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AAC Chemistry T4 Retest Review

Gases Review:

1. Calculate the ratio of the velocity of hydrogen molecules to the velocity of carbon dioxide molecules at the same temperature.

2. Under what conditions of temperature and pressure will a real gas behave most like an ideal gas?

3. How many liters of CO2 would be formed when 11 L CS2 reacts with 18 L O2 at STP?
CS2 + O2  CO2 + SO2

4. A gas at 155kPa and 25oC has an initial volume of 1.00 L. The pressure the gas increases to 605 kPa as the temperature is
raised to 125 oC. What is the new volume?

5. A sample containing 4.50 g of methane is in a 2.00 L container at 35oC. Calculate the pressure, in kPa, of the ideal gas.

6. A 3.50 L gas sample at 20oC and a pressure of 86.7 kPa expands to a volume of 8.00 L. The final pressure of the gas is 56.7
kPa. What is the final temperature of the gas, in oC?

7. As gas temperature increases at constant volume, frequency of collisions __________________ and energy of collisions
_________________ leading the pressure of the gas to __________________________.

8. The following reaction takes place in a sealed 40.0 L container at a temperature of

120oC. Ammonia(g) + oxygen(g)  nitrogen monoxide(g) + water(g)
a. When 34.0 g ammonia react with 96.0 g oxygen, what is the partial pressure of nitrogen monoxide in the container?
b. What is the total pressure in the container?
Solutions Review:

1. Determine which compounds are more likely to dissolve in water or octane (gasoline)
a. Carbon tetrachloride b. methane c. sodium sulfate d. potassium chloride
Dissolves in:

2. Match each term with the following descriptions:

(1) Does not settle out on standing (6) Homogenized milk
(2) Heterogeneous (7) Saltwater
(3) Particle size less than 1 nm (8) jelly
(4) Particles can be filtered out
(5) Particles are invisible to the unaided eye

a. solution b. Colloid c. Suspension

3. The Na+ ion concentration is 0.375 M Na+ in a sodium phosphate solution. What is the concentration of the sodium phosphate
solution?

4. When additional KCl(s) is added to an unsaturated solution of KCl at constant temperature, the conductivity of the solution
a. Increases b. decreases c. stays the same

5. The solubility of methane in water at 20oC and 1.00 atm pressure is 0.026 g/L. If the temperature is constant, what will be the
solubility at 0.60 atm?

6. How many mL of 0.500 M KCl solution would be needed to dilute to make 100. mL of 0.100 M KCl solution?

7. Calculate the molarity of a solution that contains 0.50 g NaCl dissolved in 100. mL of solution.

8. How many mL of 15.0 M sulfuric acid are required to react completely with 315 g Al(OH)3?

9. Calculate the freezing and boiling point changes (∆T) for a solution containing 12.9 g of C10H8 in 50.0 g C6H6.
For C6H6 : Kf = 5.12 oC/m Kb = 2.53 oC/m

10. The solubility of KCl in water at 20oC is 34.0 g/100 g water. A warm solution containing 50.0 g KCl in 130 g water is
cooled to 20oC. a. How many grams of KCl remain dissolved? b. How many grams of crystals formed?
Thermochemistry Review:

1. Define each of the following:

a. Endothermic d. Enthalpy
b. Exothermic e. Entropy
c. Catalyst f. Gibb’s Free Energy

2. When 50.0 mL water containing 0.50 mol HCl at 22.5oC is mixed with 50.0 mL water containing 0.50 mol NaOH at
22.5oC in a calorimeter, the temperature of the solution increases to 26.0oC. What is the enthalpy of reaction? Assume
density and specific heat capacity are the same as water.

3. When carbon disulfide is formed from its elements, heat is absorbed. Calculate the amount of heat (kJ) absorbed when
5.66 g carbon disulfide is formed. C(s) + 2 S(s)  CS2(l) ∆H = 89.3 kJ/mol rxn

4. The molar heat of solution of NaOH is -44.51 kJ/mol. In a certain experiment, 50.0 g of NaOH is completely dissolved in
1.00 L of 20.0°C water in a foam cup calorimeter. Assuming no heat loss, calculate the final temperature of the water.
Assume the specific heat capacity and density of the solution are the same as water.

5. What is the standard heat of reaction (∆Ho) for the formation of NO2(g) from NO(g) and O2(g)?
Substance ∆Hf 2 NO(g) + O2(g)  2 NO2(g)
(kJ/mol)
NO(g) 90.37
NO2(g) 33.85

6. Calculate the enthalpy change for the formation of lead(IV)chloride PbCl2(s) + Cl2(g)  PbCl4(s) ∆H =

Pb(s) + 2 Cl2(g)  PbCl4 (l) ∆H = -329.2 kJ

Pb(s) + Cl2(g)  PbCl2(s) ∆H = -359.4 kJ

7. Use the thermochemical equation N2(g) + 3 H2(g)  2NH3(g) + 92.38 kJ to calculate the ∆H for
½ N2(g) + 3/2 H2(g)  NH3(g)

8. Calculate the free energy change at 25°C for the following reaction. SO3(g) ➔ SO2(g) + O2(g)
a. ΔG = ___________
Substance ΔHf (kJ/mol) ΔS (J/Kmol)
b. Is it spontaneous? ____
c. Driving force(s)? _____ SO2 (g) -297 248
SO3 (g) -396 257
O2 (g) 0 205