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Fukuyama Group - Group Meeting Problems 08/21/2002: Ar Ar

The document discusses 5 chemical reactions. It provides reaction conditions and yields for some of the reactions. The document contains details about multi-step organic synthesis procedures.

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Nguyễn Ngô Đức
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14 views1 page

Fukuyama Group - Group Meeting Problems 08/21/2002: Ar Ar

The document discusses 5 chemical reactions. It provides reaction conditions and yields for some of the reactions. The document contains details about multi-step organic synthesis procedures.

Uploaded by

Nguyễn Ngô Đức
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Fukuyama Group - Group Meeting Problems

08/21/2002

S
1 O
S
Sn(tpp)(ClO4)2 (3 mol%) O
S +
CDCl3, 20 °C, 2 hr S S
Ar Ar S 46%
Ar Ar
=
Ar Ar

2 O
Cr(CO)5

MeO H
+
dioxane H
CHO
100 °C
OH

3 OMEM OH
hν
OMEM H2SO4 OMEM
O +
CH3CN

O hν
H2SO4

CH3CN

4
Me
1) CHBr3 (>2 eq), t-BuOK

2) MeLi (2 eq), –78 °C Me


3) H2, Pd/C Me

1)
n-Bu
5 EtO2C NH
CO2Et
OMe CSA, CH2Cl2, 0 °C, 15 h H

N 2) CH3CHO, Al2O3, CH2Cl2


Bn N
rt, 15 h; Bn
NaBH4, MeOH, rt, 1 h;
aq. HCl 38%

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