Physical Sciences GR 12 Exam Guidelines 2021 Eng
Physical Sciences GR 12 Exam Guidelines 2021 Eng
Physical Sciences GR 12 Exam Guidelines 2021 Eng
EXAMINATION GUIDELINES
GRADE 12
2021
TABLE OF CONTENTS
Page
1. INTRODUCTION 3
CONCLUSION 36
1. INTRODUCTION
The Curriculum and Assessment Policy Statement (CAPS) for Physical Sciences outlines the
nature and purpose of the subject Physical Sciences. This guides the philosophy underlying the
teaching and assessment of the subject in Grade 12.
∙ Provide clarity on the depth and scope of the content to be assessed in the Grade 12 National
Senior Certificate (NSC) Examination in Physical Sciences.
∙ Assist teachers to adequately prepare learners for the examinations.
This document deals with the final Grade 12 external examinations. It does not deal in any depth
with the school-based assessment (SBA).
2. ASSESSMENT IN GRADE 12
QUESTION 2 onwards:
Longer questions assessing skills and knowledge across cognitive levels. Numbering starts with
QUESTION 2 and will be continuous. Subquestions will be numbered by two digits, e.g. 2.1, 2.2.
Numbering is restricted to a maximum of three digits, e.g. 2.1.1, 2.1.2.
The separate information sheets for Paper 1 and Paper 2 are included in this document.
Papers 1 and 2 will include questions across four cognitive levels. The distribution of cognitive
levels in Physics and Chemistry papers is given below.
Cognitive Description Paper 1 Paper 2
level (Physics) (Chemistry)
1 Remembering (Recall) 15% 15%
∙ Design/Plan of an investigation:
o Identify variables (dependent, independent and controlled variables).
o List appropriate apparatus.
o Plan the sequence of steps which should include, amongst others:
- The need for more than one trial to minimise experimental errors.
- Identify safety precautions that need to be taken.
- Identify conditions that ensure a fair test.
- Set an appropriate control.
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∙ Graphs:
o Draw accurate graphs from given data/information.
o Interpret graphs.
o Draw sketch graphs from given information.
∙ Results:
o Identify patterns/relationships in data.
o Interpret results.
∙ Conclusions:
o Draw conclusions from given information, e.g. tables, graphs.
o Evaluate the validity of conclusions.
∙ Calculations:
o Solve problems using two or more different calculations (multistep calculations).
∙ Descriptions:
o Explain/Describe/Argue the validity of a statement/event using scientific principles.
All skills and application of knowledge learnt in Grades 10 and 11 are applicable to assessment in
Grade 12. In addition to content from Grades 10 and 11 included under examinable content for
Grade 12, skills and knowledge from Grades 10 and 11 that may be assessed in Grade 12 include
the following:
∙ The use of equations of motion in solving problems dealing with momentum, vertical projectile
motion, work, energy and power
∙ Sound waves and properties of sound
∙ Electromagnetism
NOTE: Although there will be no direct questions about these aspects, applications thereof can
be assessed.
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The final examination in Physical Sciences will cover the topics outlined below.
Impulse
∙ Define impulse as the product of the resultant/net force acting on an object and the time
the net force acts on the object.
∙ Use the impulse-momentum theorem, FnetΔt = mΔv, to calculate the resultant/net force
exerted, the time for which the force is applied and the change in momentum for a
variety of situations involving the motion of an object in one dimension.
∙ Explain how the concept of impulse applies to safety considerations in everyday life, e.g.
airbags, seatbelts and arrestor beds.
Work
∙ Define the work done on an object by a constant force F as FΔxcosθ , where F is the
magnitude of the force, Δxthe magnitude of the displacement and θthe angle between the
force and the displacement. (Work is done by a force – the use of the term 'work is done
against a force', e.g. work done against friction, must be avoided.) ∙ Draw a force diagram
and free-body diagrams.
∙ Calculate the net work done on an object.
∙ Distinguish between positive net work done and negative net work done on the system.
Work-energy theorem
∙ State the work-energy theorem: The work done on an object by a net force is equal to the
change in the object's kinetic energy OR the work done on an object by a net force is
equal to the change in the object's kinetic energy.
In symbols: Wnet = ΔK = Kf - Ki
∙ Apply the work-energy theorem to objects on horizontal, vertical and inclined planes (for
both frictionless and rough surfaces).
Power
∙ Define power as the rate at which work is done or energy is expended. In
W
symbols: P = t Δ
∙ Calculate the power involved when work is done.
∙ Perform calculations using Pave= Fvave when an object moves at a constant speed along a
rough horizontal surface or a rough inclined plane.
∙ Calculate the power output for a pump lifting a mass (e.g. lifting water through a height at
constant speed).
With light – red shifts in the universe (evidence for the expanding
universe) ∙ Explain red shifts.
∙ Use the Doppler effect to explain why we conclude that the universe is expanding.
Coulomb's law
∙ State Coulomb's law: The magnitude of the electrostatic force exerted by one point charge
(Q1) on another point charge (Q2) is directly proportional to the product of the
magnitudes of the charges and inversely proportional to the square of the distance (r)
between them:
kQ Q
for charges in one dimension (1D)
∙ Solve problems using the equation F = 21 2
r
(restrict to three charges).
kQ Q
for charges in two dimensions (2D) – for
∙ Solve problems using the equation F = 21 2
r
three charges in a right-angled formation (limit to charges at the 'vertices of a
right-angled triangle').
Electric field
∙ Describe an electric field as a region of space in which an electric charge experiences a
force. The direction of the electric field at a point is the direction that a positive test
charge would move if placed at that point.
∙ Draw electric field lines for the following configurations:
o A single point charge
o Two point charges (one negative, one positive OR both positive OR both negative)
o A charged sphere
NOTE: Restrict to situations in which the charges are identical in magnitude. ∙ Define electric
field at a point: The electric field at a point is the electrostatic force experienced per unit
positive charge placed at that point. In symbols: qF
E=
kQ
∙ Calculate the electric field at a point due to a number of point charges, using the E =to
determine the contribution to the field due to each charge. Restrict
equation 2
r
to three charges in a straight line.
Electrodynamics
(This section must be read in conjunction with the CAPS, p. 130–131.)
Photo-electric effect
∙ Describe the photoelectric effect as the process whereby electrons are ejected from a
metal surface when light of suitable frequency is incident on that surface.
∙ State the significance of the photoelectric effect.
∙ Define threshold frequency, fo, as the minimum frequency of light needed to emit electrons
from a certain metal surface.
∙ Define work function, Wo, as the minimum energy that an electron in the metal needs to be
emitted from the metal surface.
∙ Perform calculations using the photoelectric equation:
E =Wo+ Ek(max), where E = hf and Wo= hfo and Ek(max) = ½ mv2max
∙ Explain the effect of intensity and frequency on the photoelectric effect. ∙
State that the photoelectric effect demonstrates the particle nature of light.
Concentration of solutions
∙ Calculate the molar concentration of a solution.
Intermolecular Forces
(This section must be read in conjunction with the CAPS, p. 71–73.)
Intermolecular and interatomic forces (chemical bonds)
∙ Name and explain the different intermolecular forces (Van der Waal's forces): (i)
Dipole-dipole forces:
Forces between two polar molecules
(ii) Induced dipole forces or London forces:
Forces between non-polar molecules
(iii) Hydrogen bonding:
Forces between molecules in which hydrogen is covalently bonded to
nitrogen, oxygen or fluorine – a special case of dipole-dipole forces
∙ Describe the difference between intermolecular forces and interatomic forces
(intramolecular forces) using a diagram of a group of small molecules; and in words.
Example:
Intermolecular forces
H
H
Interatomic forces/chemical bonds
H
CHH
CH
H
H
∙ State the relationship between intermolecular forces and molecular size. For non-polar
molecules, the strength of induced dipole forces increases with molecular size.
Organic Molecules
(This section must be read in conjunction with the CAPS, p. 104–116.)
∙ Define organic molecules as molecules containing carbon atoms.
C
H
CCC
H
HHH
o Condensed structural formula: This notation shows the way in which atoms are
bonded together in the molecule, but DOES NOT SHOW ALL bond lines.
Example:
O
CH3CH2COCH3 OR
CH3CH2CCH3
Alkenes CC Carbon-carbon
double bond
Alkynes CC Carbon-carbon
triple bond
Esters O -
COC
o Structural isomer: Organic molecules with the same molecular formula, but different
structural formulae
∙ Identify compounds (up to 8 carbon atoms) that are saturated, unsaturated and are structural
isomers.
∙ Restrict structural isomers to chain isomers, positional isomers and functional isomers. o
Chain isomers: Same molecular formula, but different types of chains, e.g. butane and
2-methylpropane
H H H
H H H
H H HCCC
H C H
H H H
HCCCC H H
H H
H
Butane 2-methylpropane
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o Positional isomers: Same molecular formula, but different positions of the side chain,
substituents or functional groups on the parent chain, e.g. 1-chloropropane and
2-chloropropane or but-2-ene and but-1-ene
HH HCCC
HH H HCCC H
H Cl
H H H
H H Cl
1-chloropropane 2-chloropropane
H H H
H H H
H H CCCC H
CCCC
H H H HH
HH
but-1-ene but-2-ene
o Functional isomers: Same molecular formula, but different functional groups, e.g.
methyl methanoate and ethanoic acid
H H O
O
COCH H H CCH O H
H
IUPAC naming and formulae for compounds in the homologous series above ∙ Write
down the IUPAC name when given the structural formula or condensed structural formula.
∙ Write down the structural formula when given the IUPAC name or molecular formula. ∙
Compounds must be restricted to one functional group per compound (except haloalkanes).
∙ Haloalkanes restricted to two functional groups per compound.
∙ Alkyl substituents (methyl- and ethyl- only) restricted to a maximum of THREE on the parent
chain.
∙ When naming haloalkanes:
o Halogen substituents do not get preference over alkyl groups.
o Numbering should start from the end nearest to the first substituent. o When
substituents, e.g. Br and Cℓ or Cℓ and methyl, have the same number when numbered
from different ends of chain, preference is given to alphabetical order, e.g. bromo- over
chloro-; chloro- over methyl-.
∙ When writing IUPAC names, substituents are written alphabetically namely bromo, chloro,
ethyl, methyl. Ignore prefixes di and tri.
Structure and physical properties (boiling point, melting point, vapour pressure)
relationships
∙ For a given example (from the above functional groups), explain the relationship between
physical properties and:
o Strength of intermolecular forces (Van der Waal's forces), i.e. hydrogen bonds,
dipole-dipole forces, induced dipole forces
o Type of functional groups
o Chain length
o Branched chains
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Oxidation of alkanes
∙ State the use of alkanes as fuels.
∙ Write down an equation for the combustion of an alkane in excess oxygen.
Esterification
∙ Write down an equation, using structural formulae or condensed structural formulae, for the
formation of an ester.
∙ Name the alcohol and carboxylic acid used and the ester formed.
∙ Write down reaction conditions for esterification.
Activation energy
∙ Define activation energy as the minimum energy needed for a reaction to take place. ∙
Define an activated complex as the unstable transition state from reactants to products. ∙
Draw or interpret fully labelled sketch graphs (potential energy versus course of reaction
graphs) of catalysed and uncatalysed endothermic and exothermic reactions.
Equilibrium constant
∙ List the factors that influence the value of the equilibrium constant, Kc. ∙ Write down an
expression for the equilibrium constant, having been given the equation for the reaction.
∙ Perform calculations based on Kc values.
∙ Explain the significance of high and low values of the equilibrium constant.
Acid-base reactions
∙ Write down the reaction equations of aqueous solutions of acids and bases.
Examples: HCℓ(g) + H2O(ℓ) → H3O+(aq) + Cℓ-(aq) (HCℓ is a monoprotic acid.) NH3(g)
+ H2O(ℓ) → NH+4(aq) + OH-(aq)
H2SO4(aq) + 2H2O(ℓ) → 2H3O+(aq) + 2− SO4(aq) (H2SO4 is a diprotic
acid.) ∙ Identify conjugate acid-base pairs for given compounds.
∙ Describe a substance that can act as either acid or base as ampholyte. Water is a good
example of an ampholyte substance. Write equations to show how an ampholyte
substance can act as acid or base.
∙ Write down neutralisation reactions of common laboratory acids and bases.
Examples: HCℓ(aq) + NaOH(aq)/KOH(aq) → NaCℓ(aq)/KCℓ(aq) + H2O(ℓ) HCℓ(aq)
+ Na2CO3(aq) → NaCℓ(aq) + H2O(ℓ) + CO2(g)
HNO3(aq) + NaOH(aq) → NaNO3(aq) + H2O(ℓ)
H2SO4(aq) + 2NaOH(aq) → Na2SO4(aq) + 2H2O(ℓ)
(COOH)2(aq) + NaOH(aq) → (COO)2Na2(aq) + H2O(ℓ)
CH3COOH(aq) + NaOH(aq) → CH3COONa(aq) + H2O(ℓ)
NOTE: The above are examples of equations that learners will be expected to write
from given information. However, any other neutralisation reaction can be
given in the question paper to assess, e.g. stoichiometry.
Hydrolysis
∙ Define hydrolysis as the reaction of a salt with water.
∙ Determine the approximate pH (equal to, smaller than or larger than 7) of salts in salt
hydrolysis.
o Hydrolysis of the salt of a weak acid and a strong base results in an alkaline solution,
i.e. the pH > 7. Examples of such salts are sodium ethanoate, sodium oxalate
and sodium carbonate.
o Hydrolysis of the salt of a strong acid and a weak base results in an acidic solution,
i.e. the pH < 7. An example of such a salt is ammonium chloride. o The salt of a strong
acid and a strong base does not undergo hydrolysis and the solution of the salt will be
neutral, i.e. pH = 7.
Acid-base titrations
∙ Motivate the choice of a specific indicator in a titration. Choose from methyl orange,
phenolphthalein and bromothymol blue.
∙ Define the equivalence point of a titration as the point at which the acid/base has completely
reacted with the base/acid.
Define the endpoint of a titration as the point where the indicator changes colour. ∙
Perform stoichiometric calculations based on titrations of a strong acid with a strong base, a
strong acid with a weak base and a weak acid with a strong base. Calculations may include
percentage purity.
∙ For a titration, e.g. the titration of oxalic acid with sodium hydroxide: o List the
apparatus needed or identify the apparatus from a diagram. o Describe
the procedure to prepare a standard oxalic acid solution. o Describe the
procedure to conduct the titration.
o Describe safety precautions.
o Describe measures that need to be in place to ensure reliable results. o
Interpret given results to determine the unknown concentration.
∙ Explain the auto-ionisation of water, i.e. the reaction of water with itself to form H3O+ ions
and OH ions.
∙ Interpret Ka values of acids to determine the relative strength of given acids. Interpret Kb
values of bases to determine the relative strength of given bases.
∙ Compare strong and weak acids by looking at:
o pH (monoprotic and diprotic acids)
o Conductivity
o Reaction rate
Electrochemical Reactions
(This section must be read in conjunction with the CAPS, p. 134–137.)
Galvanic cells
∙ Define the galvanic cell as a cell in which chemical energy is converted to electrical energy.
∙ Define oxidation and reduction in terms of electron (e-) transfer:
Oxidation is a loss of electrons. Reduction is a gain of electrons.
∙ Define oxidation and reduction in terms of oxidation numbers:
Oxidation: an increase in oxidation number
Reduction: a decrease in oxidation number
∙ Define an oxidising agent and a reducing agent in terms of oxidation and reduction:
Oxidising agent: a substance that is reduced/gains electrons.
Reducing agent: a substance that is oxidised/loses electrons.
∙ Define an anode and a cathode in terms of oxidation and reduction:
Anode: the electrode where oxidation takes place
Cathode: the electrode where reduction takes place
∙ Define an electrolyte as a substance of which the aqueous solution contains ions OR a
substance that dissolves in water to give a solution that conducts electricity.
Electrolytic cells
∙ Define the electrolytic cell as a cell in which electrical energy is converted into chemical
energy
∙ Electrolysis: The chemical process in which electrical energy is converted to chemical
energy OR the use of electrical energy to produce a chemical change
4. GENERAL INFORMATION
The most common quantities, symbols and SI units used in introductory Physics are listed below.
A quantity should not be confused with the unit in which it is measured.
Quantity Preferred Alternative Unit name Unit
symbol symbol symbol
mass m kilogram kg
position x, y metre m
energy E joule J
work W joule J
power P watt W
force F newton N
weight w Fg newton N
tension T FT newton N
wavelength λ metre m
period T second s
magnification m (none)
charge Q, q coulomb C
emf E ε volt V
current I, i ampere A
resistance R ohm Ω
Conventions (e.g. signs, symbols, terminology and nomenclature) The syllabus and
question papers will conform to generally accepted international practices.
NOTE:
1. For marking purposes, alternative symbols will also be accepted. 2. Separate
compound units with a multiplication dot, not a full stop, e.g. m·s-1. For marking
purposes, m.s-1 will also be accepted.
3. Use the equal sign only when it is mathematically correct, e.g.
Incorrect: 1 cm = 1 m (on a scale drawing)
Correct: 1 cm = 10-2 m 1 cm represents 1 m (on a scale drawing)
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TABLE 2: FORMULAE
MOTION
vvat i Δx = v Δt + aΔtOR 2
2
f=i+ Δ i Δy = v Δt + aΔt
1
1
2
2
2
⎜
⎝⎛ +
2
2
2
vv
f = + ΔOR v v 2a y f = + Δ ⎜
⎝⎛ +
v v 2a x vv
i
i ⎟
Δx i f ⎠⎞
⎟
Δy i f ⎠⎞
=OR Δt Δt
=
2
2
FORCE
Fnet = ma p= mv
max
fk = μkN
fsN
s= μ
Gm m GM
Gm m GM
F= OR 21 2 OR
F= g=
12
2
g=
2
d 2
r d
r
E=
k mv
2
2
Pave= Fv ave
f
±± =c
vv OR
E= hf λ
Lf
= Eh
L
s
vv
s
max
k(max) mv 21
max
max mv 21
0
E = hf and W0 = hf and 2
E = OR 2
K=
ELECTROSTATICS
kQ Q kQ
E=
F= 2
12
2 r
r
W F
V=
E=
q q
Q
Q
n=
OR
n=
qe
e
ELECTRIC CIRCUITS
V emf (ε) =I(R + r)
R=
I
R R R ... s= 1 + 2 + q = I Δt
1
1
1
=++
...
R
R
R
p12
W =Vq W
P=
W =VIΔt Δt
W =I2RΔt P =VI
V Δt 2 2
PR
W =R =I
2
V
P
=
R
ALTERNATING CURRENT
I Pave Vrms rms
max
=I
I=
rms
2 2
PR
V =I
max ave rms
V
rms = 2
2 V
P
ave=
rms
R
Standard pressure θ
1,013 x 105 Pa
p
TABLE 2: FORMULAE
m N
n= n=
M NA
OR V
c= MVm n=
n Vm
c=
V
cV pH = -log[H3O+]
=
n
aa
a
n
cV
b
bb
θ
Ecell = E − E
θ
θ
cathode
anode
OR
θ
Ecell = E − E
θ
θ
reduction
oxidation
OR
θ
Ecell = E − E
θ
θ
oxidisingagent
reducingagent
(II) 3 4 5 6 7 8 9 10 11 12 13
(I)
2
(III)
14
(IV)
15 (V)
16
(VI)
17
(VII)
18
(VIII)
1 KEY Ato
H num
1
1
3 4 troneg 29 Symbo
Li Be ty Cu l
0 5 9
, , ,
1 1
7 9 63,5 1
11 12
Na Mg ic
9 2
, ,
0 1
23 24
19 20 21 22 23 24 25 26 27 28 29 30
8
K 0
Ca 3
Sc 5
Ti 6
V 6
Cr Mn
5 8
Fe 8
Co 8
Ni 9
Cu 6
Zn
, , , , , , , , , , , ,
0 1 1 1 1 1 1 1 1 1 1 1
39 40 45 48 51 52 55 56 59 59 63,5 65
37 38 39 40 41 42 43 44 45 46 47 48
8
Rb 0
Sr 2
Y 4
Zr Nb 8
Mo 9
Tc 2
Ru 2
Rh 2
Pd 9
Ag 7
Cd
0
,
1
,
1
,
1
,
92 1
,
1
,
2
,
2
,
2
,
1
,
1
,
55 56 57 72 73 74 75 76 77 78 79 80
7
Cs 9
Ba La 6
Hf Ta W Re Os Ir Pt Au Hg
0
,
0
,
139 1
,
181 184 186 190 192 195 197 201
133 137 179
87 88 89 58 59 60 61 62 63 64 65
Fr 9
Ra Ac Ce Pr Nd Pm Sm Eu Gd Tb
7
,
,
0
226
58 59 60 61 62 63 64 65
Ce Pr Nd Pm Sm Eu Gd Tb
140 141 144 150 152 157 159
90 91 92 93 94 95 96 97
Th Pa U Np Pu Am Cm Bk
232 238
− + + 0,16
+ e ⇌ Cu
g
+ 0,15
Sn4+ + 2e− ⇌ Sn2+
a
+ 0,14
S + 2H++ 2e− ⇌ H2S(g) 2H++
g
0,00
2e− ⇌ H2(g)
n
− 0,06
Fe3+ + 3e− ⇌ Fe
s
− 0,13
i
d
Pb2+ + 2e− ⇌ Pb
i
− 0,14
Sn2+ + 2e− ⇌ Sn
− 0,27
x
o
Ni2+ + 2e− ⇌ Ni
− 0,28
f
Co2+ + 2e− ⇌ Co
− 0,40
Cd2+ + 2e− ⇌ Cd
o
− 0,41
Cr3+ + e− ⇌ Cr2+
h
− 0,44
t
g
Fe2+ + 2e− ⇌ Fe
− 0,74
Cr3+ + 3e− ⇌ Cr
n
− 0,76
Zn2+ + 2e− ⇌ Zn
e
− 0,83
r
− 0,91
s
⇌ Cr
− 1,18
Mn2+ + 2e− ⇌ Mn
g
− 1,66
n
Aℓ3+ + 3e− ⇌ Aℓ
i
− 2,36
a
Mg2+ + 2e− ⇌ Mg
− 2,71
Na++ e− ⇌ Na
e
− 2,87
r
c
Ca2+ + 2e− ⇌ Ca
− 2,89
Sr2+ + 2e− ⇌ Sr
n
− 2,90
I
c
t
u
s
d
e
g
r
n
i
f
s
o
h e
t
r
g c
n n
I
e
st
o
Li++ e− ⇌ Li Hg2+ + 2e− ⇌ Hg(ℓ) + 0,96
K++ e− ⇌ K NO−3+ 4H++ 3e− ⇌ NO(g) + 2H2O Br2(ℓ) + 1,07
Cs++ e− ⇌ Cs + 2e− ⇌ 2Br− + 1,20
Ba2+ + 2e− ⇌ Ba Pt2+ + 2 e− ⇌ Pt + 1,23
Sr2+ + 2e− ⇌ Sr MnO2+ 4H++ 2e− ⇌ Mn2+ + 2H2O O2(g) + 1,23
Ca2+ + 2e− ⇌ Ca + 4H++ 4e− ⇌ 2H2O
Na++ e− ⇌ Na + 1,33
Cr2O2−
Mg2+ + 2e− ⇌ Mg + − 3+ + 1,36
7+ 14H + 6e ⇌ 2Cr + 7H2O
Aℓ3+ + 3e− ⇌ Aℓ Cℓ2(g) + 2e− ⇌ 2Cℓ− + 1,51
Mn2+ + 2e− ⇌ Mn MnO−4+ 8H++ 5e− ⇌ Mn2+ + 4H2O +1,77
Cr2+ + 2e− ⇌ Cr
H2O2 + 2H++2 e− ⇌ 2H2O + 1,81
2H2O + 2e− ⇌ H2(g) + 2OH
Co3+ + e− ⇌ Co2+ + 2,87
⇌ Zn
F2(g) + 2e− ⇌ 2F−
Cr3+ + 3e− ⇌ Cr
Fe2+ + 2e− ⇌ Fe
Cr3+ + e− ⇌ Cr2+
Cd2+ + 2e− ⇌ Cd s
Co2+ + 2e− ⇌ Co n
Ni2+ + 2e− ⇌ Ni
e
Sn2+ + 2e− ⇌ Sn
g
Pb2+ + 2e− ⇌ Pb
Fe3+ + 3e− ⇌ Fe
g
2e− ⇌ Sn2+ d
Cu2+ + e− ⇌ Cu+
e
SO2− f
+ −
4+ 4H + 2e ⇌ SO2(g)
o
−
2e ⇌ Cu h
e− ⇌ Cu
e
I2 + 2e− ⇌ 2I−
t
Fe3+ + e− ⇌ Fe2+ n
e− ⇌ Ag a
I
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5.1 Calculations
5.1.1 Marks will be awarded for: correct formula, correct substitution, correct answer with unit.
5.1.2 No marks will be awarded if an incorrect or inappropriate formula is used, even though
there may be relevant symbols and applicable substitutions.
5.1.3 When an error is made during substitution into a correct formula, a mark will be awarded
for the correct formula and for the correct substitutions, but no further marks will be
given.
5.1.4 If no formula is given, but all substitutions are correct, the candidate will forfeit one
mark.
5.1.5 No penalisation if zero substitutions are omitted in calculations where correct
formula/principle is given correctly.
5.1.6 Mathematical manipulations and change of subject of appropriate formulae carry no marks,
but if a candidate starts off with the correct formula and then changes the subject of the
formula incorrectly, marks will be awarded for the formula and the correct substitutions.
The mark for the incorrect numerical answer is forfeited.
5.1.7 Marks are only awarded for a formula if a calculation has been attempted, i.e.
substitutions have been made or a numerical answer given.
5.1.8 Marks can only be allocated for substitutions when values are substituted into formulae and
not when listed before a calculation starts.
5.1.9 All calculations, when not specified in the question, must be rounded off to a minimum of
TWO decimal places.
5.1.10 If a final answer to a calculation is correct, full marks will not automatically be awarded.
Markers will always ensure that the correct/appropriate formula is used and that workings,
including substitutions, are correct.
5.1.11 Questions where a series of calculations do not necessarily always have to follow the
same order (as in circuit calculations) full marks will be awarded provided that it is a valid
solution to the problem.
5.1.12 Any calculation that will not bring the candidate closer to the answer than the original
solution, will not count any marks.
5.2 Units
5.2.1 Candidates will only be penalised once for the repeated use of an incorrect unit within a
question.
5.2.2 Units are only required in the final answer to a calculation.
5.2.3 Marks are only awarded for an answer, and not for a unit per se. Candidates will therefore
forfeit the mark allocated for the answer in each of the following situations: - Correct
answer + wrong unit
- Wrong answer + correct unit
- Correct answer + no unit
5.2.4 SI units must be used, except in certain cases, e.g. V∙m-1instead of N∙C-1, and cm∙s-1or
km∙h-1 instead of m∙s-1 where the question warrants this.
5.3 General
5.3.1 If one answer or calculation is required, but two are given by the candidate, only the first
one will be marked, irrespective of which one is correct. If two answers are required, only
the first two will be marked, etc.
5.3.2 For marking purposes, alternative symbols (s, u, t, etc.) will also be accepted. 5.3.3 Separate
compound units with a multiplication dot, not a full stop, e.g. m·s-1. For marking purposes,
m.s-1and m/s will also be accepted.
6.1 Calculations
6.1.1 Marks will be awarded for: correct formula, correct substitution, correct answer with unit.
6.1.2 No marks will be awarded if an incorrect or inappropriate formula is used, even though
there may be relevant symbols and applicable substitutions.
6.1.3 When an error is made during substitution into a correct formula, a mark will be awarded
for the correct formula and for the correct substitutions, but no further marks will be
given.
6.1.4 If no formula is given, but all substitutions are correct, the candidate will forfeit one
mark.
Example: No Kc expression, correct substitution:
2
=2(
(2) 32)
Kc = 3
(2)(1)
6.1.5 Marks are only awarded for a formula if a calculation has been attempted, i.e.
substitutions have been made or a numerical answer has been given.
6.1.6 Marks can only be allocated for substitutions when values are substituted into formulae and
not when listed before a calculation starts.
6.1.7 The final answer to all calculations, when not specified in the question, must be rounded off
to a minimum of TWO decimal places.
6.1.8 If a final answer to a calculation is correct, full marks will not automatically be awarded.
Markers will always ensure that the correct/appropriate formula is used and that workings,
including substitutions, are correct.
6.1.9 Mathematical manipulations and change of subject of appropriate formulae carry no marks,
but if a candidate starts off with the correct formula and then changes the subject of the
formula incorrectly, marks will be awarded for the formula and the correct substitutions.
The mark for the incorrect numerical answer is forfeited.
Example:
CORRECT ANSWER (1) POSSIBLE ANSWER (2) POSSIBLE
m m n m m
n=✔ n=✔ m=🗶 n=✔ n=✔
M M M M M
m 52 0,01 M = 0,52 g ✔
0,01✔ =52 ✔ 0,01 ✔= m 🗶
= m=🗶
m = 0,52 g ✔ m = 5 200 g 🗶 52
n
= 0,002 g 52
✔
(4) (2) =0,01 (2)
( ✔
= 5 200 g🗶
(3)
0
)
6.2 Units
6.2.1 Candidates will only be penalised once for the repeated use of an incorrect unit within a
question.
6.2.2 Units are only required in the final answer to a calculation.
6.2.3 Marks are only awarded for an answer and not for a unit per se. Candidates will therefore
forfeit the mark allocated for the answer in each of the following situations:
- Correct answer + wrong unit
- Wrong answer + correct unit
- Correct answer + no unit
6.2.4 Separate compound units with a multiplication dot, not a full stop, e.g. mol·dm-3.
Accept mol.dm-3(or mol/dm3) for marking purposes.
6.3 General
6.3.1 If one answer or calculation is required, but two are given by the candidate, only the first
one will be marked, irrespective of which one is correct. If two answers are required, only
the first two will be marked, etc.
6.3.2 When a chemical FORMULA is asked, and the NAME is given as answer, the candidate
forfeits the marks. The same rule applies when the NAME is asked and the FORMULA is
given.
6.3.3 When redox half-reactions are to be written, the correct arrow should be used.
If the equation
2
)
H2S → S + 2H++ 2e- (2
is the correct answer, the marks must be given as follows:
1
H2S ⇌ S + 2H++ 2e- (2 )
0
)
H2S ← S + 2H++ 2e- (2
2
)
S + 2H++ 2e- ← H2S (2
0
)
S + 2H++ 2e- ⇌ H2S (2
6.3.4 When candidates are required to give an explanation involving the relative strength of
oxidising and reducing agents, do not accept the following:
∙ Stating the position of a substance on Table 4 only (e.g. Cu is above Mg). ∙
Using relative reactivity only (e.g. Mg is more reactive than Cu).
∙ The correct answer would be for instance: Mg is a stronger reducing agent than Cu, and
therefore Mg will be able to reduce Cu2+ ions to Cu. The answer can also be given in
terms of the relative strength as electron acceptors and donors.
6.3.5 One mark is forfeited when the charge of an ion is omitted per equation (not for the charge
on an electron).
6.3.6 The error-carrying principle does not apply to chemical equations or half-reactions. For
example, if a learner writes the wrong oxidation/reduction half-reaction in the subquestion
and carries the answer to another subquestion (balancing of equations or calculation of θ
Ecell), then the learner will not be credited for this substitution.
6.3.7 In the structural formula of an organic molecule all hydrogen atoms must be shown. Marks
must be deducted if hydrogen atoms are omitted.
6.3.8 When a structural formula is required, marks must be deducted if the candidate writes the
condensed formula.
6.3.9 When a IUPAC name is asked and the candidate omits the hyphen (e.g. instead of
pent-1-ene or 1-pentene the candidate writes pent 1 ene or 1 pentene), marks will be
forfeited.
6.3.10 When a chemical reaction is asked, marks are awarded for correct reactants, correct
products and correct balancing.
If only a reactant(s) followed by an arrow, or only a product(s) preceded by an arrow, is/are
written, marks may be awarded for the reactant(s) or product(s). If only a reactant(s) or
only a product(s) is/are written, without an arrow, no marks are awarded for the reactant(s)
or product(s).
Examples:
3
N2 + 3H2 → 2NH3 bal. 3
N2 + H2 →31
→ NH3 31
0
2
N2 + H 3
0
3
NH 3
7. CONCLUSION