Class: XI CHEMSITRY CHAPTER#06

1. For the reaction 2NO2 ⇌ N2O4 ∆H = + 61 KJ at equilibrium, the increase of

temperature would:
A. Favour the formation of N2O4 D. Stop the reaction
B. Favour the decomposition of N2O4 E. None of These
C. No effect on equilibrium
2. In a chemical reaction equilibrium is said to have established when the:
A. Concentration of reactants & products are equal
B. Operating reaction ceases
C. Velocities of opposing reactions become equal
D. Temperature of the opposing reactions are equal
E. Both a & c
3. At equilibrium which of the following reaction is not affected by pressure?
A. ½ N2 + ½ O2 ⇌ NO D. SO2Cl2 ⇌ SO2+Cl2
B. PCl5 ⇌ PCl3+Cl2 E. 2SO2+O2 ⇌ 2SO3
C. 2NO2 ⇌ N2O4
4. Which of the following value of Kc represents a reaction in which the product is
most stable?
A. Kc = 1 D. Kc = 10-5
B. Kc = 10 E. Kc = 102
-2
C. Kc = 10
5. 10 litre solution of urea (N2H4CO) contains 240g of urea. The active mass of urea
will be:
A. 4 D. 0.2
B. 0.4 E. 0.02
C. 0.04
6. Relationship between Kc & Kp is given by:
A. Kc = Kp x (RT)∆ D. Kp =
( )∆
B. Kp = Kc x (RT) ∆
E. All of these
C. Kc = ∆
( )
7. Unit of active mass of a substance is:
A. g D. mol/litre
B. mol E. Both C & D
3
C. g/dm
8. In which of the following reactions Kp & Kc will have same numerical value?
A. 2SO2+O2 ⇌ 2SO3 D. N2+O2 ⇌ 2NO
B. N2+3H2 ⇌ 2NH3 E. CaCO3 ⇌ CaO+CO2
C. PCl5 ⇌ PCl3 + Cl2
9. For a reaction 2A+B ⇌ C+D, the partial pressures of A,B,C & D are; 0.5,0.8,0.7 &
1.2 respectively at equilibrium. The value of Kp for this reaction is:
A. 0.24 D. 2.4
B. 0.42 E. 4.8
C. 4.2
10. For the reaction CO+2H2 ⇌ CH3OH:
A. Kp = Kc D. Kc = 0 but Kp ≠ 0
B. Kp < Kc E. Kc ≠ 0 but Kp = 0
C. Kp > Kc
11. Chemical equilibrium is dynamic in nature because:
A. Equilibrium is attained rapidly
B. Concentration of reactants & products become equal
C. Both forward & backward reactions occur at all times with same speed
D. Both A & C
E. All of These
12. If, the volume of the reaction vessel containing an equilibrium mixture in the
reaction SO2Cl2 ⇌ SO2+Cl2 is increased. When the equilibrium is re-established,
the amount of:
A. SO2 will have decreased D. Cl2 will have decreased
B. SO2Cl2 will have increased E. Cl2 will remain unchanged
C. Cl2 will have increased
13. Which of the following reaction will be favoured at low pressure?
A. H2+I2 ⇌ 2HI D. 2SO2+O2 ⇌ 2SO3
B. N2+3H2 ⇌ 2NH3 E. N2+O2 ⇌ 2NO

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Class: XI CHEMSITRY CHAPTER#06

C. PCl5 ⇌ PCl3+Cl2
14. In the system liquid ⇌ vapour, the increase in pressure will favour:
A. Condensation D. No effect of pressure
B. Evaporation E. None of These
C. Sublimation
15. The equilibrium constant for the reaction 2A+B ⇌ 2C is 2.25. What would be the
concentration of B at equilibrium with 2.0 moles of A & 3.0 moles of C in one
litre vessel?
A. 1 mole D. 2.5 mole
B. 0.5 mole E. 3.5 mole
C. 1.5 mole
16. 1.1 mole of A is mixed with 2.2 mole of B the mixture is kept in one litre flask till
the equilibrium A+2B ⇌ 2C+D is reached. At equilibrium 0.2 mole of C is formed.
The Kc is:
A. 0.001 D. 0.004
B. 0.002 E. 0.025
C. 0.003
17. 3g-moles of PCl5 are allowed to dissociate in a one litre flask. If 50% PCl5
dissociate at equilibrium, the equilibrium constant would be: PCl5 ⇌ PCl3+Cl2
A. 0.75 D. 1.5
B. 1.0 E. 3.0
C. 1.25
18. Molar concentration of 32g O2 in 10 dm3 is:
A. 3.2 mol/dm3 D. 0.1 mol/dm3
B. 32 mol/dm3 E. 2 mol/dm3
3
C. 1 mol/dm
19. 28g N2 & 6g H2 were mixed. At equilibrium 17g of NH3 was produced. The
weights of N2 & H2 at equilibrium are respectively: N2+3H2⇌2NH3
A. 11g, 2g D. 11g, 3g
B. 7g, 3g E. 14g, 2g
C. 14g, 3g
20. In the system CaF2 ⇌ Ca+2+2F- if the concentration of Ca+2 ions is increased 4
times, the equilibrium concentration of F- ion will change to:
A. ½ of the initial value D. 4 times of the initial value
B. ¼ of the initial value E. No effect
C. 2 times of the initial value
21. The solubility product of a sparingly soluble salt AB is 1.21 x 10-6 M. Its molar
solubility is:
A. 1.21x 10-6 M D. 1.1x 10-3 M
-3
B. 1.21x 10 M E. 1.21x 10-2 M
-6
C. 1.1x 10 M
22. The metal sulphide having maximum solubility in water is:
A. CdS (Ksp= 3.6 x 10-29) D. MnS (Ksp= 1.4 x 10-16)
-28
B. PbS (Ksp= 3.4 x 10 ) E. CoS (Ksp= 3 x 10-26)
C. NiS (Ksp= 1.4 x 10-24)
23. Solubility of PbCl2 is ‘ ’ mol/liter. Its solubility product is:
A. s2 D. 2s3
B. 2s2 E. 4s2
3
C. 4s
24. When equal volumes of the following solutions are mixed precipitation of AgCl
(Ksp = 1.8x10-10) will occur only in case of:
A. 10-4 M [Ag+] & 10-4 M [Cl-] D. 10-10 M [Ag+] & 10-6 M [Cl-]
-5 + -5 -
B. 10 M [Ag ] & 10 M [Cl ] E. 10-8 M [Ag+] & 10-8 M [Cl-]
C. 10-6 M [Ag+] & 10-6 M [Cl-]
25. Solubility product of sparingly soluble salt AB2 is 0.108 x 10-12 M at 25℃. Its
molar solubility is:
A. 3x10-6 M D. 2.7x10-4 M
-4
B. 3x10 M E. 3x10-5 M
-5
C. 2.7x10 M
26. Solubility of Ag2CrO4 in saturated solution is 5x10-2 mol/liter. Its solubility
product is:

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Class: XI CHEMSITRY CHAPTER#06

A. 5x10-6 M D. 5x10-4 M
B. 2.5x10-6 M E. 6.25x10-4 M
-6
C. 1.25x10 M
27. The equilibrium constant for the reaction 3C2H2 ⇌ C6H6 is 4. If the equilibrium
concentration of C2H2 is 0.5 mol/dm3. What is the concentration of C6H6?
A. 5 mol/dm3 D. 1.5 mol/dm3
3
B. 0.5 mol/dm E. 2.5 mol/dm3
C. 0.25 mol/dm3
28. 85 g of are present in 5 litre cylinder. Active mass of is;
A. 5 D. 1
B. 2.5 E. 0.5
C. 1.5
29. For the reaction 2A + 3B ⇌ 3C, 1 mole of each A and B is allowed to attain
equilibrium. Equilibrium mixture contain 0.6 mole of A. Moles of B & C at
equilibrium is respectively;
A. 0.6, 0.6 D. 0.4, 0.6
B. 0.4, 0.6 E. 0.1, 0.9
C. 0.6, 0.9
30. For the reaction 3A + 2B ⇌ C. The value of Kc will be;
[ ] [ ]
A. = [ ][ ] D. =[ ] [ ]
[ ] [ ] [ ]
B. = E. =[ ] [ ]
[ ]
[ ]
C. =[ ] [ ]
31. Unit of Kc for the reaction; ( )+ ( ) ⇌ ( ) is:
3 6
A. mol /dm D. dm9/mol3
3 9
B. mol /dm E. dm3/mol
C. dm6/mol2
32. For the reaction PCl5 ⇌ + ?
A. = × ( ) D. = ×( )
B. = ×( ) E. = ×( )
C. = ×( )
33. + ⇌ + . Two moles each of A & B were taken into one litre flask. The
following must always be true when the system attains equilibrium;
A. [ ] = [ ] D. [ ] + [ ] > [ ] + [ ]
B. [ ] < [ ] E. not concerned with concentration
C. [ ] > [ ]
34. In which of the following case reaction goes farthest to completion?
A. = 10 D. = 10
B. = 10 E. = 10
C. = 10
35. Kc for the reaction + ⇌ + is 10. Rate constant of forward reaction is .
Rate constant of backward reaction is?
A. 103 D. 105
4
B. 10 E. 106
-4
C. 10
36. In what manner will increase of pressure affect the equilibrium ( ) + ( ) ⇌
( ) + ( )
A. shift the equilibrium to the right D. increase in the yield of H
B. shift the equilibrium to the left E. None of these
C. no effect on equilibrium
37. The reaction in which the yield of the products can not be increased by the
application of high pressure is?
A. ( )+ ( ) ⇌ ( ) D. 2 ( )+ ( ) ⇌2 ( )
B. ( )+3 ( ) ⇌2 E. 2 ( ) + ( ) ⇌ 2
C. ( ) + ( ) ⇌ 2 ( )
38. For the reaction + ⇌ , at equilibrium 0.4 mole of AB is formed when one
mole of each A and B is taken. How much percentage of A changes into AB?
A. 20 D. 4
B. 40 E. 6

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Class: XI CHEMSITRY CHAPTER#06

C. 60
39. For the given reaction; ⇌ , =− which of the following condition will
not favour dissociation of ?
A. High temperature D. decreasing volume
B. low temperature E. All except B
C. decreasing conc. of
40. For this reaction 2AB ⇌ + ; 4 mole of AB are introduced into a two litre flask.
At equilibrium, mixture contains 2 moles of AB. Value of Kc will be:
A. 0.5 D. 1.5
B. 0.25 E. 2
C. 1
41. Which statement is correct for the reaction; ⇌ =+
A. formation of ozone is favoured at low temperature
B. dissociation of ozone is favoured at high temperature
C. high temperature will shift the equilibrium forward
D. low temperature will shift the equilibrium forward
E. high temperature will shift the equilibrium backward
42. Value of for the reaction / + / ⇌ at 273℃ is . . Value for will
be;
A. 0.5 D. 1.5
B. 0.25 E. 2.5
C. 5
43. Value of of different compounds is as; = × , ( ) = . × ,
= . × & = . × . Order for solubility of compounds is as;
A. > ( ) > > D. > ( ) > >
B. > ( ) > > E. ( ) > > >
C. > ( ) > >
44. A catalyst affects;
A. equilibrium position only D. both forward and backward reactions
B. forward reaction only E. no effect on any one
C. backward reaction only
45. If for a gaseous equilibrium n = − then;
A. = C. <
B. > D. no prediction can be made
46. At equilibrium:
A. concentration of reactants and products become equal
B. concentration of reactants is less than conc. of products
C. concentration of reactants is more than conc. of products
D. concentration of reactants and products remain same
E. None of these
47. Which of the following possess maximum active mass?
A. 10 in 5 litres. D. 56 g of in one litre
B. 96 g of in two litres. E. 127 g of I2 in one litre
C. 300 g of in two litres
48. Correct relation between & for the reaction ( )+ ( ) ⇌ ( ) is;
A. = ×( ) D. =( )
B. = ×( )
E. ×( ) =
C. =( )
49. If 10 moles of are allowed to dissociate. At equilibrium % is dissociated.
Moles of & at equilibrium are respectively:
A. 4,4 D. 2,2
B. 6,6 E. 5,5
C. 3,3
50. Solubility product of ( ) is given by the expression;
A. [ ][ ] D. [ ] [ ]
B. [ ] [ ] E. [ ] [ ]
C. [ ] [ ]
51. of is . × . Molar solubility of is:
A. 8.0 × 10 M D. 8 × 10 M
B. 1.6 × 10 M E. 4 × 10 M

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Class: XI CHEMSITRY CHAPTER#06

C. 4 × 10 M
52. Which is correct for type salt?
A. =4 D. = 108
B. = 27 E. =
C. =
53. A solution is said to be unsaturated if;
A. Ionic product < Ksp D. Ionic product > Ksp
B. Ionic product = Ksp E. None of these
C. Ksp < ionic product
54. If the concentration of chromate ion in a saturated solution of silver
chromate is × . of silver chromate will be?
A. 16 × 10 D. 8 × 10
B. 32 × 10 E. 16 × 10
C. 32 × 10
55. If the solubility of ( ) is √ , what will be the solubility product?
A. 3 D. 12√3
B. √3 E. 12
C. 27
56. Active mass of 96g of O2 contained in 2 liter vessel is?
A. 6 mol/L D. 4 mol/L
B. 3 mol/L E. 1.5 mol/L
C. 16 mol/L
57. Equilibrium constant of the reaction A + B ⇌ C + D is 10. If rate constant of
forward reaction is 203, the rate constant of backward reaction is:
A. 20.3 D. 203
B. 2.03 E. 0.203
C. 10.3
58. N2 + O2 ⇌ 2NO ∆H = +ve. The forward reaction is favoured by:
A. Decreasing pressure D. Decreasing N2 concentration
B. Increasing temperature E. None of These
C. Presence of catalyst
59. 8 moles of a gas AB3 are introduced in a one liter flask, where it dissociates as:
2AB3 ⇌ A2 + 3B2. At equilibrium 2 moles of A2 are present. Kc for the reaction is;
A. 72 D. 27
B. 36 E. 16
C. 3
60. The effect of increasing pressure on the equilibrium 2A + 3B ⇌ 3C + 2D indicates
that:
A. Forward reaction is favoured D. Reaction stops
B. Reverse reaction is favoured E. Both C & D
C. No reaction is favoured
61. At equilibrium state:
A. Forward reaction is fast D. Backward reaction stops
B. Backward reaction is fast E. Both reactions proceed at same speed
C. Forward reaction stops
62. Unit of Kc for the reversible reaction 2SO2 + O2 ⇌ 2SO3 is:
A. mol/dm3 D. dm3/mol
B. mol2/dm6 E. dm6/mol2
3 9
C. mol /dm
63. Value of Kc for the reaction C2H4 + H2 ⇌ C2H6 is equal to:
A. ( )( ) D. ( )( )
B. ( )( ) E. ( )( )

C. ( )( )
64. The equilibrium will be shifted in backward direction in PCl3 + Cl2 ⇌ PCl5 if:
A. PCl3 is added D. Pressure is decreased
B. Catalyst is added E. Both C & D
C. Volume is decreased
65. For reaction 2NO ⇌ N2O4; Kp/Kc = ?
A. RT D. (RT)2

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Class: XI CHEMSITRY CHAPTER#06

B. E.
C. √
66. Equilibrium of a reaction is not affected by:
A. Temperature D. Concentration
B. Pressure E. None of These
C. Catalyst
67. For which of the following reaction Kp = Kc?
A. ½ N2 + ½ O2 ⇌ NO
D. N2 + 3H2 ⇌ 2NH3
B. PCl5 ⇌ PCl3 + Cl2
E. SO2 + O2 ⇌ 2SO3
C. 2NOCl ⇌ 2NO + Cl2
68. Incorrect statement of following is:
A. Reversible reactions proceed in a definite direction
B. Value of Kc is independent of initial conc. of reactants
C. Composition of equilibrium mixture does not change with time
D. Rate of reaction of a substance is proportional to its active mass
E. None of These
69. Equilibrium expression for reaction 4NH3 + 5O2 ⇌ 4NO + 6H2O will be:
[ ] [ ] [ ] [ ]
A. [ ] [
D.
] [ ]
[ ] [ ] E. [ ] [ ]
B.
[ ] [ ]
[ ] [ ]
C.
[ ] [ ]
70. In the reaction A + B ⇌ C + D if the concentration of A & B is doubled, then the
equilibrium constant is?
A. Doubled D. Increases 4 times
B. Halved E. Decreases 4 times
C. Remain same
71. The volume of reaction vessel containing equilibrium mixture in the reaction
SO2Cl2 ⇌ SO2 + Cl2 is increased when equilibrium is re-established.
A. Amount of SO2 will have decreased D. Amount of Cl2 will remain unchanged
B. Amount of SO2Cl2 will have increased E. No effect on equilibrium
C. Amount of Cl2 will have increased
72. For a reversible reaction ∆ < 0. If pressure is decreased then;
A. Reaction shifts in forward direction D. More product is produced
B. Reverse reaction is favoured E. No prediction can be made
C. No effect on equilibrium
73. One mole of HI is heated in a closed container of two liters. At equilibrium half a
mole of HI has dissociated. The equilibrium constant is:
A. 0.75 D. 0.0625
B. 2.5 E. 0.625
C. 0.25
74. In a chemical equilibrium the rate constants of forward & backward reactions
are respectively 3.2x10-4 & 1.2x10-5, the equilibrium constant Kc is:
A. 26.6 D. 0.25
B. 0.37 E. 2.6
C. 3.7
75. For a reaction 2A + B ⇌ C initial concentration of [A] = 2 mol/L, [B] = 1 mol/L.
The concentration of [B] at equilibrium is 0.5 mol/L. What is the value of Kc for
reaction?
A. 0.5 D. 2.0
B. 1.0 E. 2.5
C. 1.5
76. In which of the following case does the reaction goes farthest to completion?
A. Kc = 104 D. Kc = 10-8
B. Kc = 1.0 E. Kc = 10
C. Kc = 4.0
77. Optimum temperature for the maximum yield of NH3 in Haber’s process is:
A. 400℃ − 500℃ C. 1000℃
B. -100℃ D. 100℃
78. Which set of conditions is most suitable for the oxidation of SO2 in Contact
process?

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Class: XI CHEMSITRY CHAPTER#06

A. 100℃, 400 atm D. 100℃, 1 atm

B. 450℃, 400 atm E. 100℃, 400 atm
C. 400℃, 1 atm
79. In the equilibrium system A(g)+ B(g) ⇌ C(g) ∆H = +ve decomposition of C is
favoured by:
A. Increasing pressure D. Removing C
B. Increasing volume E. Both B & C
C. Decreasing temperature
80. 256g of HI are introduced into a vessel at 25℃. At equilibrium 1g of H2 & 127g of
I2 are present. How many grams of HI are present at equilibrium:
A. 127 D. 25.4
B. 254 E. 256
C. 128
81. Which of the following factors would cause the concentration of PCl5 to decrease
in the reaction vessel?
PCl5 ⇌ PCl3 + Cl2 ∆H = +ve
A. Adding Cl2 to reaction mixture D. Increasing temperature
B. Increasing the volume of reaction vessel E. Both B & D
C. Addition of catalyst
82. For the reaction H2 + Cl2 ⇌ 2HCl Kc at 0℃ is 1.3x10-2. Value of Kp at same
temperature is?
A. 29.12x10-2 D. 1.3x10-
-2
B. 2.912x10 E. 2.5x10-4
-2
C. 1.3x10
83. Which oxide of N is most stable at 273K?
I. 2N2O5 ⇌ 2N2 + 5O2 Kc = 1034
II. 2NO2 ⇌ N2 + 2O2 Kc = 1015
III. 2NO ⇌ N2 + O2 Kc = 1030
IV. 2N2O ⇌ 2N2 + O2 Kc = 1032
V. N2O4 ⇌ N2 + 2O2 Kc = 1020
A. N2O5 D. N2O
B. NO2 E. N2O4
C. NO
84. The molar concentration of 32g O2 in 10 L is:
A. 3.2 D. 0.1
B. 32 E. 10
C. 1
85. 0.5 mole of CH3COOH & C2H5OH each, 0.2 mole of CH3COOC2H5 & H2O each are
mixed in a vessel to attain equilibrium. Kc for reaction is 4:
A. Reaction shift in forward direction D. Concentration of acid decreases
B. Reaction shift in reverse direction E. All except B
C. More ester is produced
86. On adding 0.1M solution of each of Pb+2, Ba+2, Hg+2 & Ca+2 ions in a Na2SO4
solution, specie first precipitated is: (Ksp of BaSO4 = 10-11, Ksp of CaSO4 = 10-16,
Ksp of PbSO4 = 10-5, Ksp of HgSO4 = 10-8)
A. BaSO4 D. HgSO4
B. CaSO4 E. ppt will not form
C. PbSO4
87. The precipitate of CaF2 (Ksp = 1.7x10-10) is obtained when volumes of the
following are mixed:
A. 10-4M Ca+2 & 10-4M F- D. 10-3M Ca+2 & 10-5M F-
-2 +2 -3 -
B. 10 M Ca & 10 M F E. 10-6M Ca+2 & 10-6M F-
C. 10-5M Ca+2 & 10-3M F-
88. Solid Ba(NO3)2 is gradually dissolved in 1.0x10-4M Na2CO3 solution. At what
concentration of Ba(NO3)2, BaCO3 will precipitate? (Ksp of BaCO3 = 5.1x10-9)
A. 4.1x10-5M D. 8.1x10-7M
-5
B. 5.1x10 M E. 4.5x10-6M
-5
C. 8.1x10 M
89. For unsaturated solution of an electrolyte:
A. Ksp > ionic product D. Ksp ≠ ionic product
B. Ksp < ionic product E. N.O.T

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Class: XI CHEMSITRY CHAPTER#06

C. Ksp = ionic product

90. Ksp for sparingly soluble salt Ag2S at 20℃ is 0.256x10-6 mol/dm3. Solubility of
salt in mol/dm3 is;
A. 6x10-2 D. 2.4x10-3
B. 4x10-2 E. 4x10-4
-3
C. 4x10
91. Ksp of sulphides are as Pbs = 3.4x10-28, HgS = 4.1x10-54, CoS = 3x10-26 & ZnS is
1.2x10-23. Correct order for decreasing solubility of sulphides is as:
A. HgS > PbS > CoS > ZnS D. ZnS > CoS > PbS > HgS
B. HgS > ZnS > CoS > PbS E. CoS > ZnS > PbS > HgS
C. PbS > HgS > CoS > ZnS
92. 400ml of 0.3M CaCl2 & 600ml of 0.1 M NaF are mixed together. Ionic product of
CaF2 will be:
A. 1.728x10-3 D. 1.296x10-3
-2
B. 3.24x10 E. 3.24x10-3
C. 4.32x10-4
93. Solubility of MgCl2 is 0.95 g/L at 30℃. Its Ksp will be:
A. 1x10-6 D. 3.80
B. 4x10-6 E. 1x10-2
4
C. 3.429x10
94. If solubility of a salt M3X is “s”. Its Ksp is given by:
A. 2 D. 4 3
2
B. 2 E. 27 4
2
C. 4
95. Unit of Ksp for M2X3 type salt is:
A. mol5/dm12 D. mol3/dm3
5 15
B. mol /dm E. mol4/dm12
C. mol3/dm9
96. The reaction A + B ⇌ C + D proceeds to right hand side up to 99.9%. The
equilibrium constant of the reaction will be:
A. 10-4 C. 40
B. 102 D. 1010
97. Which of the following equilibrium is not affected by change in pressure?
A. ½ N2 + 3/2 H2 ⇌ NH3 D. ½ N2 + ½ O2 ⇌ NO
B. ½ PCl5 ⇌ ½ PCl3 + ½ Cl2 E. ½ SO2 + O2 ⇌ ½ SO3
C. ½ N2O4 ⇌ NO2
98. For the reaction A + B ⇌ C + D rate constants of the forward & backward
reactions are 25x10-2 & 5x103 respectively. The value of Kc is;
A. 2.5x10-6 D. 5.0x10-5
-4
B. 2.0x10 E. 50
C. 0.5
99. In the system CaF2 ⇌ Ca+2 + 2F-1 if the concentration of Ca+2 ions is increased 4
times, the equilibrium concentration of F-1 ion will change to:
A. ½ of initial value D. 4 times of initial value
B. ¼ of initial value E. 1/8 times of initial value
C. 2 times of initial value
100. Under what conditions the reaction H2 ⇌ 2H ∆H = +ve will be favoured most?
A. High temperature high pressure D. Low temperature high pressure
B. Low temperature low pressure E. Low pressure only
C. High temperature low pressure
101. Kc for the reaction N2 + O2 ⇌ 2NO is 0.04. In presence of catalyst equilibrium is
attained 3 times faster. Value of Kc in presence of catalyst will be:
A. 3x0.04 D. 0.04/(3)2
B. 0.04/3 E. 0.04
2
C. (3) x0.04
102. If in the reaction N2O4 ⇌ 2NO2, is that part of N2O4 which dissociate, then the
number of moles of N2O4 at equilibrium will be:
A. 3 D. (1−2 )
B. (1+ ) E. (2 -1)
C. (1− )
103. At equilibrium:

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Class: XI CHEMSITRY CHAPTER#06

A. concentration of reactants & products become equal

B. Rate of forward and reverse reaction becomes equal
C. Mass of reactants & products become equal
D. The reaction stops
104. Which one is incorrect regarding chemical equilibrium?
A. At equilibrium all the substances involved are present
B. Equilibrium mixture is formed
C. Composition of equilibrium mixture remains same
D. None of these
105. In a reversible reaction at equilibrium:
A. Concentration of reactant and product becomes equal
B. Equilibrium state may change with time
C. Concentration of reactants and products remain same
D. All of these
106. Rate of reaction is proportional to:
A. Concentration of reactants C. Product of reactants
B. Molar concentration of reactants D. Product of concentration reactants
107. For the reaction PCl5 ⇌ PCl3 +Cl2
A. Kp > Kc C. Kp = Kc
B. Kp < Kc D. Kp ≠ Kc.
108. Equilibrium constant Kc depends upon:
A. Initial concentration of reactants
B. Initial concentration of products
C. Initial concentration of both reactants & products
D. Equilibrium concentration of both reactants & products
109. For reaction A +2B ⇌ 3C +2D. Kc will be equal to:
[ ] [ ] [ ] [ ]
A. C.
[ ] [ ] [ ] [ ]

[ ] [ ] [ ]
B. [ ] [ ]
D.
[ ]

110. For the reaction CH3COOH +C2 H5OH ⇌ CH3COOC2H5 +H2O the equilibrium
mixture contains 0.8 moles of H2O, 0.2 moles of CH3COOC2H5, 0.2 moles of
C2H5OH and 0.2 moles of CH3COOH. Value of Kc will be.
A. 0.2 C. 4.0
B. 0.4 D. 2
111. If the ratio of initial concentration of product and reactant is less than Kc:
A. Reaction will shift towards right C. No shifting of reaction occurs
B. Reaction will shift towards left D. Reaction is said to be in equilibrium
112. For the reaction X +Y ⇌ Z + A the equilibrium mixture contains 10 moles of
each reactant and product. Initial moles of X and Y each are:
A. 5 C. 15
B. 10 D. 20
113. If the value of Kc is very large for a reaction:
A. Forward Reaction is very fast C. Forward reaction is very slow
B. Reactant is stable D. Reverse reaction is very fast
114. The effect of different factors affecting the balance of equilibrium was studied
by:
A. Guld berg C. G.H Hess
B. Le-Chatelier D. Born Haber
115. Which factor does not affect the equilibrium position of chemical reaction:
A. Concentration C. Pressure
B. Temperature D. Catalyst
116. A catalyst:
A. Affects the forward reaction
B. Affects the reverse reaction
C. No effect on rate of reaction
D. Affects forward and reverse rates equally
117. In which of following case, the increase of pressure shifts the equilibrium
towards left?
A. 2SO2 +O2 ⇌ 2SO3 C. PCl3 ⇌ PCl3 +Cl2
B. N2 + 3H2 ⇌ 2NH3 D. H2 +I2 ⇌ 2HI

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Class: XI CHEMSITRY CHAPTER#06

118. In the reaction 2NO + O2 ⇌ 2NO2 = − if the temperature is increased which

direction would be favoured?
A. Reverse
B. Forward
C. No shifting of reaction
D. Shifting of reaction is independent of temperature
119. Catalyst used in the Haber process for the manufacture of ammonia (NH3) is.
A. Pt C. Fe
B. V2O5 D. Ni
120. The optimum conditions for the maximum yield of NH3 in Haber’s process are:
A. 400-500oC/1 atm pressure C. 50oC /1 atm pressure
o
B. 400-500 C/200-300 atm pressure D. 50oC /100-400 atm pressure
121. As the reaction for the formation of NH3 is exothermic N2 +3H2 ⇌ 2NH3 =−
The reaction is carried at high temperature because:
A. High temperature favours the formation of NH3
B. High temperature produces high yield at slower rate
C. High temperature produces low yield at higher rate
D. High yield is more important than fast rate
122. Contact process is employed for the manufacturing of:
A. H2SO4 C. SO2
B. SO3 D. NHO3
123. Which one is used as catalyst in contact process?
A. Pt C. Ni
B. V2O5 D. No- catalyst
124. Which conditions are more favorable for the oxidation of SO2 to SO3?
A. 200oC/1 atm pressure C. 450oC/1 atm pressure
o
B. 450 C /200 atm pressure D. 450oC / 150 atm pressure
125. The product of molar concentration of ions at equilibrium is called as:
A. Solubility C. Ionic product
B. Solubility product D. All of these
126. Solubility is expressed in:
A. g/dm3 C. mole/dm3
3
B. g/cm D. mole/cm3
127. Which one is a unit of solubility product?
A. molar units C. mol/litre
3
B. mol/dm D. All of these
128. Solubility product of a compound XY, having solubility of 2.5 ×10-12 mole/dm3 is:
A. 6.25 × 10-24 mole2/dm6 C. 6.25 × 10-23 mole2/dm6
B. 62.5 × 10-24 mole2/dm6 D. 6.25 × 10-24 mole2/dm3
129. The product of molar concentration of ions at any point other than equilibrium is
called as:
A. Solubility C. Ionic product
B. Solubility product D. All of these
130. A substance is precipitated from its solution:
A. Saturated C. Super saturated
B. Unsaturated D. All of these
131. Which condition of the following represents an unsaturated solution:
A. Ionic product > solubility product C. Ionic product = solubility product
B. Ionic product < solubility product D. None of these
132. Common ion effect is applicable to:
A. Soluble salts C. Sparingly soluble salts
B. Insoluble salts D. All of these
133. An electrolyte can be precipitated by:
A. decreasing the amount of undissolved solid
B. Increasing the concentration of ions
C. decreasing the concentration of ions
D. All of these
134. Common ion effect is used in:
A. Qualitative salt analysis C. Increasing chemical yields
B. Controlling chemical processes D. All of these
135. Solubility of AgCl is 2.87 ×10-2 g/dm3. Its solubility in terms of molarity will be:

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Class: XI CHEMSITRY CHAPTER#06

A. 2 ×10-4 mol/dm3 C. 2 ×10-4 g/dm3

B. 2 ×10-4 mol/dm6 D. 2 ×10-4 mol2/dm6
136. 10 moles of each H2 and I2 are introduced into a vessel. At equilibrium 4 moles
of HI are produced. The value of Kc for H2 + I2 ⇌ 2HI:
A. 0.04 C. 0.16
B. 0.25 D. 6.25
137. In equilibrium mixture the concentration of reactants and products.
A. Is equal C. May change with time
B. Remain same D. Both A & B
138. For the reaction 2HI ⇌ H2 +I2 the equilibrium mixture contains 5 moles of HI, 3
moles of each H2 and I2. The number of moles of HI at initial state are:
A. 6 C. 8
B. 5 D. 11
139. 8 moles of each PCl3 and Cl2 are mixed and allowed to react. At equilibrium 3
moles of PCl5 are present. Number of moles of PCl3 and Cl2 consumed are:
PCl3+Cl2 ⇌ PCl5
A. 3 C. 4
B. 5 D. 6
140. 1mole of each A & B is mixed and allowed to attain equilibrium. At equilibrium
0.4 moles of AB are present. Value of Kc is? A + B ⇌ AB
A. 0.111 D. 1.66
B. 1.11 E. 2.5
C. 3.75
141. The equilibrium constant Kc for the reaction AB + C ⇌ AC + B is 10. The rate
constant of forward reaction is 104.The rate constant of backward reaction is:
A. 103 D. 106
B. 104 E. 10-4
5
C. 10
142. The equilibrium concentration of X, Y & YX2 are 4,2 & 2 respectively for the
equilibrium 2X + Y → YX2 Value of Kc is:
A. 6.25 D. 0.0625
B. 6.025 E. None of These
C. 0.625
143. Active mass of 64g of HI in 2 liter flask would be? (At: mass of I = 127).
A. 0.25 D. 1.0
B. 0.5 E. 2.0
C. 0.2
144. For the reaction N2 + 3H2 ⇌ 2NH3, Kp/Kc is equal to:
A. ( ) D.
( )
B.
√ E.
C. √
145. Which of the following equilibria is not affected by changing the volume of
container;
A. 2SO2 + O2 ⇌ 2SO3 D. N2 + 3H2 ⇌ 2NH3
B. N2 + O2 ⇌ 2NO E. PCl3 + Cl2 ⇌ PCl5
C. 2NO + O2 ⇌ 2NO2
146. Ksp of KCl at 25℃ is if its solubility is 0.00745g/dm3;
A. 1x10-8mol2/dm6 D. 1x10-6 mol2/dm6
-8 2 6
B. 4x10 mol /dm E. 4x10-4 mol2/dm6
-4 2 6
C. 1x10 mol /dm
147. In the equilibrium 2SO2 + O2 ⇌ 2SO3 ∆H = -ve backward reaction is favoured by:
A. High temperature D. Decreasing SO3 concentration
B. Low pressure E. Both A & B
C. Decreasing volume
148. In a chemical reaction, equilibrium is said to be established when:
A. Concentration of reactants & products become equal
B. Opposing reactions ceases
C. Volume of reactants & products become equal
D. Temperature of opposing reactions are equal
E. None of These
149. For the gaseous reaction C2H4 + H2 ⇌ C2H6 ∆H = +32K.cal the equilibrium

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Class: XI CHEMSITRY CHAPTER#06

concentration of C2H4 cannot be increased by:

A. Increasing the temperature D. Adding H2
B. Decreasing the pressure E. Both A & D
C. Removing some H2
150. Ksp of Ag2S at 25℃ is 3.2x10-14 M3. Its molar solubility is?
A. 2x10-3M D. 6x10-7M
-5
B. 2x10 M E. 3x10-7M
C. 3x10-3M
151. The suppression of ionization of a weak acid or a weak base by adding one of its
own ion is known as:
A. Buffer action D. Ionization effect
B. Buffer capacity E. Both A & B
C. Common ion effect
152. What is Ksp of CaF2 if its solution contains 0.0078g of dissolved CaF2 per liter?
A. 10-8M3 D. 4x10-12 M3
B. 2x10-8 M3 E. 1x10-12 M3
-12 3
C. 2x10 M

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