The unit of Kc for reaction N2 + O2 2NO will be
a) mol/dm3 b) mol-1/dm3 c) mol-2/dm+6 d) No unit
283) ______ affects the value of Kc
a) Concertration b) Temperature c) Catalyst d) Pressure

284) When ionic product of a solution is greater than the solubility product at a particular temperature then the solution is said to be
a) Unsaturated b) Satrurated c) Very dilute d) Super saturate

285) If Kc of reaction is very large , it indicates that equilibrium occurs.

a) At a low product b) With the help of catalyst c) At a high product concentration d) With no forward reaction
concentration

286) For what value of Kc almost forward reaction is complete ?

a) Kc = 10-35 b) Kc = 1030 c) Kc = 2 d) Kc = zero

287) The rate of forward step in a reversible reaction

a) Increases during the reaction b) Becomes constant just after c) Decreases as the reaction d) Reaction same
the start of reaction proceeds

288) For a reversible reaction , if the concentration of a reactant is doubled , then value of equilibrium constant Kc is
a) Halved b) Doubled c) Not changed d) 1/3rd of the original value

289) In a gaseous reversible reaction in a closed container which is exothermic in nature , as increase in temperature changes .
a) Pressure of gases b) Kc ( Equilibrium constant ) c) Conc. Of both reactant and d) Conc. Of reactants only
product

290) The units of Kc for the reaction of ammonia synthesis are

a) mol-2dm6 b) mol-1dm6 c) mol-2dm3 d) mol-2dm2

291) The synthesis of Ammonia was developed by German chemist .

 a) Bohar b) Le-chaterlier c) F.Haber d) None of these

292) The process of synthesis of Ammonia was first used in

a) 1934 b) 1933 c) 1935 d) 1932

293) ____ is king of chemicals .

a) HNO3 b) H2SO4 c) H2O d) HCl

294) The most effective calalyst in contact process is

a) V2O5 b) Platinum c) Both A & B d) None of these

295) The ionization constant of pure water ( Kw ) at 250C is

a) 1.8 × 10-16 mole dm-3 b) 1.0 × 10-16 mole dm-3 c) 1.6 × 10-14 mole dm-3 d) 3 × 10-14 mole dm-3

296) The milk in nature is

a) Acidic b) Basic c) Neutral d) Normal

297) The value of ionic product of water at 250C is

a) 0.11 × 10-14 b) 0.30 × 10-14 c) 1 × 10-14 d) 3.0 × 10-14

298) Which of the following solutions have highest pH ?

a) 0.1M H2SO4 b) 0.02 M CH3COONa c) 0.01 M NaOH d) 0.01 M NaHCO3

299) The pH of human blood is

a) 7.0 b) 7.4 c) 4.0 d) 6.5

300) The values of Kw of water at 250C is

a) 0.11 × 10-14 b) 0.30 × 10-14 c) 1.0 × 10-14 d) 7.5 × 10-14

301) The term pH was introduced by

a) Henderson b) Sorenson c) Goldstein d) Thomson

302) The sum of pH and pOH at 250C always equal to

a) 7 b) Zero c) 14 d) 10-14

303) The pH of Milk of Magnesia is

a) 10.5 b) 3.5 c) 8.5 d) 11.5

304) pH of soft drinks at 250C is about

a) 3.0 b) 10.0 c) 1.0 d) 7.0

305) The pH of 10-3 mol dm-3 of an aqueous solution of H2SO4 is

a) 3.0 b) 2.7 c) 2.0 d) 1.5

306) The units for kw of H2O are

a) mol dm3 b) mol2 dm-6 c) mol-2 dm-6 d) mol-2 dm-3

307) The pH of tomatoes is

a) 1.2 b) 4.2 c) 7.2 d) 9.2

308) Strength of an acid can determined by

a) pKa b) pKb c) pKw d) pOH

309) Ionization of weak acid is expressed in terms of which of the following constants ?
a) Kw b) Kn c) Kp d) Ka
310) The pH of rain water is
a) 7 b) 7.3 c) 6.2 d) 5.0

311) Sum of Pka and Pkb is equal to

a) 7 b) 1 c) 14
312) Strength of a base can be determined by
a) pKa b) pKb c) pKw d) pOH

313) If a solution has zero pH . The hydrogen ion concentration will be

a) 10-4 b) 10-3 c) 10-7 d) 1
314) According to common Ion effect ______ soluble salt is precipitated out first .
a) More b) Less c) Unreactive d) Insoluble

315) The suppression of ionization of weak electrolyte by adding a _____ from outside is called common ion effect.
a) Acid b) Base c) None of these d) Common ion

316) Common ion effects finds extensive applications in the qualitative analysis and the preparation of
 a) Ammonia b) NaOH c) Buffers d) None of these

317) An acidic buffer solutions can bee prepared by mixing.

a) A weak Acid and weak Base b) A strong Acid and strong c) A strong Acid and weak Base d) A weak Base and its Salt
Base with strong acid

318) To prepare a buffer with pH close to 9.0 you could use mixture of
a) NH4OH and NH4Cl b) HNO2 and NaNO2 c) CH3COOH and CH3COONa d) H2CO3 and NaHCO3

319) A basic buffer solution can be prepared by mixing

a) Weak acid and its salt with b) Strong acid and its salt with c) Strong base and its salt with d) Weak base and its salt
strong base weak base weak acid with strong acid

320) A buffer can be explained by

a) Common Ion effect b) Le-Charterlier c) Law of mass action d) Bronsted Acid-Base
Theory

321) Buffers are not used in

a) Clinical Analysis b) Cell Biology c) Analytical Chemistry d) Salt Analysis
322) What will be the pH of buffer solution containing ( CH3COOH ) = 1.0M and [ CH3COONa ] = 0.1M : if Ka for acid is 1.85 10-5 ?
a) 4.74 b) 5.74 c) 3.75 d) 3.94

323) Those solutions which show positive or negative deviations from Raoult's Law are called.
a) Ideal solutions b) Conjugate solutions c) Non ideal solutions d) Saturated solutions

324) Which of the following is non-ideal solution ?

a) Benzene - toluene b) Ethanol - water c) Benzene - ether d) None of these

325) Which of the following mixtures exhibitsive deviation from Raoult's law and azeotropic mixture with maximum boiling point ?
a) Acetone + CS2 b) Methanol c) Benzene d) Ethanol + Benzene
326) Raoult's law is represented by
a) b) d) All of these
c)

327) In azeotropic mixture showing positive deviation from Raoult's law , the volume of the mixture is
a) Slightly more than the total b) Slightly less than the total c) Equal to the volume of the d) None of these
volume of the components volume of the components components

328) Azeotropic mixture cannot be separated into pure components by

a) Distillation b) Vacuum distillation c) Fractional distillation d) Freezing

329) The number of water molecules in CuSO4 attacked with Cu2+ ion
a) One b) Two c) Three d) Five
330) If 5.85 g of NaCl ( Mol , mass 58.5 ) is dissolved in 90 g of H2O , the mole fraction of NaCl will be
a) 0.01 b) 0.1 c) 0.0196 d) 0.3

331) Which one of the following salt dissolves in water to form a solution with a pH greater than 7 ?
a) NaCl b) CuSO4 c) Na2CO3 d) NH4Cl

332) The solubility of Ce ( SO4 )3

a) Is independent of temperature b) Decreases with the c) Decrease with the decrease in d) Increases with the increases
increase in temperature temperature in temperature

333) In discontinuous solubility curves , the sudden change in direction is due to

a) Appearance of new phase b) Change in no . of molecules c) Change in vapour d) Appearance of new phase and
of water of crystallization pressure solubility of substance

334) The solubility of sugar in water is due to

a) High dielectric constant of b) Hydrogen boning with c) High solvation energy d) High dipole moment of
water water water

335) Solubility of which substance decreases by increasing temperature

a) NaNO3 b) KNO3 c) NaCl d) Ce2( SO4 )3
336) The normal colligative properties are the properties of
a) Dilute solutions which b) Concentrated solutions which c) Substance which are d) Solutions which deviate
behave ideally behave nonideally electrolytes from Raoult's Law

337) Colligative properties are useful in calculating the

a) Solubility of the substance b) No . of water molecules of c) Molecular masses of the d) Valence of ions
crystallization solute
338) Depression of freezing point of equimolal aqueous solutions will be maximum for
a) Sucrose b) Glucose c) NaCl d) Urea

339) The relative lowering of vapour pressure is equal to the mole fraction of the solute . The law is known as
a) Ostwald's dilution law b) Vant Hoff's law c) Raoult's law d) Henry's law

340) Vapour pressure of a solution when non-volatile solute is added to a solvent is always
a) Abovethe vapour pressure of b) Equal to the vapour pressure c) Less than the vapour d) Equal to atmospheric pressure
the pure solvent of the solvent pressure of the pure solvent

341) Which of the following solutions will have the highest boiling point ?
a) 0.1M NaCl b) 0.1M CaCl2 c) 0.1M FeCl3 d) 0.1M Glucose

342) Which of the following solutions has the highest boiling point ?
a) 5.85% solution of NaCl b) 18% solution of glucose c) 6% solution of urea d) All have the same boiling
point

343) The molal boiling point constant is the ration of the elevation in boiling point to
a) Molarity b) Mole c) Mole fraction of solvent d) Mole fraction of solute

344) Colligative properties are the properties of

a) Dilution solutions which b) Concentrated solutions which c) Both A & B d) Neither ( a ) nor ( b)
behave as nearly ideal solutions behave as nearly non-ideal solutions

345) The depression in freezing point can be measured by

a) Landsberger's method b) Backmann's apparatus c) Solubility curves d) Monometric method

346) The molarity of solution containing 1.5 g urea in 100 cm3 of the solution is
a) 1 molar b) 0.1 molar c) 0.2 molar d) 0.25 molar
347) The molality of toluene ( C6H8 ) solution in benzene is 0.22 . What is the mass of toluene present in 500g of C6H6 ?
a) 267 b) 260 c) 240 d) 10.12
348) Freezing point of equimolal aqueous solutions will be minimum for
a) Fructose b) Urea c) Glucose d) NH4Cl
349) Liquids which are practically immiscible

a) H2O + C6H6 b) H2O + HCl c) H2O + C2H5 - OH d) H2O + CH3 - O - CH3

350) The amount of NaOH required to prepare 250 cm3 of 0.1 M . Solution is
a) 1 g b) 10 g c) 2 g d) 6 g

351) Both Ebullioscopic and cryoscopic constants depend upon

a) Nature of solvent b) Nature of solvent and solute c) Nature of solute d) None of the above

352) Which of the following is solution in which solvent and solute both are solids ?
a) Butter b) Mercury in silver c) Smoke d) Steel
353) The sum of the mole fractions of the components of a solution is equal to
a) Zero b) One c) Two d) Three

354) Which salt when dissolved in water forms a solution with a pH greater than 7
a) NaCl b) CuSO4 c) Na2CO3 d) NH4Cl

355) A redox reaction is

a) Ion combination reaction b) Proton transfer reaction c) Electron transfer reaction d) Proton combination reaction

356) Which of the following process always involve the decrease in oxidation number ?
a) Hydrolysis b) Decomposition c) Reduction d) Oxidation

357) Which of the following redox reactions is feasible ?

a) Zn(s) + 2Ag+ (aq) b) Zn(s) + 2Ag (aq) 2Ag+2 (aq) c) Zn+2(aq) + 2Ag+ (s) 2Ag+2 d) Zn+2(aq) + Ag+ (aq)
Zn+2 (aq) + 2Ag(s) + 2Ag+2(aq) Ag(s) (aq) + Zn(s)

358) The oxidation number of C in C12H22O11 is

a) Zero b) -6 c) +6 d) 12

359) The oxidation number of chromium in K2Cr2O7 is

a) 4 b) 2 c) 6 d) 3

360) Oxidation number of Cr in K2CrO4 is

a) +2 b) +4 c) +6 d) +8

361) The oxidation state of oxygen in OF2 is

a) -2 b) -1 c) +2 d) +1
362) The oxidation state of Mn in KMnO4 is

a) +7 b) +6 c) +2 d) +5

363) The reduction potential of Zn is

a) + 0.76V b) - 0.34V c) + 0.34V d) - 0.76V

364) The electrolysis of aqueous solution of NaCl is employed to prepare caustic soda on commercial scale . The reaction at the cathode is
a) Formation of water molecule c) Reduction of H ions d) Reduction of Na ions
b) Oxidation of Cl ions

365) Cu metal can be purified in electrolytic cell by making the impure Cu are
a) Anode b) By making its CuSO4 solution c) Cathode d) SHE

366) The electrode reaction of a voltaic cell can be reversed when

a) Concentration of solutions is b) Electrodes are interchanged c) Temperature is increase d) External circuit is
changed employed to supply the
source of electricity

367) A salt bridge contains

a) Gelatin + HCl b) Gelatin + NaOH c) Gelatin + H2SO4 d) Gelatin + HCl
368) Which one of the following is not an example of voltaic cell
a) Ni - Cd cell b) Fuel cell c) Down's cell d) Silver oxide battery

369) Which of the following statements is correct about Galvanic cell ?

a) Anode is negatively b) Cathode is positively charged c) Reduction occurs at anode d) Oxidation occurs at cathode
charged

370) If a salt bridge is not used between two half-cells , then the voltage
a) Decreases repidly b) Does not change c) Decreases slowly d) Drops to zero
371) The cell in which electrical energy is converted into chemical energy is called
a) Galvanic cell b) Electrolytic cell c) Fuel cell d) Daniel cell

372) When Non-spontaneous redox reaction is carried out by using the electrical current , then the process is called
a) Decomposition of the substances b) Electrolysis c) Hydrolysis d) Exothermic process

373) The cathodic reaction in the electrolysis of dilute H2SO4 with Pt electrodes is

a) Reduction b) Oxidation c) Both Oxidation and d) Neither oxidation not

Reduction reduction

374) The standard electrode potential ( in volt ) of SHE is taken as

a) 0.00 b) 1.00 c) 10.0 d) 100

375) The standard reduction potential of Ag and Zn are + 0.80 and - 0.76V respectively . Which of the following conclusions can be drawn from
the data ?
a) Ag is a poor Oxidizing agent b) Zn has greater tendency c) Zn will always act as a d) Ag dsplaces Zn from a
than Ag to from positively reducing agent solution containing Zn ion
charged ion

376) The least value of reduction potential is for

a) Li+1 b) F2 c) K+1 d) Na+1

377) The electrode potential of standard hydrogen electrode is arbitrarily taken as

a) Positive b) Zero c) Negative d) Vary with situation

378) The overall positive values for cell potential predicts that the process is energetically .
a) Feasible b) Not feasible c) Not possible d) Cannot be predicted

379) In electro-chemical series , the electrodes are compared with SHE and they are arranged in the decreasing order of
a) Cell voltage b) Reduction potential c) Ionization potential d) Oxidation potential
380) The electrochemical cell stopts working after sometime because
a) The reaction reverse its b) Electrode potentials of c) Electrode potentials of both d) One of electrode completely
direction both the electrodes equalize the electrodes becomes zero vanishes

381) If the rate equation of a reaction 2A + B products is , rate = k [A]2[B], and A is present in large excess , then order of reaction is
a) 1 b) 2 c) 3

382) The unit of rate constant depends on

a) Number of reactants b) Order of reaction c) Concentration terms d) Molecularity of reaction

383) The rate of reaction

 a) Increases as the reaction b) Increase in activation energy c) Increases in number of d) Decreases as the reaction
proceeds of reactans effective collisions proceeds

384) The unit of the rate constant is same us that of the rate of reaction in
a) First order reaction b) Zero order reaction c) Second order reaction d) Third order reaction

385) Velocity constant is the rate of reaction when the concentrations of reactants are
a) Zero b) Unity c) Two d) Three

386) When a reaction proceeds in more than one steps the overall rate is determined by
a) Fastest step b) Rate cannot be determined c) Slowest step d) Any step can be used

387) Velocity constant is the rate of reaction when the concentrations of reactants are
a) Zero b) Unity c) Two d) Three

388) When a reaction proceeds in more then one steps the overall rate is determined by
a) Fastest step b) Rate cannot be determined c) Slowest step d) Any step can be used

389) The half life period for the decomposition of N2O5 is

a) 48 minutes b) 24 minutes c) 48 minutes d) 50 minutes

390) If the energy of the activated complex lies close to energy of reactants , it means that reactions is
a) Slow b) Fast c) Exothermic d) Endothermic

391) Rate of a chemical reaction depends upon

a) The number of fruitful b) The number of fruitless c) The number of total collisions d) The number of molecules
collisions per second collisions per second per second taking part in a chemical
reaction

392) Under a given set of experimental conditions , with increase of concentration of the reactants , the rate of a chemical reaction .
a) Always decrease b) First decreases , than c) Always increases d) Remains same
increases

393) The minimum energy more than the average energy required for the molecules to undergo reaction is
a) Internal energy b) Free energy c) Activation energy d) Kinetic energy

394) The Chemical reactions in which reactants requite high amount of activation energy are generally

a) Slow b) Fast c) Instantaneous d) Spontaneous

395) The value of activation energy is primarily determined by

a) Temperature b) Concentration of reactants c) Collision frequency d) Chemical nature of
reactants and products

396) After 2 half lives of a chemical reaction , the % fraction of the amount left is
a) 6.25 b) 75 c) 12.5 d) 50

397) All radioactive disintegration nuclear reactions are of

a) First order b) 2nd order c) 3rd order d) Zero order

398) Hydrolysis of Tertiary butyl bromide has order of reaction

a) First order b) Pseudo first order c) Second order d) Third order

399) Half life of a second order reaction in inversely proportional to

a) Initial concentration of b) Initial concentration of c) Final concentration of d) Final concentration of
products reactants reactants products

400) In zero order reaction , the rate is independent of

a) Temperature of reaction b) Concentration of products c) Concentration of reactants d) Pressure of reaction

401) For a hypothetical reaction A + 2B products , the rate law is rate = k [A] [B]. the order of reactions is
a) 1 b) 2 c) 3 d) 4

402) The order of the reactions is 2NO + 2H2 2H2O + N2

a) Zero b) One c) Two d) Three
403) A second order rate constant can have the units
a) dm-6 mole2 s-1 b) dm3 mole s-1 c) dm6 mole-2s-1 d) dm3 mole-1 s-1
404) Many elements have fractional atomic masses . This is because .
a) The mass of the atom is itself b) Atomic masses are average c) Atomic masses are average d) Atomic masses are average
fractional masses of isobars masses of isotopes masses of isotopes proportional to
their relative abundance

405) In zero order reaction , the rate is independent of .

a) Temperature of reaction b) Concentration of products c) Concentration of reactants d) None of these
406) If the rate of reaction for 2A + B products is rate = k [A]2 [B] and A is present in large excess , then order of reaction is .

a) 1 b) 2 c) 3 d) 4

407) The rate of reaction .

a) Increase as the reaction b) Decreases as the reaction c) Remains the same as the d) May decrease or increase as
proceeds proceeds reactions proceeds the reaction proceeds

408) With increases in 100C temperature , the rate of reaction doubles . This increase in rate of reaction is due to .
a) Decrease in activation energy b) Decrease in the number of c) Increase in activation energy d) Increase in number of
of reaction collisions between reactant of reaction effective collisions
molecules

409) The unit of the rate constant is same as that of the rate of reaction in .
a) First order reaction b) Zero order reaction c) Second order reaction d) Third order reaction

410) The cathodic reaction in the electrolysis of dil . H2SO4 with Pt electrodes is .

a) Reduction b) Oxidation c) Both oxidation and reduction d) Neither oxidation and
reduction

411) Which of the following statements is not correct about Galvanic cell ?
a) Anode is negatively charged b) Cathode is positively charged c) Reduction occurs at anode d) Reduction occurs at cathode

412) Strong the oxidizing agent , greater is the .

a) Oxidation potential b) Redox potential c) Reduction potential d) E.M.F of cell

413) If the salt bridge is not used between two half cells , then the voltage .
a) Decreases repidly b) Decreases slowly c) Does not change d) Drops to zero
414) If a strip of Cu metal is placed in a solution of Fe SO4 .
a) Cu will be deposited down b) Fe is precipitated out c) No reaction takes place d) Cu and Fe both dissolve

415) 18g glucose is dissolved in 90 g of water. The relative of vapour pressure is equal to
a) 1/5 b) 5.1 c) 1/51 d) 6

416) An azeotropic mixture of two liquids boils at a lower temperature than either of them when
a) It is saturated b) It shows positive deviation c) It shows negative deviation d) None of these
from Raoult's law from Raoult's law

417) In azeotropic mixture showing positive deviation from Raoult's law , the volume of the mixture is .

a) Slightly more then the total b) Slightly less then the total c) Equal to the total volume of the d) None of these
volume of the components volume of the components components

418) Which of the following has the highest boiling point?

a) 5.85% solution of sodium b) 18.0% solution of glucose c) 6.0% solution of urea d) All have the same boiling
chloride point

419) Two solutions of NaCl ans KCl are prepared separated by dissolving same amount of solution in water. Which of the following statement is
true for these solutions?
a) KCl solution will have higher b) Both the solutions have c) KCl and NaCl solution d) KCl solution possess lower
boiling point than NaCL different boiling points possess same vapour pressure freezing point than NaCl

420) The molar boiling point constant is the ratio of the elevation in boiling point to
a) Molarity b) Molality c) Mole fraction of solvent d) Mole fraction of solute

421) Colligative properties are the properties of :

a) Dilute solution which b) Concentrated solution which c) Both A & B d) None of these
behave as nearly ideal solution behave as nearly non-ideal solution

422) The nature of positive rays depends on

a) The nature of electrodes b) The nature of discharge tube c) The nature of residual gas d) All of these

423) The nature of residual gas

a) Independent of its wavelength b) Depends on its wavelength c) Equal to its square of its d) Depends on its source
magnitude

424) The wave number of the light emitted by a certain source is 2 × 106 m-1 . The wavelength of this light will be .

a) 500nm b) 500m c) 200nm d) 5 × 107 m

425) Rutherford's atomic model failed because of :

a) The atoms did not have a b) It did not account for the c) It did not account for the d) There is actually no space
nucleus and electrons attraction between protons and stability of the atom between the nucleus and the
neutrons electrons

426) Bohr's atomic model of atom is contradicted by:

 a) Plank quantum theory b) Pauli exclusion principle c) Heisenberg's uncertainty d) All of these
principle

427) Splitting of spectral lines when atoms are subtracted to strong electric field is called?
a) Zeeman effect b) Stark effect c) Photoelectric effect d) Compton effect

428) In the ground state of an atom ,the electrons is present

a) In the nucleus b) In the second shell c) Nearest to the nucleus d) Farther from the nucleus

429) Quantum number value for 2p orbitals are

a) n = 2 , l = 1 b) n = 1 , l = 0 c) n = 0, l = 2 d) n = 2, l = 0

430) Orbital having same energy are called

a) Hybrid orbital b) Valence orbital c) Degenerated orbital d) d-orbital

431) For which system does the equilibrium constant Kc has units of ( concentration ) ?
a) N2 + 3H2 2NH3 b) 2NO2 N2O4 c) H2 + I2 2HI d) 2HF H2 + F2

432) Which statement about the following equilibrium is correct ?

2SO2(g) + O2(g) 2SO3(g) H = - 188.3 kJ mol-1
a) The value of Kp falls with a rise b) The value of Kp falls with c) Adding V2O5 catalyst increases d) The value of Kp is equal
in temperature increasing pressure the equilibrium yield of sulphur to Kc
trioxide

433) The pH of 10-3 mol dm-3 of an aqueous of H2SO4 is

a) 3.0 b) 2.7 c) 2.0 d) 1.5

434) The excess of aqueous silver nitrate is added to aqueous. Barium chloride and precipitate is removed by filtration .What are the main ions in
the filtrate .
a) Ag+ and NO-3 only b) Ag+ and Ba2+ and NO3- c) Ba2+ and NO3- d) None of these

435) If an endothermic reaction is allowed to take place very rapidly in the air, the temperature of the surrounding air
a) Remains constant b) Decreases c) Increases d) Remains unchanged

436) In endothermic reactions, the heat content of the

a) Products is more than that b) Reactants is more than that of c) Both (a) and (b) d) Reactants and products are
of reactants products equal

437) Calorie is equivalent to

a) 0.4184J b) 41.84J c) 4.184J d) 418.4J

438) The change in heat energy of a chemical reaction at constant temperature and pressure is called

a) Enthalpy change b) Bond energy c) Heat of sublimation d) Internal energy change

439) Which of the following statements is contrary to the first law of thermodynamics?
a) Energy can neither be b) One form of energy can be c) In an adiabatic process, the d) Continuous production of
created nor destroyed. transferred into an equivalent work done is independent of its mechanical work without
amount of other kinds of path. supplying an equivalent amount
energy. of heat is possible.

440) For a given process, the heat changes at constant pressure (qp) and at constant volume (qv ) are related to each other as
a) qp = qv b) qp < qv c) qp > qv d) qp =qv / 2

441) For the reaction: NaOH+HCl NaCl+H2 O the change in enthalpy is called
a) Heat of reaction b) Heat of neutralization c) Heat of formation d) Heat of combustion

442) The net heat change in a chemical reaction is same,whether it is brought about in two or more different ways in one or several steps. It is
known as
a) Henry’s law b) Hess’s law c) Joule’s principle d) Law of conservation of energy

443) Enthalpy of neutralization of all the strong acids and strong bases has the same value because
a) Neutralization leads to the b) Strong acids and bases are c) Acids always give rise to d) The net chemical change
formation of salt and water. ionic substances. H+ ions and bases always involve the combination of H+
furnish OH- ions. and OH- ions to form water

444) An ionic compound A+B- is most likely to be formed when

a) The ionization energy of A is b) The ionization energy of c) Both the ionization energy of d) Both the ionization energy of
high and electron affinity of B A is low and electron affinity of A andelectron affinity of B are A and electron affinity of B are
is low. B is high. high. low.

445) The number of bonds in nitrogen molecule is

a) one ó and one b) one ó and two c) three sigma only d) two ó and one

446) Which of the following statement is not correct regarding bonding molecular orbitals?
 a) Bonding molecular orbitals b) Bonding molecular c) Every electron in the bonding d) Bonding molecular orbitals are
possess less energy than atomic orbitals have low electron molecular orbitals contributes to formed when the electron waves
orbitals from which they are density between the two nuclei. the attraction between atoms. undergo constructive interference.
formed.

447) Which of the hydrogen halides has the highest percentage of ionic character?
a) HCl b) HBr c) HF d) Hl

448) Which of the following species has unpaired electrons in antibonding molecular orbitals.
a) 02 2+ b) N2 2- c) B2 d) F2

449) London dispersion forces are the only forces present among the
a) Molecules of water in liquid b) Atoms of helium in gaseous c) Molecules of solid iodine. d) Molecules of hydrogen
state state at high temperature chloride gas.

450) Acetone and chloroform are soluble in each other due to

a) Intermolecular hydrogen b) Instantaneous dipole c) Ion-dipole interaction d) All of the above
bonding

451) NH, shows a maximum boiling point among the hydrides of Vth group elements due to
a) Very small size of nitrogen b) lone pair of electrons c) Enhanced electronegative d) Pyramidal structure of NH3
present on nitrogen. character of nitrogen

452) When water freezes at 0"C, its density decreases due to

a) Cubic structure of ice b) Empty spaces present in c) Change of bond lengths d) Change of bond angles
the structure of ice

453) Pressure remaining constant, at which temperature the volume of a gas will become twice of what it is at 0°C.
a) 546°C b) 200°C c) 546K d) 273K

454) Number of molecules in one dm3 of water is close to

a) 55.6 x 6.02 x 1023
b) c) d)

455) Which of the following will have the same number of molecules at STP?

a) 280 cm3 of CO2 and 280 b) 11.2 dm3 of O2 and 32 g of c) 44 g of CO2 and 11.2 dm3 of d) 28 g of N2 and 5.6 dm3 of
cm3 of N2O O2 CO oxygen

456) If absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume of the gas will
a) Remain unchanged b) Increase four times c) Reduce to 1/4 d) Be doubled

457) How should the conditions be changed to prevent the volume of a given gas from expanding when its mass is increased?

a) Temperature is lowered b) Temperature is increased and c) Temperature and pressure d) Temperature and pressure
and pressure is increased pressure is lowered both are lowered both are increased

458) The molar volume of CO2 is maximum at

a) STP b) 127°C and 1 atm c) 0°C and 2 atm d) 273°C and 2 atm

459) The order of the rate of diffusion of gases NH3, SO2, Cl2, an CO2 is:
a) NH3 > SO2 > Cl2 > CO2 b) NH3 > CO2 > SO2 > Cl2 c) Cl2 > SO2 > CO2 > NH3 d) NH3 > CO2 > Cl2 > SO2

460) Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction of total pressure exerted by oxygen is

a) 1/3 b) 8/9 c) 1/9 d) 16/17

2. Write "T" for a true statement and "F" for a false statement
461) The half-life order reaction increases with temperature .
☐ True ✅ False

462) The reactions having zero activation energies are instantaneous .

✅ True ☐ False

463) There is difference between rate law and the law of mass action .
✅ True ☐ False

464) The order of reaction is strictly determined by the Stoichiometry of the balanced equation .
☐ True ✅ False

465) In electrolytic conduction electrons flow through the electrolyte .

✅ True ☐ False

466) In the process of electrolysis , the electrons in the external circuit flow from cathode to anode .
☐ True ✅ False

467) Sugar is a non - electrolyte in solid form and when dissolved in water will allow the passage of an electric current .
☐ True ✅ False

468) A metal will only allow the passage of an electric current when it is in cold state .
 ☐ True ✅ False

469) The electrolyte products of aqueous copper ( II ) chloride solution are copper and chlorine .
✅ True ☐ False

470) Zinc can displace iron form its solution .

✅ True ☐ False

471) SHE cats as cathode when connected with Cu electrode .

☐ True ✅ False

472) A voltaic cell produces electrical energy at the expense of chemical energy .
☐ True ✅ False

473) The solubility of a substance decreases with increase in temperature if the heat of a solution is negative .
✅ True ☐ False

474) The rate of evaporation of a liquid is inversely proportional to the intermolecular forces of attraction.
✅ True ☐ False

475) The molecular mass of an electrolyte determined by lowering of vapour pressure is less than the theoretical molecular mass .
✅ True ☐ False

476) Boiling point elevation is directly proportional to the molality of the solution and inversely proportional to boiling point of solvent .
✅ True ☐ False

477) All solutions containing 1 g of non - volatile non - electrolyte solutes in some solvent will have the same freezing point .
☐ True ✅ False

478) The freezing point of a 0.05 molal solution of a non - volatile non - electrolyte solute in water is - 0.930 C .
☐ True ✅ False

479) A neutron is slightly lighter particle than a proton.

☐ True ✅ False

480) A photon is the massless bundle of energy but has momentum .

✅ True ☐ False

481) The unit of Rydberg constant is the reciprocal of unit of length .

✅ True ☐ False

482) The actual isotopic mass is a whole number .

☐ True ✅ False

483) Heisenberg's uncertainty principle is applicable to macroscopic bodies .

☐ True ✅ False

484) The nodal plane in an orbital is the plane of zero electron density .
✅ True ☐ False

485) The number of orbitals present in a sublevel is given by the formula ( 2l 1).
✅ True ☐ False

486) Magnetic quantum number was introduced to explain Zeeman and stark effects .
✅ True ☐ False

487) Spin quantum number tells us the direction of spin of electron around the nucleus .
✅ True ☐ False

488) When a reversible reaction attains equilibrium both reactants and products are present in a reaction mixture .
✅ True ☐ False

489) The Kc of the reaction A + B C + D is given by therefore it is assumed that [A] = [B] = [C] = [D]

☐ True ✅ False

490) A catalyst is a compound , which increases the speed of the reaction and consequently increases the yield of the product .
✅ True ☐ False

491) Ionic product Kw of pure water at 250 C is 10-14 dm-6 and is represented by an expression Kw = [H+][OH-] = 10-14 mol2 dm-6
✅ True ☐ False

492) The work done by the system is given the positive sign.
☐ True ✅ False

493) Enthalpy is a state function but internal energy is not.

☐ True ✅ False

494) Total heat content of a system is called enthalpy of the system.

✅ True ☐ False

495) The core of an atom is the atom minus its valence shell.
✅ True ☐ False
496) The molecules of nitrogen (N ≡ N) and acetylene (HC ≡ CH) are not isoelectronic.
☐ True ✅ False

497) There are four coordinate covalent bonds in NH4 + ion.

☐ True ✅ False

498) A ó -bond is stronger than a -bond and the electrons of s-bond are more diffused than -bond.
☐ True ✅ False

499) The bond energy of heteroatomic diatomic molecules increases with the decrease in the electronegativities of the bonded atoms.
☐ True ✅ False

500) The first ionization energies of the elements rise steadily with the increasing atomic number from top to bottom is a group.
☐ True ✅ False

501) A double bond is stronger than a single bond and a triple bond is weaker than a double bond.
✅ True ☐ False

502) The bonds formed between the elements having electronegativity difference more than 1.7 are said to be covalent in nature.
☐ True ✅ False

503) The re pulsive force between the two bonding pairs is less than that between the two lone pairs.
☐ True ✅ False

504) The number of covalent bonds an atom can form is related to the number of unpaired electrons it has.
✅ True ☐ False

505) The rules which govern the filling of electrons into the atomic orbitals also govern filling of electrons into the molecular orbitals.
☐ True ✅ False

506) Dipole-dipole forces are weaker than dipole-induced dipole forces.

☐ True ✅ False

507) The ion dipole interactions are responsible for the dissolution of an ionic substance in water.
✅ True ☐ False

508) The high polarizability of iodine is responsible for its existence in solid form and its difference from other halogens.
✅ True ☐ False

509) The strong hydrogen bonding in H2S makes it different from water.
☐ True ✅ False

510) Hydrocarbons are soluble in water because they are polar compounds.
☐ True ✅ False

511) The viscosities of liquids partially depend upon the extent of hydrogen bonding.
✅ True ☐ False

512) Ice does not show any vapour pressure on its surface at -1oC.
☐ True ✅ False

513) Kinetic energy of molecules of a gas is zero at 0oC.

☐ True ✅ False

514) A gas in a closed container will exert much higher pressure at the bottom due to gravity than at the top.
☐ True ✅ False

515) A solute distributes itself between two immiscible liquids in a constant ratio of concentrations depending upon the amount of solvent added.
☐ True ✅ False

516) Paper chroma tography is a technique of partition chromatography.

✅ True ☐ False

517) Neon has three isotopes and the fourth one with atomic mass 20.18 amu.
☐ True ✅ False

518) The number of atoms in 1.79 g of gold and 0.023 g of sodium are equal.
☐ True ✅ False

519) The number of electrons in the molecules of CO and N2 are 14 each, so 1 g of each gas will have same number of electrons.
✅ True ☐ False

520) Actual yield of a chemical reaction may be greater than the theoretical yield.
☐ True ✅ False

3. Fill in the blanks.

521) The rate of an endothermic reaction _________ with the increase in temperature.
Increases
522) All radioactive disintegration nuclear is of _______ order.
First
523) For a fast reaction the rate constant is relatively ______ and half - life is __________
large , small
524) The second order reaction becomes _______ if one of the reactants is in large excess.
First order
525) Arrhenius equation can be used to find out ________ of a reaction.
Energy of activation
526) The oxidation number of O atom is ______ in OF2 and is _______ in H2O2 .
+2 , -1
527) Conductivity of metallic conductors is due to the flow of _____ while that of electrolytes is due to flow of .
Electrons Ions
528) Reaction taking place at the _______ is termed as oxidation , and at the _______ is called reduction .
Anode , Cathode
529) ______ is setup when a metal is dipped in its own ions .
Equilibrium
530) The reduction potential of Zn is _______ volts and its oxidation potential is _______ volts .
-0.76 , + 0.76
531) 100 g of a 10 % aqueous solution of NaOH contains 10 g NaOH in _________ g of water .
90
532) When an azeotropic mixture is distilled , its __________ remains constant .
Composition
533) The molar freezing point of an azeotropic solution of two liquids is lower than ether of them because the solution shows _______ from
Raoluls's law .
Ctyoscopic
534) Among equimolal aqueous solution of NaCI , BaCI2 and FeCI3 , the maximum depression in freezing point is shown by _____ solution .
Positive deviation
535) A solution of ethanol in water shows _____ deviations and gives azeotropic solutions with ________ b.p. than other components .
FeCI3
536) Colligative properties are used to calculate _________ of a compound .
Positive ; lower
537) The boiling point of an azeotropic solution of two liquids is lower than either of them because the solution show ________ from Raoult's
law .
Molar mass
538) The hydration energy of Br- ion is __________ than that of F- ion.
Lesser
539) The aqueous solution of NH4CI is ___________ while that of Na2SO4 is ________
Acidic ; neutral
540) - particles are nothing but _______ moving with a very high speed .
Electrons
541) The charge on one mole of electrons is ________ coulombs.
96500 C
542) The mass of hydrogen atom is ________ grams .
1.66 × 10-24 g
543) The mass of one mole of electron is ________ .
0.55 mg
544) Energy is ________ when electron jumps higher to a lower orbit .
Emitted
545) The ionization energy of hydrogen atom can be given by formula ______ .
Bohr
546) For d sub - shell , the azimuthal quantum number has a value of ________ .
2
547) The number of electrons is a given sub - shell is given by formula _______
2 ( 2l + 1 )
548) Law of mass action states that the rate at which a reaction proceeds is directly proportional to the product of the active masses of the
________ .
Reactants
549) In an exothermic reversible reaction, ________ in temperature will shift the equilibrium towards the forward direction .
Decrease
550) The equilibrium constant for the reaction 2O3 3O2 is 1055 at 250 C , it tells that ozone is __________ at room temperature .
Unstable
551) In a gas phase reaction , if the number of moles of reactants are equal to the number of moles of the products , Kc of the reaction is
________ to the Kp .
Equal
552) Buffer solution is prepared by mixing together a weak base and its salt with ________ or a weak acid and its salt with _______ .
Strong acid , Strong base
553) The substance undergoing a physical or a chemical change forms a chemical .
System
554) The change in internal energy__________ be measured.
Can
555) Solids which have more than one crystalline forms possess_______ values of heats of formation.
Different
556) A________ is a macroscopic property of a system which is__________ of the path adopted to bring about that change.
State function ; Independent
557) The tendency of atoms to attain maximum ________ of electrons in the valence shell is called completion of octet.
Eight
558) The geometrical shape of SiCl4 and PCl3 can be explained on the basis of__________and________ hybridizations.
Sp3 , Sp2
559) The VSEPR theory stands for__________________ .
Valence shell electron pair repulsion
560) For N2 molecule, the energy of ó (2p)x orbital is________________ than (2py ) orbital.
Greater
561) The paramagnetic property of O2 is well explained on the basis of MO theory in terms of the presence of_________________ electrons in
two MO orbitals.
Un-pairs electron
562) The polarizability of noble gases________down the group and results in the increase in their boiling points.
Increases
563) ________ is developed in acetone and chloroform when they are mixed together .
H-bounding
564) The concept of dynamic equilibrium is the ultimate _______of all reversible systems.
Acidic strength
565) Hv of C6H14 should be_____ than that of C2H6.
Greater
566) The concept of dynamic equilibrium is the ultimate _______of all reversible systems.
Result / goal
567) During the formation of ice from liquid water there is a______ % increase in volume.
9
568) A layer of ice on the surface of water____the water underneath for further heat loss.
Insulates or prevents
569) The product PV has the S.I. unit of _____________
atm dm3
570) Eight grams each of O2, and H2, at 27 °C will have total K.E in the ratio of _____________
1:16
571) Smell of the cooking gas during leakage from a gas cylinder is due to the property of_____________ of _____________ gases.
Diffusion of sulphur
572) A complete chemical characterization of a compound must include_________.
Qualitative & quantitative analysis
573) A solvent used for crystallization is required to dissolve _______ of the substance at its boiling point and_______ at the room temperature.
Large amount , small amount
574) Repeated solvent extractions using small portions of solvent are__________________ than using a single extraction with larger volume of
the solvent.
More efficient
575) The unit of relative atomic mass is_________________.
amu
576) The exact masses of isotopes can be determined by________________ spectrograph.
Mass
577) The phenomenon of isotopy was first discovered by .____________________
Soddy
578) A limiting reagent is that which controls the quantities of____________
Products
579) 4g of CH4 at 0°C and 1 atm pressure has _____________molecules of CH4
1.505 × 1023
580) Stoichiometric calculations can be performed only when ________________ is obeyed.
Conservation