Class 11th JEE

MRJM/11 Milestone Test-01 Phase-1

DATE: 26/05/2024

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (3) 31. (4) 61. (3)
2. (3) 32. (1) 62. (4)
3. (3) 33. (3) 63. (4)
4. (3) 34. (3) 64. (4)
5. (1) 35. (3) 65. (4)
6. (3) 36. (3) 66. (4)
7. (4) 37. (4) 67. (2)
8. (3) 38. (4) 68. (3)
9. (2) 39. (4) 69. (3)
10. (4) 40. (1) 70. (2)
11. (3) 41. (3) 71. (1)
12. (3) 42. (3) 72. (2)
13. (3) 43. (2) 73. (2)
14. (3) 44. (1) 74. (3)
15. (1) 45. (3) 75. (4)
16. (1) 46. (1) 76. (2)
17. (1) 47. (1) 77. (1)
18. (4) 48. (1) 78. (2)
19. (3) 49. (1) 79. (4)
20. (1) 50. (3) 80. (2)
21. (9) 51. (16) 81. (10)
22. (24) 52. (3) 82. (4)
23. (1) 53. (743) 83. (77)
24. (4) 54. (3) 84. (200)
25. (4) 55. (25) 85. (1)
26. (2) 56. (2) 86. (4)
27. (4) 57. (25) 87. (16)
28. (5) 58. (3) 88. (1)
29. (135) 59. (1) 89. (3)
30. (181) 60. (0) 90. (1)
 SECTION-I (PHYSICS)
1. (3) 7. (4)
1 1 α +β 2 2 sin function has a period of 2π with equal positive
+ =2 2 and negative regions in one cycle
α 2
β α β
2

 α + β = 2 and αβ = 2 8. (3)
By using distance formula d
( 2)
2
− 2⋅2
∴
1
+
1
= = ( x2 − x1 ) 2 + ( y2 − y12 )
α 2
β 2 4
⇒ 13 = ( 3 − (−9) )2 + ( 3 − a )2
1
= − ⇒ 132 = 122 + (3–a)2 ⇒ (3–a)2 = 132 – 122 = 52
2
⇒ (3–a) = ±5 ⇒ a = –2 cm or 8 cm
2. (3)
9. (2)
cos 2θ = 1 – 2 sin2 θ
Given, 16 sin 20° sin 40° sin 80°
2 sin2 θ = 1 – cos 2θ = 16 sin 40° sin 20° sin 80°
⇒ sin2 θ =  1 − cos 2θ  4 (4 sin (60-20) sin (20) sin (60 + 20))
 2  = 4sin (3 × 20°)
[∴ sin 30 = 4 sin (60 – θ)sin θ sin (60 + θ)]
3. (3) = 4 x sin 60°
By comparison with the standard quadratic equation 3
=×
4 =2 3
a = 2, b = 5 and c = –12 2
−5 ± (5)2 − 4 × 2 × (−12)
x= 10. (4)
2× 2 1
−5 ± 121 −5 ± 11 +6 −16 3
∫ ydx 1
= = = , or x = , –4 
x  
1
= ∫ ( 2 x + 3) dx =  2   + 3x 
2
4 4 4 4 2 yav = 0
1− 0  
0   2   0
4. (3) = 12 + 3(1) – 02 – 3(0) = 1 + 3 = 4
1
= a
Here, a = 1, r = − So, S∞= =
1 2
2 1− r  −1  3 11. (3)
1−  
 2  n
Here a = 4, d = 4, n = 16 So, sum = [First
2
5. (1) 16
term + last term] = [4 + 64] = 8(68) = 544
∴ cos  π + θ  = –sinθ 2
2 
[cos in ΙΙ quadrant gives negative value] 12. (3)
sin (θ – π) = sin[–(π – θ)] = –sin(π – θ) c 2m − 1
Product of the roots = =3=
= – sin θ a m
3m – 2m = – 1. Thus, m = – 1
6. (3)
Let meet point be (x1, y1) then y1 – x1 = 0 and 13. (3)
When particle comes to rest, v = 0
x12 + y12 = 8 −3 ± 9 − 4(1)(−4)
2
So t2 + 3t – 4 = 0 ⇒ t =
Therefore, 2x1 = 8 ⇒ x12 = 4 ⇒ x1 = ±2; so 2(1)
possible points are (2, 2) and (–2, –2). ⇒ t = 1 or –4
Neglect negative value of t, Hence t = 1 s
14. (3) dS dr dr
∴ = 4π ⋅ 2r = 8πr = constant=k(say)
(100 + 4)1/2 dt dt dt
=10 [1 + 0.04]1/2 dS
= k ⇒ S = kt + c
≈ 10[1 + 0.02] dt
≈ 10.2 ∴ 4πr 2 = kt + c
Intially t = 0, r = 3
15. (1) c = 36π
1 so, 4πr 2 = kt + 36π
cos 120° = sin (180° – 60°) = –cos 60° = –
2 When = t 5, r= 7, k= 32π
When t = 9, r = 9
16. (1)
22. (24)
5 2
5 2
 r2  (5 2) 2 ( 2) 2
tan θ ~ θ = D ∫
= rdr

=
 
2  2
–
2
= 25 – 1 = 24
rm 2  2
θ is radians 180° = π-radians
π 1 π 23. (1)
⇒ 0.5° = × =
180 2 360 d d d
(x sin x) = x (sin x) + sin x. (x)
⇒ D = θ. rm dx dx dx
π = x cos x + sin x
= × 384000 ≅ 3350 km
360
24. (4)
17. (1) π π
1 – cos 2 x
∫ sin x dx = ∫
2 dx
tan 45° + tan 30°
=
tan 75° tan ( 45° +=
30° ) 0 0
2
1 − tan 45° tan 30° π π
1 cos 2 x
1+
1 = ∫ 2 dx – ∫ 2 dx
3 3 +1
= =
0 0
1 3 −1 π 1 π π π
1− = – [sin 2 x ]0 = –0=
3 2 4 2 2
= ( 3 + 1) = 3 + 1 + 2 3= 4 + 2 3= 2 + 3
2

2 2 2 25. (4)
dy
18. (4) For maximum/minimum value =0
dx
dy 1
= sec2 x – cosec2 x ⇒ 50 x − 10 = 0 ⇒ x =
dx 5
2
19. (3) Now at x = 1 , d y =50, which is positive
2
5 dx
=y x2 + 1 2
1 1
2
Let u = x + 1 So y min = 25  − 10  + 5 = 1 − 2 + 5 = 4
1 x 5 5
dy dy du
Then = = ·2 x =
dx du dx 2 u x +1
2 26. (2)
4
Volume of the spherical bubble V = 3 πR
3
20. (1)
 A+ B   A− B  Differentiating both sides w.r.t. time
sin A + sin B =
2sin   cos  
 2   2  dV d 4  4 dR dR
=  πR 3  =π.3R 2 . =
4πR 2
dt dt  3  3 dt dt
21. (9) dV 2 1
Surface area, S = 4πr2 at R = 1 cm, = 4π × (1) × = 2π cm3 /s
dt 2
27. (4) 1/3
5
y = ln x2 + sin x = n  
2
dy d ln x
=
(
2
+
)
d ( sin x )
dx dx dx 29. (135)
1 d y = 3x2 – 7x +5
= (x2) + cos x
2 dx dy
Slope = = 6 x − 7
x
1 dx
= . 2x + cos x
x2 dy
At (1, 1) = −1
2 dx
= + cos x ∴ tan θ = – 1 ⇒ θ = 135°
x

28. (5) 30. (181)

dA d t
1 
1
Rate of increase of area = (3t 2 + + 2)
 3 ln ( 3 x +2 )  dt dt 3
 0 1
= 6t +
1 3
= (ln 5 – ln2)
3  dA  1 181 2
1 5   =6 × 10 + = m /s
= ln .  dt t =10s 3 3
3 2

SECTION-II (CHEMISTRY)
31. (4) (3) Kinetic energy of ΙΙ excited state of He+
Species having same atomic mass are isobar.
22
= 13.6 × 2 = 6.04 eV …(i)
32. (1) 3
c (4) Ionisation potential of He+
Given, λ = 219 m Thus, ν = = 13.6 × 22 = 54.4 V …(iii)
λ

ν = 3.0 × 10 = 1.3 × 106 Hz

8
or 36. (3)
219
Bohr’s modal is applicable for Be+3 ion.
33. (3)
For photoelectric effect to take place, Elight > φ 37. (4)
hc hc or For Lymen series n1 = 1
∴ ≥ λ ≤ λ0 .
λ λ0 For shortest ‘λ’ of Lyman series the energy
difference in two levels showing transition should
34. (3)
be maximum
–13.6 Z2
= RH  1 – 1  = 109678 cm–1
1
En = (i.e. n2 = ∞)
n 2 λ 12 ∞ 2 
E1 = –13.6Z2 = 100 unit = 911.7 × 10–8 = 911.7 Å
2
E2 = –13.6 Z = 25 unit 38. (4)
4
hc 1
=
λ ∴ λα
35. (3) ∆E ∆E
(1) Energy of ground state of He+
= – 13.6 × 22 = – 54.4 eV …(iv) 39. (4)
(2) Potential energy of Ι orbit of H-atom λ1 V2 200 2
= = = .
= – 27.2 × 12 = – 27.2 eV …(ii) λ2 V1 50 1
40. (1) IV: Inert gases have no unpaired electrons.
h ∴ spin magnetic moment = 0 (True).
For a charged particle λ = ,
2mqV
45. (3)
1
∴ λ∝ . The lobes of orbital are aligned along X and Y
V axis. Therefore, the probability of finding the
electron is maximum along x and y-axis.
41. (3)
h 46. (1)
According to ∆x × ∆p =
4π Energy α n
h 6.62 × 10−34
=
∆x =
∆p × 4π 1 × 10−5 × 4 × 3.14 47. (1)
The electron having same principle quantum
= 5.27 × 10–30 m
number and azimuthal quantum number will be
having the same energy in absence of magnetic
42. (3)
and electric field.
Number of radial nodes = n –  – 1 = 1, n = 3. (iv) n = 3, l = 2, m =1
∴  = 1. (v) n = 3, l = 2, m = 0
have same n and l value.
Orbital angular momentum
h h
=  ( + 1) = 2 . 48. (1)
2π 2π
28Ni → [Ar]3d 4s
8 2

3d 4s 4p
43. (2)
Shortest wave length of Lyman series of H-atom
Number of unpaired electrons (n) = 2
1 1  1 1 
= =R  2 −  µ= n(n + 2) = 2(2 + 2) = 8 ≈ 2.84
λ x  (1) (∞) 2 
1 49. (1)
so, x=
R It is factual.
For Balmes series
1 
 1 
1  50. (3)
= R (1)2  2 − 2 
λ  (2)
 (3) 

It is factual.
1 1 5
= × 51. (16)
λ x 36 2
36x r1 = 0.529 Å; r4(X) = r1 × n ;
so, λ = Z
5
r4(X) ⇒ 0.529 × (4)
2
; Z = 16
Z
44. (1)
I : For n = 5, lmin = 0.
52. (3)
∴ Orbital angular momentum
For II to I transition,
= ( + 1)  = 0.(False) 4E E
∆E = – E = hc ; = hc
II: Outermost electronic configuration = 3s1 or 3s2. 3 λ ΙΙ→Ι 3 λ ΙΙ – Ι
∴ possible atomic number = 11or 12 (False). For ΙΙΙ to Ι transition,
III: Mn25 = [Ar] 3d5 4s2. hc hc
∆E = 2E – E = or E =
∴ 5 unpaired electrons. λ λ
5 hc
∴ Total spin = ± (False). ∴ = hc λΙΙ–Ι = 3λ
2 3× λ λ ΙΙ – Ι
53. (743) By equations (i) and (ii),
E = E1 + E2 u 8π3 Z2 me 4
hc hc hc Angular velocity (ω) = = ....(iii)
= + r n 3h 3
λ λ1 λ 2 −28 −10 4
= 8 × (22 / 7) × (2) × (9.108 × 10 ) × (4.803 × 10 )
3 2
1 1 1
= + (2)3 × (6.626 × 10−26 )3
λ λ1 λ 2
= 2.067 × 1016 sec–1.
1 1 1
= +
710 1360 λ 2
57. (25)
λ2 = 1485.53 nm. 12400
λ2 Energy of one photon = = 4eV
 743nm 3100
2 = 4 x 96 = 384 kJ mol–1
384 − 288
54. (3) % of energy converted to K.E. =
384
2nd excited state will be the 3rd energy level.
13.6 96
13.6 = x 100 = 25%
En = 2 eV or E = = 1.51 eV. 384
n 9

55. (25) 58. (3)

Maximum number of unpaired electrons is K.E ∝ Frequency of incident radiation.
possessed by Mn with atomic number = 25
59. (1)
56. (2) It would be same in x and y axis for d .
Velocity of an electron in He+ ion in an orbit x 2 − y2

= 2πZe
2
.....(i) 60. (0)
nh
Since 4f orbital has higher energy than 5p, number
n 2h 2
+
Radius of He ion in an orbit = .....(ii) of electrons = 0.
4π2 me 2 Z

SECTION-III (MATHEMATICS)
61. (3) 64. (4)
1  1
2 5x + 2 < 3x + 8 ⇒ 2x < 6
x2 + = x+  – 2 = 4 – 2 = 2
x2  x ⇒ x < 3 ...(i)
x+2
<4
62. (4) x −1
5+3 7 (5 + 3 7) 2 x+2
= ⇒ –4<0
5 − 3 7 (5 − 3 7)(5 + 3 7) x −1
25 + 63 + 30 7 88 + 30 7 44 15 −3 x + 6
= = = − − 7 ⇒ <0
25 − 63 −38 19 19 x −1
x−2
63. (4) ⇒ >0
x −1
1 1
+ + ⇒ x ∈ (– ∞ , 1) ∪ (2, ∞ ) ...(ii)
1 + logb a + logb c 1 + log c a + log c b
1 Taking intersection of (i) and (ii)
1 + log a b + log a c x ∈ (– ∞ , 1) ∪ (2, 3)
1 1 1
= + + 65. (4)
logb abc log c abc log a abc
= logabc b + logabcc + logabca = logabcabc = 1 x = 2log 3 , y = 3log 2 = 2log 3 = x
66. (4) x2 + 3x > 0
x2 + 9 < (x + 3)2 < 8x + 25 ⇒ x ∈ (−∞, −3) ∪ (0, ∞) … (i)
⇒ (x + 3)2 > x2 + 9 ⇒ x > 0 ...(i) and x + 3x ≤ 4
2

and (x + 3) 2 < 8x + 25 x2 + 3x – 4 ≤ 0
⇒ x2 – 2x – 16 < 0 (x + 4) (x – 1) ≤ 0
⇒ x ∈ (1 – 17 , 1 + 17 ) ...(ii) x ∈ [–4, 1] … (ii)
(i) ∩ (ii) ⇒ x ∈ (0, 1 + 17 ) (i) ∩ (ii) ⇒ x ∈ [–4, –3) ∪ (0, 1]
Number of integers = 5
74. (3)
67. (2) ( x + 1)( x − 1)
≤ 0 ⇒ x ≤ −1
x 2 ( x 2 − 3 x + 2) ( x − 1)
≥0
x 2 − x − 30
75. (4)
x 2 ( x − 1)( x − 2)
⇒ ≥0 1
≤0
( x + 5)( x − 6) ( x − 4)( x + 1)
x ≠ − 5,6 x ∈ (−1, 4)

76. (2)
x ∈ (−∞, − 5) ∪ [1, 2] ∪ (6, ∞) ∪ {0} Minimum value at x ∈ [−1, 1] i.e. 2

77. (1)
68. (3) Statement-1 : y = log1/3(|x – 3| + 1) is max.
log2 x < 1
When |x – 3| + 1 min.
0<x<2
ymax = log1/31 = 0
Statement-1 is true
69. (3)
|x| < 3
−3 < x < 3

70. (2)
32 log3 x – 2x – 3 = 0
Statement-2 : logax ≤ 0 for x ≥ 1, 0 < a < 1
⇒ x 2 – 2x – 3 = 0
∴ Statement-2 is true
(x – 3) (x + 1) = 0
⇒ x = 3, x = –1 but x ≠ –1
78. (2)
∴ x = 3.
x2 − 4 x + 3
−3< 0
71. (1) 2x + 1
log0.3 (x – 1) < log0.09 (x –1); x 2 − 10 x
<0
log 0.3 ( x − 1) 2x + 1
log0.3 (x – 1) <
2 – + – +
⇒ log0.3 (x – 1) < 0 ⇒ x – 1 > 1 –1/2 0 10
⇒ x>2 {1, 2, 3, 4, 5, 6, 7, 8, 9}

72. (2) 79. (4)

f ( x) =
( x − 1)( x − 4 ) 7
3|x – 3| = 7 ⇒ x – 3 = ±
( x − 2 )( x − 3) 3
16 2
so x= ,
73. (2) 3 3
2 – log 2 (x 2 + 3x) ≥ 0 32
Product of roots =
⇒ log 2 (x 2 + 3x) ≤ 2 9
80. (2) = log10(log2210) = log10(10) = 1
x2 + |x| – 6 = 0
assume that |x| = t 86. (4)
t2 + t – 6 = 0 Let |x–1| = t; t2 – 3t + 2 = 0
(t – 2)(t + 3) = 0 ⇒ t = 1, 2
t = 2, –3 |x–1| = 1 |x–1| = 2
so |x| = 2 and |x| = –3 not possible x = 0, 2 x = –1, 3
⇒x = ± 2
roots are real & sum = 0
87. (16)
81. (10) |x–4| = 5 or |x – 4| = 3
– 5 ≤ x < 10 ⇒ x = – 5, –4, –3,.......9 x = 9, –1 x = 7, 1
and 0 ≤ x ≤ 15 means x = 0,1, 2,.......9, 10, 11,
12,....15 88. (1)
Required integers values of x are 0,1, 2, 3, 4,........9 y= 6 + 6 + 6 + ...∞
⇒ Number of integers values of x = 10
y2 = 6 + y ⇒ y = 3
|log2 log93| = 1
82. (4)
1
5 = 16
log 25 16
=
log 25 5
=
16 2 4 89. (3)
Case I: x2 –5x + 5 = 0 and x2 + 4x – 60 can be any
83. (77) real number then x = 1, 4
sum = 2 + 3 + 5 + 7 + 11 + 13 + 17 + 19 = 77 Case II: x2 –5x + 5 = –1 and x2 + 4x – 60 can be any
real number then x = 2, 3 (3 Rejected)
84. (200) Case III: x2 –5x + 5 can be any real number and
2log10x – log10(2x – 75) = 2 x2 + 4x – 60 = 0, then x = –10, 6
Sum of all values of x = –10 + 6 + 2 + 1 + 4 = 3
x2
⇒ = 102 = 100
2 x − 75 90. (1)
⇒ x2 – 200x + 7500 = 0
(–3,2)
⇒ x = 50, x = 150 •
• •
(–5, 0) (–1, 0)
85. (1)
log10 (log23) + log10 (log34) + log10 (log45) + ........ + P = 2 only
log10(log10231024) = log10 (log21024) no. of values of P is 1

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