Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

2019/758

SAFETY DATA SHEET

ALL PURPOSE PRIMER

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : ALL PURPOSE PRIMER

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Consumer use

Uses advised against

None
Product use : Solvent borne coating for interior and exterior use.

1.3 Details of the supplier of the safety data sheet

ICI Paints AkzoNobel,
Wexham Road,
Slough,
Berkshire,
SL2 5DS, U.K.
Tel.: +44 (0) 333 222 70 70
www.duluxtrade.co.uk
e-mail address of person : [email protected]
responsible for this SDS

1.4 Emergency telephone number

National advisory body/Poison Center
Telephone number : +44 (0)344 892 0111

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226
Aquatic Chronic 3, H412
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.

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ALL PURPOSE PRIMER

SECTION 2: Hazards identification

See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H226 - Flammable liquid and vapor.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements
General : P102 - Keep out of reach of children.
P101 - If medical advice is needed, have product container or label at hand.
Prevention : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P273 - Avoid release to the environment.
Response : Not applicable.
Storage : P403 + P235 - Store in a well-ventilated place. Keep cool.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national or international regulations.
Supplemental label : Repeated exposure may cause skin dryness or cracking. Warning! Hazardous
elements respirable droplets may be formed when sprayed. Do not breathe spray or mist.
Annex XVII - Restrictions :
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture

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ALL PURPOSE PRIMER

SECTION 3: Composition/information on ingredients

Specific Conc.
Product/ingredient name Identifiers % Classification Type
Limits, M-factors
and ATEs
Hydrocarbons, C10-C13, n- REACH #: ≥15 - ≤20 Asp. Tox. 1, H304 - [1]
alkanes, isoalkanes, cyclics, 01-2119457273-39 EUH066
< 2% aromatics EC: 918-481-9

Hydrocarbons, C9-C11, n- REACH #: ≤10 Flam. Liq. 3, H226 - [1]

alkanes, isoalkanes, cyclics, 01-2119463258-33 STOT SE 3, H336
<2% aromatics EC: 919-857-5 Asp. Tox. 1, H304
EUH066

titanium dioxide REACH #: ≤10 Carc. 2, H351 - [1] [*]

01-2119489379-17 (inhalation)
EC: 236-675-5
CAS: 13463-67-7

hydrocarbon, C9-C11, n- REACH #: ≤5 Flam. Liq. 3, H226 - [1]

alkane, iso-alkane, cyclic, 01-2119463258-33 STOT SE 3, H336
<2% of aromatics EC: 919-857-5 Asp. Tox. 1, H304
CAS: 64742-48-9 EUH066
Index: 649-327-00-6

1-methoxy-2-propanol REACH #: ≤1.9 Flam. Liq. 3, H226 - [1] [2]

01-2119457435-35 STOT SE 3, H336
EC: 203-539-1
CAS: 107-98-2
Index: 603-064-00-3

Reaction mass of REACH #: <1 Flam. Liq. 3, H226 ATE [Dermal] = [1] [2]
ethylbenzene and xylene 01-2119488216-32 Acute Tox. 4, H312 1100 mg/kg
EC: 905-588-0 Acute Tox. 4, H332 ATE [Inhalation
Skin Irrit. 2, H315 (vapours)] = 11 mg/
Eye Irrit. 2, H319 l
STOT SE 3, H335
STOT RE 2, H373
Asp. Tox. 1, H304
Aquatic Chronic 3,
H412

trizinc bis(orthophosphate) REACH #: ≤0.3 Aquatic Acute 1, H400 M [Acute] = 1 [1]

01-2119485044-40 Aquatic Chronic 1, M [Chronic] = 1
EC: 231-944-3 H410
CAS: 7779-90-0
Index: 030-011-00-6
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a physical, health or environmental hazard
[2] Substance with a workplace exposure limit
[*] The classification as a carcinogen by inhalation applies only to mixtures placed on the market in powder form
containing 1% or more of titanium dioxide particles with aerodynamic diameter ≤ 10 μm not bound within a matrix.
Occupational exposure limits, if available, are listed in Section 8.

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ALL PURPOSE PRIMER

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses if easy to do. Continue to rinse
for at least 10 minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser.
Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

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ALL PURPOSE PRIMER

SECTION 4: First aid measures

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
substance or mixture In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. This material is harmful to aquatic life with long
lasting effects. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
sulfur oxides
phosphorus oxides
metal oxide/oxides

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
precautions drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities.

6.3 Methods and materials for containment and cleaning up

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ALL PURPOSE PRIMER

SECTION 6: Accidental release measures

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations. Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance.
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid
release to the environment. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Store and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. Ensure spraying away from persons.
Avoid inhalation of vapor, spray or mist. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
Seveso Directive - Reporting thresholds
Danger criteria
Category Notification and MAPP Safety report threshold
threshold
P5c 5000 tonne 50000 tonne

7.3 Specific end use(s)

Recommendations : Not available.

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SECTION 7: Handling and storage

Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
1-methoxy-2-propanol EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 560 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 375 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Reaction mass of ethylbenzene and xylene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 441 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.
TWA: 220 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
Hydrocarbons, C10-C13, n-alkanes, DNEL Long term 0.41 mg/m³ General Systemic
isoalkanes, cyclics, < 2% aromatics Inhalation population
DNEL Long term 1.9 mg/m³ Workers Systemic
Inhalation
DNEL Long term 178.57 mg/ General Local
Inhalation m³ population
DNEL Long term Oral 300 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 300 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 300 mg/kg Workers Systemic
bw/day
DNEL Short term 640 mg/m³ General Local
Inhalation population
DNEL Long term 837.5 mg/ Workers Local
Inhalation m³
DNEL Short term 1066.67 Workers Local
Inhalation mg/m³
DNEL Short term 1152 mg/ General Systemic
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SECTION 8: Exposure controls/personal protection

Inhalation m³ population
DNEL Short term 1286.4 mg/ Workers Systemic
Inhalation m³
hydrocarbon, C9-C11, n-alkane, iso- DNEL Long term 0.41 mg/m³ General Systemic
alkane, cyclic, <2% of aromatics Inhalation population
DNEL Long term 1.9 mg/m³ Workers Systemic
Inhalation
DNEL Long term 178.57 mg/ General Local
Inhalation m³ population
DNEL Long term Oral 300 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 300 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 300 mg/kg Workers Systemic
bw/day
DNEL Short term 640 mg/m³ General Local
Inhalation population
DNEL Long term 837.5 mg/ Workers Local
Inhalation m³
DNEL Short term 1066.67 Workers Local
Inhalation mg/m³
DNEL Short term 1152 mg/ General Systemic
Inhalation m³ population
DNEL Short term 1286.4 mg/ Workers Systemic
Inhalation m³
1-methoxy-2-propanol DNEL Long term Oral 33 mg/kg General Systemic
bw/day population
DNEL Long term 43.9 mg/m³General Systemic
Inhalation population
DNEL Long term Dermal 78 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 183 mg/kg Workers Systemic
bw/day
DNEL Long term 369 mg/m³ Workers Systemic
Inhalation
DNEL Short term 553.5 mg/ Workers Local
Inhalation m³
DNEL Short term 553.5 mg/ Workers Systemic
Inhalation m³
Reaction mass of ethylbenzene and DNEL Long term Oral 1.6 mg/kg General Systemic
xylene bw/day population
DNEL Long term 14.8 mg/m³ General Systemic
Inhalation population
DNEL Long term 77 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 108 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 180 mg/kg Workers Systemic
bw/day
DNEL Short term 289 mg/m³ Workers Local
Inhalation
DNEL Short term 289 mg/m³ Workers Systemic
Inhalation
trizinc bis(orthophosphate) DNEL Long term Oral 0.83 mg/ General Systemic
kg bw/day population
DNEL Long term 2.5 mg/m³ General Systemic
Inhalation population
DNEL Long term 5 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 83 mg/kg General Systemic
bw/day population
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SECTION 8: Exposure controls/personal protection

DNEL Long term Dermal 83 mg/kg Workers Systemic
bw/day
PNECs
Product/ingredient name Compartment Detail Value Method Detail
manganese neodecanoate Fresh water 85.3 µg/l Assessment Factors
Marine water 2.7 µg/l Assessment Factors
Sewage Treatment 121.3 mg/l Assessment Factors
Plant
Fresh water sediment 230.6 mg/kg dwt Assessment Factors
Marine water sediment 23.06 mg/kg dwt Assessment Factors
Soil 167.33 mg/kg dwt Assessment Factors

8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
When prolonged or frequently repeated contact may occur, a glove with a
protection class of 6 (breakthrough time >480 minutes according to EN374) is
recommended. Recommended gloves: Viton ® or Nitrile, thickness ≥ 0.38 mm.
When only brief contact is expected, a glove with protection class of 2 or higher
(breakthrough time >30 minutes according to EN374) is recommended.
Recommended gloves: Nitrile, thickness ≥ 0.12 mm.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.

The performance or effectiveness of the glove may be reduced by physical/

chemical damage and poor maintenance.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.

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SECTION 8: Exposure controls/personal protection

Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves. Refer to
European Standard EN 1149 for further information on material and design
requirements and test methods.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Wear a respirator conforming to EN140 with type A/P2 filter or
better.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust
and/or hazardous fumes. Wet sanding/flatting should be used wherever possible. If
exposure cannot be avoided by the provision of local exhaust ventilation, suitable
respiratory protective equipment should be used.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to
controls ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

9.1 Information on basic physical and chemical properties

Appearance
Physical state : Liquid.
Color : Gray.
Odor : Characteristic.
Odor threshold : Not available.
Melting point/freezing point : Not available.
Boiling point, initial boiling : 149°C (300.2°F)
point, and boiling range
Flammability : Not available.
Lower and upper explosion : Greatest known range: Lower: 1.48% Upper: 13.74% (1-methoxy-2-propanol)
limit
Flash point : Closed cup: 45°C (113°F) [Pensky-Martens]
Auto-ignition temperature :
Ingredient name °C °F Method
1-methoxy-2-propanol 270 518

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, 280 to 470 536 to 878

cyclics, < 2% aromatics

hydrocarbon, C9-C11, n-alkane, iso-alkane, cyclic, 280 to 470 536 to 878

<2% of aromatics

Decomposition temperature : Not available.

pH : Not applicable. [DIN EN 1262]
Viscosity : Kinematic (room temperature): 650 mm2/s [DIN EN ISO 3219]
Kinematic (40°C): 201 mm2/s [DIN EN ISO 3219]
Solubility(ies) :

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SECTION 9: Physical and chemical properties

Media Result
cold water Not soluble [OECD (TG 105)]

Partition coefficient: n-octanol/ : Not applicable.

water
Vapor pressure :
Vapor Pressure at 20˚C Vapor pressure at 50˚C
Ingredient name mm Hg kPa Method mm Hg kPa Method
1-methoxy-2-propanol 8.5 1.1

Hydrocarbons, C10-C13, n- 0.75 to 2.25 0.1 to 0.3

alkanes, isoalkanes, cyclics, < 2%
aromatics

hydrocarbon, C9-C11, n-alkane, 0.75 to 2.25 0.1 to 0.3

iso-alkane, cyclic, <2% of
aromatics

Relative density : 1.231

Vapor density : Not available.
Particle characteristics
Median particle size : Not applicable.
Percentage of particles with : 0
aerodynamic diameter ≤ 10
μm

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

10.5 Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.

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SECTION 11: Toxicological information

Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Acute toxicity
Product/ingredient name Result Species Dose Exposure
Hydrocarbons, C10-C13, n- LC50 Inhalation Vapor Rat 8500 mg/m³ 4 hours
alkanes, isoalkanes, cyclics,
< 2% aromatics
LD50 Oral Rat >6 g/kg -
hydrocarbon, C9-C11, n- LC50 Inhalation Vapor Rat 8500 mg/m³ 4 hours
alkane, iso-alkane, cyclic,
<2% of aromatics
LD50 Oral Rat >6 g/kg -
1-methoxy-2-propanol LC50 Inhalation Gas. Rat 10000 ppm 5 hours
LD50 Dermal Rabbit 13 g/kg -
LD50 Intraperitoneal Rat 3720 mg/kg -
LD50 Intravenous Mouse 5300 mg/kg -
LD50 Intravenous Rabbit 1200 mg/kg -
LD50 Intravenous Rat 4200 mg/kg -
LD50 Oral Mouse 11700 mg/kg -
LD50 Oral Rabbit 5700 mg/kg -
LD50 Oral Rat 6600 mg/kg -
LD50 Subcutaneous Rabbit 5 g/kg -
LD50 Subcutaneous Rat 7800 mg/kg -
trizinc bis(orthophosphate) LD50 Intraperitoneal Mouse 552 mg/kg -
LD50 Intraperitoneal Rat 551 mg/kg -
Conclusion/Summary : Not available.
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
Reaction mass of ethylbenzene and xylene N/A 1100 N/A 11 N/A
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
1-methoxy-2-propanol Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Skin - Mild irritant Rabbit - 500 mg -
Reaction mass of Eyes - Mild irritant Rabbit - 87 mg -
ethylbenzene and xylene
Eyes - Severe irritant Rabbit - 24 hours 5 -
mg
Skin - Mild irritant Rat - 8 hours 60 Ul -
Skin - Moderate irritant Rabbit - 100 % -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Conclusion/Summary : Not available.
Sensitization
Conclusion/Summary : Not available.
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SECTION 11: Toxicological information

Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, Category 3 - Narcotic effects
<2% aromatics
hydrocarbon, C9-C11, n-alkane, iso-alkane, cyclic, <2% Category 3 - Narcotic effects
of aromatics
1-methoxy-2-propanol Category 3 - Narcotic effects
Reaction mass of ethylbenzene and xylene Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
Reaction mass of ethylbenzene and xylene Category 2 - -
Aspiration hazard
Product/ingredient name Result
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, < 2% ASPIRATION HAZARD - Category 1
aromatics
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% ASPIRATION HAZARD - Category 1
aromatics
hydrocarbon, C9-C11, n-alkane, iso-alkane, cyclic, <2% of ASPIRATION HAZARD - Category 1
aromatics
Reaction mass of ethylbenzene and xylene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : Defatting to the skin. May cause skin dryness and irritation.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion : No specific data.

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SECTION 11: Toxicological information

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

Conclusion/Summary : Not available.

General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

11.2 Information on other hazards

11.2.1 Endocrine disrupting properties
Not available.
11.2.2 Other information
No additional information.

SECTION 12: Ecological information

12.1 Toxicity
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
classified for eco-toxicological properties accordingly. See Sections 2 and 3 for details.
Product/ingredient name Result Species Exposure
titanium dioxide Acute LC50 >1000 mg/l Fresh water Fish - Pimephales promelas 96 hours
Reaction mass of Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
ethylbenzene and xylene
trizinc bis(orthophosphate) Acute LC50 90 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Conclusion/Summary : Not available.

12.2 Persistence and degradability

Conclusion/Summary : Not available.

12.3 Bioaccumulative potential

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SECTION 12: Ecological information

Product/ingredient name LogPow BCF Potential
Hydrocarbons, C10-C13, n- - 10 to 2500 high
alkanes, isoalkanes, cyclics,
< 2% aromatics
hydrocarbon, C9-C11, n- - 10 to 2500 high
alkane, iso-alkane, cyclic,
<2% of aromatics
1-methoxy-2-propanol <1 - low
Reaction mass of 3.12 8.1 to 25.9 low
ethylbenzene and xylene
trizinc bis(orthophosphate) - 60960 high

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties

Not available.

12.7 Other adverse effects

No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Disposal considerations : Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no
longer apply and the appropriate code should be assigned.
For further information, contact your local waste authority.
European waste catalogue (EWC)
The European Waste Catalogue classification of this product, when disposed of as waste, is:
Waste code Waste designation
EWC 08 01 11* waste paint and varnish containing organic solvents or other hazardous substances
Packaging

Date of issue/Date of revision : 2-7-2024 Version : 1.01

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SECTION 13: Disposal considerations

Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Disposal considerations : Using information provided in this safety data sheet, advice should be obtained from
the relevant waste authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Dispose of containers contaminated by the product in accordance with local or
national legal provisions.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID IMDG
14.1 UN number UN1263 UN1263
or ID number
14.2 UN proper PAINT PAINT
shipping name
14.3 Transport 3 3
hazard class(es)

14.4 Packing III III

group
14.5 No. No.
Environmental
hazards
Additional information
ADR/RID : Viscous liquid exception This class 3 viscous liquid is not subject to regulation in
packagings up to 450 L according to 2.2.3.1.5.1.
Tunnel code (D/E)
IMDG : Emergency schedules F-E, _S-E_
Viscous liquid exception This class 3 viscous liquid is not subject to regulation in
packagings up to 450 L according to 2.3.2.5.

14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

14.7 Transport in bulk : Not applicable.

according to IMO
instruments

Date of issue/Date of revision : 2-7-2024 Version : 1.01

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SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
UK (GB) /REACH
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
VOC : The provisions of Directive 2004/42/EC on VOC apply to this product. Refer to the
product label and/or technical data sheet for further information.
VOC for Ready-for-Use : Not available.
Mixture
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Air
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Water
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Persistent Organic Pollutants
Not listed.
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c
Biocidal products regulation
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.

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SECTION 15: Regulatory information

Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

15.2 Chemical Safety : No Chemical Safety Assessment has been carried out.
Assessment

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Aquatic Chronic 3, H412 Calculation method
Full text of abbreviated H statements
H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H370 Causes damage to organs.
H372 Causes damage to organs through prolonged or repeated
exposure.
H373 May cause damage to organs through prolonged or repeated
exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Full text of classifications [CLP/GHS]

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SECTION 16: Other information

Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Acute 1 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1 AQUATIC HAZARD (LONG-TERM) - Category 1
Aquatic Chronic 3 AQUATIC HAZARD (LONG-TERM) - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Carc. 2 CARCINOGENICITY - Category 2
Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
STOT RE 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
STOT SE 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -
Category 1
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -
Category 3
Date of printing : 2-7-2024
Date of issue/ Date of : 2-7-2024
revision
Date of previous issue : 26-1-2024
Version : 1.01
Unique ID : DA7DF488320C1EEEAF899934A0EF81B6
Notice to reader
IMPORTANT NOTE: The information in this data sheet is not intended to be exhaustive and is based on the present
state of our knowledge and on current laws: any person using the product for any purpose other than that specifically
recommended in the technical data sheet without first obtaining written confirmation from us as to the suitability of the
product for the intended purpose does so at his own risk. It is always the responsibility of the user to take all necessary
steps to fulfill the demands set out in the local rules and legislation. Always read the Material Data Sheet and the
Technical Data Sheet for this product if available. All advice we give or any statement made about the product by us
(whether in this data sheet or otherwise) is correct to the best of our knowledge but we have no control over the quality
or the condition of the substrate or the many factors affecting the use and application of the product. Therefore, unless
we specifically agree in writing otherwise, we do not accept any liability whatsoever for the performance of the product
or for any loss or damage arising out of the use of the product. All products supplied and technical advice given are
subject to our standard terms and conditions of sale. You should request a copy of this document and review it
carefully. The information contained in this data sheet is subject to modification from time to time in the light of
experience and our policy of continuous development. It is the user's responsibility to verify that this data sheet is
current prior to using the product.

Brand names mentioned in this data sheet are trademarks of or are licensed to Akzo Nobel.

Date of issue/Date of revision : 2-7-2024 Version : 1.01

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Date of issue/Date of revision : 2-7-2024 Version : 1.01

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