1411 Practice Exam 3 Brown 9-12

CHEMISTRY 1411 Practice Exam 3, Chapters 9–12 Brown
Chapter 9 questions (1-13) are duplicated from Exam 3 Chapters 7-9

___________________________________________________________________________
Some constants and equations:
1 atm = 760 torr PA = XAPT r1/r2 = (M2/M1)1/2

R = 0.08206 L.atm/mol.K = 8.314 J/ mol.K
A periodic table is also attached to the end of the exam.

__________________________________________________________________________
Chapter 9
1. The central carbon atom in the carbonate ion, CO32–, has
a) 3 , 0  bonds b) 2 , 1  bonds
c) 3 , 1  bonds d) 3 , 2  bonds
2. Which molecule is polar?

a) CS2 b) PCl3 c) BCl3 d) SCl6
3. Predict the overall geometry about the carbon atoms (left carbon, right
carbon) in the molecule acetaldehyde shown below:
a) square planar, trigonal planar

b) bent, tetrahedral
c) tetrahedral, trigonal pyramidal
d) tetrahedral, trigonal planar
4. What is the molecular geometry of an NH3 molecule?

a) linear b) bent
c) trigonal pyramidal d) tetrahedral
5. Which one of the following molecules or ions would be expected to have bond
angles of 120?
– –
a) SO3 b) ClO3 c) NCl3 d) BCl4
6. What is the hybridization of the nitrogen atom in the

nitrate ion, NO3–?
a) sp b) sp2 c) sp3 d) sp3d e) sp3d2
7. Side to side overlap of two p-orbitals resulting in two regions of

electron density in common to the two nuclei are known as
a) a sigma bond b) a pi bond c) a delta bond d) a double bond
8. A triple bond consists of
a) one sigma and two pi bonds
b) two sigma and one pi bond
c) three sigma bonds
d) three pi bonds
9. The hybridizations of carbon and oxygen in carbon dioxide are

a) sp and sp3 b) sp2 and sp3
2
c) sp and sp d) sp and sp
e) sp2 and sp2
10. According to molecular orbital theory, what is the bond order of the
bond between the two atoms in the NO molecule?
a) 0 b) 1 c) 2 d) 2.5 e) 3
11. Which one of the following molecules is paramagnetic?

a) N2 b) B2 c) F2 d) C2
12. In the trigonal bipyramidal geometry, lone electron pairs occupy the
a) axial positions b) equatorial positions
13. The overall geometry (EDG) and molecular geometry (MG) of bromine
trifluoride, BrF3, are, respectively
a) trigonal planar, trigonal planar
b) tetrahedral, trigonal pyramidal
c) trigonal bipyramidal, T-shaped
d) octahedral, square planar
Chapter 10
14. A balloon originally had a volume of 5.39 L at 44.0C and a pressure of
755 torr. To what temperature must the balloon be cooled to reduce its
volume to 4.00 L at a pressure of 620 torr?
a) 18.4C b) 0C c) -50.1C d) -79.9C
15. A gas in a 500 milliliter container is found to have a pressure of

758 torr at 22.0C. How many moles of gas are in the flask?
a) 2.47 X 10-2 b) 2.06 X 10-2 c) 9.42 d) 12.4
16. What is the density of O2 gas in grams per liter at STP?

a) 1.43 b) 1.97 c) 2.86 d) 3.19
17. The ratio of the rates of effusion of CO2 and gas X is 1.0224.
What is gas X?
a) O2 b) F2 c) SO2 d) NO2
18. A sample of aluminum metal was reacted with hydrochloric acid,

producing AlCl3(aq) and H2 gas. If 5.00 g of aluminum was reacted,
how many liters of H2 gas would be produced at STP?
a) 6.23 b) 5.19 c) 4.58 d) 9.74
19. A gas mixture consists of 1.00 g of H2 and 1.00 g of O2. If the total
pressure is 2.50 atm, what is the partial pressure of H2?
a) 0.249 atm b) 0.500 atm c) 1.73 atm d) 2.35 atm
Chapter 11
20. What type of intermolecular force occurs between water molecules?

a) ion-dipole b) dipole-dipole c) London dispersion d) covalent
21. What type of intermolecular force would be important when KBr dissolves
in water?
a) ion-dipole b) dipole-dipole c) London dispersion d) covalent
22. Which molecule exhibits hydrogen bonding interactions with water?

a) CCl4 b) CH3OH c) CBr4 d) Ar
23. Which substance will have London dispersion forces as its primary
intermolecular attractive force?
a) CCl4 b) CH3OH c) NaCl d) H2O
24. Viscosity is
a) The energy required to expand the surface of a liquid.
b) The attraction between molecules.
c) The resistance to flow of a liquid.
d) The energy required to melt a solid.
25. The attraction between water molecules and a glass surface is an
example of
a) adhesion
b) cohesion
c) viscosity
d) surface tension
26. The conversion of a solid to a gas is called

a) melting
b) vaporization
c) condensation
d) sublimation
27. How much heat is required to convert 50.0 g of ice at 0°C to water
vapor at 100°C? The heat of fusion of water is 334 J/g, the heat of
vaporization of water is 2257 J/g, and the specific heat of water is
4.184 J/g°C.
a) 78.45 kJ b) 150.47 kJ c) 234.15 kJ d) 316.23 kJ
Chapter 12
28. What is the net number of atoms inside the unit cell in a solid metal with
a face-centered unit cell?
a) 1 b) 2 c) 3 d) 4
29. The basic repeating unit of a crystalline solid is called the
a) lattice point b) unit cell c) crystal shape d) coordination number
30. “Alpha” iron metal crystallizes with the body-centered cubic unit
cell. If the unit cell is 287 pm on each side, what is the density
of alpha iron?
a) 3.42 g/cm3 b) 5.43 g/cm3 c) 7.85 g/cm3 d) 8.64 g/cm3
Answers for Practice Exam 3 Chapters 9-12 Brown
1. C 11. B 21. A
2. B 12. B 22. B
3. D 13. C 23. A
4. C 14. D 24. C
5. A 15. B 25. A
6. B 16. A 26. D
7. B 17. D 27. B
8. A 18. A 28. D
9. C 19. D 29. B
10. D 20. B 30. C

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CHEMISTRY 1411 Practice Exam 3, Chapters 9–12 Brown

Chapter 9 questions (1-13) are duplicated from Exam 3 Chapters 7-9

1 atm = 760 torr PA = XAPT r1/r2 = (M2/M1)1/2

A periodic table is also attached to the end of the exam.

2. Which molecule is polar?

a) square planar, trigonal planar

4. What is the molecular geometry of an NH3 molecule?

6. What is the hybridization of the nitrogen atom in the

7. Side to side overlap of two p-orbitals resulting in two regions of

9. The hybridizations of carbon and oxygen in carbon dioxide are

11. Which one of the following molecules is paramagnetic?

15. A gas in a 500 milliliter container is found to have a pressure of

16. What is the density of O2 gas in grams per liter at STP?

18. A sample of aluminum metal was reacted with hydrochloric acid,

20. What type of intermolecular force occurs between water molecules?

22. Which molecule exhibits hydrogen bonding interactions with water?

26. The conversion of a solid to a gas is called

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