APPLIED CHEMISTRY FOR CSE STREAM BCHES102/202

MODULE-5

E-WASTE MANAGEMENT

E-Waste: Introduction, sources of e-waste, Composition, Characteristics, and Need of E-

waste management. Toxic materials used in manufacturing electronicand electrical products;
health hazards due to exposure to e-waste. Recycling and Recovery: Different approaches of
recycling (separation, thermal treatments, hydrometallurgical extraction, pyrometallurgical
methods, direct recycling). Extraction of gold from E-waste. Role of stake holders in
environmental management of e-waste (producers, consumers, recyclers, and statutory
bodies).
Self-learning: Impact of heavy metals on environment and human health.

Define waste.
Waste refers to any material that is not wanted or needed and is discarded or disposed of.
Classification of Waste:
Waste can be classified into several categories including household waste, industrial waste,
hazardous waste, and e-waste (waste from electronic devices).
Define waste management.
Waste management refers to the collection, transportation, treatment, and disposal of waste
materials to reduce their negative impact on the environment and human health.
Define E-waste management.
E-waste management refers to the processes and systems used to collect, transport, treat, and
dispose of electronic waste (e-waste) in an environmentally responsible and safe manner.

Sources of electronic waste (e-waste):

The main sources of electronic waste (e-waste) include:
1. Consumer electronics such as smartphones, laptops, televisions, and household
appliances.
2. Office equipment such as computers, printers, copiers, and fax machines.
3. Medical equipment such as X-ray machines, monitors, and diagnostic equipment.
4. Electronic toys and games.
5. Military and government surplus equipment.
6. Obsolete technology such as outdated computer equipment and VCRs.
7. Discarded or broken electronic devices.
8. Colleges often use electronic equipment such as projectors, computer equipment, and
audio-visual equipment in classrooms and laboratories.

Composition of E-waste
The composition of electronic waste (e-waste) can vary depending on the typeof device and
its components. In general, e-waste contains a mixture of materials including:
1. Metals: E-waste often contains valuable metals such as copper, gold, silver, and
aluminium.
2. Plastics: Many electronic devices contain plastic components, including casings,
insulation, and cables.
3. Glass: Electronic devices often contain glass components, such as screensand lenses.
4. Circuit boards: Many electronic devices contain circuit boards, which contain a
mixture of metals and other materials.
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5. Batteries: Some electronic devices contain batteries, which can contain hazardous
materials such as lead, mercury, and cadmium.
6. Other hazardous materials: E-waste may also contain other hazardous materials, such
as flame retardants, heavy metals, and polychlorinated biphenyls (PCBs).

Characteristics of E-waste:
The characteristics of electronic waste (e-waste) can include:
1. Complexity: E-waste often contains a complex mixture of materials, making it
challenging to recycle and dispose of properly.
2. Hazardousness: E-waste can contain hazardous materials such as heavy metals,
flame retardants, and batteries, which can pose significant environmental and health
risks.
3. Volatility: E-waste is a rapidly growing waste stream due to the increasing use of
electronic devices and the limited lifespan of many electronic products.
4. Global issue: E-waste is a global issue, as electronic devices are manufactured, used,
and discarded worldwide.
5. Resource depletion: The extraction of raw materials for electronic devices
contributes to resource depletion, and the improper disposal of e- waste can lead to
environmental contamination and waste of valuable resources.
6. Environmental and health impacts: Improper disposal of e-waste can lead to
significant environmental and health impacts, including soil and water contamination,
air pollution, and harm to human health.

Need of E- Waste Management:

E-waste management is necessary because it helps to address several environmental,
health, and resource-related concerns, including:
 Protecting the environment: E-waste contains toxic substances, such as lead, mercury, and
cadmium that can have harmful effects on the environment and human health if not properly
managed.
 Conserving resources: E-waste contains valuable resources, such as metals, that can be
recovered and reused through proper recycling.
 Reducing greenhouse gas emissions: The production of new electronic products releases
greenhouse gases, such as carbon dioxide, into the atmosphere. Proper recycling and disposal
of e-waste can reduce theenvironmental impact of electronic products.
 Reducing landfilling: Landfilling of electronic waste can result in the release of toxic
materials into the environment and contribute to soil and water pollution.
 Protecting public health: Improper handling and disposal of e-waste canexpose workers and
the general public to hazardous materials and cause serious health problems.
 E-waste can be toxic, is not biodegradable and accumulates in the environment, in the soil,
air, water and living things.
 Causes air pollution, Soil pollution and water pollution.
 Electronic Recycling Promotes Soil Fertility and Maintain Nutrient.
 E-waste management programs aim to promote responsible recycling and disposal of
electronic waste and minimize the release of hazardous materials into the environment.
This helps to protect the environment, conserve resources, and promote public health and
safety.
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Toxic materials used in manufacturing Electronic and Electrical products.

Electronic and electrical products can contain a variety of toxic materials,including:
1. Lead: Lead is a toxic heavy metal commonly used in the manufacture of batteries,
computer monitors, and other electronic components.
2. Mercury: Mercury is used in some fluorescent lights, batteries, and other electronic
devices.
3. Cadmium: Cadmium is a toxic heavy metal used in rechargeable batteries, pigments,
and plastic stabilizers.
4. Polyvinyl Chloride (PVC): PVC is a common plastic used in electronic cables and
other components. It can release toxic chemicals, such as dioxins, when burned or
during disposal.
5. Brominated flame retardants (BFRs): BFRs are used in the manufacture of
electronic products to prevent fires. However, they are toxic and can harm the
environment and human health.
6. Barium: Barium is used in some electronic components, including cathode ray tubes.
7. Rechargeable Batteries contains Lithium is used in batteries, but it can be toxic if
not handled properly. Cadmium, Lead, Sodium, Lithium, Nickel etc.,
8. Chlorofluorocarbons (CFCs) are toxic chemicals that were widely used ascoolants and
solvents in electronic products, such as refrigerators, air conditioners. They cause
ozone depletion.
Exposure to electronic waste (e-waste) can have serious health consequences,including:
Health hazardous due to exposure of e waste:
 Poisoning: E-waste can contain toxic substances, such as lead, cadmium, and
mercury, that can cause poisoning if they enter the body.
 Respiratory problems: Exposure to dust and fumes generated during the dismantling
and disposal of e-waste can cause respiratory problems, such as asthma and
bronchitis.
 Neurological effects: Exposure to toxic substances in e-waste, such as lead and
mercury, can cause neurological effects, including memory loss,
tremors, and coordination problems.
 Reproductive problems: Exposure to toxic substances in e-waste, such as cadmium,
can cause reproductive problems, including infertility and birth defects.
 Cancer: Exposure to carcinogenic substances, such as dioxins and polychlorinated
biphenyls (PCBs), found in e-waste, can increase the risk of cancer.
It is important to effectively manage e-waste to minimize the exposure of workers and the
public to hazardous materials and to prevent serious health problems.

NEED FOR E WASTE MANAGEMENT CONCRENING GLOBAL PERSPECTIVE

E-waste management is an important global concern due to address environmental, health,

and economic concerns and to ensure that electronic waste is disposed of in a responsible and
sustainable manner.
1. Environmental impact: Improper disposal of e-waste can result in release of toxic
substances like lead, mercury, and cadmium into the environment, causing soil, and air and
water pollution.
2. Resource depletion: E-waste contains valuable materials such as gold, silver and copper
that can be recovered and recycled. This can help to conserve natural resources and reduce
the need for new resource extraction.
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3. Health risks: E-waste can pose health risks to workers involved in the informal recycling
sector and to communities living near e-waste dump sites.
4. Data security: E-waste can contain sensitive personal information and confidential
business data that could be exploited if not properly managed.
5. Economic benefits: Proper e-waste management can create job opportunities and generate
revenue from the sale of recovered materials.
6. Rapid growth of electronics industry: India is one of the fastest growing electronics
markets in the world, leading to a growing volume of e-waste.
7. Lack of proper disposal infrastructure: In many parts of India, there is a lack of proper
facilities and infrastructure for the disposal and management of e-waste.
Therefore, it is important to implement effective e-waste management policies and practices
globally to address these issues.

E waste recycling:
Explain process recycling of e waste?
The process of e-waste recycling typically involves the following steps:
1. Collection and transportation: E-waste is collected from various sources such as
households, businesses, and recycling facilities. It is then transported to a recycling
plant for processing.
2. Sorting and dismantling: E-waste is sorted into different categoriesbased on the type
of material and the manufacturer. The recyclers then dismantle the devices to separate
the valuable materials from the hazardous components.
3. Shredding: The e-waste is shredded into smaller pieces to make it easier to separate
the different materials. The shredded pieces are then sorted into different categories
based on their composition.
4. Separation: The valuable materials, such as metals, plastics, and glass, are separated
from the other components through a series of physical and chemical processes.
5. Processing: The separated materials are processed to remove any impurities and
contaminants, and to prepare them for reuse. For example, metals are smelted to
produce pure metal alloys, while plastics are meltedand molded into new products.
6. Disposal of hazardous waste: The hazardous components of e-waste, such as
batteries and LCDs, are properly disposed of to prevent pollution and health hazards.

E waste recycling and recovery different approaches (recycling, separation and thermal
treatments)
E-waste recycling and recovery can be achieved through different approaches, including
separation and thermal treatments.
Separation: This involves physically separating different components of e- waste, such as
metals, plastics, and circuit boards. This can be done manually or
through automated processes, and the separated materials can then be processed further for
recycling or disposal. Such as using specialized equipment to sort materials by density, size,
or magnetic properties. Some common examples of e-waste components that are separated
during the recycling process include:
Thermal treatments: E-waste thermal treatment refers to the use of high temperatures to
recover valuable metals and other materials from electronic waste. This process can include
incineration or other pyrometallurgical techniques, and typically involves melting down the
waste to separate the metal components. The separated metals can then be recovered and
reused. Thermal treatment can be an effective method for e-waste recycling.
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Hydrometallurgical extraction of E waste:
E-waste hydrometallurgical extraction is a process used to extract valuable metals and other
materials from electronic waste through chemical reactions in aqueous solutions. The process
typically involves the following steps:
1. Pre-treatment: This involves the fragmentation and size reduction of electronic
waste to prepare it for further processing.
2. Leaching: The e-waste is treated with chemical reagents in a solution to dissolve the
metals and other materials, creating a leachate.
3. Separation: The leachate is then processed to separate and purify the metals and
other materials, through methods such as precipitation or ion exchange.
4. Recovery: The extracted metals and other materials are then recovered and processed
for reuse.
Hydrometallurgical extraction is a more environmentally friendly alternative to thermal
treatments, as it generates less hazardous waste and can be more easily regulated to minimize
environmental impact.

Pyrometallurgical methods E-waste recycling:

E-waste pyrometallurgical methods refer to the process of extracting valuable metals and
other materials from electronic waste using high temperatures. Thesemethods include:
1. Smelting: The e-waste is melted in a furnace and then separated into individual metals
and other materials.
2. Refining: The metals from the smelted e-waste are further processed to remove
impurities and improve their quality.
3. Incineration: Electronic waste is burned at high temperatures to reduce its volume and
recover metals.
Pyrometallurgical methods are effective at recovering valuable metals from e- waste, but they
also generate hazardous byproducts and require significant energy inputs. Additionally, these
methods can pose a risk to the environment and human health if not properly regulated and
monitored.

Direct recycling of e waste:

Direct recycling of e-waste refers to the process of recovering valuable materials from
electronic waste without the need for intermediate processing steps. This can include
processes such as shredding, granulating, and sorting, which are used to separate the different
components of e-waste, such as metals, plastics, and glass. The separated materials are then
processed to extract the valuable components and prepare them for reuse.
Advantages of direct recycling:
several advantages over other methods of e-waste recycling, including lower energy inputs,
lower environmental impact, and the potential for higher quality end products.
By combining direct recycling with other methods, such as chemical and pyrometallurgical
processing, it is possible to maximize the recovery of valuable materials from electronic
waste and minimize the environmental impact of e-waste management.

Extraction of gold from e-waste (Explain the Principle and experimental procedure):

Principle:The principle behind the extraction of gold from e-waste is based on the fact that
gold is a relatively non-reactive metal, which allows it to be recovered from complex
electronic waste matrices through a series of chemical and physical processes.
Experimental procedure:
1. Collection and segregation of e-waste: The first step involves collecting and
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segregating the e-waste into different categories, such as computer motherboards, cell
phones, and other electronic devices.
2. Physical separation: The e-waste is physically separated into different components,
such as plastics, metals, and glass.
3. Leaching: The metals, including gold, are leached from the e-waste using a suitable
reagent, such as aqua regia (a mixture of hydrochloric acid and nitric acid), to dissolve
the gold.
Au + HNO3 + 4HCl → HAuCl4 + NO + 2H2O
4. Precipitation: The dissolved gold is then precipitated out of the solution through the
addition of a suitable reducing agent, such as sodium metabisulfite.
2H[AuCl4] + 3Na2S2O5 + 3H2O → 2Au + 3SO2 + 3Na2SO4 + 8HCl
5. Purification: The precipitated gold is then purified through processes such as ion
exchange, electrowinning, or distillation, to remove impurities and improve its
quality.
6. Recovery: The purified gold is then recovered for reuse.

Advantages:
High yield expected.
Faster extraction of gold is possible.

Disadvantages:
Chemicals are used.
Acid residues are not disposed of properly, which harms the environment.

Flow chart:
E-waste (computer motherboards, cell phones, etc.) -> Physical separation -> Leaching (aqua
regia) -> Precipitation (sodium metabisulfite) -> Purification (ion exchange, electrowinning,
distillation) -> Recovery (purified gold)

Role of stakeholders in the environmental management of e-waste: Who are called

stakeholders – a local and global perspective:

The role of stakeholders in the environmental management of e-waste can vary depending on
the stakeholder and their level of involvement.
From a local perspective, stakeholders in the environmental management of e- waste may
include:
 Governments: responsible for creating and enforcing regulations and policies to
manage e-waste, as well as promoting public awareness and education about e-waste
management.
 Manufacturers: responsible for the design, production, and disposal of electronic
products, and may be involved in the collection and recycling of e-waste.
 Consumers: responsible for properly disposing of e-waste and making informed
choices about the purchase of electronic products.
 E-waste recyclers and processors: responsible for the safe and responsible
management of e-waste, including the collection, dismantling, and recycling of
electronic waste.
 Environmental organizations: responsible for advocating for sustainable and
responsible e-waste management practices and raising public awareness about e-waste
issues.
 Community groups: responsible for organizing and participating in e- waste
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recycling programs and events and promoting awareness of e-waste issues in the local
community.
From a global perspective, stakeholders in the environmental management of e-waste may
include:
 International organizations: such as the United Nations, World Trade Organization,
and the International Telecommunication Union, that are responsible for setting global
standards for e-waste management and promoting cooperation and collaboration
among countries.
 Transnational corporations: responsible for the design, production, and distribution
of electronic products on a global scale, and have a significant impact on e-waste
management practices.
 Global e-waste trade networks: responsible for the transportation and processing of
e-waste between countries and may impact the environmental and health outcomes of
e-waste management.
 Governments of developed and developing countries: responsible for creating and
enforcing regulations and policies to manage e-waste, as well as promoting public
awareness and education about e-waste management.
 Environmental organizations: responsible for advocating for sustainable and
responsible e-waste management practices and raising public awareness about e-waste
issues on a global scale.
 International community: including consumers, NGOs, and civil society
organizations, that can raise awareness about e-waste issues,
demand responsible e-waste management practices, and push for change at the
international level.

Role of stakeholders - producers, consumers, recyclers, and statutory bodies.

In the management of electronic waste (e-waste), the following stakeholders play important
unique role in the management of e-waste:
1. Producers - are responsible for designing and producing electronic products and may
also be involved in the collection and recycling of e- waste.
2. Consumers - play a crucial role in the responsible disposal of e-waste and making
informed choices about the purchase of electronic products.
3. Recyclers - are responsible for safely and responsibly managing e-waste, including
the collection, dismantling, and recycling of electronic waste.
4. Statutory bodies - such as governments, are responsible for creating and enforcing
regulations and policies to manage e-waste and promoting public awareness and
education about e-waste management.
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Self-learning: Impact of heavy metals on environment and human health.

Heavy metals are considered toxic, non-biodegradable, and persist in the environment for a
long time. When released into the environment, heavy metals can cause significant damage to
the environment and harm human health.
Environmental impact:
1. Soil contamination: Heavy metals can contaminate the soil through industrial
activities, agriculture, and mining operations. This can lead to adecline in soil fertility
and reduce the quality of crops grown in the area.
2. Water pollution: Heavy metals can contaminate water bodies through industrial
discharge, agriculture, and sewage discharge. This can lead to the death of aquatic life
and affect the quality of drinking water.
3. Air pollution: Heavy metals can enter the atmosphere through industrial emissions
and natural sources. This can cause respiratory problems and other health issues for
people and wildlife in the area.
4. Food contamination: Heavy metals can enter the food chain through contaminated
water and soil. This can lead to the accumulation of heavy metals in the food, which
can pose a threat to human health.
Health impact:
1. Chronic exposure to heavy metals can lead to serious health problems, including
neurological disorders, cardiovascular disease, and cancers.
2. Children are more susceptible to heavy metal toxicity, as they are stilldeveloping,
and their bodies are more susceptible to damage.
3. Heavy metals can cause respiratory problems, such as bronchitis, asthma, and
emphysema.
4. They can also lead to developmental problems in children, includingreduced IQ
and behavioral issues.

E-WASTE MANAGEMENT (MODULE 05) DEPARTMENT OF CHEMISTRY