M.

Prakash Institute
STD XII
Cumulative Test

Test-45 Mains F3 Batch 01/06/2024

Marking Scheme

Sec 1: 20 questions Single Choice 4, -1

Sec 2: 5/10 questions Numerical Type 4, 0

Syllabus

Physics Maths Chemistry

 M. Prakash Institute

Std : XI(F2 and F3) Exam type : JEE - Mains

Batch : F2 and F3 Date - 01/06/2024

Section I - Single Option correct : 20 questions (+4, -1)

1. A carnot engine has efficienct 10 % but used as refrigerator. If the electrical energy
consumed is 10 J, how much energy in J is pumped out of the room by this refrig-
erator.
a. 100
b. 99
c. 10
d. 90

2. In Platinum resistance thermometer, resistance of platinum wire is calibrated to

read the temperature. The resistance of the wire is recorded as 11 Ω at tripple
point of water. What will be the exact reading of temperature in degree F when
the resistance is 33 Ω?
a. 1015.4o F
b. 1015.7o F
c. 546.3o F
d. 1025.4o F

3. The coefficient of linear thermal expansion of certain metal is function of tem-

perature as α = (20000 + T 2 )10−10 /o C, where T is in deg C. What will bw the
average coefficient of thermal expansion in temperature range from 100o C to 200o C
in 10−6 /o C
a. 16/7
b. 14/5
c. 13/3
d. 3/2

4. One mole of ideal monoatomic gas is linearly compressed from 2V to V when pres-
sure increases from P to 3P. What is the maximum temperature of the gas during
the process?
a. 15PV/8R
b. 25PV/8R
c. 3PV/R
d. 16PV/7R

5. The idea gas follows the adiabatic process by following the relation U = 2 + 3P V .
Figure out the nature of the gas
a. Mono-atomic
b. Diatomic
c. Linear Triatomic

1
 d. Non-linear Triatomic

6. The distance between the centres of two stars of mass 16M (radius 2a ) and M(
radius a ) is 10a. With what minimum speed the small body of mass m should be
thrown
q from the surface of larger star towards the smaller one to reach on it.
15GM
a. 4a
q
25GM
b. 2a
q
15GM
c.
q 2a
45GM
d. 4a

7. The particle is released from rest at height of R/2 above the deep well of depth R/2.
With
q what speed the particle will strike the bottom of the well?
a. 17GM
5R
q
17GM
b.
q 2R
17GM
c.
q 12R
15GM
d. 4R

8. By what percent the acceleration due to gravity drops at lattitude of 45o due to
spinning of the earth?.
a. 0.23
b. 0.17
c. 0.54
d. 0.84

9. The satellite is rotating in circular orbit at height R. The work done by external
agent to reset it in circular orbit such that the time period of rotation becomes eight
times is

3GM m
a. 16R

7GM m
b. 2R

GM m
c. 5R

GM m
d. 2R

10. Spherical volume of charge having radius R has non uniform charge distribution in-
side it. The volume charge density varies linearly from zero at centre to maximum
at the surface. If the total charge is Q what will be the ellectric field at half way
along the radius.
kQ
a. R2

2
 3kQ
b. 4R2

kQ
c. 4R2

kQ
d. 2R2

11. The point charge +q is kept at the radial and axial centre of hollow cylinder of
radius 3 cm and length 8 cm. The electric flux linked with curved surface of the
cylinder would be
q
a. 10o

4q
b. 5o

2q
c. o

q
d. 5o

12. The parallel plate capacitor has both plates in the form of discs of radius R sepa-
rated by distance d. The capacitance with air in between is C. Now, the dielectric
disc of thickness d, radius R/2 and relative permitivity 6 is introduced inside the
plates co-centrically. The capacitance becomes

7C
a. 2

7C
b. 3

9C
c. 4

5C
d. 2

13. The unbalanced Wheat Stone bridge has arm resistances in cyclic order as 2Ω, 4Ω, 6Ω and 8Ω and
bridge resistance is 10Ω. If the main current entering the bridge circuit is 3/8 amp.,
the currecnt flowing through the bridge is ( in amp).
1
a. 30

1
b. 4

1
c. 8

1
d. 40

14. We have cubical skeleton of wires with each wire having equal resistance R. Let R1

3
 , R2 and R3 are resistances of this skeleton across the edge, face digonal and space
digonal respectively. The ratio R1:R2:R3 is
a. 3 : 5 : 8
b. 7 : 9 : 11
c. 7 : 9 : 10
d. 3 : 5 : 6

15. Galvanometer, resistance of 90 ohm and cell of internal resistance 10 ohm are all
connected in series to form the circuit. Now when galvanometer is shunted with 10
ohm , it shows 9 mA whereas shunted with 50 ohm shows 30 mA. The resistanec of
galvanometer coil in ohm is ..

700
a. 3

300
b. 5

300
c. 7

700
d. 9

16. There is an infinite wire grid with square cells. The resistance of each wire between
neighbouring joint connections is equal to R. The resistance whole grid across any
two adjacent points of the cell is ..
a. R
b. R/2
c. R/4
d infinite

17. The gap between the plates of a parallel-plate capacitor is filled with glass of resis-
tivity ρ = 100GΩ · m. The capacitance of the capacitor equals C = 4.0nF. Find the
leakage current of the capacitor in micro amp when a voltage V = 2.0kV is applied
to it.
a. 3.5
b. 2.8
c. 1
d. 1.5

18. The battery is formed by using six identical cells of emf 2 V and int. res. 1 ohm
each. When cells are in order current driven through the load is 1 amp. If now two
cells are connected in reverse order what will be the current in amp flowing through
the same given load.?
a. 1/4
b. 1/6
c. 1/3
d 1/2

4
19. The capacitor of capacitance 400 µF is connected via. resistance of 650 ohm to the
cell. The time in micro second after which 90 % of the charging will be done.
a. 0.6 µs
b. 1 µs
c. 6 µs
d. 2 µs

20. Let Eo is the external field due to free charges and E is the net electric field inside
dielectric slab. Let  is the permitivity of the dielectric material and o is the per-
mitivity of free space. The polarisation inside the slab will be ..
a. ( − o )E
b. ( − o )Eo
c. o E
d. E

Section II - Numerical Answer Type : questions (+4, -1)

21. A one litre glass flask has some mercury inside it. When the complete system is
heated, it is observed that volume of air inside the flask does not change. What is
the volume of mercury in cc inside the flask. Use the data: αglass = 9X10−6 /o C
and cubical dilation of mercury 1.8X10−4 /o C

22. A particle is projected from the surface of the earth with escape speed at angle 45o .
The angle in degree at which it will be moving with respect to tangential direction
at the instant it is at height R above the surface of earth is ..

23. Co-axial cable has central metalic thick wire ( acting as one electrode) of radius 1.5
cm, two co-centric claddings of dilectric material over the core( first of thickness 1.5
cm and K=2 and second of thickness 3 cm and K =4) further having conducting
shell of radius 6 cm.( serving as second electrode). The running capacitance( capac-
xπo
itance per unit length) of this cable is 3ln(2) where the value of x is ..

24. Capacitor of capacitance 10 µF is charged to 40 Volt and second capacitor of capac-

itance 15 µF is charged to 30 Volt independently. The charge will get redistributed
once both are connected across each other. The charge which will flow from smaller
capacitor to larger capacitor in µC is ..

25. EMF of very old cell is measured by using potentiometer( reading is 1.55 volt )
and then by using voltmeter of resistance 280 Ω ( reading 1.4 volt). The internal
resistance of the cell in Ω is

26. The metalic wire of radius 1 mm and length 1 Km has current of 70 amp flowing
through it. The total linear momentum of all electrons( mass being 9.1X10−31 Kg)
is xX10−8 N s where x is equal to ..

5
27. In potentiometer set-up, the length of potemtiometer wire is 6 m and the electron
inside it experiences the force of 2.4X10−19 N. The EMF of potentiometer battery
in volt is ..

28. Voltmeter, ammeter and cell all are connected in series. It is observed that when
voltmeter is shunted with some resistance, ammeter now reads three times more
than earlier where as voltmeter now reads three times less. What is the ratio of
resistance of voltmeter to resistance of ammeter.

29. We have two immersion heaters. If one of them is used separately across the res-
idential electrical source then given water boils in 6 min whereas if second used
separetely then it takes 8 min. If both heaters are connected in series and used
across the same source, same given water will boil in ........min.

30. The free surface charge density is 6 µCm−2 . What will be the bound surface charge
density in µCm−2 on the surface of dielectric slab having electric successptibilty 5?

6
Test 45 F3 - mains - Second One third test Date 01/06/2024

Section I -Single Option Correct - 20 questions

r
√ √
q
31. lim ( x + x + x − x) =
x→∞
1 1
(A) 0 (B) 1 (C) (D) .
2 3
 1
x2 esin x if x 6= 0
32. Let f : R → R given by f (x) = . Then at x = 0, f is
0 if x=0
(A) continuous but not differentiable (B) continuous and differentiable
(C) neither continuous nor differentiable (D) differentiable but not continuous.

1
33. Range of f (x) = x2 + 2 is
x +4
 
1
(A) [−2, ∞) (B) ,∞ (C) [4, ∞) (D) N.O.T.
4
 
1 5
34. If f is convergent for large values of x and f (x) = f (x + 1) + and
3 f (x + 2)
f (x) > 0 ∀x ∈ R then lim f (x) =
x→∞
r r
2 5
(A) (B) (C) ∞ (D) None.
5 2
35. Number of points where the function f (x) = max(| tan x|, cos |x|) is not differen-
tiable in the interval (−π, π) is
(A) 4 (B) 6 (C) 3 (D) 5
x
36. The function f (x) = , x ∈ R − {−2, 8}
x2− 6x − 16
(A) decreases in (−∞, −2) ∪ (−2, 8) ∪ (8, ∞)
(B) decreases in (−∞, −2) and increases in (8, ∞)
(C) decreases in (−2, 8) and increases in (−∞, −2) ∪ (8, ∞)
(D) increases in (−∞, −2) ∪ (−2, 8) ∪ (8, ∞)

37. Let f be a function defined by f (x) = 2|log2 x| , then at x = 1

(A) f is continuous as well as differentiable (B) continuous but not differentiable
(C) differentiable but not continuous (D) neither continuous nor differentiable.
r p !
2
1 + xn 1 − x0
38. If xn+1 = and |x0 | < 1, n ∈ W then lim =
2 n→∞ x1 x2 x3 · · · xn+1
(A) -1 (B) 1 (C) cos−1 (x0 + 1) (D) cos−1 (x0 )

1
 1 − x2
 
1
39. Let y = loge , −1 < x < 1. Then at x = , the value of 225 (y 0 − y 00 ) is
1 + x2 2
equal to
(A) 746 (B) 742 (C) 736 (D) 732

40. A unit vector in the xy−plane, that makes an angle of 450 with the vector î + ĵ and
an angle of 600 with the vector 3î − 4ĵ is
1 1 1
(A) √ (13î+ĵ) (B) √ (î+ĵ) (C) √ (î−ĵ) (D) None of these.
170 2 2

41. The equation of the plane which contains the line of intersection of the planes
x + 2y + 3z − 4 = 0 and 2x + y − z + 5 = 0 and perpendicular to the plane
5x + 3y + 6z + 8 = 0 is
(A) 51x + 15y − 50z + 173 = 0 (B) 51x + 15y − 50z = 0
(C) 51x + 15y − 50z + 10 = 0 (D) None of these.

→
− →
− →
−
42. If |→
−
a | = 2, | b | = 3 and →
−a . b = 0 then→
−
a × (→
−
a × (→
−a × (→
−
a × b ))) is equal to
→
− →
− →
−
(A) 48 b (B) −48 b (C) 48→
−
a (D) 16 b

→
− −
43. Let →
−r ,→
−
a , b ,→c be four non - zero vectors such that → −r ·→
−a = 0,
→
− →
− →
− →
− →
− →
− →
− →
− →
− →
− →
−
| r × b | = | r || b | and | r × c | = | r || c | , then [ a b c ] =
(A) 0 (B) 2|→−
r| (C) |→ −r| (D) None of these.

44. Let a, b, c be natural numbers such that LCM of a, b is 1000, LCM of a, c is 2000
and LCM of b, c is 2000. Then the number of ordered triplets (a, b, c) is
(A) 63 (B) 90 (C) 70 (D) N.O.T.
10
1 + 22n+1
 
X a
45. If the equation cot−1 n
= cot−1 , where a and b are coprime positive
n=0
2 b
 
b+a
integers. The value of log2 , is:
a−b
(a) 9 (b) 10 (c) 11 (d) 12
46. The least non-negative integral value of λ for which the equation
2x2 − 2(2λ + 1)x + λ(λ + 1) = 0 has one root less than λ and other root greater
than λ, is equal to:
(a) 0 (b) 1 (c) 2 √ (d) 4


2
47. Let f, g : R → R given by f (x) = ln x + 1 + x and g(x) = x|x|. Then
(A) Both f, g are odd functions (B) Both f, g are even functions
(C) One of f, g is odd and other is even (D) One of f, g is neither odd nor even.

4
48. The equation of the tangent to the curve y = x + , that is parallel to the x-axis is
x2
(A) y = 0 (B) y = 1 (C) y = 2 (D) y = 3.

49. If a function f : [−2a, 2a] → R is an odd function such that f (x) = f (2a − x) for
x ∈ [a, 2a] and the left hand derivative at x = a is zero then left hand derivative at
x = −a is

2
 (A) a (B) 0 (C) −a (D) 1

50. Let f (x + y) = f (x)f (y) for all x and y. Suppose that f (3) = a and f 0 (0) = b then
f 0 (3) is given by (a, b ∈ R)
(A) ab (B) a + b (C) 2ab (D) 2a + b

Section II- Numerical Answer (10 questions) Solve any 5

51. If f (x) = x3 + x2 + x + a sin x + b cos x is invertible then maximum value of a2 + b2
is

sin x
52. Assuming that the following limit exists, find it. lim x+
x→0 sin x
x+
sin x
x+
x + ···∞
53. Let f (x) = (x+3)2 (x−2)3 , x ∈ [−1, 4]. If M and m are the maximum and minimum
values of f , respectively in [−4, 4]. then the value of M − m is

54. The number of solutions of equation, sin sin−1 [x] + cos−1 (cos x) = 1 is : (where [.]

denotes the greatest integer function)

55. tan sin−1 cos sin−1 x (tan (cos−1 (sin (cos−1 x)))) where x ∈ (0, 1) is equal to :

→
− −
56. →
−a , b ,→c are three vectors of equal magnitude and the angle between each pair of
vectors √
→
− −
is 600 . If |→
−
a + b +→ c | = 6, the |→−a | = ......

57. The distance of the point (1, −2, 3) from the plane x − y + z = 5 measured parallel
x y z
to the line = = − is . . . . . .
2 3 6

58. The length of the shortest distance between the lines ,

→
−
r1 = −3î + 6ĵ + λ(−4î + 3ĵ + 2k̂) and →
−
r2 = −2î + 7k̂ + µ(−4î + ĵ + k̂) is . . . . . .
→
−
59. If →
−
a = î + 2ĵ + 3k̂, b = 2î − ĵ + k̂, →
−c = 3î + 2ĵ + k̂ and
→
− →
− →
−
a ×( b ×→ −c ) = p→−a + q b + r→
−c ; then p + q + r = . . . . . .

60. n is a natural number such that 1 ≤ n ≤ 100. For how many n, is the number
2n + 3n + 5n divisible by 4?

3
 Single Correct Type
Q61) A compound containing Zn, Al and S crystallizes with a closed packed array of sulphide ions.
Aluminium ions are found in one-eighth of the tetrahedral holes and Zinc ions in one half of the
octahedral holes. What is the empirical formula of the compound?

(A) ZnAl2S4 (B) ZnAlS4 (C) Zn2AlS4 (D) ZnAl2S8

Q62) The 𝛥𝐻 to form one mole of 𝐹𝑒3 𝑂4 from 𝐹𝑒 and 𝑂2 is:

3
2𝐹𝑒 + 𝑂2 → 𝐹𝑒2 𝑂3 ; 𝛥𝐻 = 𝑥𝐾𝐽/𝑚𝑜𝑙
2
2𝐹𝑒 + 𝑂2 → 2𝐹𝑒𝑂; 𝛥𝐻 = 𝑦𝐾𝐽/𝑚𝑜𝑙
𝑥 2𝑥+𝑦
(𝐴) + 𝑦 (𝐵)
2 2

2𝑥−𝑦 𝑦−2𝑥
(𝐶) (𝐷)
2 2

Q63) 𝐼𝐹7 + 𝐵𝐹3 → [𝑋]

What is the shape of cationic and anionic part in ionic compound [𝑋] respectively?
(A) Trigonal bipyramidal and Octrahedral
(B) Trigonal bipyramidal & Tetrahedral
(C) Octahedral & Tetrahedral
(D) Pentagonal bipyramidal & Tetrahedral

Q64) Aqueous solution of NaCl containing a small amount of MeOH (Methyl orange) is
electrolysed using Pt-electrodes. The colour of the solution after some time will:
(A) Remains yellow (B) Change from yellow to colourless
(C) Change from yellow to red (D) Remain red

Q65) Tautomerism is not be possible in:

Q66) Which of following species can not exhibit geometrical isomerism ?

Q67) Which of the following relation is incorrect :

Q68) Which shows the correct stereo chemical structure of product ?

Q69) Which order is correct for nucleophilicity and basicity ?

Q70) Arrange PH of the given compounds in decreasing order:

(i) Phenol (ii) Ehtyl alcohol

(iii) Formic acid (iv) Benzoic acid

(A) (i) > (ii) > (iii) > (iv)

(B) (ii) > (i) > (iv) > (iii)

(C) (iii) > (ii) > (iv) > (i)

(D) (iv) > (iii) > (i) > (ii)

Q71) Decreasing order of stability of the following carbanion is:

 (A) II > III > IV > I

(B) III > IV > I > II

(C) I > IV > III > II

(D) II > I > III > IV

Q72) The species which are stable at room temperature is:

Q73) Which of the following is arranged in correct order of the properties mentioned.
Q74) Observe the following reaction sequence

(X) can be

Q75) The product formed in the reaction

Q76) Cl-O bond length in 𝐶𝑙𝑂2− , 𝐶𝑙2 𝑂, 𝐶𝑙𝑂2+ and 𝐶𝑙𝑂2 follows the order.
(A) 𝐶𝑙𝑂2− < 𝐶𝑙2 𝑂 < 𝐶𝑙𝑂2 < 𝐶𝑙𝑂2+
(B) 𝐶𝑙𝑂2+ < 𝐶𝑙𝑂2 < 𝐶𝑙𝑂2− < 𝐶𝑙2 𝑂
(C) 𝐶𝑙𝑂2+ < 𝐶𝑙𝑂2− < 𝐶𝑙𝑂2 < 𝐶𝑙2 𝑂
(D) 𝐶𝑙𝑂2+ < 𝐶𝑙2 𝑂 < 𝐶𝑙𝑂2 < 𝐶𝑙𝑂2−

Q77) A substance 𝑋𝑌3 decomposes as:

XY3(g) → XY(g) + Y2(g); △oH1 = 50 KJ/mol
XY3(g) → XY(g) + Y2(g); △oH2 = 60 KJ/mol
The ratio of partial pressure of 𝑋𝑌 and 𝑋𝑌2 in the mixture of gases obtained by decomposition of
𝑋𝑌3(𝑔) is 2: 1. Find the total enthalpy change for the decomposition of one mole of 𝑋𝑌3(𝑔).
(A) 53.33𝐾𝐽/𝑚𝑜𝑙 (B) 160𝐾𝐽/𝑚𝑜𝑙
(C) 110𝐾𝐽/𝑚𝑜𝑙 (D) 1110.33𝐾𝐽/𝑚𝑜𝑙

Q78) Which of the following does not give a precipitate with alcoholic AgNO3 ?
(A) Benzyl chloride (B) Chlorobenzene

(C) Allylchloride (D) t-butyl chloride

Q79) Order of hydrolysis of the following in increasing order is ;

(A) (I) < ( II) < (III) < (IV)

(B) (IV) < (III) < (II) < (I)

 (C) (I) < ( II) < (IV) < (III)

(D) (I) < ( IV) < (II) < (III)

Q80) Identify the product (D) in the following reaction

Useful Data: 𝑁𝐴 : 6 × 1023

Atomic numbers: 𝐻: 1, 𝐿𝑖: 3, 𝐵: 5, 𝐶: 6, 𝑁: 7,0: 8, 𝑁𝑎: 11, 𝑀𝑔: 12, 𝐴𝑙: 13, 𝑆: 16, 𝐶𝑙: 17, 𝐴𝑟: 18,
𝐾: 19, 𝐶𝑎: 20, 𝐶𝑢: 29, 𝐵𝑟: 35, I: 53
Atomic masses: 𝐻: 1, 𝐿𝑖: 7, 𝐵: 11, 𝐶: 12, 𝑁: 14, 𝑂: 16, 𝑁𝑎: 23, 𝑀𝑔: 24, 𝐴𝑙: 27, 𝑆: 32, 𝐶𝑙: 35.5
Ar:40, K:39, Ca:40, Ti: 48, Cr : 52, Fe: 56, Mn: 55, Cu: 63.5, 𝑍𝑛: 65, 𝐵𝑟: 80, 𝐼: 127, 𝐵𝑎: 137

Numerical Type
Q81) Five isomers of C4H8Br2 are formed in the above reaction. How many structures are possible
for F?
H3C CH3 +
H Br2, CCl4
-H2O F C4H8Br2
OH

Q82)
The number of structural and configurational isomers of a bromo compound, C5H9Br formed by
addition of HBr to 2-pentyne respectively are X and Y. Find X + Y
Q83)
OH
+
CH3 H
CH3
CH3
CH3 CH3
CH3
For the above transformation, how many out of the four following steps are involved
(a) Protonation at the C=C linkage
(b) Protonation at -OH group
(c) Formation of 20 carbocation
(d) Formation of 30 carbocation

Q84) Product ‘B ’in the following reaction is assigned by number ______.

Q85) A 7𝑐𝑚3 solution of 𝐻2 𝑂2 liberates 0.508𝑔 of iodine from an acidified KI solution. Calculate
the strength of 𝐻2 𝑂2 solution in term of volume strength at STP.

Q86) A sample of 0.56 gm of an organic compound was treated according to Kjeldahl's method.
The ammonia evolved was absorbed by 2.45 gm of H2SO4. The residual acid required solution
containing 0.72 gm. NaOH for neutralisation. Find the percentage composition of nitrogen in the
compound ?

Q87) A vessel contains 8.64 grams TiO2, 11.52 grams C and 6.39 grams Cl2, suppose the reaction
goes to completion as written, the maximum gram of TiCl4 that can be produced are P.QRS grams.
What is the value of ‘P’ ?
Given reaction : TiO2 (s) + C(s) + Cl2 (g) → TiCl4 (g) + CO2 (g) + CO(g)

Q88) One mole of NaCl(s) on melting absorbed 30.5 KJ of heat and its entropy is increased by 28.8
J/K. What is the melting point of sodium chloride?

Q89) You are given some marbles with a diameter of 10mm. They are to be placed such that their
centres are lying in a square bond by four lines each of length 40 mm. The arrangements of marbles
in a plane is made such that maximum number of marbles can be placed inside the entire area. The
𝑥
number of molecules per unit area is calculated as . What is the value of ‘x’ ?
𝑦
o √3
(Sin 60 = )
2
Q90) n-butane is produced by the monobromination of ethane followed by Wurtz reaction.
Calculate the volume of ethane at STP required to produce 44.37 grams n-butane if the bromination
takes place with 90% yield and the Wurtz reaction with 85% yield.