PHYS SCIENCES P2 GR11 QP NOV2019 - English
PHYS SCIENCES P2 GR11 QP NOV2019 - English
PHYS SCIENCES P2 GR11 QP NOV2019 - English
SENIOR CERTIFICATE
GRADE 11
NOVEMBER 2019
PHYSICAL SCIENCES P2
(CHEMISTRY) (EXEMPLAR)
MARKS: 150
TIME: 3 hours
1. Write your full NAME and SURNAME in the appropriate spaces on the
ANSWER BOOK.
2. This question paper consists of TEN questions. Answer ALL the questions
in the ANSWER BOOK.
1.1 Which ONE of the bonds below will have the SHORTEST bond length?
A C–O
B C–N
C C–F
D C – Br (2)
1.2 When sulphuric acid reacts with water, the temperature of the reaction
mixture increases.
Which ONE of the following correctly describes the heat of the reaction (∆H)
between sulphuric acid and water from the graph below?
P3
Potential energy
P2
P1
A P3 – P2
B P1 – P2
C P3 – P1
D P2 – P1 (2)
P R
A HCℓ CCℓ4
B HCℓ H2O
C NaCℓ CCℓ4
D I2 H2O
(2)
1.4 The boiling points of three compounds are given in the table shown below.
Compound Boiling point (K)
Cℓ2 238
Br2 332
I2 457
The increase in boiling point from top to bottom of the table is due to an
increase in the strength of …
A London forces.
B ion-dipole forces.
C dipole-dipole forces.
D hydrogen bonds. (2)
1.5 The pV vs p sketch graphs for four gases, He, CO, CH4, and an ideal gas are
shown below.
Which sketch graph CORRECTLY shows the pV vs p relationship for He?
C
pV (J)
D
p (Pa) (2)
A Volume
B Enthalpy
C Pressure
D Temperature (2)
1.8 5 grams of each of the salts given below is completely dissolved in water to
make 100 cm3 of solution at 30 °C.
Which salt solution will have the highest concentration of sodium ions (Na +)?
A NaCℓ(aq)
B Na2CO3(aq)
C Na2SO4(aq)
D NaHCO3(aq) (2)
A Zn (s) to Zn2+(aq).
B Cu2+(aq) to Cu (s).
C Zn(s) to Cu2+(aq).
D Zn2+(aq) to Cu (s). (2)
A -2.
B +6.
C +1.
D +4. (2)
[20]
Study the molecules given below and answer the questions that follow.
2.2 Use the VSERP model to predict the molecular geometry of the following:
2.4 Explain why it is possible for NH3 to form a dative covalent bond with H+ but it
is not possible for CCℓ4 to form a dative covalent bond with H+. (2)
2.5 Is the H2S molecule POLAR or NON-POLAR? Explain the answer. (4)
[14]
The boiling points of the hydrogen halides and group 4 hydrogen compounds are
compared in the graph below.
350
Boiling point (K)
HF
300
HI
250 HBr
HCℓ
200
SnH4
150 CH4 GeH4
SiH4
100
2 3 4 5
Period
3.3 Explain why the boiling points of the hydrogen halides are higher than those
of corresponding group 4 hydrides from period 3 to 5, by referring to the type
of intermolecular forces present in these compounds and energy involved. (4)
3.4 Write down the name of the intermolecular force present in HF responsible
for the high boiling point. (2)
3.5 Which one of HBr and GeH4 will have the highest vapour pressure? Give a
reason for the answer by referring to data in the graph. (2)
[11]
Pressure (kPa)
4.1.1 Write down the name of the law which formulates the pressure-
volume relationship shown by the graph. (1)
Experiment 1
Volume (cm3)
Experiment 2
Pressure (kPa)
4.2.2 Give a reason why real gases deviate from ideal gas behaviour at
high pressure. (2)
4.3 The diagram below shows the apparatus that is used to demonstrate the
relationship between pressure and temperature at constant volume.
kPa
Jollybulb
Thermometer
A certain gas is trapped inside the Jolly bulb. At temperature 25 °C the gas
exerts a pressure of 101 kPa. The water-bath is then heated to a
temperature of 60 °C.
4.3.1 Write down the name of the law which is studied using the above
apparatus. (1)
In 1783 Jacques Charles filled an air-balloon with 2 600 g of diatomic gas X. The
pressure of the gas was 100 × 103 Pa at a temperature of 23 °C and it occupied a
volume of 31,98 m3.
5.1 Give the term for a gas that obeys the general gas equation pV = kT
under all pressure and temperature conditions. (1)
5.2 Determine, by calculation, the FORMULA of the gas. (7)
[8]
The diagram shows the potential energy changes during the following chemical
reaction:
2 H2 (g) + Cℓ2 (g) → 2 HCℓ (g)
Potential energy (kJ·mol-1)
679,1 kJ·mol-1
184,7 kJ·mol-1
Time
6.3 What is the total bond energy (H2 and Cℓ2) of the reactants?
Give a reason for the answer. (3)
6.4 Determine the energy released by the bond formation of the HCℓ molecule. (3)
6.5 What effect will the addition of a catalyst have on the value 184,7 kJ·mol -1?
11,79% Carbon
69,57% Chlorine
18,64% Fluorine
7.2 When heated, lithium reacts with nitrogen to form lithium nitride.
8.1 Sulphuric acid (H2SO4) can react with water through a multistep reaction.
The two reactions below show the multistep reaction.
8.1.3 Write down the chemical formula of the substance that acts as an
ampholyte in the above reactions. (2)
8.1.4 Write down a balanced chemical equation for the reaction between
sulphuric acid and sodium hydrogen carbonate. (3)
The equation for the reaction is given by the balanced equation shown
below:
2 CH3COOH (aq) + CaCO3 (s) → Ca(CH3COO)2 (aq) + H2O (ℓ) + CO2 (g)
The equation for the reaction is given by the balanced equation below:
9.3 Write down the symbol of the reducing agent. Explain the answer in terms of
oxidation numbers. (3)
9.5 Write down the balanced equation for the net redox reaction by using the
ion-electron method. (Show ALL steps in the balancing of the equation.) (7)
[16]
The flow diagram below shows the purification process of gold in the mining
industry.
X Y Z
Gold Gold solutions Gold Pure gold
Ore (Au+) precipitate
10.1 Give the name of the location in South Africa where the gold-rich ore is
mined. (1)
10.3 Write down the name of the metal used in process Y in the recovery of gold. (2)
10.4 Write down the name of the new substance used in process Y. (2)
TOTAL: 150
m n m
n= or/of c= or/of c = pH= -log[H3O+]
M V MV
Kw = [H3O+][OH-] = 1x10-14
N ca Va na at /by 298K
n= or/of =
NA
cb Vb nb
V
n= Vm
TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
(I) (II) Atoomgetal (III) (IV) (V) (VI) (VII) (VIII)
KEY/ SLEUTEL Atomic number
1 2
2,1
H He
1 29 4
Elektronegatiwiteit Simbool
3 4 Cu 5 6 7 8 9 10
1,9
Symbol
1,0
1,5
2,0
2,5
3,0
3,5
4,0
Electronegativity
Li Be 63,5 B C N O F Ne
7 9 11 12 14 16 19 20
11 12 13 14 15 16 17 18
0,9
1,2
1,5
1,8
2,1
2,5
3,0
Na Mg Benaderde relatiewe atoommassa Aℓ Si P S Cℓ Ar
Approximate relative atomic mass
23 24 27 28 31 32 35,5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
0,8
1,0
1,3
1,5
1,6
1,6
1,5
1,8
1,8
1,8
1,9
1,6
1,6
1,8
2,0
2,4
2,8
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39 40 45 48 51 52 55 56 59 59 63,5 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
0,8
1,0
1,2
1,4
1,8
1,9
2,2
2,2
2,2
1,9
1,7
1,7
1,8
1,9
2,1
2,5
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
86 88 89 91 92 96 101 103 106 108 112 115 119 122 128 127 131
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
0,7
0,9
1,6
1,8
1,8
1,9
2,0
2,5
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tℓ Pb Bi Po At Rn
133 137 139 179 181 184 186 190 192 195 197 201 204 207 209
87 88 89
0,7
0,9
Fr Ra Ac
226 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140 141 144 150 152 157 159 163 165 167 169 173 175
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232 238
Fe 3+
+e − ⇌ Fe 2+
+ 0,77
O2(g) + 2H+ + 2e− ⇌ H2O2 + 0,68
I2 + 2e − ⇌ 2I − + 0,54
Cu+ + e− ⇌ Cu + 0,52
SO2 + 4H+ + 4e− ⇌ S + 2H2O + 0,45
2H2O + O2 + 4e − ⇌ 4OH − + 0,40
Cu 2+
+ 2e − ⇌ Cu + 0,34
2−
SO 4 + 4H+ + 2e− ⇌ SO2(g) + 2H2O + 0,17
Cu2+ + e− ⇌ Cu +
+ 0,16
Sn4+ + 2e− ⇌ Sn2+ + 0,15
S + 2H + 2e + − ⇌ H2S(g) + 0,14
2H+ + 2e− ⇌ H2(g) 0,00
Fe3+ + 3e− ⇌ Fe − 0,06
Pb 2+
+ 2e − ⇌ Pb − 0,13
Sn2+ + 2e− ⇌ Sn − 0,14
Ni2+ + 2e− ⇌ Ni − 0,27
Co2+ + 2e− ⇌ Co − 0,28
Cd 2+
+ 2e − ⇌ Cd − 0,40
Cr3+ + e− ⇌ Cr2+ − 0,41
Fe2+ + 2e− ⇌ Fe − 0,44
Cr3+ + 3e− ⇌ Cr − 0,74
Zn 2+
+ 2e − ⇌ Zn − 0,76
2H2O + 2e− ⇌ H2(g) + 2OH− − 0,83
Cr2+ + 2e− ⇌ Cr − 0,91
Mn2+ + 2e− ⇌ Mn − 1,18
Aℓ 3+
+ 3e − ⇌ Aℓ − 1,66
Mg2+ + 2e− ⇌ Mg − 2,36
Na+ + e− ⇌ Na − 2,71
Ca 2+
+ 2e − ⇌ Ca − 2,87
Sr2+ + 2e− ⇌ Sr − 2,89
Ba2+ + 2e− ⇌ Ba − 2,90
Cs+ + e- ⇌ Cs - 2,92
+
K +e − ⇌ K − 2,93
Li+ + e− ⇌ Li − 3,05
Ag+ + e− ⇌ Ag + 0,80
2+
Hg + 2e − ⇌ Hg(ℓ) + 0,85
−
NO 3 + 4H+ + 3e− ⇌ NO(g) + 2H2O + 0,96
Br2(ℓ) + 2e − ⇌ 2Br −
+ 1,07
Pt2+ + 2 e− ⇌ Pt + 1,20
MnO2 + 4H+ + 2e− ⇌ Mn2+ + 2H2O + 1,23
O2(g) + 4H + 4e + −
⇌ 2H2O + 1,23
2−
Cr2O 7 + 14H+ + 6e− ⇌ 3+
2Cr + 7H2O + 1,33