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Solutions to JEE Advanced -11 |JEE 2022 | Paper-1

PHYSICS

1.(ABC)
Initially when sand starts falling but it doesn’t hit the surface DE.
Reading  (m0  M ) g  tg
2h
At time t1  sand starts hitting the surface
g
2h
Reading just before t  t1 is (m0  M ) g  g  (m0  M ) g   2 gh
g
When sand starts hitting the surface.
2h
Reading  (m0  M ) g   2 gh   g  (m0  M ) g
g
m0
After time t2  upper reservoir will be empty.

Reading till all sand hits DE (for t  t2 ) is  (m0  M   (t  t2 ) g )
And for time t  t3 (All sand has reached lower reservoir)
Reading  ( M  m0 ) g

2.(BCD)
5 105  (2 106 ) (2a(0.1)2  0)
V
a  1.25  103
m2
Any plane parallel to x  y plane z  constant
V  ax2  ay 2  const.
ax2  ay 2  V0  const.  K (a circle)
Substituting a, v and z  2
6250  (1.25 103 ) ( x2  y 2  2  2)  x2  y 2  1

3.(ACD)
2 cos  2  0.07  cos0
(i) h  3
 2.8 102 m  2.8 cm
rg (0.5 10 ) 10 10
3

(ii) The vertical height h of water column will remain the same = 2.8 cm
Length of water column is
h
l  2h  5.6 cm
cos60
But only 5 cm of tube is available
 l  5 cm
When accelerating up (setup-2)
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2 cos  h
h  1.87 cm ; l  3.73 cm
 3g  cos60
r  
 2 
4.(ACD)
At t  t

dq
i
dt
(Q0  q) q L di
  0
C C dt
2q  Q0 L di
 0
C dt
d 2q 2  Q 
  q 0 
dt 2 LC  2 
Q0
 q  A0 sin(wt  )
2
2 2
w    2 LC
LC w
 CV
Initially i  0 and q  CV so   and A0 
2 2
3CV CV
So q   cos(wt )
2 2
3CV CV
So qmax    2CV
2 2
5.(AD) The resultant figure can be redrawn as in figure.

The field at P due to upper and lower squares will cancel out. Resultant field at P will due to the square
2 0 I
BCGF as shown in the figure. Solve to get, BP 
 3a
6.(ABC)
(A) Work done in process A to B is (see figure)
 P 3PV 3RT
W1  area of trapezium ABCD   P  V   (for 1 mole)
 2 2 2

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If the process A to B were isothermal, the work done would be

V 
W2  RT log e  2   RT log e (2)  0.69RT
 V1 
Thus, W1  W2
So, choice (A) is correct
P
(B) Slope of line    slope of adiabat at point ( P , V )
2V
3 PV 
 P  …….. (1)
10 V
Equation of line
PV  3P
P    …….. (2)
2V 2
15V
 V 
8
RT
(C) Since V  , Eq. (i) becomes
P
P RT V0 P 2
 1  T  V0 P  …… (ii)
P0 PV0 RP0
Which represents a Parabola
So, choice is correct
(D) Let P0 and V0 be the intercepts on the P and V axes. The equation of straight line AB is
P0
P (V  V0 )
V0
P V
  1 …… (i)
P0 V0
RT
Since P , Eq. (i) becomes
V
RT V PV PV 2
 1  T 0
 0
VP0 V0 R RV0
Which represents a parabola on the T – V graph
So temperature first increases reaches a maximum and then decreases.

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7.(34.64)

From A(t  0) to B(t  6)

F f
a  105  5 m/s2
m
1 1
s1  at 2  (5)(36)  90m
2 2
Velocity at B  at  5(6)  30 m/s
After B, the direction of F is reversed.
As velocity is in forward direction, friction acts backwards till block comes to instantaneous rest at C.
From B to C
(F  f )
a  (10  5)  15 m/s2
m
u  30 m/s
v2  u 2  2as2
0  (30)2  2(15)s2  s2  30m
While returning from C to A, F acts towards left but friction acts towards right (as velocity is towards left)
s  ( s1  s2 )  120m
(F  f )
a  5m/s2
m
v2  u 2  2as  0  2(120)(5)
v2  1200  v  20 3  20(1.732)  34.64 m/s

8.(0.33) Let  be the mass per unit area (it will be same for the shell and the plate)
m1  (2R 2 ), m2  (R 2 )
To find the CM, we can replace the hemispherical shell and the
circular plate by point mass located at their CM as shown.
CM of the system from C
m1 ( R / 2)  m2 (0) (2R 2 )( R / 2) R
    0.33R
m1  m2 3R 2 3
9.(0.50)
Rr
sin  
Rr

2 Rr
cos   1  sin 2  
Rr
Smaller roller :  about O   N1 r   N 2 r
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 N1  N 2
Forces along X : N 2  N1 cos (90  )  N1 cos 
N1  N1 sin   N1 cos 

 R  r  2 Rr r 1
 1       0.5
 Rr Rr R 2

10.(49.5)
2  6  3  4 24
VCM    4m / s
24 6
In the figure of C.M at t  0

4 4 4
Block perform SHM about CM with time period T  2  2 
3k 3000 30 10
T  V
At t   , V  max
6 45 10 2
2
1 1  1  49
K.E.   2(1  4)2   4     4   25  2   25  24.5  49.5 J
2 2  2  4

11.(3.60)
After closing the switch capacitor between B and S changes
its potential from V/3 to V where as other capacitor
connected to point B continued to maintain its voltage at V.
Let the charge flown from A to B be x then.
x = change in charge on capacitor ‘1’
CV 2CV
 CV    3.60
3 3
12.(3.14)
F  thrust ; W  weight
kx0  W  F
If displaced by x total energy
1 1 1
E  (W  F ) x  k ( x  x0 )2  mv 2  Vv 2
2 2 4
dE
0
dt

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dx dx dv 1 dv
 O  (W  F )  k ( x  x0 )  mv  Vv
dt dt dt 2 dt
k
 a x
1
V  m
2
1 1
m  V 20  (1000)(0.16)
2 2 2
T  2  2  
k 400 2
13.(1.78)
P
When mirror is absent I 
4a 2
2
 I 16 I  16
With mirror present I    I    I    1.78
 3  9 I 9
14.(2.78)
1 1 3
Increase in kinetic energy of particle  m(2v)2  mv 2  mv 2
2 2 2
Work done by the uniform electric field, E, in going from P to Q = (qE) × 2a = 2qEa
3
Hence, 2qEa  mv12
2
3mv 2
or E
4qa
3 6.6 1027 (3 104 ) 2
   2.78 V /m
4 1.6 1019 10

15.(B) 16.(D)
ax 02 x dy
tan    
ay g dx
d2y 02

dx 2 g
3/2
2  3/2   2 2 
  dy  1   0 x  
1       g  
  dx  
  Radius of curvature     
d2y w02

dx 2 g
Using mirror formulae :
2 1 1
 
 x 0 yi y0
202 1 1 gy0
   yi 
g yi y0 g  202 y0
g
For real image yi  0  y0  2
20

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  0i  1 0 niS
17.(A) q    2l  n  S   Q
R  2l  R R

18.(A)    ( B1  B2 )  dA n   ( B1  B2 )  dl ndA   B1  dl ndA  Depends on i1 .

As  B2  dl  0 (Ampere’s law)

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CHEMISTRY

1.(CD) 2Pb(NO3 )2   2PbO  4NO2  O2
 1
2LiNO3   Li 2O  2NO2  O2
2
2.(ACD)
As the M – C  bonding increases the C – O bond length increases
As the electron density on the central metal atom increases, the C – O bond length increases
In Cr(CO) 6 ; EAN = 24 + 12 = 36

3.(BC) Nitrogen being second period element, d-orbitals are not available for bonding

4H3PO3   3H3PO4  PH3
The reducing nature of hydrides increases down the group
The basic nature of oxides increases down the group.

4.(AB)

(I) and (II) are geometrical isomers and diastereomers.

5.(ABCD)

(A)

(B)

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(C)

(D)  H2PO4  H
H3PO4 

6.(BD) At point a,
P0V0
P0 V0  1 RT0  T0 
R
At point b,
4P0V0
P0  4V0  1 R  Tb  Tb   4T0
R
At point c,
8P0V0
2P0  4V0  1 R  Tc  Tc   8T0
R
3 9
Ua b  1 R  (4T0  T0 )  RT0
2 2
3
Ubc  1 R  (8T0  4T0 )  6 RT0
2
9
U a c  U a b  U b c  RT0  6RT0
2
21
Ua c  RT0
2
Wa b   P0  (4V0  V0 )  3P0 V0  3RT0
U a  b  q a b  Wa b
9
RT0  qa b  3RT0
2

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9 15
qa b  RT0  3RT0  RT0
2 2
Process a  b is isobaric
15
Hence q a  b  H a b  Ha b  RT0
2

7.(5) Paramagnetic species  O2 , O2 [AsF6 ], KO2 , [Cu(NH3 ) 4 ]2 and (NH 4 ) 2 [CoCl 4 ]

8.(3106)
1584
Number of moles of (NH4 )2 SO4   12
132
(NH 4 ) 2 SO 4  Ca(OH) 2 
 CaSO 4  2H 2O  2NH 3
12 0 0
0 12 24

Moles of NH 3 formed = 24
1066
Number of moles of CrCl3  6H2O  4
266.5
CrCl3  6H 2O  6NH3 
 [Cr(NH3 )6 ]Cl3  6H 2O
4 24 0
0 0 4
Mass of gypsum = 12 × 172 = 2064 gram
Mass of [Cr(NH3 )6 ]Cl3  4  260.5  1042 gram
Total mass of gypsum and [Cr(NH 3 ) 6 ]Cl3 = 2064 + 1042 = 3106 gram

9.(155)
Z M
d
a3  NA
99.9
Z  4  3.996
100
3.996  40
d
(0.556 107 )3  6 1023
d  1.55 gram/cm3
Hence 100 d = 155

10.(100)
0.06
E  log K
n
Fe  Zn 2 Fe2  Zn
1 0
1– y y
0.06 y
E  0.33  log (1  y 1)
2 (1  y)
 y  1 1011  [Fe2 ]  1  1011  100  1013  x  1013  x  100

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11.(150)
U  q  W
W  U  q
= 400 – 5059.8
W = – 4659.8 J
V2 20

W   PdV   1 V
dV

W  20 ln V2
W  20  2.3 log V2 litre-atm
W  20  2.3  101.3 log V2 Joule
 4659.8  20  2.3  101.3 log V2
 log V2  1  V2  10 litre
Hence, 15V2  150

12.(50) Ps  x A PA  x B PB
109.13  x A  200  (1  x A )  75
 x A  0.273
x A  PA
yA 
Ps
0.273  200
yA 
109.13
y A  0.5
Mole percent of A  y A 100  0.5 100  50%

13.(50) MgF2(s) Mg 2  2F , K sp

S 2S

1
F + H HF
Ka
2S 104
1/2
 K sp 
  104 2S
 S 
1 2s
 1/2
Ka  K sp 
4
10   
 S 
1 2s3/2
104  4
3.5 10  (Ksp )1/2
1
S3/2   (Ksp )1/2
7
1
S3   Ksp
49

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1
S3   6.125 109
49
S  5  10 4
S  50  105 mol/litre  Y  105
 Hence Y = 50

14.(30) For solute S

Tb  i  0.1  K b
For other solute
Tb  1  0.08  K b
Hence, i  0.1  K b  0.08  K b
 i  0.8
3S S3
a 0
a(1  ) a /3
a
a(1  ) 
i 3
a
2
i  1
3
2
0.8  1 
3
2
 0.2    0.3  30 102  Y  30
3
15.(A) 16.(C)

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17.(D) 18.(B)

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MATHEMATICS

1.(ABD)
2.(AB) Given that a  5 3, b  5, c  5
b 2  c 2  a 2 52  52  (5 3) 2
cos A  
2bc 255
25 1
 cos A    
50 2
A = 120°
1 1 1 3 25 3
Area of ABC  bc sin A   5  5  sin120   5  5  
2 2 2 2 4
25 3
 4 5
Radius of incircle of ABC  r    (2 3  3)
s 10  5 3 2
2
abc 5 3  5  5
Radius of circumcircle of ABC  R    5 cm
4 25 3
4
4
3.(BCD)
i j k

(A) n  2 1 1  i  3 j  5k
1 2 1
Equation of plane is
–1(x – 3) + 3(y – 2) + 5(z + 1) = 0
–x + 3y + 5z + 2 = 0
x – 3y – 5z = 2
2  2 1 1
(B) cos   
6 6 6
(D) Any plane passing through the intersection of P1 and P2 is
(2 x  y  z  2)  ( x  2 y  z  3)  0
5
(1, 3, –2) lies on it, therefore  
6
Equation of required plane is
5
(2 x  y  z  2)  ( x  2 y  z  3)  0  17 x  4 y  z  27  0
6
4.(ABC)
(A) lim f ( x 2 )  lim( f ( x)) 2  f (0)  1
x 0 x 0

Continuity forces f ( x)  1 for all x

n n
(B) If f (a) = 0  f (a 2 )  ( f ( a )) 2  f (1)  0
Assume for some b f (b) > 0
n n
 f (b 2 )  ( f (b) 2  f (1)  1 contradiction
(C) Define  t  (2, )
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 xt 1 x  (0, 1) 
 
ft ( x)   1 x 1 
 (t 1) 
x x  (1, ) 

f t ( x ) satisfies the given property that ft ( x 2 )   ft ( x)   x  (0, )

2


1 1 2
 ft ( x) dx  t  t  t  1
0
Hence, infinite such functions

5.(ABCD)
f ( f ( x))  x  f ( f (0))  0  f (1)  0
Now f ( f ( x))  f ( x)  1  f is decreasing and f (1) = 0
f :[0,1]  [0,1] is invertible
1
1
Let 
I  ( x  f ( x)) 2020 dx, put f ( x)  t  I
2021
0

6.(BCD)
Notice f(0) = 0 and f ( x)  2 f ( x )  f ( x)  0  x

7.(1)  log3 7 8log(log9 49) 7  58log5 7

8
 log3 7 8log(log3 7) 7  5log5 7
8
 log3 7 log(log3 7) 7  78  78  7 8  1
8.(216) Sum of all digits in set is 0 + 1 + 2 + 3 + 4 + 5 = 15
Case I
If number is formed using 1, 2, 3, 4, 5 then number of numbers = 5! = 120
Case II
If number is formed using 0, 1, 2, 4, 5 then number of numbers = 4 × 4! = 96
So, total numbers = 120 + 96 = 216
9.(3638)
Common elements in X and Y are 18, 38, 58, 78, ……, 8078
Number of common elements in X and Y is 404
So, Number of elements in XUY is
2021 + 2021 – 404 = 3638
   x
   x 
 x /2 x x 2
10.(1) cos 1    cos1   2
x 1 x  1  x x
 1   1 
 2   2

VMC |JEE-2022 | Paper -1 15 Solutions |JEE Advanced-11

 Vidyamandir Classes

1 1 x x
     x3  2 x 2  5 x  2  0  y  3 x 2  4 x  5
1 x 2  x 1 x 2  x y a  0 and D  0


y  0

1
and y    ve
2

 1
There exist a unique solution in  0, 
 2
1
  n  2  n  4  n  6   n  2n   2
11.(5) Pn       
  n  n  n   n 
n n
 ln1 n   ln1 n 
1 2r 1 2r
lim
n n n
 Pn  e r 1  Le r 1

1
 I  1. ln(1  2 x) dx
0 II I
1
1 2 x 3
 2 x  1 dx
1
I  ln(1  2 x)  x 0   I  ln 3  1
0
2
3
ln 31 27
 L  e2  L
e
 Le  27

[ Le]  5
   
12.(5) a  c  | a | | c | cos 
 
a  c  3cos 
 
b  c  3cos 
    
 c  m a n b a  b
 
a  c  m  3cos 
 
b  c  n  3cos 
    
 Let m  n  3cos     c a b  ab
  
 | c |2   2   2  | a  b |2  9  2 2  1  9
 2  4

9cos 2   4

VMC |JEE-2022 | Paper -1 16 Solutions |JEE Advanced-11

 Vidyamandir Classes

13.(2) 3 p sin x  2q cos x  r

 3 p sin   2q cos   r
3 p sin   2q cos   r
   
 3 p(sin   sin )  2q(cos   cos )  0  3 p cos  2q sin
2 2
p 2  p 2 1
  tan   
q 3 2 q 3 3
14.(9)

1 1
 PQR is right angled at P  A1   PQ  PR   2  2  1
2 2
 Area of shaded portion  0.6  A1
1
1
  x dx  2 11  0.6
n

1 1 1
  0.6  0.5    n9
n 1 n  1 10

15.(C)

Equation of chord of contact to a circle drawn from (h, k) is:

hx  ky  4
(1) Equation of M1M 2 : y  1  M 3 (0, 4)
(2) Equation of N1N 2 : x  1  N3 (4, 0)
(3) Equation of H1H 2 : y  1  ( x  1)
x  y  2  H 3 ( 2, 2)

VMC |JEE-2022 | Paper -1 17 Solutions |JEE Advanced-11

 Vidyamandir Classes

16.(D) Tangent at ‘P’ is given by

x cos   y sin   2
 2   2 
 A ,0  , B  0, 
 cos    sin  
 Let ‘M’ is midpoint of AB and let M be (h, k)
2 2
0 0
 h  cos  ,k sin 
2 2
1 1
 cos   , sin  
h k
1 1
 cos 2   sin 2   2  2  x2  y 2  x2 y 2
h k

Number of favourable arrangements D3

17.(A) Probability  
Total number of arrangements 4!
 De-arranging of 3 objects
 1 1 1 2 1
D3  3!1      
 1! 2! 3!  24 12
D3  2

18.(A) Number of total arrangements = 4!

Number of arrangements favouring E2  E3  E4 :
 constraints of P1 and P4 are same Constraints of P2 and P3 are same
 P1 P3 _ _  No such arrangement  P2 P4 P1 P3
is possible
P1 P4 P2 P3  No such that arrangement  P3 P1 P4 P2
is possible
There are
 No such arrangement where P1 , P4
Occupies 1st position
2 1
 Probability ( E2  E3  E4 )  
4! 12

VMC |JEE-2022 | Paper -1 18 Solutions |JEE Advanced-11