Scribd Logo
Upload

Welcome to Scribd!

  • 6 views

    Amines ...

    Uploaded by

    mr.padips.jai

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Amines ...

    Uploaded by

    mr.padips.jai
    6 views3 pages

    Original Title

    AMINES_...

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    6 views3 pages

    Amines ...

    Uploaded by

    mr.padips.jai

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    TOTAL 40 MARKS AMINES

    1 HOUR

    Question 1.

    Why is an alkylamine more basic than ammonia?

    Question 2.

    Arrange the following compounds in an increasing order of basic strengths in their aqueous solutions
    : NH3, CH3NH2, (CH3)2NH, (CH3)3N

    Question 3.

    Give the IUPAC name of H2N — CH2—CH2—CH = CH2.

    Question 4.

    Arrange the following compounds in an increasing order of their solubility in water : C6H5NH2,
    (C2H5)2NH, C2HSNH2

    Question 5.

    Give a chemical test to distinguish between ethylamine and aniline.

    Question 6.

    Arrange the following in the decreasing order of their basic strength in aqueous solutions: CH3NH2,
    (CH3)2 NH, (CH3)3N and NH3

    Question 7.

    Arrange the following in increasing order of their basic strength in aqueous solution: CH3.NH2,
    (CH3)3N, (CH3)2NH

    Question 8.

    Write the structure of 2-aminotoluene.

    Question 9.

    Write the structure of n-methylethanamine.

    Question 10.

    Write the structure of prop-2-en-l-amine.

    2 mark questions

    Question 1.

    Give the chemical tests to distinguish between the following pairs of compounds :

    (i) Ethyl amine and Aniline


    (ii) Aniline and Benzylamine

    Question 2.
    Identify A and B in each of the following processes : (All India 20100

    Question 3.

    Give the chemical tests to distinguish between the following pairs of compounds :

    (i) Methylamine and Dimethylamine

    (ii) Aniline and N-methylaniline

    Question 4.

    Describe the following giving the relevant chemical equation in each case :

    (i) Carbylamine reaction

    (ii) Hofmann’s bromamide reaction

    Question 5.
    Complete the following reaction equations : (All India 2012)
    (i) C6H5N2Cl + H3PO2 + H2O →
    (ii) C6H5NH2 + Br2 (aq) →

    3 mark questions

    Question 1.
    How would you account for the following :
    (a) Aniline is a weaker base than cyclohexyl amine.
    (b) Methylamine in aqueous medium gives reddish-brown precipitate with FeCl3.

    Question 2.
    Illustrate the following reactions :
    (a) Sandmeyer’s reaction
    (b) Coupling reaction

    Question 3.
    Give chemical tests to distinguish between the following pairs of compounds :
    (a) Aniline and Ethylamine
    (b) Ethylamine and Dimethylamine

    Question 4.
    Give reasons :
    (a) Aniline is a weaker base than cyclohexyl amine.
    (b) It is difficult to prepare pure amines by ammonolysis of alkyl halides.

    Question 5

    Complete the following reaction equations :


    (i) C6H5Cl + CH3COCl →
    (ii) C2H5NH2 + C6H5SO2Cl →
    (iii) C2H5NH2 + HNO2 →

    5 mark

    State reasons for the following :

    (i) pKb value for aniline is more than that for methylamine.
    (ii) (ii) Ethylamine is soluble in water whereas aniline is not soluble in water.
    (iii) Primary amines have higher boiling points than tertiary amines.

    (iv) Nitrobenzene to benzoic acid.

    (v) Benzyl chloride to 2-phenylethanamine

    (vi) Aniline to benzyl alcohol.

    You might also like