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    Chemical Bonding 13 - Class Notes - Prayas JEE 2.0 2025

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    Chemical Bonding 13 - Class Notes - Prayas JEE 2.0 2025

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    YJYRJ

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    Chemical Bonding 13 _ Class Notes __ Prayas JEE 2.0 2025

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    3 views19 pages

    Chemical Bonding 13 - Class Notes - Prayas JEE 2.0 2025

    Uploaded by

    Abhishan Sharma
    YJYRJ

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    © All Rights Reserved
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    of 19

    Lecture - 13 Inorganic Chemistry

    Chemical Bonding

    OM PANDEY , IIT Delhi


    Topics to be covered
    1 Revision Through HW

    2 MOT part-2
    OM Sir Special - Doubt & HW Discussion
    QUESTION [2019/10 Jan/Shift-1]

    Match the orbital overlap figures shown in List-I with the description given in
    List-II and select the correct answer using the code given below the lists.

    P Q R S P Q R S

    A 2 1 3 4 B 4 3 1 2

    C 2 3 1 4 D 4 1 3 2
    n ≤ 14 Electronic Configuration

    s-p mixing

    B2

    C2

    N2
    n > 14

    No , s-p mixing

    F2

    HOMO

    LUMO

    Colour

    Magnetic Behaviour
    N2 N2+ N2–

    Nb

    Nab

    BO

    BL

    BS

    BDE

    Magnetic
    Behaviour
    O22+ O2+ O2 O2– O22–

    Nb

    Nab

    BO

    BL

    BS

    BE
    Magnetic
    Behaviour
    Bond Order

    14

    13 15

    12 16

    11 17

    10 18

    9 19

    8 20
    MOT for heteronuclear diatomic

    Isoelectronic species N2 CO NO+ CN–

    N2– NO
    BaO2 O3 O2 NaO2

    Bond Order

    Bond Length

    KO2 O2 O2[BF4] O2[PtF6]

    Bond Order

    Bond Length
    NO NOCl NOClO4

    Bond Order

    CO CO2 CO32-
    Bond Order

    Bond Length : NO NO+ CO CO+

    Magnetic Behaviour : O2 S2 B2
    Assume violation of Hund’s rule in B2 Assume no 2s–2p mixing in B2 molecule, then
    molecule, then calculate bond order & calculate bond order & magnetic behaviour?
    magnetic behaviour?
    QUESTION [2023/24 Jan/Shift-2]

    What is the number of unpaired electron(s) in the highest occupied


    molecular orbital of the following species : N2 ; N2+; O2; O2+?

    A 0, 1, 2, 1

    B 2, 1, 2, 1

    C 0, 1, 0, 1

    D 2, 1, 0, 1
    QUESTION [2023/29 Jan/Shift-2]

    According to MO theory the bond orders for O22–, CO and NO+


    respectively, are

    A 1, 3 and 3

    B 1, 3 and 2

    C 1, 2 and 3

    D 2, 3 and 3
    QUESTION [2022/24 June/Shift-2]

    The correct order of bond orders of C22–, N22– and O22– is respectively.

    A C22– < N22– < O22–

    B O22– < N22– < C22–

    C C22– < O22– < N22–

    D N22– < C22– < O22–


    QUESTION [2022/25 June/Shift-1]

    Bonding in which of the following diatomic molecule(s) become(s)


    stronger, on the basis of MO Theory, by removal of an electron ?

    A NO

    B N2

    C O2

    D C2

    E B2
    Module Homework

    Prarambh ( Topic Wise ) : 21 to 28 , 32 to 36

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