) OBJECTIVE CHEMISTRY-Xi a av 8 ATOMIC STRUCTURE Fundamental particles, Atomic number, Mass number, Isotopes, isobars, Isotones : 1, The constancy of eém ratio for electron shows that A) Blectron’s mass is 1/1837" of the mass of proton lectrons are universal particles of all matter '3) Electrons are produced in discharge tubes only 4y None of the above 2. The radius of the atom is of the order of A) 10"! em (2710-3 em “37 10-8. cm Mien 3. The charge of an electron is 1.6 x 10°"? coulombs. What will be the-value of charge on Na* ion MPSXwPC 32K 1O"C By2A x10 C ALK 16 x 10% 4. The increasing order of e/m values for electron, proton, neutron and alpha particle is AY, Pym, ATM, Py & OL AB ty By Ob € fren 5. Tlie number of protons, electrons and neutrons in ,.Br* are respectively 1735, 35, 80 Fs A) 80, 80, 35 4) 45, 45, 35 6. The number of neutrons in the dipositve zine ion (Mass number of Zn = 65) PF L BS33 B65 AOI 7.” Mass numbers-of Li, Be and B are 7, 9 and 10 respectively. Which of the following has two electror three protons and four neutrons? Bt 5 Be Bur AN Be 8. Sodium ion is isoelectrapic with the atom” A) Mg* x Ar Bre Ayn 9.- Given abundence of isotope “Fe, “Fe, *"Fe, aré 5%, 90%, and 5% respectively. The atomic mass Fe is Ms MESS A) 56 45 55.66 10, An oxide of nitrogen has'a molecular weight of 30. Total number of electrons in one molecule the compound is : gett as 7530 Ay As 45 00 Rutherford’s Atomic model, electromagnetic radiation, Duel nature of light, Quanum theor Photo electirc effect : The frequency associated with photon of radiation having a wavelength of 6000A° is 5 x 104 Hz 2) 5 x 10! Hz 3) 2x 10! Hz 4) 5x 10" Hz 12/ If the wavelength of an electomagnetic radiation is 2000°A. What is the energy in ergs? 9.94 x 10-7 2) 9.94 x 10-0 3) 4.97 x 10°? 4) 4.97 x 10°17 . 130 Which of the following properties of a wave is independent of the other? 1) Wave number 2) Wave length. 3) Frequency[OBJECTIVE CHEMISTRY-XIA_ fe ——_—_———_—# i ATOMIC STRUCTURE 14. Which of the following isznoLan electromagnetic radiation? se 1) Gamma rays i rays 3) Radio waves 4) X-rays 15. Which of the following relates to photon Bott as waye-tnotion and as a stream of particles? 1) E= me? WZ Photcectic effect 3) Diffraction 4) Interference 16. The metal best used in photoelectric cells is, 1) Na 2) Mg yal fxs 17. Which of the following statements is incorrect? 1) Particle nature of radiations can be. experimehtally demonstrated by Compton effect 2) Wave nature of electrons can be experimentally demonstrated by diffraction experimen 3) The value of Planck's constant, h is 6.62%1074J.s AM iowensity of light is directly proportional to its frequency. 18. When the frequency of light incident on a metallic plate is doubled, the KE of the emitte photo electron will be 1) Doubled 2) Halved AMA Tocreased but more than double of previous KE 4) Remains unchanged ‘ 19. If a certain metal is irradiated by using two different light radiations of frequency ‘x’ and *2x" the 54. kinetic energies of ejected electrons are ‘y" and “3y" respectively. The threshold frequency of metal will be. 4 x + 3x. x x x x a & D3 4G a7 3 F)._1F one photon has 35 eV energy and the work function of the material is 7 eV, then the value of ye Stopping potential wil 1)32V. 18 Ve 3)3.3V 4) zero : % Bohr's atomic model, Hydrogen spectrum : ‘ 21, Bohr’s theory is applicable to A yuie 2Lit 3) Het AP oth: | and 3 22. Which of the following transistions in hydrogen atom will require the highest amount of energy In=lton=2 n=lton=3 3)n=2ton=1 4)n=3ton=4 ) x 7 23. Splitting of spectral lines under the influence of strong magnetic field is called Ns 1) Stark effect A Leeman effect 3) Photoelectric effect 4) None of these 24. As the electron moves‘away from the nucleus its potential energy and kinetic energy 1) Decreases, increases _ 2) Increases, increases 3) Decreases, decreases MP increases, decreases 25. ‘The energy of the electron when it is at an assert from the nucleus is 1) Infinity fe inimum 4) Can not be predicted 26. If the electron of a hydrogen atom is present in the first orbit, the total energy of the electron is a a oP m Tn a N\ oF 2F BSE XI Students f+ #9] APEX SERIES for Sti GI(Rrowic STRUCTURE jp —______—y[ OBJECTIVE CHEMISTRY) eeradius of this Bohr’s orbit is 27. Jar momentum of an electron revolving in Bohr’s orbit Fi 0 o> 1) 0.529 a° 21.0584" 3) 2.116A° 464 A 28. Identity the correctly matched set from the following lists. T-A 1) Energy ~ I) Velocity I) Rydberg constant IV) Radius = b, M-a, Hl -0,1V-d Ai-e,0-a,l-c.1V-4 -b, 0 m-d,IV-c 3)I-e,-b, M-e,IV-d ‘The ratio of the radii of the first three orbits in an atom of hydrogen is 29. 1:4:9 2) 9:4:1 3) 1:23, 4)3:2:1 30. Velocity of the electron in the 1** Bohr orbit of hydrogen atom", (8 72-18x108 cm/sec 2) 2.18x10F m/sec 3) 2.18x10!6 emv/seC 4) 36559x10* cm/sec 31. (A): Hydrogen has only one electron in its orbit but produces several spectral lines (R) : There are many excited energy levels available in a sample of Hydrogen gas joth (A) and (R) are true and (R) is the correct explanation of (A) 2) Both (A) and (R) are true and (R) is not the correct explanation of (A) 3) (A) is true bat.(R) is false 4) (A) is false but (R) is true 32. The first emission line of hydrogen atomic spectrum in the Balmer series with respect to the Rydberg a constant, R is : y SR yt 9) Rem! 5) Rem! 4) Rem! Px«% Da » aa » 400 33. A spectral line of hydrogep with ) = 4938A° belongs to the series, 1) Lyman Balmer 3) Paschen 4) Pfund 34, ‘Ina H-atom, the transition takes place from L to K shell. If R = 1.08 x 107m-!, the wave length of the light emitted is nearly ™, 1) 4400A° 1250A° 3) 1650A° 4) 1850A° 35. The total energy of electron in an atom is a combination Sf,potential energy (P.E) and kinetic energy(K.E). If total energy is -E for an electron in an atom, then its (K.E) and (P.E) respectively are 1) 26, -E 2) 2E, E * wt 2E 4)E,-E APEX SERIES for Sti Chaitanya CBSE X! StudentsOBJECTIVE CHEMISTRY-XIA $+ —______________+f{ATOMIC STRUCTURE deBroglies's theory, Heisenberg principle, Schrodinger’s wave equation : 304\The de-Broglie’ jon treats an clectron to be v1) a particle 2) 0 wave 3) ray AF oth (1) and 2 37, The momentum of a particle of wave length 1A 1) 6.625 x 1077 g. cms! 6.0625 « 10°? g. ems! 3) 6.625 x 10! g. cms! 4) 6.625 x 10° g. cms The de ae wavelength of a particle with mass 1 g and velocity 100 m/s is 63 x 10-3 m 2) 6.63 x 10-4 m 3) 6.63 x 105 m 4) 6.63 x 10% m If uncertainity in position is zero, the unceflainity in momentum of an electron will be 1) Zero PPrisinity 3) Unity 4) Zero or infinity 40. Uncertainity in position of a minute particle,of mass 25g in space is 10S m. What is the uncertainity in its velocity (in ms!) ? (h = 6.6 x 10 Js) (AIEEE) 1) 2.1 x 10 270.5 x 19-4 B21 x 10% 4)05 x 109 41, If ‘Ao’ is threshold wavelength for photo electronic emission, "A" F:the wavelength of light falling ve on the surface of metal. If ‘m’ is the mass of electron, then the debroglie’s wavelength of emitted electron is hQA ) 7? ‘A hy -a)]” gy | Mo=aw) i ROOD Ele mee ->) 2me(Ay) » | 2me(hAg) ® [2meQ—%o) J. 42. The debroglie wavelength (.) of elect‘on is related to its accelerating potential (V) by the equation 150 12.27 40 12.27 150 eA 2 2= a= . 4) A= fe ie paar 3) aA ) Ae eam 43. The maximum probability of finding an electéon of a particular energy in an orbital is about 1) 80% 2) 85% Irn 4) 100% 44, In the radial probability distribution curve for the 2s orbital of the hydrogen atom, the minor maximum, the node and the major maximum occur at the following distances from the nucleus respectively 1) 1.1A°,0.53A°,2.6A° 153A°,1.1A°,26A° 3)2.6A°,1.1A°,0.53A° 4) 0.53A°,2.116A°,2.6A° shack “bh x, y and z are respectively 1) R, R? and4ar?R? fe R and 4nr?R? 3) 4mr?R? and R,R 4) R, 4mr?R? and R Quantum numbers, Atomi ees * 46. Which of the following is indicated by the Magneti@ quantum number? 1) Size 2) Shape Spatial orientation 4) Spin 7 3p 1 47. When n = 3 and = 1, the designation given to 1) 4s 2) 4p APEX SERIES for Sri Chaital CBSE XI StudentsATOMIC STRUCTURE OBJECTIVE CHEMISTRY: 48. The impossible set of quantum numbers is ,1=0, m=0,s= 41/2 2)n=2,J21, m=0,8= +12 120, ft 1, 82-12 4yn=3,f=1, mals -V2 For the p, orbital, conventionally m is e 1) -2 2) 42 fo 0 1 number is not obtained from the Schrodinger’s wave © 4) Any of these squation is 50. ‘The qun Da 21 3)m ws 51. The number of orbitals in the quantum level n = dis na . 16 4) 18 52. Which of the following is correct with respect to ‘p’ orbitals? ‘ 1) Spherical ‘rong directional character 3) Five fold degenerate 74) No directional character 53. Which d-orbital has its four Jobes along the axes. nay 3) dy 4) dye 54. The number of nodes and nodal planes in 4p orbital are respectively Pl 2) 1,2 3)2,3 43,2 . sf The density of electron cloud of the orbital d,, in yz plane 16 0. 2) Maximum 3) Not determined 4) None ‘Aotbau principle, Paul's exclusion principle, Hund!'s rule, Electronic configurations : s 56. Nitrogen atom has 3 unpaired electrons in its ground state, It ean be explained by 1) Auf-bau principle . 2) Pauls principle jund’s rule 4) None of these 57. ‘The correct valence electronic configurationMior Cu(Z = 29) is 1) 3d? 4s? 10 4s! 3) 3410 4s? 4) 308 4s? 58. Which one of the following pairs of ions have the same electronic configuration 1) Cr, Fe Be Mn® > 3) Fe™, Co 4) Sc*, Cr* ‘ 59. The energy of the electron in the hydrogen atom depends on he principal quantum number only 2) All the quantum numbers 3) The Azimuthal quantum number 44) The principal and azimuthal quantum number: 60, In potassium the order of energy levels is 1) 4s > 3d ras < 3d 3) 4s < 3p 4) 4s = 3d 61. The values of quantum numbers n, / and m for the fifth electron of boron is 21=2,ms-1 4)n=1,/=2,mscl 63. 2} Tae jm2-1 2)n=2,/=0m=-1 3) 627 Total no.of electrons in phosphorous atom with magnetic quantum number (m) as zero are 13m, 26 41s, In which of the following Ayfbau principlesis violated? » LA 4 ) 2s 2», 2s 2p 2s 2p 2s 28 he APEX SERIES for Sri Gi BSE XI StudentsOBJECTIVE CHEMISTRY-XIA |i ATOMIC STRUCTURE, 64. Which of the following has maximum unpaired d-electrons? 1) Zn* ret 3) N* 4) Cut 65. The ratio of magnetic moments of Fe(II) and Coll) is DEN Fs. 07:3 9) V5 66. ‘al angular momentum and spin angular momentum of an electron in ‘p’ orbital is 3 & fi R ni ; p 2 ae Be +r v5 = Fundamental Particles, Atomic number, Mass number, Isotopes, Isobars, Isotones : 1. The number of nucleons present in chlorine-37 is iy 2)20 3) 54 4x 2. Consider the following pairs of ions A) Sc*} and Tit B) Mn*? and Fe‘? C) Fe*? and Cot D) Cut and Zn*? Among these pairs of ions, isoelectronic pairs would include 1) B, C and D PACandD 3) A, Band D 4) A, Band C 3), The ratio Gerween tha nevtons freseb.(8 carbon, ikem ot ‘icon atoms with mass numbers C\ 12 and 28 is i D733 B37 1:2 421 ‘ 4, 7 Size of nucleus is of the order % aD 10 m firem 3) 10? m 4) 10 m a Under the same potential difference between electrode plates maximum deflection exhibited by } electron 2) proton 3) neutron 4) He 6. The isotopes of neutral atoms of an element differ in 1) Atomic number 272) Mass number 3) Number of electrons 4) Chemical properties 1. In the following heaviest fundamental particle is ; as 2) electron 2) proton @) veutron 4) positron ¥' If velocity of electron increased by increasing the potential of electric field, then it’s specific charge “ 1) Increases /B Decreases 3) No change 4) Cannot be predicted ‘The following set which doesn't belongs to any of the category of Isotopes, Isoténes or Isobars 1) Pb, 2’Pb 2) 7H, 3He 3) PCN P sco XQ 0. Atomic mass majorely depends on 1) no.of protons only 2) no.of neutrons only 3) no.of electrons only no.0f nucleons only APEX SERIES for SH nya CBSE XI Students [13]a aa ATOMIC STRUCTURE OBJECTIVE CHEMISTRY-XiA of light, Quanum theory Rutherford’s Atomic model, electromagnetic radiation, Duel nature Photo electirc effect : % wi ‘The ratio of energies of two photons of wavelengths 2000 and 4000 A". isa 24st gid — hat is the wave number jr radiation is 19.875 x 10 13 ergs. 12. ‘The energy of an electromagnet 3 x 10! cm.see"!) cml? (h= 6.625 x 1077 erg, 3) 100 10,000 1) 1000 2) 10° etic radiation 1-3 x-10-Cergs. What is iis wavelength in nanometers 13. The energy of an electro (h = 6625x107 erg.see, C = 3x10!” em. st <1) 400 2) 228.3 3) 3000 Ars ¥\ ‘According to Plank’s quanum theory the correct statements are a) The vibrating pagticle in the black body does not emit continuously b) Radiation is emitted in the form of small packets call associated with emmitted radiations is inverse ated in the form of waves. bd 4) b, dsc led Quanta Jy proportional to frequency. c) Energy 4d) The emitted radiant energy is propag: Iabe 2)b.¢ i tos eee oe ig ee Oe ee of radiation of frequenc 4.67 x 10! see"! that must be absorbed to melt 10g ice is 2) 3.205 x 10 3) 9.076 x 102, 4) None , 1,065 x 10°? 16/ Energy equal to the mass of one electron is fi 82x Were 2) 9.2 x 10*erg at a frequency of 880 Hz. How many photons per secon 3) 8.2 x 10-erg 4) 4.1 x 10-*erg 17, A 1-KW radio transmitted operates does it? 2) 1.71 x 10° 3) 6,02 x 1078 ATI x 108 1) 1.71 x 10" 18, If 10-"7J of light energy is needed by the interior of human eye to see an object. The photons green light (A=550nm) needed to see the object are 3) 29 4) 30 27 28 = 310A0 is subjected to a metal sheet having work functio’ 19. Electromagnetic radiations having = 310A 108 eV. What will be the velocity of photoelectrons having maximum kinetic energy 1) 0, no emission will occur 2) 4.325 x 106 mis i x 108 ms 4) 8.72 x 108 m/s» (vs) v curves in the photo electric effect gives ( * The ratio of slopes of K,,, (Vs) V and Vo frequency, Ky,,, =Ywaximum kinetic energy, Vy = Stopping potential) 2) planck's constant F charge of electron 3) work function 4) the ratio of planck’s constant to electronic charge APEX SERIES forOBJECTIVE CHEMISTRY-XIA_ ATO! STRUCTURE 21, Threshold frequeney of a metal is fy, When light of frequency y = 2f, is incident on the metal plate: maximum velocity of e emitted is V When frequency of incident radiation is Sf,, maximum i : ‘ A veloc Find the ratio of 5 Vy Died 4:2 32:1 441 of emitted eis tn a photo electric experiment the stopping potential “V" is plotted auinst the frequency y of the incident light The resulting curve is a straight line which makes an angle @ with the x-axis, Then 8 will be equal to : (here = work function of the surface) fire 2) eh _ Dole 4) eho 4O00A" photon is used to break the iodine molecule, then the % of energy converted to the K.E. of iodine atoms if bond dissociation energy ofl; molecule is 246.5 kJ/mol 18% 2) 12% A 4) 25% Bohr's atomic model, Hydrogen spectrum : 24. The radius of which of the following orbit is sanie as first Bohr’s orbit of hydrogen atom 1) He*(n=2) 2) Li?*(n=2) 3) Li?*(n=3) DP Be*(n=2) \ In hydrogen atom the kinetic energy of electron is 3.4 eV. The distance of that electron from'the nucleus 2.116A° 2) 0.529a° 3) 1.587A° 4) 21.16A° x Which of the following mono electronic species have kinetic energy of electron as +1312 k.J/mol 1) The electron is present in the 2 orbit of He* ion Il) The electron is present in the 2" orbit of H atom II) The electron is present in the 3° orbit of Li*? ion IV) The electron is present in the 4" orbit of Het ion 1) and It 2) M1 and Mi Aina 4) IM and IV ¥ Tonisation energy of He* is 19.6 x 10-'S atom™!. The energy of the first stationary state of Li2* is % 1) -441 x 10" Jatom! = 441 x 1017 Jato! 3) = 44.1 x 10"!6 J.atom-! 4) - 8.72 x 10" Jaton"! 18. The kinetic energy of an electron in an orbit of hydrogen atom is 3.4ev/atom. Then identify. the correctly matched set for that electron LIST +1 LIST -2 A) Potential energy 1) 1.09 x 108 emfec B) Total energy 2) 2.116 x 10 em ©) Velocity 3) -6.8 ev/atom D) Its distance from nucleus 4) 3.4 eviatom The correct match is ABCD ABCD ABCD ABCD N43 21 3.412 See 4 5 43421 APEX SERIES for Sri Clfaltanya CBSE XI Students 75]‘ATOMIC STRUCTURE |it+ —________——+¢[ OBJECTIVE CHEMISTRY-x| 29. The wavelength of radiation required to remove the electron of hydrogen atom (Lonisation ene 21.7 « 10 erg) from orbit ton = 00 is 1) 3.664 x 104 em 3.66 x 10Sem 3) 3.66 10% em 4) 3.664 10-7 cm 30. The radii of two of tH€ first four Bohr orbits of the hydrogen atom are in the ratio 1:4. The ener difference between them may be 1) 0.85 eV 10.2 eV 3) 3.40 eV 4) 13.6eV I hydrogen atom is 7.29 x 107 emvsec. The potential energy of that electron 1) -13.66V 2) -3.4eV 02eV 4) -1.7eV 32. The radius of hydrogen atom in the ground state is 0.53 A°, the radius of Li?* in the similar Mae 1) 1.06 ae 2) 0.265 A° pf 0.175 Ae 4) 0.53 A° 33. The wavelength of the first member of the Balmer series in hydrogen spectrum is x A. Then ¢ wave length (in A®) of the first member ofyman series in the same spectrum 1s 5 on 4? 7 The ratio of wavelength values of series limit lines (n, = 2) of Balmer series and Paschen series ¢ “ngs 32:3 4) 3:2 fa a greater number of electrons from excited hydrogen atoms reach the ground state, then 4 ‘The intensity of spectral lines in Lyman series increases 2) The number of lines in Lyman series increases AX 3) Both the intensity and number lines in Lyman series increase, 4) There is no observable change in spectrum - 31. The velocity of electra 4 2 ast a5 ast 4) 36" 36, What electronic transition in Li*? produces the radiation of the same wave length as the first line i the Lyman series of hydrogen? I)n=4ton=2 Dn=9 ton=6 3)n=9ton=3 Mn=6ton=3 37. Energy of the radiation emitted during transition between the energy levels ‘n,” and ‘n,’ of hydrogi ; atom, for which n,-n, = 2 and “2 i : my | 1) 10.2 eV/atom 2) 13.6 eV/atom 1 12.75 Viatom 4) 0.85 eV/atom 38. Total speciral line, possible and visible respectively during electronic transition from 6" ener level to ground level in H-atom are 16,4 fs 3) 15,5 45.4 39. In an atom two electrons move around nucleus in circular orbits of radii R and 4R, The ratio of t time taken by them to complete one revolution 8 48:7 Di: 24:1 2, 1 40, The difference of n'* of (n+1)" bohr’s radius of H-atom is equal to (n=1)!" Bohr’s radius. Hence, t value of ‘n’ is Ht 22 16 ba Va CBSE XI StucOBJECTIVE CHEMISTRY-XIA + —_____________ atomic STRUCTURE 41, Ithe wavelength of the electron is numerically equal to the distance travelled by it in one second, then f P = ft wt 4 pre niad arse 4M 12. A hydrogen molecule and helium atom are moving with the same velocity. Then the ratio of their deBroglie wavelength is » _-— 2) 1:27 SP A) 23 P| The wavelength associated with a golf bafSweighing 200mg and moving at a speed of 5 m/h is of the order (IIT Screening) 110 m 2) 10 m F107 m 4) 10 m 4. The size of a mircorscopic particle is 1 micron and its mass is 6 »@10°Mg. If its position may be ‘measured to within 0.1% of its size, the uncertainity in velocity (in em!) is approximately 107 lo = De 3) 10° 4) 108 5. The uncertainities in the velocities of two particles A and B are 0.05 and 0.02m.sec~' respectively. The mass of B is five times to that of mass A. What is the ratio of uncertainities (=) in their positions : pf 2) 0.25 Noa 4 6, The uncertainity in the position of an electron (mass 9.1 x 10-%g) moving with a velocity of 3.0 x 10cm"! accurate up to 0.011%, will be sx 1) 1.92em 2) 7.68em BB) 0.175em 4) 3.84 cm is Broglie’s wavelgngth of electron in first Bohr's orbit of H-atom is °°. The circumference of 4! Bohr's orbit of H-atdm is “ N22 2)42 3) 8% B) 162. a 8. Incorrect statement in the following is For all orbitals, the radial wave function (YW ) and probability density (yP) approaches zero as “t’ become zero. 2) The radial distribution function (D-function) for 1S-orbital is minimum at nucleus. 3) In plot of radical wave function (W), Y change it’s sign at the nodes 4) W remains constant at the boundary. 1. Which of the following set has same no.of Anti nodes 13s UI) 3P. TI) 4d TV) 4P. DLn -~ Li 3) H,1V Buy I Hs '. Given that wave function of an orbital of ygrogen atom V0 ‘(or je“. The most probable ME Tay distance of the electron present in the given orbital from the nucleus is (Hint: 0 at orbital) Dae 3 \ He ae Pr 3) 5% Ss 4) 2ay PEX SERIES for $f Chaitanya CBSE XI Students 17a[ OBJECTIVE CHEMISTRY-X| Quantum numbers, Atomic orbitals : $1, Anelectron in an atom has m = -2 value, Then » value should be greater than 2 I) its I) its *P value should be 2 Iv) its ‘g° value should be +1/2 “7 value should be greater than | 1) Land II are correct 2) Wand Ill are correct 3) II and IV are correct (FB and IV are correct 52, The maximum number of electrons that canbe present in an orbit with s 3 ip and | = 2 D1 2)3 + value of azimuthal quantum number (D> the total number of magnetic quanty 53. For a particula number values (m) is given by i pe amt mmzl ale => m+! pe fies 5, “Tae vob cf seaman tetas. ‘at wi "pens for fer shown in the radial probability cun are ! Yn=2;1=0 4yna3l=3 y 1g orbitals described by the three quantum numb (AIEEY ast one Iyn=31=2 2n=4; 55, Ina multi-electron atom, which of the followi ‘will have the same energy in the absence of magnetic and electric field n=ll=0,m=0 2)n=2,/=0,m=0 3)n=2,/=lm=1 4)n=3l=%m=1 S)n=3/=2m= 1) Land 2 2) 2 and 3 3) 3 and 4 4 and 5 56. (A): For n =3,1 may be 0, 1, 2 and ‘m’ may be 0; (+1 and 0); (22,'41 and 0) (R) : For each value of n there are 0 to (n-1) possible values of 1 and for each value of / values ‘m’ are - +l fh Both (A) and (R) are true and (R) is the correct explanation of (A) 2) Both (A) and (R) are true and (R) is not the correct explanation of (A) 3) (A) is true but (R) is false 4) (A) is false but (R) is true 57. Which of the following orbital donot have nodal planes DP, ad, 3) dai By b. 58. The maximum number of electrons that can be filled into all the orbitals corresponding to azimuthal quantum number, = 3 is 2 26 3) 10 59. The number of different spatial arrangements for the orbital with | = 1 03 BS 60. The orbital angular momentum of electron in 2S- tal is pt h Nae ero ae x————— DBJECTIVE CHEMISTRY-XIA |} ft, ATOMIC STRUCTURE |. The subshell that arises after f is called the g subshell. How many electrons may occupy the g subshell ne _ Bis \ufbau principle, Pauli's exclusion principle, Hund’s rule, Electronic configuration: nd 2) 22 aut . ¥ , 2. Consider the ground state of Cr atom (Z'= 24). The numbers of electrons with the azimuthal quantum numbers, ! = 1 and 2 are, respgetively (AIEEE) 1) and 4 2) 16 and 5 3) 16 and 4 Aven s 3. The electrons identified by quantum numbers n and / are ys n=4l=1 MI) n=4,1=0 Peas 3,/=2 IV)n=3,f=1 can be placed in order. of igeresing energy as IW I> IV > TIT of spin multiplicity : IV > Il = 1 >I }) V does not violate all the three rules of electronic configuration 4) If IV represents A and A* when kept near a magnet, acts as diamagnetic substance i. The correct increasing order of magnetic moment of the following ions is i) Nie ii) Ca* iii) CP* iv) Fe fi iv 2) iv, iti, 3) i, ii, iv, i 4) i, iv ii, ii |. Magnetic moment of an ion M'* of the element M (Z = 26) is 5.916 BM. Value of ‘x’ is 1 22 44 If Hund’s rule is not followed, magnetic moment of Fe, Mn* & Cr will be 1) Fe®* < Mn* < Cr "e+ = Cr < Mn* 3) Fe? = Mn* < Cr 4) Mnt = Cr< Fe ‘Numerical value type questions ‘An ion Mn*™ has the magnetic moment equal to 4.9 BM. The value of a. 4 e first stationary state 4 “nisaon ‘energy of He* is 19.6 x 10""J atom. If energy of electron in th (n= 1) of Lit is x x 10" . What is the value of x ’\ The energy of an electron in the first Bohr’s orbit of H is - 13.6 eV. Then the energy electron in the first excited state of hydrogen atom e- \PEX SERIES for jitanya CBSE XI Students s 19[OBIE M\.7f\hecording to Bobr's theory if angular momentum of an electron in 5” orbit | ATOMIC STRUCTURE | \ the value of x ~3% ps2 If radius of second stationary orbit in Bohr’s atom is R, we in the rudius of third orbj, t terms of R. om z 1 73. How many electrons in 3d subshell contain §= +> $ 74. Uncertainty in position of a minute particle of mass 25g in space is 10-%m. The uncertainty jn velocity (in ms!) in terms of xx 10m/sec, Find out the value of x g oM| x h i ua of - x. xe. What isthe value of x. ¥) %\ For ad- electron, the orbital angular momentum is * 76. What is the maximum number of electrons in 4f subshell vy 77\S*Find out the number of waves made by a Bohr electron in on of H ~ atom. KEY SHEET (LEVE! 1)2 24 31 44 §)2 61 73 8)3 92 10)1 11)112)413)4 142 15)2_—«16)4_— 17/4 18)3_—19)2_— 20) 25)2 26)3 27)4 + 28)2 + 29)1 30) 1 31)1 -32)1.--33)2_—s34)2_—-35)3_-36)4_—37)2_ 38) 1 99)2 40)3 41)1 42)1«-43)3—«44)2_—=45)2_46)3_ 47/4 48)3— 49) 50) 4 51)3 52)2--53)2_—«B4)1—« 55) 1-56). «57/2 5B)2_~—-H9)1-80)2 61)1 62)3 63)2_-««64) 2 GH)2_—«GB)B. ~ e ~" revolution in its 34 21)4 — 22)2-23)2 24) 1)4 2)2 32 42 6)2 73 82 9)4 10)4 11)4- 12)4 13) 14)3_—18)116)1— 17/4 18)2_— 193-20) 21)2 -22)1-«-23)3.— 24) = -25)126)3_«27)2_-28)2_~—s-2Q)2_~—-30)2 31)3 a2) 3 33)1 34)1—-35)1.--36)4 = -37)3. 382 -39)340)4 41)1 43) 43)3—44)1— 45) 46) 47)4 481 49)4 —50)2 51)4 52)353)2 S4)3_««55)456)1 «57/4 58)4 593 60)2 614 —62)4 ay, \aed) 2 65)166)3_67)2_68)4 69) 44.1 70)-3.4 71) 94 72) 2.25 73)5 75) 2.4476) 14 77)3 ae