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Class XI P REPARED BY :
E R . V INEET L OOMBA
(B.T ECH . IIT R OORKEE )
DPP
DAILY PRACTICE PROBLEMS

TARGET : JEE Main/Adv Atomic Structure

8. Which of the following statements on quantum

1. The atomic number at which filling of a g-orbital numbers is not correct?
is likely to begin is :
a) 121 b) 116 c) 106 d) 124 a) Quantum numbers n, l, m and ms are needed
2. The expression for the Bohr radius of hydrogen to describe an electron in an atom completely.

m
- like species is b) Quantum numbers n, l, m and s are obtained
by solving the Schrodinger wave quation.
 h2  c) A subshell in an atom can be designated with
2
a) n  
 4 m  Ze / 4 0  
2 2 two quantum numbers n and l.

o
d) The maximum value of l is equal to n - 1 and
  that of m is l .
1
b) n2  2
h2

 4 m  Ze / 4 0  
2

.c 9. Which of the following statements is not correct?

a) The wave function depicting the dependence
on r involves two quantum numbers n and l.
ba
 4 2 mh 2  1  4 2 mh 2  b) The wave function depicting the angular
2
c) n   d) n 2  Ze 2 / 4  dependence involves two quantum numbers l and
  Ze / 4 0     0 
2
 m.
3. The expression of Rydberg constant is c) The spin quantum number is not the outcome
om

of the Schrodinger equation.

2 2 mh 2 c 2 2 m  e2 / 4 0 
2
d) The lowest energy state of an atom corresponds
a) e 2 / 4 2 b)
 0 h3 c to n = 0
10. In an orbital, the signs of lobes indicate the
2

c)
e 2
/ 4 0  2 2 mh3c
d) 2
a) sign of the wave function
b) sign of the probability distribution
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2 2 mh3c e / 4 0
c) presence or absence or electron
4. The number of nodal points in the plot of Rn ,0 d) sign of charge
versus r is equal to the value of 11. Whcih of the following statements is not correct?
et

a) n b) l c) n-l d) n-(l+a) a) Special stability associated with half-filled and

5. Which of the following orbitals will have zero fully-filled configurations amongst s and p blocks
probability of finding the electron in yz plane? elements is refected in ionization potential trends
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along a period.
a) px b) p y c) pz d) d yz b) Special stability associated with half -filled
6. Which of the following symbols correctly and fully-filled configurations amongst s and p
represents and orbitals in an atom? blocks elements is reflected in electron affinity
trends along a period.
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a)  n .l .m  Rn1 m b)  n ,l , m  Rn ,l1 m
c) Aufbau order is not obeyed in cases where
c)  n .l .m  Rn .l l .m  m d)  n,l ,m  Rn,l l , m  m energy difference between ns and (n-a)d subshells
7. The z- component of angular momentum of an is larger.
electron in an atomic orbital is governed by the d) Special stability of half - filled subshell is
a) azimuthal quantum number at tributed to higher exchange energy of
b) principal quantum number stabilization
c) magnetic quantum number 12. If nuclear radius is 1013 cm and atomic radius is
d) spin quantum number
Class (XI) 2
10 cm , then what fraction of the atomic volume
8 mass of the elctron, then the velocity of ejected
is occupied by the nucleus? electron is given by
1/ 2 1/ 2
 2h   2hc
4
 1013 
3 4
 108 
3
a)        b)   0   
3 3 m   m 
a) 4 3 b) 4 3
 108   1013 
1/ 2 1/ 2
 2hc  0     2hc  1 1 
3 3 c)     d)    
1  m  0   m  0  
c) 10 18 d) 18. Which of the following statemens is not correct
1837
regarding cathode rays?
13. The best evidence that electrons are arranged in
a) The rays carry negative charge
definite orbits or energy levels is based on the b) The charge / mass of these rays is considerably
observation that smaller than for positive rays.
a) atomic spectra consist of discrete lines and not c) The rays produce mechanical effect
continuous bands d) The charge / mass ratio is independent of the
b) electrons in the beta ray have high kinetic nature of the gass taken in the discharge tube.
energy 19. Which of the following statements is not correct

m
c) the penetrating power of cathode ray electrons regarding electromagnetic spectrum?
depends upon the voltage used to produce a) The velocity of X-rays is more than that of
them microwaves
d) electrons revolve around the nucleus

o
b) Infra-red radiations have larger wavelength
14. If electron, hydrogen, delium and neon are all than cosmic rays
moving wit h the velocity of light , then

the orders.
a) e > H > He > Ne b) e > He > H > Ne.c
wavelength associated with these particles are in
c) The frequency of microwaves is less than that
of ultra - violet rays
d) X-rays have larger wave number than micro
waves
ba
c) e < H < He < Ne d) Ne < He < H < e 20. The quantum number not obt ained from
15. Photo electric emission is observed from a Schrodinger wave equation is :
surface for frequencies v1 and v2 of the in two a) n b) l c) m d) s
cases are in ratio 1 : K, then the threshold 21. The photoelectric emission from a surface starts
om

frequency v0 is given by only when the light incident upon the surface has
certain minimum
v2  v1 Kv1  v2 a) intensity b) wavelength
a) b)
K 1 K 1 c) frequency d) velocity
Kv2  v2 v2  v2 22. Among the following particles, which will have
lo

c) d) the shortest wavelength when accelerated by one

K 1 K million eV?
16. Ruther ford’s experiment, which established the
a) Neutron b) Tritium atom
nuclear model of the atom used a beam of
c)  -particle d) Electron
et

a)  -particles which impinged on a metal foil 23. The kinetic energy of the photoelectrons depends
and got absorbed upon
b)  -rays, which impinged on a metal foil and a) intensity of radiation
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ejected electrons b) frequency of radiation

c) helium atoms, which impinged on a metal foil c) the intensity and frequency of radiation
and got scattered d) none of these
d) helium nuclei, which impinged on a metal foil 24. The threshold frequency for photoelectric
and got scattered
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emission of electrons from platinum is 1.3 ×

17. If 0 is the threshold wavelength for 1015 s 1 .
photoelectric emission,  the wavelength of light a) The number of electrons ejected from the metal
falling on the surface of a metal and m is the surface will depend upon the intensity

ENJOY SOLVING !!

Prepared By: MATHEMATICS

Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 3
b) The radiation having energy 1 × 1018 J will be equal, then uncertainty in velocity is :
able to cause photoelectric effect. h 1 h
c) If radiation having frequency 1.3 a) b)
 2 
× 1014 s 1 strikes the platinum surface, photo -
electrons will not be ejected. 1 h h
c) d) 2m
d) The kinetic energy of the emitted electrons 2  
will increase with increase in frequency 34. The ionization energy of H atom is x kJ. The
provided it is greater than 1.3 × 1015 s 1 . enrgy required for the elctron to jump from n = 2
25. Which of the following has the largest de Broglie to n =3 will be :
wavelength provided all have equal velocity? a) 5x b) 36x/5 c) 5x/36 d) 9x/4
a) Carbon dioxide molecule 35. The wave length of a spectral line for an
b) Ammonia moleculec) Oxygen molecule electronic transition is inversely related to
d) Nitrogen molecule a) velocity of electron undergoing transition
26. The shape of an orbital is decided by b) number of elctrons undergoing transaction
a) Radial wave function c) the difference in energy levels involved in the
b) Angular wave function transition

m
c) Magnetic quantum number d) none of these
d) Spin quantum number 36. In an atom, the signs of lobes indicate the
27. Light of wavelength 1 shines on a metal surface a) sign of charges
with intensity x and the metal emits y electrons b) sign of probability distribution

o
per second of average energy, z. What will happen c) sign of the wave function
to y and z if x is doubled? d) presence or absence of electron

.c
a) y will be doubled and z will become half
b) y will remian same and z will be doubled
c) both y and z will be doubled
37. Which of the following statements is wrong
about cathode rays ?
a) They produce heating effect
ba
d) y will be doubled but z will remain same b) They carry negative charge
28. The angular wave function depends upon c) They produced X-rays when strike with
quantum numbers. material having high atomic masses
a) n and l b) l and m c) l and m d) m and s
d) None of the above
om

29. The number of photons of light having wave

number x in 1 J of energy source is (Planck’s 38. The correct statement about proton is :
constant = h, velocity of light = c) a) It is a nucleus of deuterium
b) It is an ionized hydrogen atom
x 1
a) hcx b) hc/x c) d) c) It is an ionized hydrogen molecule
hc hcx d) It is an   particle
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30. The kinetic energy of electrons ejected by using

39. Which of the following statements is incorrect?
light having frequency equal to threshold
a) The charge on electron and proton are equal
frequency  n0  is : and opposite
et

a) hv0 b) Almost zero b) Neutrons have no charge

c) The mass of proton and electron are nearly the
c) very large d) h / v0 same
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31. Which of the following conditions is incorrect d) None of the above is incorrect
for 40. Which of the following is true for Thomson’s
a)  must be single valued at any particular point
model of atom
b)  must be finite c)  must be positive
a) The radius of an electron can be calculated by
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d)  must be a continuous function of its

using this model
coordinates
32. If moving with equal speeds, the longest b) In an undisturbed atom, the electron will be at
wavelength of the following matter waves is that their equilibrium position, where the attraction
for a (an) between
a) Electron b)  -particle c) the cloud of positive charge and the electrons
c) Proton d) Neutron balances their mutual repulsion.
33. When uncertainty in position and momentum are d) None of the above

Prepared By: MATHEMATICS

Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 4
41. The conclusions of Rutherford scattering
3e 2 3e
experiment does not include: a)  b)  4 r
a)   particle can come within a distance of the 4 0 r 0

order of 1014 m of the nucleus. 3e 2 3e2

b) The radius of the nucleus is less than 1014 m c)  d) 
4 0 r 4 0 r 2
c) scattering follows Coulomb’s law 47. The argument which favours the particulars
d) The (+) vely charged parts of an atom move nature of cathode rays is :
with extremely high velocities. a) they produce fluorescence
42. Choose the incorrect relation on the basis of b) they travel through vacuum
Bohr’s theory : c) they get deflected by electric and magnetic
1 fields
a) Velocity of electron  d) they cast shadows of objects present in their
n
way
1 48. Which of the following reactions led to the
b) Frequency of revolution 
n3 discovery of neutrons ?

m
c) Radius of orbit  n 2 Z 1
7 N 14  0n
a) C 14  1 p1 
6
1
d) Force on electron 

o
n4 n1
b) Be9  He4 
 6 C 12
 0
4 2
In Moseley’s equation  v  a  Z  b   :
43.

.c
a) b depends on metal and a is independent of
metal
c) B11  D 2 
5 1  6 C 11
 0 n1
ba
1
b) both a and b are metal dependent d) Be8  He4 
4 2 6 C11  0n
c) both a and b are independent of metal 49. Which of the following pairs have identical
d) a is metal dependent while b is not values of e/m?
44. Which of the following is not be basic postulate a) a Proton and a neutron
om

of Dalton’s atomic theory ? b) A proton and deuterium

a) Atoms are neither created not destroyed in a c) Deuterium and an   particles
chemical reaction d) An electron and   rays
b) In a compound, the relative number and kinds 50. Choose the arrangement which show the increasing
of atom are constant. value of e/m for e, p, n and  particle :
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c) Atoms of all elements are alike, including their a) n    p  e b) e  p    n

masses c) n  p  e   d) p  n    e
d) Each element is composed of extremely small 51. The electronic configuration with maximum
et

particles called atoms exchange energy will be

45 The mass of electron moving with the velocity
a) 3d 1xy 3d 1yz 3d zx1 4 s1
of light is :
ne

a) 2me b) 3me c) zero b) 3d 1xy 3d 1yz 3d zx1 3d x12  y 2 3d z12 4 s1

d) can be calculated as  by formula c) 3d xy2 3d yz2 3d zx2 3d x22  y 2 3d z12 4 s1
me d) 3d xy2 3d yz2 3d zx2 3d x22  y 2 3d z22 4 s1
vi

m'e 
2
v 52. After np 6 electronic configuration, the next
1  
c orbital filled will be :
46. The potential energy of an electron present in the a)  n  1 d b)  n  1 s
ground state of Li 2  ion is :
c)  n  1 f d) none of the above
53. From the discharge tube experiment it was

Prepared By: MATHEMATICS

Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 5
concluded that : c) their outermost electrons are at different energy
a) mass of proton is in fraction levels
b) matter contains electrons d) all of the above.
c) nucleus contains positive charge 61. Choose the correct statement among the
d) positive rays are heavier than protons following :
54. The characteristic not associated with Planck’s a)  2 represents the atomic orbital
theory is : b) The number of peaks in radial distribution is n-1
a) radiations are associated with energy c) A node is a point in space around nucleus where
b) the magnitude of energy associated with a the wave function  has zero value
quantum is proportional to frequency d) all of the these
c) radiation energy is neither emitted nor 62. For an electron in a hydrogen atom, the wave
absorbed continuously. function  is proportional to exp, where a0 is
d) radiation energy is neither emitted nor
the Bohr’s radius. What is the ratio of the
absorbed discontinuously
probability of finding the electron at the nucleus
55. Which of the following transitions are not to the probability of finding it at a0 ?
allowed in the normal electronic emission a) e b) e2 c) 1/e2 d) zero

m
spectrum of an atom? 63. Choose the incorrect statement :
a) 2s  1s b) 2 p  1s a) The shape of an atomic orbital depends upon
c) 3d  4 p d) 5 p  3s the azimuthal quantum number
b) The orientation of an atomic orbitals depend

o
56. The mass of an electron is m, its charge e and it
upon the magnetic quantum number
is accelerated from rest through a potential
c) The energy of an electron in an atomic orbital
calculated by formula :
a) V / m b) eV / m
.c
difference V. The velocity of electron will be of multi-electron atom depends on principal
quantum number.
d) The number of degenerate atomic orbitals of
ba
one type depends on the value of azimuthal
c)  2cV / m  d) none of these and magnetic quantum numbers.
57. In photoelectric effect the number of p h o t - 64. Consider the following statements :
electrons emitted is proportional to a) Electron density in XY plane in 3d x2 2y orbital
om

a) intensity of incident beam

b) frequency of incident beam is zero
c) wavelength of incident beam b) Electron density in XY plane in 3d z2 orbital is
d) all the above zero
58. If Ee , E , and E p represents the kinetic energies c) 2s orbital has only one spherical node
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of an electron alpha particle and a proton d) For 2pz orbital YZ is the nodal plane
respectively, each moving with same de Broglie The correct statements are :
wavelength then : a) 2 and 3 b) 1,2,3,4 c)Only 2 d)1 and 3
et

a) Ee  E  E p b) Ee  E  E p 65. Which of the following statements regarding an

orbital are correct
c) E  EP  Ee d) Ee  E p  E
a) An orbital is a definite trajectory around the
ne

59. The de Broglie wavelength relates to applied nucleus in which electron can move
voltage as : b) An orbital always has spherical trajectory
12.3 0 12.3 0 c) An orbital is the region around the nucleus
a)   A b)   A
where here is a 90 - 95% probability of finding
h V
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all the electrons of an atom

12.3 0
c)   A d) Both (B) and (C) d) An orbital is characterized by 3 quantum
E numbers n, l and m
60. the line spectra of two elements are not identical 66. Which of the following statements is incorrect ?
because : a) Extra stability of half filled and completely
a) the elements do not have the same number of filled orbitals among s and p block elements
neutrons
is reflected in trends of IE across a period.
b) they have different mass numbers
Prepared By: MATHEMATICS
Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 6
b) Extra stability of half filled and completely d) none of the above is incorrect
filled orbitals among s and p block elements 71. An electron, a proton and an alpha particle have
is reflected in E.A. trends across a period. K.E. of 16E, 4E and E respectively. What is the
c) Aufbau principle is incorrect for cases where qualitative order of their de-Broglie wavelengths
:
energy difference between ns and  n  1 d
a) c   p   b)  p    e
subshell is larger
d) Extra stability to half filled subshell is due to c)  p  c   d)   e   p
higher exchange energies. 72. The velocity of electron in first orbit of H-atom
67. Gases begin to conduct electricity at low pressure as compared to the velocity of light is :
because : 1 1 1
a) at low pressure gases turn to plasma a) th b) th c) th d) same
10 100 1000
b) colliding electrons can acquire higher K.E. due
73 The construction of an electron microscope
to increased mean free path leading to
isbased on
ionization of atoms
a) de Broglie’s principle
c) atoms break up into electrons and photons b) Heisenberg’s principle

m
d) the electrons in atoms can move freely at low c) Bohr’s theory d) Rutherford concept
pressure. 74 The nature of anode rays depends upon
68. For the atomic radius of the order of 10-8 cm and a) Nature of gas filled in the discharge tube

o
nuclear radius of the order of 10-13 cm. The b) Nature of electrode
fraction of atom occupied by the nucleus will be c) None of these
:
a) 1013  atomic volume
b) 1014 atomic volume
.c 75 As an electron is brought from an infinite distance
close of nucleus of the atom, the energy of
electron
ba
a) increases to a grater +ve value
c) 1015  atomic volume b) decreases to a smaller +ve value
d) 1016  atomic volume a) increases to a grater -ve value
b) decreases to a smaller -ve value
69. Light of wavelength  strikes a metal surface
om

76 Which of the following is main cause of late

with intensity X and the metal emits  electrons
discovery of neutron
per second of average energy Z. If X is halved,
a) Neutron is highly unstable particle
the  and Z will be :
b) Neutron in nucleus moves very fast
a)  will be halved, Z will be doubled c) Neutron is chargeless particle
b)  will be doubled, Z will be halved
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d) All of these
c)  will be halved & Z will remain same 77 The probability of finding an electron in a
d)  will remain the same and Z will be halved.
d xy orbital is maximum
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70. The incorrect statement about Bohr’s orbit of

Hydrogen atom is : a) Parallel to x-axis
b) Parallel to y-axis
  c) Parallel to x and y-axis
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 
2  h2  d) At an angle of 450 from x and y axis.
a) r  v  2 
2  e  78 Visible light photons do not show Compton effect
 4 m  
  4 0   because they
vi

a) Move very slowly

b) K.E. of electron = P.E. of electron
b) Have no momentum
 2  e2   c) Have very less mass
 2 m   d) Have larger wavelength
1   4 0  
c) E   2  79 An oil drop has 6.39 1019 charge. What will
 h2 
  be the number of electrons in this drop?
 
a) 2 b) 4 c) 8 d) 16
Prepared By: MATHEMATICS
Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 7
80 Which statement is correct? c) 1  2  3  0 d) 32  12  22
34  86 Photoelectric effect of the phenomenon in which
a) Volume of proton is approximately   r  a) Photon comes out of a metal when it is hit by
3 
a beam of electrons
1.5 1038 cm3 b) Photons come out of the nucleus of an atomic
under the action of an electric field
b) The radius of electron is 42.8 1013 cm c) Electrons come out of a metal with a constant
velocity which depends on the frequency and
c) The density of nucleus is 1014 g / cm3
intensity of incident light we have
d) All of the above d) Electrons come out of metal with different
81 The ratio e/m i.e., specific charge for a cathode ray. velocities not greater than a certain value
a) has the smallest value when the discharge tube which depends only on the frequency of the
is filled with H 2 incident light wave and not on its intensity
87 A surface ejects electrons when hit by green light
b) is constant
but not when hit by yellow light. Will electrons
c) varies with the atom number of gas in the
be ejected if the surface i8s hit by red light

m
discharge tube
a) Yes b) No
d) varies with the atomic number of an element c) Yes, if the red bream is quite intense
forming the cathode d) Yes, if the red beam continues to fall upon

o
82 When greater number of excited hydrogen atoms
reach the ground state, then 88 If 1 and 2 are the wavelength of characteristic
X-rays and gamma rays respectively, then the

.c
a) more number of lines are found in Lyman series
b) the intensity of lines in Balmer series increase
c) the intensity of lines in Lyman series increase
relation between them is

a) 1 
1
ba
d) both the intensity and number of lines in
2 b) 1  2 c) 1  2 d) 1  2
Lyman series increases
83 The value of charge on the oil droplets 89 Wavelength of an electron is equal led by it in
one second, then correct relation is
experimentally observed were 1.6 1019 and
om

h h
4 1019 coulomb. The value of the electronic a)   b)  
charge, indicated by these results is
p p

a) 1.6 1019 b) 2.4 1019 h h

c)   d)  
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c) 4 1019 d) 0.8 1019 m m

90 When the speed electron increases, the specific
84 If S1 be the specific charge  e / m  of cathode charge
et

rays and S 2 be that of positive ray then which is a) Decreases b) Increases

true? c) Remains same d) None
a) S1  S 2 b) S1  S2 91  2  psi  the wave function represents the
ne

c) S1  S 2 d) Either of these probability of finding electron. Its value depends

85 Energy levels A, B, C of a certain atoms a) Inside the nucleus
corresponding to increasing values of every level b) Far from the nucleus
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c) Near the nucleus

i.e., E A  EB  EC . If 1 , 2 and 3 are the
d) Upon the type of orbital
wavelengths of radiations corresponding to the
transitions C to B, B to A and C to A respectively 92 If RH is the Rydberg constant, then the energy of
which of the following statement is correct? an electron in the ground state of Hydrogen atom
is
12
a) 3  1  2 b) 3 
1  2

Prepared By: MATHEMATICS

Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 8

RH C 1 hc
a) b) R c) d)  RH hc
h H ch RH
93. Which is not true with respect to cathode rays?
a) A stream of electrons
b) Charged particles
c) Move with speed same as that of light
d) Can be deflected by magnetic fields
94. Planck’s constant has the same dimensions as that
of
a) power b) work
c) radiant energy d) angular momentum.
95. The kinetic energy of an electron accelerated
from rest through a potential difference of 5V
will be
a) 5J b) 5erg c)5eV d) 8  1010 eV

m
96. Which of the following statements on the atomic
wave function  is not correct?
a)  may be a real valued wave function

o
b)  may be in some cases be a complex function
c)  has a mathematical significance only

97.
an electron
.c
d)  is proportional to the probability of finding

Which of the following relates to photons both

ba
as wave motion and as a stream of particles?
a) interference b) E  mc 2
c) diffraction d) E = hv
98. Wave properties are only important for particles
om

having
a) high mass and low velocities
b) low mass and no velocity
c) high mass and high velocities
d) low mass and high velocities ANSWER KEY
lo

1) a 2) a 3) b 4) d 5) a 6) d
7) c 8) b 9) d 10) a 1a) c 1b) a
1c) a 1d) a 15) b 16) d 17) c 18) b
et

19) a 20) d 21) c 22) c 23) b 24) a

25) b 26) c 27) d 28) b 29) d 30) b
31) c 32) a 33) c 34) c 35) c 36) c
ne

37) d 38) b 39) c 40) b 41) d 42) c

43) d 44) c 45) d 46) c 47) c 48) b
49) c 50) a 51) d 52) b 53) b 54) d
55) a 56) b 57) b 58) d 59) b 60) c
vi

61) d 62) d 63) c 64) d 65) d 66) c

67) b 68) c 69) c 70) d 71) a 72) b
73) a 74) a 75) d 76) c 77) d 78) d
79) b 80) d 81) b 82) c 83) d 84) c
85) b 86) d 87) b 88) c 89) d 90) a
91) a 92) d 93) d 94) d 95) c 96) d
97) d 98) d

Prepared By: MATHEMATICS

Er. Vineet Loomba (IIT Roorkee)