CH 13.the Periodic Table

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The periodic table

The periodic table is a method of classifying elements and its use to


predict properties of elements.

Periodic trends

Groups

Elements are arranged in order of proton number. Elements with similar


chemical properties are placed in the same vertical column called
groups. Elements in a group have similar chemical properties, same
outer electron numbers, and usually the same valency. Going down the
group, the elements become more metallic in character.

Periods

The horizontal rows are called periods. Moving across a period, the
elements change from metallic to non-metallic. The number of valency
electrons increases across the period but the number of occupied
energy levels (i.e. shells) stays the same.

Metals vs non-metals

The main physical differences are-


The main chemical differences are -

Group properties

Group 1 – Alkali metals (i.e. Li, Na, K)

These are extremely reactive metals. The alkali metals (despite being
metallic) are rather soft and have low m.p/b.p compared to other metals.
They are good conductors of heat and electricity and demonstrate shiny
surfaces when freshly cut.

Due to their low valency, these metals are extremely reactive. Each
element will react with cold water to form a hydroxide and hydrogen.

 Physical trends down the group


 Increasing softness
 Decreasing melting/boiling points
 Increasing densities

 Chemical trends down the group


 Increasing reactivity
 Lithium reacts steadily with water whereas
potassium may cause an explosion
Group 7 – Halogens (i.e. Cl, Br, I)

Halogens are a collection of diatomic non-metals showing both physical


and chemical trends down the group.

 Physical trends down the group


 Colour gets darker down the group
 Chlorine is yellow/green
 Bromine is brown
 Iodine is a black solid with purple vapour
 M.p and b.p increase down the group
 Chlorine is a gas (rtp)
 Bromine is a liquid (rtp)
 Iodine is a solid (rtp)

 Chemical trends down the group


 Decreasing reactivity
 Chlorine can displace both bromine and
iodine from their compounds:

* Note- chlorine is more reactive than both bromine and iodine.


Therefore, in reaction (1), chlorine has the ability to ‘kick out’ the bromide
ion from the compound and take its place. Chlorine will therefore
become an ion to form an ionic bond with potassium (KCl), whereas
bromine becomes a molecule (gas).
Transition elements

These are metallic elements placed in the middle of the periodic table.

 Physics properties
 Compared to groups I and II, they have higher
densities and melting points. They are also harder
and stronger.
 Chemical properties
 Compared to groups I and II, they are a lot less
reactive
 They do not react with cold water but many
react when heated in steam:

 They have more than one valency. Iron (Fe),


for example, forms two different types of
ions:

 This means that they can either


decide to lose 2 or 3 electrons to
become an ion
 They form coloured compounds
 Iron (II) salts are pale green
whereas iron (III) salts are
yellow/brown
 Copper (II) salts are blue
 Nickel salts are bright

Group 0 – Noble gases

Noble gases are unreactive; they have a valency of 0. Their outer


electron shell is already complete.

Noble gases have various uses:

 Helium is used in balloons. The balloon will float because


helium is less dense than air and also safer (because they
cannot catch fire due to their unreactiveness)
 Argon is used to fill electric light bulbs because it is inert

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