Reaserch Paper - 24
Reaserch Paper - 24
Reaserch Paper - 24
MAJID BAGHERINIA
R. KAGAN AKBULUT1
Technical Vocational School of Higher Education, Ataturk University, Erzurum,
Turkey, 25240, [email protected]
Key Terms: Deep Mixing, Polyester, Guar Gum, excavation support walls, liquefaction mitigation,
Unconfined Compressive Strength, Freeze-Thaw environmental remediation, in situ reinforcement,
and large-volume ground treatment applications
(Bruce et al., 1998; Bruce and Bruce, 2003; and Tera-
ABSTRACT shi and Kitazume, 2009, 2011). The deep mixing
Deep mixing is an improvement method performed in the method involves in situ mixing of soil and binder mate-
creation of mixed columns, which includes the in situ rials with special equipment, frequently by using rigs
mixing of soil and lime or Portland cement using special with counter-rotating augers (Taki and Yang, 1991).
equipment (using rigs with counter-rotating augers). In The method was first performed in the United States
this study, series of unconfined compression tests were in 1954. The Intrusion Prepakt Co. (United States)
carried out on soft clayey soils using deep mixing with developed the earlier deep mixing application (the
polymers. In the experiments, two polymers (i.e., mixed-in-place technique), which saw only sporadic
polyester and guar gum) and lime were used as binder use in the United States in 1954 (Bruce et al., 1999).
materials at different ratios. Samples cured for 14, 28, Japan and Scandinavia have carried out large-scale
and 150 days were exposed to five and 10 cycles of freeze- researches and applications regarding deep mixing
thaw, and samples that were not exposed to freeze-thaw since 1967. Specifically, soft clays have been improved
cycles were tested in order to investigate the freeze-thaw with lime columns in Sweden. Similarly, the Japan
effect. The unconfined compressive strength increased Ministry of Transport studied stabilization of soft sea
continuously with the increase of polyester and curing soils with grained lime in 1967. Over the past few
period, while the changes in unconfined compressive years, the deep mixing method has often been used to
strength with increase of freeze-thaw cycles were solve infrastructure and seismic problems and to
insignificant. The overall evaluation of the results has enhance environmental remediation in the United
revealed that polyester and guar gum showed potential as States (Bruce et al., 1998; Bruce and Bruce, 2003).
candidates for deep mixing applications in soft clayey soils. Lime and cement have been used as the primary bin-
der materials in deep mixing applications since the
1970s, and they are now currently used extensively
INTRODUCTION worldwide. Commonly, two different techniques are
utilized: column installation and slurry pressure injec-
The deep mixing method is mostly used in slope sta- tion. These two techniques decrease soil moisture con-
bility, embankment supports, hydraulic cut-off walls, tent, thereby reducing shrinkage and swelling while
enhancing strength and compaction properties (Glen-
1
Corresponding author email: [email protected]. dinning and Rogers, 1996; Threadgold, 1996; Bruce
Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12 1
Arasan, Bagherinia, Akbulut, and Zaimoglu
et al., 1998; Rogers et al., 2000; Ahnberg et al., 2003; Table 1. Index properties of clay (Bagherinia, 2013).
Bruce and Bruce, 2003; and Arasan and Nasirpur,
2015). The binder type and its mixing ratio are two CL Clay
important factors influencing deep mixing performance. Clay content, ,0.002 mm (%) 10
Numerous experimental studies dealing with the effects Finer content, ,0.075 mm (%) 80
of binder types and ratios on deep mixing method are Specific gravity, GS 2.77
Liquid limit, wL (%) 40
available in the literature. Some of these studies have Plastic limit, wP (%) 23
focused on the soil/binder (cement and/or lime) ratios Plasticity index, IP (%) 17
and the water/cement-lime (w/c) ratio (Okumura and Optimum moisture content*, OMC (%) 15
Terashi, 1975; Terashi and Tanaka, 1981; Ahnberg, Maximum dry unit weight, γdmax (kN/m3) 18.3
Hydraulic conductivity**, k (cm/s) 6.974 6 10−7
1996; Porbaha et al., 1998, 2000; Bahner and Naguib,
2000; Jacobson, 2002; Lorenzo and Bergado, 2004, *From standard Proctor test.
2006; Rutherford, 2004; Pathivada, 2005; Lewsley, **From standard Proctor optimum moisture content.
2008; Shrestha, 2008; Şengör, 2011; Miura et al.,
2002; Horpibulsuk et al., 2005; Maher et al., 2007; A polyester is defined as a condensation or step-
Tang et al., 2011; and Dias et al., 2012), while others growth polymer containing in-chain ester units,
have studied curing periods (Hartlen and Holm, 1995; because it is the long chains that give polymers their
Andromalos and Bahner, 2004). Most researchers unique properties (McIntyre, 2004). With an 18 per-
have pointed out that the unconfined compressive cent market share of all plastic materials produced,
strength (UCS) values increased when binder ratio and polyesters are widely used as thermoset plastic, fiber,
curing time were increased, and the w/c ratio was and fabric for many industries, such as auto and mar-
decreased. The UCS values obtained by these research- ine body parts, building panels, clothing, carpet, furni-
ers were between 0.1 and 8.0 MPa with 28 days of cur- ture, etc. Significant research efforts have therefore
ing time. Matsuo et al. (1996) reported that UCS values been performed in polymer science (McIntyre, 2004;
between 1.4 and 7.4 MPa were obtained when marine Scheirs and Long, 2005). However, very limited infor-
clays were mixed with 13–32 percent cement (cement mation exists on polymers in concrete technology
to dry soil). Similarly, Bergado and Lorenzo (2005) (Ates, 2008; Lim et al., 2009; Jamshidi et al., 2013;
reported that UCS values of 0.3–1.0 MPa were and Martínez-Barrera et al., 2013) and soil stabiliza-
obtained when Bangkok clays were mixed with 10–15 tion (Akbulut et al., 2013; Bagherinia, 2013).
percent cement (cement to dry soil). Taki (2002) also Biopolymers are polymers that are produced by liv-
reported that UCS values between 1.7 and 4.9 MPa ing organisms. In other words, they can be described
were obtained when marine clays were mixed with as polymeric biomolecules. Commercially available
200–300 kg/m3 cement (cement per unit volume of wet biopolymers include gum arabic, guar gum, and locust
soil). Filz et al. (2005) and Liu et al. (2008) mentioned bean gum from botanic sources; starches from corn or
similar results from their studies. tapioca; xanthan gum from bacteria; and gelatin
There are a limited number of studies in the literature derived from animal skin or bones (Van de Velde and
on the utilization of materials other than cement or lime Kiekens, 2002; Chang and Cho, 2012). Biopolymers
in the improvement of soils using the deep mixing are used for soil improvement in the fields of geotechni-
method (Ahnberg and Holm, 1996; Ahnberg, 2006; cal engineering and geo-environmental engineering
and Ajorloo, 2010.). Silica fume, fly ash, and slag are (Cabalar and Canakci, 2011; Chang and Cho, 2012;
generally used with or without cement in deep mixing Bagherinia, 2013; Khatami and O’Kelly, 2013; and
applications. However, one group of researchers Arasan and Nasirpur, 2015), reducing permeability of
focused on the stabilization of soils using polymers soils (Bouazza et al., 2009; Wiszniewski et al., 2013),
(Ahmed, 1995; Bishop et al., 1998; Al-Khanbashi and and as soil drilling mud and temporary excavation sup-
Abdalla, 2006; Gallagher et al., 2007; Gupta et al., ports (Mitchell and Santamarina, 2005). Similar to this
2009; Naeini and Ghorbanalizadeh, 2010; and Cabalar trend, theoretical and experimental verifications of the
and Canakci, 2011). Polymers are widely used in indus- interactions between various types of biopolymers and
try, but they are rarely used in soil stabilization applica- soil media are necessary in the geotechnical and geo-
tions. In this respect, some commercially available and environmental fields (Chang and Cho, 2012). More-
non-traditional additives, such as emulsions, acids, lig- over, it can be said that biopolymers could reduce the
nin derivatives, enzymes, tree resins, and silicates, can degree of saturation and contaminant leaching (He
be used as soil stabilization binders. These binders et al., 2013; Arasan and Nasirpur, 2015).
may exist in liquid or solid form and may be applicable Soft clayey soils have great potential for stability
for most soils (Newman and Tingle, 2004). problems, such as landslides, bearing capacity failure,
2 Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12
Polymers to Improve Soft Clay
and collapse. For that reason, studies on the stabiliza- to pass through a 1 mm sieve for easy processing
tion of clay soils with polymers using the deep mixing and uniform water content. Then, the clay was mixed
method became more important for geotechnical with the required water content. The properties
knowledge and practice. The current study was per- of clay are shown in Table 1. Water content of
formed to investigate the effects of polyester and 40 percent (mass) was chosen for experiments in this
guar gum on unconfined compressive strength and study on the basis of the liquid limit value of
freeze-thaw properties of soft clayey soil, i.e., low-plas- clay. According to the X-ray diffraction results for
ticity clay (CL) under three different curing periods soft clay, the material sampled is composed of clay
(14, 28, and 150 days) and three different freeze-thaw (56 percent), quartz (28 percent), cristobalite (11 per-
cycles (0, 5, and 10 cycles). cent), and tridymite (5 percent). The clay particles are
also composed of only kaolinite minerals (100 per-
cent), as shown in Figure 1.
MATERIALS AND METHODS
Soft Clayey Soil Polymers
The CL clay was brought from the field (Çankırı, The experiments were carried out with polyester
Turkey) and then dried. The dry clay was powdered used as the polymer, guar gum as the biopolymer,
Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12 3
Arasan, Bagherinia, Akbulut, and Zaimoglu
Table 3. Some properties of guar gum. Table 5. Preliminary test results of additives (Bagherinia, 2013).
4 Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12
Polymers to Improve Soft Clay
Materials (%)
Specimen Clay at 40% Guar
Name Water Content Polyester Gum Lime Total
S1 100 — — — 100
S2 96.98 — 0.02 3 100
S3 96.75 — 0.25 3 100
S4 91.98 5 0.02 3 100
S5 91.75 5 0.25 3 100
S6 86.98 10 0.02 3 100
S7 86.75 10 0.25 3 100
S8 76.98 20 0.02 3 100
S9 76.75 20 0.25 3 100
Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12 5
Arasan, Bagherinia, Akbulut, and Zaimoglu
Figure 3. UCS versus polyester ratio for the samples that were cured for 14 days.
at 0 percent, 5 percent, 10 percent, and 20 percent and 7.0 MPa, respectively (Figure 3). It should be
polyester ratios were obtained as 0.43, 0.54, 0.72, also noted that the lowest UCS value obtained in
and 7.3 MPa, respectively. On the other hand, the this study is higher than that of the lower UCS limit
UCS values of the 0.25 percent guar gum sample at of fine-grained soil (0.2 MPa) for the deep mixing
0 percent, 5 percent, 10 percent, and 20 percent method reported by Bruce and Bruce (2003) and
polyester ratios were obtained as 0.41, 0.52, 0.71, Bruce et al. (1998).
Figure 4. 3-D column illustration of UCS/curing period/polyester ratio of samples with respect to the guar gum (GG)
ratio.
6 Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12
Polymers to Improve Soft Clay
Figure 5. SEM micrographs of samples cured for 150 days: (a) raw clay, (b) 0.25 percent guar gum with 20 percent
polyester, sample S9, (c) 0.02 percent guar gum with 20 percent polyester, sample S8, and (d) pure polyester.
On the other hand, Figure 3 shows that the UCS polyester and guar gum may be used for deep mixing
values of samples without adding polyester (only applications in clayey soils.
guar gum and lime added to clayey soils samples S2 The column graphs of Figure 4 are drawn in three
and S3) are higher than 0.2 MPa, the lower UCS limit dimensions to display the combined effect of polyester
of fine-grained soil. It is also mentioned that the guar ratio, guar gum ratio, and curing periods on UCS. It
gum reduces the moisture degree of the samples as can clearly be seen in Figure 4 that UCS values
observed by Gupta et al. (2009), Bagherinia (2013), increase drastically after a 20 percent polyester ratio
and Arasan and Nasirpur (2015). Due to the decreas- is reached for each curing period. Nevertheless, the
ing moisture degree and the chemical reactions occur- UCS values of all samples are higher than 0.2 MPa
ring between guar gum, lime, and clayey soil, the (the lower UCS limit of fine-grained soil). However,
samples became strengthened structures. On the basis the increase during the curing period has no important
of these results, it could therefore be concluded that effect on the UCS values of 0 percent, 5 percent, and
Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12 7
Arasan, Bagherinia, Akbulut, and Zaimoglu
Figure 6. SEM micrographs at different magnifications of samples cured for 150 days: (a1–a2) raw clay sample, and
(b1–b2) 0.25 percent guar gum with 20 percent polyester, sample S9.
10 percent polyester samples. The highest UCS value respectively. This different behavior suggests that the
of this study was obtained from sample S9 with 0.25 guar gum ratio is more effective on the UCS values
percent guar gum and 20 percent polyester ratio and after 28 days of curing time. On the other hand, the
a curing period of 150 days. The UCS values of this UCS values of the 20 percent polyester samples gave
sample for the curing periods of 14 days, 28 days, higher values than 7 MPa. This positive behavior indi-
and 150 days were 7.0 MPa, 7.2 MPa, and 13.4 cates that the samples become a polyester-clay compo-
MPa, respectively (Figure 4). However, sample S8 site material when 20 percent polyester is added to the
(0.02 percent guar gum with 20 percent polyester) clayey soil. In other words, polyester dominates the
gave maximum UCS values for the curing periods of behavior of the samples mixed with 20 percent
14 and 28 days. The UCS values of sample S8 for the polyester.
curing periods of 14 days, 28 days, and 150 days This striking increase in UCS of the 20 percent
were recorded as 7.3 MPa, 8.0 MPa, and 12 MPa, polyester samples is attributed to the adhesion
8 Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12
Polymers to Improve Soft Clay
Environmental & Engineering Geoscience, Vol. XXIII, No. 1, February 2017, pp. 1–12 9
Arasan, Bagherinia, Akbulut, and Zaimoglu
On the basis of this study, it could therefore be con- BAGHERINIA, M., 2013, Utilization of unsaturated polyester in
cluded that polyester and guar gum may be used for improvement of clays with deep mixing method: Master Thesis,
Ataturk University, Erzurum, Turkey (in Turkish with an
deep mixing applications in clayey soils. It should be English summary).
noted that model tests and field studies of polyester BAHNER, E. W. AND NAGUIB, A. M., 2000, Ground improvement
and guar gum applications are needed to confirm the for large above ground petroleum storage tanks using deep
results of this study. It is also recommended that a mixing. In Geodenver 2000: Denver, CO.
BERGADO, D. T. AND LORENZO, G. A., 2005, Economical mixing
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