Class 12th JEE

MRJM/12 Milestone Test-03 Phase-1

DURATION: 180 Minutes DATE: 07/07/2024 M.MARKS: 300

Topic Covered

Physics : Electric Charges and Fields, Electrostatic Potential and Capacitance, Current Electricity
Chemistry : Solutions, Electrochemistry, Chemical Kinetics, Organic 11th - Revision {GOC & Hydrocarbon},
Haloalkanes and Haloarenes
Mathematics : Determinants, Matrices, Basic Mathematics, Relations and Functions, Inverse Trigonometric Functions

GENERAL INSTRUCTION
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 90 questions. The maximum marks are 300.
4. There are three sections in this question paper. Sections I, II and III, are of Physics, Chemistry and
Mathematics, respectively. Each section consists of 30 questions, of which the first 20 are mandatory and
are of Multiple Option type and the last 10 are of integer answer type. You need to attempt any 5 integer
type questions (out of 10) in each of the three sections. Answer to integer type questions shall be rounded
off to nearest integer if needed.
5. There is only one correct response for each question.
6. Each correct answer will give 4 marks while 1 Mark will be deducted for a wrong response.
7. No student is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc. inside the examination room/hall.
8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
 SECTION-I (PHYSICS)
Single Correct Type Questions (1-20) (4) The force on one plate due to the other plate is
1. A large sheet carries uniform surface charge density Q2
. A rod of length 2 has a linear charge density λ
20 d 2
on one half and – λ on the second half. The rod is
hinged at mid-point O and makes an angle  with the
normal to the sheet. The torque experienced by the 4. Two equal point charges are fixed at x = –a and
rod is x = + a on the x -axis. Another point charge Q is
placed at the origin. The change in the electrical
potential energy of Q, when it is displaced by a very
small distance x along the x-axis, is approximately
proportional to
(1) x (2) x2
(3) x3 (4) 1 / x

 2 5. A force of 10 N acts on a charged particle placed

(1) 0 (2) sin 
20 between two plates of a charged capacitor. If one
 2 
plate of capacitor is removed, then the force acting
(3) sin  (4) on that particle will be
0 2 0
(1) 5 N (2) 10 N
2. In conversion of a galvanometer to ammeter if 2% of (3) 20 N (4) Zero
the main current is to be passed through the
galvanometer of resistance G, the resistance of shunt 6. A metallic shell of radius R has a charge – Q on it.
required is : A point charge +Q is placed at the centre of the shell.
G G Which of the graphs shown below represent the
(1) (2)
49 50 variation of the electric field E with distance r
(3) 49 G (4) 50 G from the centre of the shell

3. In the figure shown the plates of a parallel plate

capacitor have unequal charges. Its capacitance is (1) (2)
'C'. P is a point outside the capacitor and close to the
plate of charge –Q. The distance between the plates
is 'd' then which statement is wrong

(3) (4)

(1) A point charge at point 'P' will experience

electric force due to capacitor 7. If R1 and R2 are respectively the filament resistances
(2) The potential difference between the plates will of a 200 W bulb and a 100 W bulb designed to
3Q operate on the same voltage.
be
2C (1) R1 is two times R2
(3) The energy stored in the electric field in the (2) R2 is two times R1
9Q 2 (3) R2 is four times R1
region between the plates is
8C (4) R1 is four times R2
8. Two short electric dipoles are placed as shown at 9 10
(1) (2)
large distance r. The energy of electric interaction 8 11
 1  8
between these dipoles will be  k =  (3) (4) None of the above
 40  9

11. Charges 5  C and 10  C are placed 1 m apart. Work

done by external agent to bring these charges at a
distance of 0.5 m from each other slowly.
(1) 45×10–2 J (2) 90×10–2 J
(3) 55×10–3 J (4) 95 J
−kP1P2 cos  −2kP1P2 cos 
(1) 3
(2)
r r3 12. A given charge situated at a certain distance from a
−2kP1P2 sin  −4kP1P2 cos  short electric dipole on axial position, experiences a
(3) (4)
r3 r3 force F. If the distance of charge is tripled, in the
same direction the force acting on the charge will be
9. Statement-1: A point charge q is placed inside a F F
cavity of conductor as shown. Another point charge (1) (2)
27 8
Q is placed outside the conductor as shown. Now as
F F
the point charge Q is pushed away from conductor, (3) (4)
64 9
the potential difference (VA-VB) between two points
A and B within the cavity of conductor remains
13. As shown five identical charges are kept at five
constant.
vertices of a regular hexagon. Match the following
Statement-2: The electric field due to charges on
two columns at centre of the hexagon. If in the given
outer surface of conductor and outside the conductor
situation electric field at centre is E. Then,
is zero at all points inside the conductor.

(1) Statement-1 is true, statement-2 is true and

statement-2 is correct explanation for
statement-1. Column I Column II
(2) Statement-1 is true, statement-2 is true and If charge at B is removed,
statement-2 is NOT the correct explanation for (a) then electric field will (P) 2E
statement-1. become
(3) Statement-1 is true, statement-2 is false. If charge at C is removed,
(4) Statement-1 is false, statement-2 is true. (b) then electric field will (Q) E
become
10. Find the ratio of currents as measured by ammeter in If charge at D is removed
two cases when the key is open to the current when (c) then electric field will (R) Zero
become
the key is closed:
If charges at B and C both
(d) are removed, then electric (S) 3E
field will become

a b c d
(1) Q S P R
(2) S Q R P
(3) P R Q S
(4) R P S Q

[3]
14. In the circuit diagram with discharge capacitors, the
current through the battery immediately after the
switch S is closed is given as :

R0
(1) R0 (2)
3
R0 R0
(3) (4)
2 3

19. An ammeter and a voltmeter are joined in series to a

cell. Their readings are A and V respectively. If a
resistance is now joined in parallel with the
voltmeter:
E
(1) Zero (2) (1) Both A and V will increase
R1 (2) Both A and V will decrease
E E (3) A will decrease, V will increase
(3) (4)
R1 + R 2 R2  R3 (4) A will increase, V will decrease
R2 + R3
20. The length of each side of a cubical closed surface is
. If charge q is situated on one of the vertices of the
15. Total electric flux coming out of a unit positive
cube. The flux passing through shaded face of the
Nm 2
charge put in air is P  4  109 . The value of cube is.
C
P is
(1) 2 (2) 3
(3) 4 (4) 9
q q
16. In the following circuit, the resultant capacitance (1) (2)
240 6 0
between A and B is xF. Find x
q q
(3) (4)
8 0 12 0

Integer Type Questions (21-30)

21. If 400 of resistance is made by adding four 100
(1) 1F (2) 2F resistance each of tolerance 5%, then the percentage
1 tolerance of the combination is x%. Find x.
(3) 3F (4) F
2
22. An infinite ladder network of resistances is
17. Four point charges –8Q, –q, 3q and 4Q are kept at constructed with 1 Ω and 2 Ω resistances, as shown
each corner of the square taken in order. The relation in figure. The 12 V battery between A and B has
between Q and q for which the potential at the centre negligible internal resistance. What is the current (in
of the square is zero is amperes) that passes through the 2 Ω resistance
q q connected between CD?
(1) Q = − (2) Q =
2 4
q −q
(3) Q = (4) Q =
2 4

18. In the circuit, the total resistance between points A

and B is R0. The value of resistance R is
[4]
23. A capacitor 4 μF charged to 50 V is connected to 27. Two opposite and equal charges, each of magnitude
another capacitor of 2μF charged to 100 V with plates 4×10–8 coulomb when placed 2×10–2 cm away, form a
of like charges connected together. The total energy dipole. If this dipole is placed in an external electric
y field 4×108 Nm, the value of maximum torque is
after connection is ×10–2 J. Find y.
3 x × 10–4 Nm. Find x.

24. In the shown circuit for maximum power to be 28. A 2μF capacitor is charged to 100 volt and then its
delivered to the network of 9 resistances each of plates are connected by a conducting wire. The heat
resistance R, from the battery, the internal resistance produced is (in mJ)
r of battery should be x Ω. Find x (given R = 9 Ω)
29. One end of a Nichrome wire of length 2L and cross-
sectional area A is attached to an end of another
Nichrome wire of length L and cross-sectional area
2A. If the free end of the longer wire is at an electric
potential of 8.0 volts, and the free end of the shorter
wire is at an electric potential of 1.0 volt, the
potential (in volt) at the junction of the two wires is
N
equal to . Find N.
10
25. The area of the plates of a 3F parallel plate capacitor, if
the separation between the plates is 5 mm, is
30. A charge + Q is uniformly distributed over a thin
x  10−3 2
m . Find x. fixed ring of radius R and very large mass. A particle
0 of charge –Q and mass m starts from rest at a point
on the axis of the ring far away from the centre of the
26. In the transient circuit shown in figure, the time ring. The velocity of this particle at the moment it
kRC
constant of the circuit is Then the value of xkQ 2
4 passes through the centre of the ring is . The
mR
integer k is:
 1 
value of x is  k = .
 40 

SECTION-II (CHEMISTRY)
Single Correct Type Questions (31-50) dCP
(3) = kC2A  CB
31. The molal lowering of vapour pressure of water at dt
100ºC, is dCP
(1) 750 mm Hg (2) 76 mm Hg (4) = kC2A  C2B
dt
(3) 7.6 mm Hg (4) 13.43 mm Hg
33. The resistance of a decinormal solution of a salt
32. A + B → Product (C)
occupying a volume between two platinum
If concentration of A is doubled, rate increases 2
times. If concentration of A and B are doubled, rate electrodes 1.80 cm apart and 5.4 cm2 in area was
increases 8 times. The differential rate equation of formed to be 50 ohm. The specific conductivity (in
the reaction will be (where CP represent S cm–1) and equivalent conductivity (in S cm2 eq–1)
concentration of product) respectively are :
dCP (1) 6.67 × 10–3 and 23.87
(1) = kCA  C2B
dt (2) 0.0208 and 6.67 × 10–3
dCP (3) 0.0104 and 104.16
(2) = kC2A  C3B
dt (4) 6.67 × 10–3 and 66.67
[5]
34. The variation of equivalent conductivity of weak 39. The freezing point of aqueous solution that
electrolyte with concentration is correctly contains 5% by mass urea, 1.0% by mass KCl and
shown in figure : 10% by mass of glucose is : (Consider 100%
dissociation of KCl)
( Kf H2O = 1.86 K molal−1 )
 eq
(1) eq (2) (1) 290.2 K (2) 285.5 K
C C (3) 269.33 K (4) 250 K

eq eq 40. When an ideal binary solution is in equilibrium

(3) (4) with its vapour, relation between molar ratio of the
C C X 
two components in the solution phase  A  and
 XB 
35. The correct order of stabilities of the following
Y 
resonance structures is: in the vapour phase  A  is
     YB 
H2C = N = N(I) H2 C− N = N(II)
(Given: PAo  PBo , where A and B are two
   
H2 C− N  N(III) H2 C− N = N(IV) components of solution)
(1) I > II > IV > III X A YA
(1) =
(2) I > III > II > IV X B YB
(3) II > I > III > IV X A YA
(2) 
(4) III > I > IV > II X B YB
X A YA
36. A compound(X) when passed through dil H2SO4 (3) 
X B YB
containing HgSO4 gives a compound (Y) which on
(4) Nothing can be predicted about the relation.
reaction with HI and red phosphorous gives C2H6.
The compound (X) is
41. E1 , E2 , and E3 are the emfs of the following three
(1) Propene (2) Ethyne
(3) But-2-ene (4) But-2-yne galvanic cells respectively
I. Zn (s) | Zn 2 + (0.1 M) || Cu 2+ (1 M) | Cu (s)
37. The electrochemical equivalent of a substance is II. Zn (s) | Zn 2 + (1 M) || Cu 2+ (0.1 M) | Cu (s)
0.0006735. Its equivalent weight (in gm eq−1) is
III. Zn (s) | Zn 2 + (1 M) || Cu 2+ (1 M) | Cu (s)
(1) 6.5 (2) 65
Which one of the following is true?
(3) 67.35 (4) 130
(1) E2  E1  E3
Br (2) E1  E 2  E3
Mg/ether D2O Na/ether (X) (3) E2  E 3  E1
38.
1 (eq.) (4) E1  E3  E2
Cl
The compound (X) is:
D D 42. 2-chlorobutane obtained by chlorination of butane,
Cl Br
(1) (2) will be:
(1) meso -form
D D (2) Racemic form
D
(3) (4) (3) d -form
D (4) -form

[6]
43.
46. (major product)
(A)
H2 + Pt Na + Liq.NH 3 The product B is
+ EtOH
(B) (C)
Compound (B) and (C) are:
(1) (2)

(1)

(3) (4)
H H

(2) n-Decane
47. On treating a mixture of two alkyl halides with
sodium metal in dry ether, 2-methyl propane was
H obtained. The alkyl halides are
(1) 2-chloropropane and chloromethane
(3) n-Decane H (2) 2-chloropropane and chloroethane
(3) Chloromethane and chloroethane
(4) Chloromethane and 1-chlorobutane
H

H 48. Aryl halides are less reactive towards nucleophilic

(4)
substitution reaction than alkyl halides due to:
(1) Delocalisation of lone pair of electrons of
chlorine
44. The rate of formation of SO3 in the following reaction
(2) Stability of carbonium ions
2SO2 + O2 ⎯⎯
→ 2SO3 is 100 gm/min,
(3) High boiling point
The rate of disappearance of O2 is (4) Longer carbon halogen bond.
(1) 50 gm min–1 (2) 100 gm min–1
–1
(3) 200 gm min (4) 20 g min–1
49. If E Fe2+ / Fe = −0.441 V and E Fe3+ /Fe2+ = 0.771 V,

45. Match the column: the standard e.m.f. of the reaction

Column-I Column- II Fe + 2Fe3+ → 3Fe2+ will be :
(1) 0.33 V (2) 1.212 V
Ebullioscopic
(A) Tf (p) (3) –0.33 V (4) –1.212 V
constant

Molal depression 50. The treatment of propene with Cl2 at 500 – 600ºC
(B) Tb (q)
constant produces (major product)
(1) 1, 2 – dichloropropene
Elevation in boiling
(C) Kf (r) (2) Allyl chloride
point
(3) 2, 3–dichloropropene
Depression in freezing (4) 1, 3–dichloropropene
(D) Kb (s)
point
Codes: Integer Type Questions (51-60)
A B C D 51. A certain current liberates 1.008 g of hydrogen in 2
(1) p s r q hr. How many grams of copper can be deposited by
(2) s r q p the same current flowing for the same time in
(3) q p s r CuSO4 solution? [Mw of Cu : 63.5 u] (Nearest
(4) r q p s Integer)

[7]
 Me observed to freeze at −0.465 C. The molecular
CH O
O3 formula of the compound is CxHyOz. Find the sum
52. (A) + OHC CH3 of x + y + z
Me2S
The number of geometrical isomers of (A) can be: ( Kf of water = 1.86 kg K mol−1 )

53. A hydrocarbon (X) with minimum number of 57. The following mechanism has been proposed for
carbon atoms (n) containing one double, one triple the formation NOBr(g)
bond and show geometrical isomerism. The value NO ( g ) + Br2 ( g ) NOBr2 ( g ) ...(i)
of n is NOBr2 ( g ) + NO ( g ) → 2NOBr ( g ) ...(ii)
54. A compound (X) trimerises in benzene having If the second step is the rate determining step, the
van’t Hoff factor 0.66. What is the percentage order of the reaction with respect to Br2(g) is
degree of association?
58. If methyl iodide and ethyl iodide are mixed in equal
55. I2 ( s ) | I ( 0.1 M ) half-cell is connected to a
−
proportions, and the mixture is treated with metallic
sodium in presence of dry ether, the number of
H + ( aq ) H 2 (1 bar ) Pt half-cell and emf is found
possible combination products formed is:
to be 0.7714 V. If E I − = 0.535 V, find the pH of
2 /I
59. Maximum number of molecules of CH3 I that can
H+ / H2 half-cell (Nearest Integer)
react with a molecule of CH3 NH2 are
56. A solution containing 1.8 g of a compound
60. An isotope has a half-life of 6 hours. What
(empirical formula CH2O ) in 40 g of water is
percentage of it will be left after 12 hours?

SECTION-III (MATHEMATICS)
Single Correct Type Questions (61-80) 0 2 y z 
64. If the matrix  x y − z  is orthogonal, then the
61. The square matrix A = [aij] given by aij = (i – j)3, is
 x − y z 
(1) Symmetric matrix
1 1 1
(2) Skew-symmetric matrix value of 2 + 2 + 2 , is equal to
x y z
(3) Diagonal matrix
(1) 9 (2) 12
(4) Identity Matrix
(3) 11 (4) 7

62. If log8 = , log = –1 and log1/4  = –1, then the 65. Which of the following graphs represents graph of
log ( 2 + 4  2 ) a function?
1  5

value of  + 1 is equal to
 
(1) (2)
(1) 5
(2) 5
(3) 25
(4) 625 (3) (4)

63. Let A = {1, 2, 3, 4}. Which of the following is an

equivalence relation on A ? 66. The value of tan–1(1) + tan–1(0) + tan–1(2) + tan–1 (3)
(1) {(1, 1), (2, 2), (1, 2), (2, 1)} is equal to
5
(2) {(1, 2), (2, 1), (3, 1), (1, 3)} (1)  (2)
4
(3) {(1, 2), (4, 1), (1, 4), (3, 1)}
 3
(4) {(1, 1), (2, 2), (3, 3), (4, 4), (1, 2), (2, 1)} (3) (4)
2 4
[8]
67. The function f : R → R defined as 2
74. Statement I: Equation tan −1 x + 2cot −1 x = has
f(x) = (x – 1) (x – 2)(x – 3) is 3
(1) One-one but not onto exactly one solution.
(2) Onto but not one-one 
(3) Both one-one and onto Statement II: Equation tan −1 (1 − x 2 ) + cot −1 (4 x) = ,
2
(4) Neither one-one nor onto
has exactly two solutions.
(1) Statement I is correct statement II is incorrect
0 −1
68. If the matrix B =   , then B
1027
is equal to (2) Statement I is incorrect and statement II is
1 0 
correct.
 −1 0   0 1 (3) Both statement I and statement II are correct
(1)   (2)  
 0 −1  −1 0  (4) Both statement I and statement II are incorrect
1 0   −1 0 
(3)   (4)  
0 1   0 1 1 + ax 1 + bx 1 + cx
75. If 1 + a1 x 1 + b1 x 1 + c1 x is equal to
x −1 1 + a2 x 1 + b2 x 1 + c2 x
69. The complete set of values of x satisfying 0
x+2
2x − 5
= A0 + A1x + A2 x2 + A3 x3 , then A0 is equal to
and  1 is
x−2 (1) abc (2) 0
(1) (2, ) (2) (2, 3] (3) 1 (4) –1
(3) (−, 3] (4) [1, )
76. A and B are two matrices such that the order A is

(3 – x ) ( x2 − 3 x + 7 )
3 × 4, if A'B and BA' are both defined, then
70. Domain of f(x) = is (1) order of B' is 3 × 4
( x − 7 )( x ) (2) order of B'A is 4 × 4
(1) (–, – 7)  [3, ) (3) order of B'A is 3 × 3
(2) (–7, – 3]  [3, 7) (4) B'A is undefined
(3) (–3, 3)
(4) (–7, 7) 77. If 9 x 2 + 6 x + 1  ( 2 − x ) , then

71. Relation R is defined by R = {(a, b) | a – b + 3 is  3 1  3 1

(1) x − ,  (2) x  − , 
an irrational number} on real numbers, then  2 4  2 4
relation R is  3 1 1
(1) only reflexive (3) x  − ,  (4) x 
 2 4 4
(2) only reflexive and symmetric
(3) only reflexive and transitive
(4) Equivalence 5 6 1 0  T
78. If A =   ,B=   , C = ABA and
 4 5   3 1 
 2x 
If x (1,  ) , then tan −1 
T 2
X = A C A, then det X is equal to
2 
72. equals
1− x  (1) 30 (2) 1
(1) 2tan −1 x (2) − + 2tan −1 x (3) 5 (4) 15
(3)  + 2tan −1 x (4) – – 2 tan–1x
79. If the system of equations
73. The solution set of the inequality ||x – 1| + 2|  2 x + 2 y + 3 z = 5, 2 x + 3 y + z = 9,
has 4 x + 3 y + z =  has infinite number of solutions,
(1) exactly one value of x
then  +  is equal to
(2) no value of x
(3) infinite values of x (1) 1 (2) 2
(4) exactly two values of x (3) 3 (4) 4
[9]
80. Match the Column-I with Column-II a b  2
84. If A =   and it follows A = A and
Column-I Column-II  c 1 − a 
The domain of
f ( x ) = x − x 2 and bc = then the value of
1 5
I  x2  P (0, 1)
f ( x) = sin −1   is 4 f (a)
 2 
  is
The domain of
Q 1 3
II cos −1 x  ,  3
f ( x) = is .4 4  85. If sin −1 x + sin −1 y + sin −1 z = , then the value of
x 2
The range of 9
(sin −1 x + tan −1 x + sec−1 x)
x100 + y100 + z100 − is
III f ( x) = R [−1, − 1] − {0} x101 + y101 + z101
()

is
The range of 86. If A, B and C are n × n matrices and det(A) = 2,
 sec−1 x + tan −1 x  p
det(B) = 3 and det(C) = 5, det(A2BC–1) = , then
IV   S (− 2, 2) q
  
the minimum value of (p + q) is
is
T [− 2, 2] 
87. For n  N , if cot −1 3 + cot −1 4 + cot −1 5 + cot −1 n = ,
(1) I → T, II → R, III → Q, IV → P 4
(2) I → R, II → P, III → Q, IV → S then the value of n is
(3) I → T, II → R, III → T, IV → Q
(4) I → T, II → S, III → Q, IV → P ( x − 1)2 ( x − 4)3 ( x + 3)5
88. If x ∈ R, and  0 , then
Integer Type Questions (81-90)
( x + 7 ) x3
2+ x number of integral values of x satisfying above
81. If 2 f ( x ) = , x  (−2, 2) and inequality is equal to
2− x
 8x 
f ( x ) = f   then value of ‘2’ will be 89. The number of solutions of the equation
 4 + x2 
2[x] = x + {x}, is equal to
2 − k 2  (where [] denotes G.I.F. and {} denotes fractional
If A = 
3 − k 
82. is non-invertible, then the part function)
 1
value of |k2 – 5k|, is equal to 90. If A is a square matrix of order n with |A| = 9 and
|adj(adj(adjA))| = 316, then number of elements in
83. The value of (–17)  tan  2 tan −1 1 −    , is A, is equal to
  5 4 

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