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    Tutorial 12 Solution

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    Chem 120 tutorial 12 solutions

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    Tutorial 12 Solution

    Uploaded by

    ciraolwethu0
    17 views3 pages
    Chem 120 tutorial 12 solutions

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    Tutorial 12 solution

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    Chem 120 tutorial 12 solutions

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    17 views3 pages

    Tutorial 12 Solution

    Uploaded by

    ciraolwethu0
    Chem 120 tutorial 12 solutions

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    CHEM120 - Tutorial No.

    12

    1. (a) Provide at least three common regents that can be used to oxidize a secondary alcohol to
    a ketone.

    (i) CrO3 (ii) PCC (iii) KMnO4 (iv) K2Cr2O7

    (b) Provide a suitable alkene that can react with ozone, O3, and dimethyl sulfide, (CH3)2S
    to give methanal and propan-2-one as the major products.

    Answer:

    H CH3 H CH3
    O3
    (CH3)2S
    O + O + (CH3)2S=O
    H CH3 H CH3

    2-methylpropene methanal propan-2-one dimethyl sulfide

    2. (a) Draw the structures for reaction products in the following reactions

    F OH F O
    (i)
    Cl
    + PCC
    Cl
    Cl Cl OH

    OH
    O
    O
    (ii) H3C OH + O
    CH3

    OH
    O
    (iii) + H2/Pt CH3
    CH3 H3C
    H3C

    H O
    H3C
    (iv)
    H3C + K2Cr2O7/H2SO4
    OH OH

    1
    O O
    (v)
    Cl
    + NH2CH2CH3
    H3C NHCH2CH3
    H3C

    (vi) O CH3 OH O
    H 2O
    + KOH + K+ O
    –
    CH3

    CH3
    .. ..
    NH N
    (vii) + H3C Br + HBr

    3. Use the Zaitsev’s rule to predict the major and minor product in the following
    elimination reaction. Draw and label the structure of major and minor products.

    Cl

    CH3 CH3CH2O-Na+
    H3C

    H3C

    Ans:
    Cl
    CH3
    H2C
    CH3 CH3CH2O-Na+ minor
    H3C
    H3C
    H3C
    +
    CH3
    H3C major
    H3C

    2
    3

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