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Chapter 1 Numerical Assignment

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38 views

Chapter 1 Numerical Assignment

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INFWHAT
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© © All Rights Reserved
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Numerical Assignment

( Basic Concepts In Chemistry)


Q1. State the number of significant figures in the following numbers.
i) 62.4 ii) 0.0405 iii) 8.8674 iv) 50.0
v) 0.0025 vi) 208 vii) 126000
viii) 600.05 ix) 3.0034
Q2. What is the difference between 3.0 g and 3.00 g
Q3. Express the following in scientific notation.
i) 0.0048 ii) 236000 iii) 8008 iv) 600.0
v) 500 vi) 783.42
Q4. Express the following numbers to four significant figures.
i) 5.607892 ii) 32.392800 iii) 1.78986 X 103 iv) 0.007837
Q5. Simplify and express the answers of the following calculations to appropriate number of
significant figures.
i) 3.24 X 0.08666 / 5.006 ii) 0.58 + 324.65 iii) 943 X 0.00345 + 101 (A = 0.0561, 325.23, 104)
Q6. Simplify the following.
i) 43000  6500 (ii) 2.5 X 10-3 + 3.4 X 10-4 (iii) (0.25) X (3.5 X 103)
5000
(A = 5.6 X 10-4, 2.8 X 10-3, 8.75 X 102)
Q7. In a chemical reaction, 14 g of NaHCO3 was allowed to react with 10 g of CH3COOH.
After the completion of the experiment only 16.67 g solution was left in the container.
What was the mass of gas which escaped into the atmosphere. (A = 7.33 g)
Q8. 6.488 g of lead combine directly with 1.002 g of oxygen to form lead peroxide. Lead
peroxide is also produced by heating lead nitrate and it was found that the percentage
of oxygen present in lead peroxide is 13.38%. Use this data to illustrate the law of constant
composition.
Q9. CuO was prepared by following methods.
a) 1.75 g of metal were dissolved in nitric acid and igniting the residual copper nitrate
yielded 2.19 g of CuO.
b) In the second case, 1.14 g of metal dissolved in nitric acid were precipitated as Cu (OH)2
by adding caustic alkali solution. The precipitated Cu (OH)2 yielded 1.43 g of CuO after
heating.
c) 1.45 g of Cu when heated in air gave 1.83 g of CuO. Show that the data illustrate the law
of constant composition.
Q10. Two oxides of a certain metal were separately heated in a current of hydrogen until
constant weights were obtained 2 g of each oxide gave 0.2517 g and 0.4526 g of water.
Show that the result is in agreement with law of multiple proportions.
Q11. The average atomic mass of copper is 63.5. It exists as two isotopes 2963Cu and 29 65
Cu .
Calculate the percentage of each isotope in it. (A = 75%, 25 %)
Q12. Calculate the molecular mass of
a) HCl b) HNO3 c) Glucose (C6H12O6) d) sucrose (C12H22O11)
e) NaOH f) oxalic acid (COOH – COOH) g) CaCO3 h) NaNO3
Q13. What is the mass of 0.4 mole of oxygen gas. (A = 12. 8 g)
Q14. Calculate the mass of 1 atom of carbon. (A = 1.992 X 10-23 g)
Q15. Calculate mass of 10 moles of CO2 (A = 440 g)
Q16. 0.50 moles of a certain substance weigh 30 g. What is the molar mass of the substance.
( A = 60 g mol-1)
Q17. Chlorophyll contains 2.68% Mg. Calculate the no. of magnesium atoms in 2 g of
chlorophyll. ( A = 1.34 X 1021 atoms)
Q18. Arrange the following in order of their increasing masses in grams.
a) one atom of silver (A = 1.793 X 10-22 g)
b) one gram atom of nitrogen (A = 14 g)
c) one mole of calcium (A = 40 g)
d) one mole of oxygen molecules ( A = 32 g)
e) 10 atoms of carbon
23
( A = 1.993 g)
f) one gram of Fe ( A = 1 g)
Q19. Calculate the volume occupied at S. T. P by
a) 14 g Nitrogen gas b) 1.5 moles of CO2 c) 1021 molecules of oxygen gas
(11.2 L, 33. 6 L, 37. 2 L)
Q20. What weight of calcium contains the same no. of atoms as are present in 3.2 g sulphur
(A=4 g)
Q21. From 200 mg of CO2, 10 molecules are removed. How many moles of CO2 are left?
21

(A= 2.89 X 10 -3 mol)


Q22. The red colour of blood is due to haemoglobin. It contains 0.335% of Fe. Four atoms of
iron are present in each molecule of haemoglobin. What is the molecular mass of
haemoglobin. (A= 66675 u)
Q23. The cost of table salt and table sugar are Rs 2 per kg and Rs 6 per kg. Calculate the cost
per mole. (A = 12 paise, 2 rupees)
Q24. Calculate a) the actual volume of a molecule of water.
b) the radius of a water molecule assuming it to be spherical = 1g/ cm3
(A= 2.99 X 10-23 CC, 1.925 A0)
Q25. Calculate the percentage of water of crystallization in blue vitriol. (A=36.07 %)
Q26. The percentage composition of Mohr’s salt is 14.32 % Fe , 9.20 %, NH4+, 49 % SO42- and
2+

27.57 % H2O.
What is the empirical formula of the compound. (A = FeSO4(NH4)2 SO4. 6H2O)
Q27. A crystalline salt on being rendered anhydrous loses 45.6 % of its weight. The percentage
composition of anhydrous salt is
Al = 10.5 % K = 15.1 % S = 24.96 % D = 49.92 %
Find the simplest formula of anhydrous and crystalline salt. (A = KAl S2O8. 12H2O)

Q28. An organic substance contained carbon, hydrogen and oxygen. The percentage
composition is C = 40.687 % , H = 5.085 %, O = 54.228 %. The vapour density of the
compound is 59. Calculate the molecular formula.
( Hint = molecular mass = 2 X vapour density) (A = C4H6O4)
Q29. Calculate the mass of iron which will be converted to Fe3O4 by the action of 18 g steam
on it. (A = 42 g)
Q30. 1.84 g of a mixture of CaCO3 and MgCO3 was strongly heated till no further loss of mass
takes place. The residue weighs 0.96 g. Calculate percentage composition of mixture
(A=54.35, 45.65)
Q31. KClO3 on heating decomposes to give KCl and O2. What is the volume of O2 liberated by
0.1 mole of KClO3. (A= 3.36 L)
Q32. The reaction 2C + O2 → 2CO is carried out by taking 24 g of carbon and 96 g of O 2. Find
out a) which reactant is left in excess. b) How much of it is left
c) How many grams of the other reactant should be taken so that nothing is left at the end
of reaction. ( A = O2, 64 g, 72 g)
Q33. 1 g of Mg is burned in a closed vessel containing 0.5 g of O 2. Which is the limiting
reactant. What is the amount of MgO formed in reaction. (A = O2, 1.25 g)
Q34. A solution is prepared by dissolving 5 g of urea in 95 g of water. Calculate the mass
percent of urea in the solution (A = 5 %)
Q35. Calculate the molarity of a solution obtained by dissolving 4 g of NaOH in 500 mL of
solution. (A=0.2 M)
Q36. What is the molality of a solution which contains 36 g of glucose in 250 g of water.
(A = 0.8 m)
Q37. What is the molarity of the resulting solution obtained by mixing 2.5 L of 0.5 M urea
solution and 500 mL of 2 M urea solution. (A = 0.75 M)
Q38. 49 g of H2SO4 is dissolved in 250 mL of solution to make a solution of H 2SO4. Calculate
molarity and normality of this solution.
Q39. How many moles of NaOH are contained in 27 mL of 0.15 M NaOH. (A=4.05 X 10-3 mol)
Q40. What volume of 36M and 1M sulphuric acid must be mixed to get 1L of 6M sulphuric
acid. (A= 857.2mL)
Q41. a) A solution is prepared by dissolving 3.65 g of HCl in 500 mL of the solution. Calculate
the normality of the solution.
b) Calculate volume of this solution required to prepare 250 mL of 0.05 N solution.
(A=0.2N, 62.5mL)
Q42. Molarity of H2SO4 is 0.8 M and its density is 1.06 g/ cm3. What will be the concentration
of the solution in terms of molarity and mole fraction?
Q43. Calculate the molality and molarity of 93% H2SO4 (w/v). The density of the solution is
1.84 g/L. (A = 9.49M, 10.43 m)
Q44. What is the molality of 1 M solution of sodium nitrate if its density is 1.25 g/cm3.
(A=0.858 m)
Q45. The density of 2 molal aqueous solution of NaOH is 1.10 g/ L calculate molarity of
solution. (A = 2.04 M)

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