22/08/2023 A

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005,

Ph.011-47623456

MM : 2209 chemistry 14 Time : 100 Min.

Basic concept of chemistry

1. If 56 g N2 and 64 g CH4 are mix with 80 g 6. SI Unit of thermodynamic temperature is

SO3 gas, then mole fraction of CH4 is 1) Celsius
1) 0.52 2) Kelvin
2) 0.57 3) Ampere
3) 0.42 4) Candela
4) 0.24
7. Molarity of 100 dm3 solution in which 0.2
2. Concentrated aqueous sulphuric acid is mol NaOH is present is
98% H2 SO4 by mass. How many grams of 1) 0.2 M
concentrated sulphuric acid solution should 2) 0.02 M
be used to prepare
3) 0.002 M
250 ml of 2.0 M H2 SO4 ?
4) 0.0002 M
1) 98 g
2) 50 g
8. This section contains 1 Assertion-Reason
3) 110 g
type question, which has 4 choices (A), (B),
4) 100 g (C) and (D) out of which ONLY ONE is
correct.
A : 0.0078 has four significant figure.
3. Molarity of 100 dm3 solution in which 0.2
R : Zeros preceding to first non-zero digit are
mol NaOH is present is
not significant.
1) 0.2 M 1) Both (A) and (R) are true and (R) is the
2) 0.02 M correct explanation of (A)
3) 0.002 M 2) Both (A) and (R) are true but (R) is not
4) 0.0002 M the correct explanation of (A)
3) (A) is true but (R) is false
4. Number of atoms present in 0.2 mol of 4) (A) is false but (R) is true
Na2 S4 O6 is (NA = Avogadro’s number)
1) 1.2NA 9. Maximum number of molecules are present
2) 2.0NA in
1) 32 g O2
3) 2.4NA
2) 10 g H2
4) 0.2NA
3) 22 g N2 O
4) 14 g N2
5. Which among the following contains highest
number of atoms ?
1) 8 g of O2 10. Which of the following has maximum
2) 9 g of H2 O number of electrons?
1) 72 g of O3
3) 25 g of CaCO3
2) 34 g of NH3
4) 10 g of He
3) 1.5 g molecules of SO2
4) 44.8 L of CO2 at STP

1
chemistry 14

11. The maximum number of atoms is present in 16. Which of the following set represents precise
1) 224 ml of CH4 at STP measurements of a physical quantity?
2) 18 g of glucose (C6 H12 O6 ) 1) 8.0, 8.5 , 8.6
2) 8.23, 8.66, 8.86
3) 22 g of CO2
3) 8.1, 8.13, 8.15
4)
4) 8.0, 9.0, 7.0
0.2 mole of urea

17. The concentration of aq. 40% (w/v) glucose

solution in ppm is (density of solution is 1.2
12. Concentrated aqueous sulphuric acid is g/ml)
98% H2 SO4 by mass. How many grams of 1) 3.3 × 105 ppm
concentrated sulphuric acid solution should 2) 4.5 × 104 ppm
be used to prepare
250 ml of 2.0 M H2 SO4 ? 3) 5.5 × 106 ppm

1) 98 g 4) 1.5 × 108 ppm

2) 50 g
3) 110 g 18. Number of urea molecules present in 400
4) 100 g mL of 2.5 M aqueous solution of urea is
1) 3.01 × 1022
13. If 4 moles of a gas ‘x’ weighs 176 g, then the 2) 6.02 × 1023
gas ‘x’ can be 3) 6.02 × 1026
1) NH3
4) 3.01 × 1024
2) CO
3) CO2
19. 500 mL of 1 M HCl is diluted to get 0.2 M
4) O2 aqueous solution. The amount of water
added is
14. A : In a homogeneous mixture the 1) 2 L
components completely mix with each other 2) 1 L
and give a uniform composition. 3) 1.5 L
R : Milk is a homogeneous mixture.
4) 2.5 L
1) Both Assertion & Reason are true and
the reason is the correct explanation of
the assertion 20. In 1 molal aqueous solution of urea, the
2) Both Assertion & Reason are true but mole fraction of urea is
the reason is not the correct 1) 0.018
explanation of the assertion 2) 0.15
3) Assertion is true statement but Reason 3) 0.025
is false
4) 0.001
4) Both Assertion and Reason are false
statements
21. If mass ratio of N2 and CO2 is 4 : 11 then the
ratio of their number of atoms will be
15. Paragraph for below question
A majority of reactions in the laboratories are 1) 8 : 33
carried out in solutions. Therefore, it is 2) 8 : 21
important to understand as how the amount 3) 4 : 11
of substance is expressed when it is present
4) 5 : 9
in the form of a solution. The concentration
of a solution or the amount of substance
present in its given volume can be 22. 100 ml of 0.2 M aqueous solution is mixed
expressed many ways such as molarity, with 400 ml H2 O. The molarity of resultant
molality, mole fraction or mass per cent. solution is
Q. The molarity of nitric acid solution which
1) 0.1 M
has density 1.3 g ml–1 and having mass per
2) 0.05 M
cent of nitric acid 31.5 %, is
1) 6.5 M 3) 0.025 M
2) 9.75 M 4) 0.04 M
3) 3.15 M
4) 13 M

2
chemistry 14

23. A compound contains 8% sulphur by mass. 30. The empirical formula of a compound is
Minimum molecular mass of the compound CH2 Cl then its molecular mass cannot be
is 1) 49.5 u
1) 200 u
2) 99 u
2) 400 u
3) 54 u
3) 600 u
4) 148.5 u
4) 1200 u

31. Which of the following has same molecular

24. An organic compound contains carbon, and empirical formula?
hydrogen and oxygen. Its elemental analysis 1) CH3 COOH
gave C = 40% and H = 6.67%. The empirical
formula of the compound would be 2) HCOOH
1) HCO 3) C6 H12 O6
2) H2 CO 4) H2 O2
3) HC2 O
4) H2 C2 O 32. 500 mL of an aqueous solution contains 2
moles of NaOH, if the solution is diluted so
that the final volume becomes 2 L, then the
25. 134.5 g of metal chloride contain 71 g of molarity of resultant solution will be
chlorine. The equivalent weight of the metal 1) 1 M
is
2) 0.5 M
1) 63.5 g
3) 2 M
2) 31.75 g
4) 1.5 M
3) 35.5 g
4) 13.45 g
33. Total number of electrons in 1 mol P3– ions
is
26. If the mass percentage (w/w) of urea in an
1) 18
aqueous solution is 15% then the molality of
urea in the solution will be (Molar mass of 2) 18 NA
urea = 60 g mol–1 ) 3) 15 NA
1) 6.25 m 4) 10 NA
2) 1.84 m
3) 4.21 m
34. Number of g atoms of sodium present in 230
4) 2.94 m g of sodium is (Atomic mass of sodium = 23
u)
27. A biomolecule contains 2% magnesium by 1) 10 NA
mass. The minimum molecular mass of 2) NA
biomolecule is
3) 10
1) 1200 u
4) 0.1
2) 1800 u
3) 2400 u
35. Mass of sulphur present in 1.2 g molecule of
4) 2000 u
SO2 (g) is
1) 7.68 g
28. The crystalline salt, Na2 SO4 ·xH2 O contains
2) 19.2 g
40.4% Na2 SO4 by mass. The formula of
3) 38.4 g
crystalline salt is
4) 48 g
1) Na2 SO4 ·2H2 O
2) Na2 SO4 ·7H2 O
36. 6.02 × 1021 molecules of glucose are
3) Na2 SO4 ·12H2 O
present in 250 mL of its aqueous solution.
4) Na2 SO4 ·5H2 O The molarity of the solution is
1) 0.01 M
29. Molality of an aqueous solution having mole 2) 0.4 M
fraction of solvent as 0.95 is approximately 3) 0.04 M
1) 2 4) 0.02 M
2) 3
3) 4
4) 5

3
chemistry 14

37. Number of neutrons in 9 g H2 O will be 44. A volumetric flask contains 50% (w/w)
1) 0.5 NA H2 SO4 solution. How many grams of the
given sulphuric acid solution is required to
2) NA prepare 200 mL of 0.5 M H2 SO4 solution?
3) 4 NA 1) 25 g
4) 5 NA 2) 19.6 g
3) 9.8 g
38. 0.1 mole of molecules are present in 4) 15 g
1) 9 g of H2 O
2) 1.6 g of CH4 45. A bottle contains 2L of milk. The volume of
3) 1.7 g of NH3 milk in m3 is
1) 20 × 10–3
4) Both (2) and (3)
2) 2 × 103
39. 0.9 g oxalic acid is treated with conc. H2 SO4 . 3) 20 × 103
The evolved gaseous mixture is passed 4) 2 × 10–3
through NaOH pellets. Weight of the
remaining gaseous product at STP will be
1) 0.72 g 46. Which of the given solution is most
2) 0.46 g concentrated?
1) 20 mL of 5 M HCl
3) 0.62 g
2) 10 mL of 2 M HCl
4) 0.28 g
3) 10 mL of M HCl
20

40. 4 g of Mg is reacted with 8 g of O2. Mole of 4) 30 mL of M

HCl
10
MgO produced in the reaction is
1) 1
4
47. The mass of 1.5055 × 1023 CO molecules is
2) 1

8 1) 14 g
3) 1 2) 7 g
6
3) 3.5 g
4) 1

3 4) 28 g

41. The number of atoms in 22 g of CO2 is 48. Total number of valence electrons present in
1) 0.5 NA 6.4 g of oxygen atoms is
1) 3.6 NA
2) NA
2) 3.2 NA
3) 1.5 NA
3) 1.6 NA
4) 4.5 NA
4) 2.4 NA

42. If the mass ratio of He to N2 in a container is

2 : 1 then the ratio of their moles will be 49. 200 ml of 3 M NaOH solution is diluted by
1) 2 : 1 400 ml water. The molarity of the resulting
solution is
2) 4 : 1
1) 1 M
3) 7 : 1
2) 2 M
4) 14 : 1
3) 1.5 M
4) 2.25 M
43. Total number of electrons in 1 mol P3– ions
is
50. If an element z having atomic weight x exists
1) 18 in two isotopes of mass number (x – 1) and
2) 18 NA (x + 2) then the percentage abundance of
3) 15 NA heavier isotope is
1) 25%
4) 10 NA
2) 66.6%
3) 33.3%
4) 20%

4
chemistry 14

51. If the mass percentage of methanol in water 58. If mass percentage of glucose in aqueous
is 16% then the molality of methanol in the solution is 36% then the molality of the
solution is solution is
1) 7.25 m 1) 2.250 m
2) 3.21 m 2) 3.125 m
3) 8.27 m 3) 5.125 m
4) 5.95 m 4) 4.612 m

52. Volume of water required to prepare 0.1 M 59. 12.04 × 1022 molecules of urea are present
solution from 1.6 L, 0.2 M solution of KOH in 500 mL of its solution. The molarity of the
1) 0.1 L solution is
2) 0.8 L 1) 4 M
3) 1.6 L 2) 0.4 M
4) 3.2 L 3) 2.5 M
4) 0.2 M
53. The number of oxygen atoms present in 90 g
of water is 60. 25 g MCl4 contains 0.5 mol chlorine atoms.
1) NA Its molar mass is
2) 5NA 1) 100 g mol–1
3) 2.5NA 2) 200 g mol–1
4) 10NA 3) 250 g mol–1
4) 400 g mol–1
54. A metal oxide containing 70% of metal (At.
wt of metal = 56) and rest oxygen. Its
empirical formula would be 61. 32°F is equal to
1) MO 1) 0°C
2) MO2 2) 32°C
3) 100°C
3) M2 O3
4) 132°C
4) M2 O

62. Number of chloride ions present in 200 ml of

55. Ten days is equal to 0.4 M CaCl2 solution is
1) 60 s × 60 s 1) 2.4 × 1021
2) 10 × 60 × 60 s
2) 6.02 × 1020
3) 24 × 60 × 60s
3) 9.6 × 1022
4) 10 × 24 × 60 × 60s
4) 4.8 × 1021
56. The number of water molecules present in 1
ml of water (dH2
O = 1g/ml) is 63. Number of nucleons present in 0.2 mol D2 O
is
1) 55.5 × NA
1) 2 NA
2) 18 × NA
2) 0.4 NA
3) NA

18 3) 3.2 NA
4) NA
4) 4.0 NA
55.5

57. Number of glucose molecules present in 64. Number of He atoms in 52 u of He is

250 mL of 0.4 M aqueous solution of 1) 52
glucose is 2) 13
1) 6.02 × 1025 3) 26
2) 6.02 × 1024 4) 65
3) 6.02 × 1023
4) 6.02 × 1022

5
chemistry 14

65. Maximum mass among the following is of 72. If NA is Avogadro’s number then number of
1) 12 g-atoms of O valence electrons in 3.2 g of oxide ions
2) 6 g-molecules of O2 (O2– ) is
3) 5 mole of O3 1) 1.6 NA

4) 224 L of O2 at STP 2) 0.8 NA

3) 16 NA

66. If 50 ml of 0.2 M NaOH solution is mixed with 4) 8 NA

100 ml of 0.4 M HCl solution, then the
molarity of HCl in the aqueous solution will
73. 44 g CO2 is equivalent to
be
1) 0.1 M 1) 0.5 mol of CO2
2) 0.01 M 2) 5 molecules of CO2
3) 0.02 M 3) 1.0 mol of CO2
4) 0.2 M 4) 1.0 molecule of CO2

67. The mass of 1.5055 × 1023 CO molecules is 74. An organic compound containing C, H and
1) 4 NA u O gave the following analysis C = 40%, H =
6.67% and O = 53.3%. Its empirical formula
2) 7 NA u would be
3) 8 NA u 1) CH2 O2
4) 12 NA u 2) CH3 O
3) CH2 O
68. Which of the following set represents most 4) C2 H4 O
precise measurements of a physical
quantity?
1) 8.0, 8.5 , 8.6 75. A gaseous mixture contains H2 and N2 in
2) 8.23, 8.66, 8.86 the volume ratio of 1 : 2 under STP
conditions. Their molar ratio in the mixture is
3) 8.1, 8.13, 8.15
1) 3 : 1
4) 8.0, 9.0, 7.0
2) 2 : 1
3) 1 : 2
69. 3.01 × 1022 molecules of sucrose are 4) 1 : 7
present in 200 ml of its solution. The
concentration of the solution is
1) 0.5 M 76. Volume of CO2 obtained at STP on complete
decomposition of 2.1 g of magnesium
2) 1.5 M
carbonate is
3) 1 M
1) 5.6 L
4) 0.25 M
2) 2.8 L
3) 0.56 L
70. The mass of NH3 containing 9 g of `H' atoms 4) 0.28 L
is
1) 17 g
77. The number of atoms in 22 g of CO2 is
2) 42 g
1) 2.5 NA
3) 51 g
4) 17 g 2) NA
3
3) 1.5 NA
4) NA

71. Number of electrons in 9.6 g of SO4 2– ions is 2

approximately
1) 5 NA 78. If boiling point of a liquid is 80°C then the
2) 3 NA value in °F scale will be
1) 150°F
3) 2.5 NA
2) 180°F
4) 4 NA
3) 176°F
4) 135°F

6
chemistry 14

79. Mass of CaCO3 required to react completely 86. A container contains H2 and CO in the mass
with 100 mL of 2.5 M HCl solution is ratio of 1 : 2. The molar ratio of the two gases
1) 25 g in the mixture is
2) 37.5 g 1) 1 : 2
3) 21.2 g 2) 3 : 2
4) 12.5 g 3) 5 : 1
4) 7 : 1
80. If the molality of the aqueous solution is
0.111, then the mole fraction of solute will be 87. Paragraph for below question
1) 0.02 A majority of reactions in the laboratories are
carried out in solutions. Therefore, it is
2) 0.002
important to understand as how the amount
3) 0.2 of substance is expressed when it is present
4) 0.1 in the form of a solution. The concentration
of a solution or the amount of substance
present in its given volume can be
81. If two elements P and Q combine to form two expressed many ways such as molarity,
compounds PQ and P2 Q3 . When 0.2 mol of molality, mole fraction or mass per cent.
PQ weight 34 g and 0.5 mol of P2 Q3 weighs Q. The mole fraction of methanol in its
220 g, the atomic weights of P and Q aqueous solution is 0.1, then the molality of
respectively are the solution is
1) 50, 120 1) 6.17 m
2) 55, 115 2) 5.82 m
3) 110, 60 3) 7.82 m
4) 70, 100 4) 6.78 m

82. If 6.022 × 1022 molecules of glucose are 88. If mass percentage of Co2+ in a biomolecule
dissolved in 500 g of water, then the molality is 0.59% then the minimum molecular
of this solution is weight of the biomolecule will be (molar
1) 0.2 m mass of Co = 59 g mol–1 )
2) 0.1 m 1) 100
3) 1 m 2) 1000
4) 0.5 m 3) 10000
4) 40000
83. 49 g H2 SO4 is added in 1500 g of water. The
molality of the solution is (mol mass H2 SO4 89. If vapour density of gas X2 is 30 then
= 98 u) number of atoms in 15 g of X2 is
1) 0.24 m 1) NA
2) 0.33 m 2) 2 NA
3) 0.98 m
3) 0.2 NA
4) 1.33 m
4) 0.5 NA

84. If the density of 3 M NaOH solution is 2

g/cm3 then the molality of the solution will be 90. If mole fraction of H2 SO4 in aqueous

(Molar mass of NaOH = 40 g mol–1 ) solution is 0.1 then molality of H+ and

2−

1) 1 m SO
4
ions respectively are (Assume 100%
ionisation of H2 SO4 )
2) 1.6 m
1) 6.17 m, 6.17 m
3) 2 m
2) 6.17 m, 12.34 m
4) 3.2 m
3) 12.34 m, 6.17 m
4) 12.34 m, 12.34 m
85. Which of the following sample contains the
highest number of atoms at NTP?
1) 22.4 L of CO2
2) 22.4 L of NH3
3) 22.4 L of N2 O4
4) All have same number of atoms

7
chemistry 14

91. 44.8 g of CaO is reacted with 28.4 g of 98. Total number of electrons in 2 mol of
P4 O10 . Mass of calcium phosphate obtained sulphide ion is
in the reaction is 1) 3.6 × 1024
1) 85 g 2) 3.6 × 1023
2) 75 g
3) 2.16 × 1025
3) 73.2 g
4) 2.16 × 1023
4) 62 g

92. Mass of NaOH that must be added to water 99. Number of atoms present in 60 g of urea
to prepare 500 mL of 2 M aqueous solution is
is
1) 30 g 1) 2.4 × 1024
2) 10 g
2) 4.8 × 1020
3) 20 g
3) 4.8 × 1024
4) 40 g
4) 6.02 × 1025
93. Molarity of OH– ions in a mixture of 100 mL
of 0.1 M H2 SO4 and 300 mL of 0.1 M NaOH 100. If mole fraction of H2 SO4 in aqueous
is solution is 0.1 then molality of H+ and SO2−
4

1) 0.1 M ions respectively are (Assume 100%

2) 0.50 M ionisation of H2 SO4 )
3) 0.050 M 1) 6.17 m, 6.17 m
4) 0.025 M 2) 6.17 m, 12.34 m
3) 12.34 m, 6.17 m
94. If mass percentage of zinc in a biomolecule 4) 12.34 m, 12.34 m
is 0.4% then the minimum molecular mass of
the biomolecule will be (Atomic mass of zinc
101. If the mass ratio of H2 and CH4 in a mixture
= 65.4 u)
is 1 : 4, then their mole ratio will be
1) 12250 u
1) 1 : 4
2) 22275 u
2) 2 : 1
3) 16350 u
3) 1 : 2
4) 6250 u
4) 1 : 1

95. Mole fraction of ethanol in aqueous solution

102. In an organic compound containing carbon,
is 0.5. The concentration of solution in terms
hydrogen and oxygen, the percentage of
of percent by mass of ethanol is
carbon and hydrogen in it are 40% and
1) 50.55 6.67% respectively. Its molecular formula
2) 62.52 may be
3) 71.87 1) C2 H5 OH
4) 36.58 2) CH3 CHO
3) C6 H12 O6
96. 24
The mass of 3.01 × 10 atoms of triatomic 4) C12 H22 O11
gas is 80 g. The molecular mass of gas is
1) 240
103. Mass of CaCO3 required to react completely
2) 40
with 100 mL of 0.5 M H2 SO4 is
3) 26.67
1) 10 g
4) 48
2) 5 g
3) 15 g
97. The number of atoms in 67.2 L of NH3 (g) at
4) 25 g
STP is
1) 9 NA
104. The term 'formula mass' is used for
2) 12 NA
1) C6 H12 O6
3) 3 NA
2) Na2 SO4
4) 4 NA
3) H2 O
4) C6 H6

8
chemistry 14

105. 400 ml of 2 M NaOH solution is mixed with 112. In the reaction,

600 ml of 1 M NaOH solution. The final 4NH3 (g) + 5O2 (g) → 4NO(g) + 6H2 O(g)
molarity of the solution becomes When 1.5 moles of ammonia and 2 moles of
1) 1.2 M O2 are made to react to completion
2) 1.4 M 1) 2 moles of H2 O is produced
3) 1.6 M 2) 2 moles of NO will produced
4) 1.5 M 3) 1.5 moles of H2 O is produced
4) 1.5 moles of NO is produced
106. Which among the following has maximum
number of molecules?
113. Element X has two isotopes A and B. If %
1) 4.4 g CO2 abundance of A and B is 50% each, then
2) 4.8 g O3 average atomic mass of element X is (At.
mass of A = 10 u and B = 20 u)
3) 4 g H2
1) 10 u
4) 32 g SO2
2) 15 u
3) 20 u
107. Percentage of magnesium in a biomolecule 4) 30 u
is 0.1%. The minimum molecular mass of the
biomolecule is (Atomic mass of Mg = 24 u)
1) 600 u 114. Hydrogen combines with oxygen to form two
compounds, namely, water and hydrogen
2) 24 × 105 u
peroxide. The masses of oxygen which
3) 1200 u combine with fixed mass of hydrogen bear
4) 24000 u simple ratio i.e. 1 : 2 this illustrates
1) Law of conservation of mass

108. If 0.3 mole of BaCl2 is mixed with 0.4 moles 2) Law of definite proportions
of Na3 PO4 , then maximum number of moles 3) Law of multiple proportions
of Ba3 (PO4 )2 and NaCl formed are 4) Gay Lussac's Law of gaseous volumes
respectively
1) 0.2 and 1.6 115. Which of the following pair of compounds
2) 0.3 and 1.8 illustrate the law of multiple proportion?
3) 0.1 and 0.6 1) BaO and Ba(OH)2
4) 0.4 and 2.4 2) H2 O and H2 S
3) PbO and SnO
109. 25 g of calcium carbonate sample on 4) H2 O and H2 O2
decomposition gives 3.5 g of calcium oxide.
The percentage purity of calcium carbonate
sample is 116. Maximum number of significant figures is in
1) 25% 1) 0.000010
2) 40% 2) 0.281
3) 50% 3) 4.1 × 106
4) 10% 4) 0.032

110. If mass percentage of glucose in aqueous 117. Law of conservation of mass is not valid for
solution is 36% then the molality of the 1) Acid-base reactions
solution is
2) Nuclear reactions
1) 2.250
3) Combustion reactions
2) 3.125
4) All of these
3) 5.125
4) 4.612
118. 1 amu is equal to
1) 6.02 × 10–23 g
111. Density of NO2 gas in g/L at STP will be
2) 1.66 × 10–24 g
1) 1.02
2) 4.5 3) 1 g
3) 2.05 4) 1 mg

4) 3.1

9
chemistry 14

119. Law of multiple proportion is not applicable 125. Boron has two stable isotopes, 10 B (19%)
for the pair
and 11 B (81%). The average atomic weight
1) CO & CO2 of boron is
2) H2 O & H2 O2 1) 11.81 u
3) CH4 & C2 H6 2) 10.0 u
4) O2 & H2 O 3) 10.81 u
4) 10.5 u

120. The incorrect statement regarding Dalton’s

atomic theory is 126. Which of the following is a compound?
1) Matter consists of indivisible atoms 1) C
2) Atoms can neither be created nor 2) H2
destroyed in a chemical reaction 3) NH3
3) Compounds are formed when atoms of 4) S8
different elements combine in variable
ratio.
4) All the atoms of a given element have 127. Which has maximum number of atoms?
identical properties 1) 23 g of Na
2) 9 g of H2 O
121. All the sample of ammonia contains nitrogen 3) 18 g of Mg
and hydrogen in the mass ratio of 14 : 3.
4) 8 g of H2
This is in accordance with
1) Law of multiple proportions
2) Law of conservation of mass 128. Let two elements A and B combine to form
two compounds AB and AB2 . If 0.2 mole of
3) Avogadro’s law
AB weighs 20 g and 0.15 mole of AB2
4) Law of definite proportions
weighs 24 g then atomic weights of A and B
respectively are
122. Total number of significant figures in 50 1) 30, 70
books are 2) 40, 60
1) 0 3) 80, 20
2) 2 4) 35, 65
3) 1
4) Infinite
129. The mole fraction of NaCl in 4.5 molal
aqueous solution of NaCl is
123. An element X has the following isotopic 1) 0.39
composition 60 X : 60% and 62 X : 40%. The 2) 0.057
weighted average atomic mass of the 3) 0.075
naturally occurring element X is
4) 0.57
1) 60.4 amu
2) 60.5 amu
3) 60.2 amu 130. If the percentage composition of oxygen in a
compound is 20%, then according to law of
4) 60.8 amu definite proportion, the weight of oxygen in
20 g sample of the compound is
124. "Equal volume of gases at the same 1) 3 g
temperature and pressure should contain 2) 6 g
equal number of molecules". This fact is 3) 8 g
derived from
4) 4 g
1) Law of definite proportions
2) Dalton's Atomic theory
131. 4 g mixture containing equal masses of
3) Law of gaseous volume Na2 CO3 and CaCO3 is heated. The evolved
4) Avogadro's hypothesis gaseous product is passed through 1 L, 0.1
M lime water to give a substance having
milky appearance. The mass of the
substance is
1) 0.02 g
2) 4 g
3) 2 g
4) 100 g

10
chemistry 14

132. Which of the following concentration terms 138. If the molality of methanol in an aqueous
depend upon temperature? solution is 6 then the mass percentage of
1) Molality methanol in the solution will be
2) Mole fraction 1) 24.2%
3) Normality 2) 16.1%
4) (w/w)% 3) 8.4%
4) 31.5%
133. When a metal is burnt in O2 , then its mass
increases by 50%. Equivalent mass of metal 139. Equal masses of CH4 , O2 and SO2 gases
and metal oxide respectively is are mixed together in a container. The mole
1) 16, 24 fraction of CH4 in the mixture is
2) 20, 28 1) 4

7
3) 16, 20 2) 1

4) 18, 28 7

3) 5

134. What will be the pH of solution obtained by 4) 2

mixing 25 ml of 0.2 M HCl with 25 ml of 0.2 7

M Ba(OH)2 ?
1) 7 140. Mass of one amu in kg is
2) 1 1) 1.66 × 10–27
3) 13 2) 6.022 × 10–27
4) 14 3) 6.022 × 10–23
4) 1.66 × 10–24
135. A : Sulphur and oxygen are known to form
two compounds containing 51% and 41%
sulphur respectively. These data illustrate 141. Mass of water produced by the combustion
the law of multiple proportions. of 32 g of methane is
R : Ratio of oxygen in oxides of sulphur is 2 : 1) 18 g
3. According to law of multiple proportions,
the relative amounts of an element 2) 32 g
combining with some fixed amount of a 3) 72 g
second element in a series of compounds 4) 16 g
are the ratios of small whole number.
1) Both Assertion & Reason are true and
the reason is the correct explanation of 142. 20 g of H2 gas is exploded with 160 g of O2
the assertion gas. The incorrect statement for this reaction
is
2) Both Assertion & Reason are true but
the reason is not the correct 1) Oxygen gas will be consumed
explanation of the assertion completely
3) Assertion is true statement but Reason 2) Hydrogen gas will be consumed
is false completely
4) Both Assertion and Reason are false 3) Eight moles of water molecules are
statements formed
4) The reaction follows law of
conservation of mass
136. Find out false statement.
1) Molecular volume is the volume
occupied by 1mole of a gas 143. 2 litres of 0.1 M HCl solution is mixed with
another 1 litre of 0.2 M HCl solution. The
2) SI unit of thermodynamic temperature
molarity of the resulting solution will be
is Kelvin
1) 0.13 M
3) Vapour density is unitless
2) 0.23 M
4) SI unit of pressure is Pascal
3) 0.31 M
4) 0.47 M
137. For complete oxidation of 12 litres of CO at
NTP, the required volume of O2 at NTP is
1) 6 L
2) 1 L
3) 0.5 L
4) 12 L

11
chemistry 14

144. An element A has the following isotopic 150. The charge on 1 gram ions of Al3+ is (e =
composition 12 A : 40%, 15 A : 60%. The electronic charge)
average atomic mass of the element A is 1) 3 × NAe coulomb
1) 13.8 u
2) 1
NAe coulomb
2) 14.5 u 27

3) 12.7 u 3) 1
× NAe coulomb
9

4) 13 u 4) 1

3
× NAe coulomb

145. Which among the following has maximum

number of molecules? 151. Which of the following pairs of compounds
1) 22 g CO2 does not follow law of multiple proportions?
1) CO2 , CO
2) 40 g SO3
2) NO2 , N2 O5
3) 10 g CH4
3) H2 O, H2 O2
4) 20 g NO2
4) SO2 , N2 O

146. 500 mL of water is added in 500 mL of 0.2 M

NaCl solution, the molarity of resultant 152. If vapour density of gas X2 is 30 then
solution becomes number of atoms in 15 g of X2 is
1) 0.1 M 1) NA
2) 0.2 M 2) 2 NA
3) 0.5 M 3) 0.2 NA
4) 1 M
4) 0.5 NA

147. If x g of a metal chloride contains y g of metal

then equivalent weight of metal will be 153. 104 °F is equal to
1) 35.5 x 1) 40 K
x−y 2) 40°C
2) 35.5 y 3) 318 K
x−y
4) 318°C
3) 35.5 x

4) x 154. Number of electrons present in 8 g of O2– is

35.5 y
1) NA
2) 5 NA
148. Mole fraction of the solute in 0.5 molal
aqueous solution is nearly 3) 0.5 NA
1) 1 4) 10 NA
112

2) 1

56 155. Mole fraction of the solute in 0.5 molal

3) 1 aqueous solution is nearly
25
1) 1

4) 1 150
150
2) 1

56

149. The mass percentage of carbon in ethanol 3) 1

112
(C2 H5 OH) is nearly
4) 1

1) 30% 25

2) 52%
3) 60% 156. A solution of known normality is diluted five
times. Which of the following changes during
4) 72%
dilution?
1) Mole of solute
2) Milli equivalent of solute
3) Normality of solution
4) All of these

12
chemistry 14

157. Calculate the number of gram atoms in 100 163. The density of a stock solution of 49 % (w/w)
ml mercury. H2 SO4 is 1.5 g/ml. The volume of this stock
Given: Density of Hg = 13.6 g ml–1 and solution required to prepare 2.5 L of 0.1 M
molar mass of Hg = 200 g mol–1 H2 SO4 solution is
1) 2.26 1) 33.33 ml
2) 6.8 2) 25.55 ml
3) 6.8 × NA 3) 43.23 ml
4) 2.26 4) 38.25 ml
NA

164. Mole fraction of solute in aqueous solution of

158. Mole fraction of urea in its 4.45 m aqueous 40% (w/w) of NaOH will be nearly
solution is 1) 0.18
1) 0.254 2) 0.23
2) 0.074 3) 0.29
3) 0.153 4) 0.32
4) 0.372
165. A solution containing 2 g per 100 mL of urea
159. In 2 m aqueous urea solution, mole fraction (molecular mass = 60 g mol–1 ) is isotonic
of urea is (molar mass of urea = 60 g mol–1 ) with a 5% (w/v) solution of a non-volatile
1) 2 solute. The molecular mass of this non-
55.5 volatile solute is
2) 2
1) 175 g mol–1
57.5

3) 55.5 2) 200 g mol–1

57.5
3) 350 g mol–1
4) 1

55.5
4) 150 g mol–1

160. The equivalent weight of metal whose 1 g

166. Which has maximum number of molecules
carbonate on heating gives 0.6 g of metal
oxide, is among the following?
1) 25 g 1) 32 g O3
2) 30 g 2) 80 g SO3
3) 35 g 3) 42 g CO
4) 40 g 4) 1 g H2

161. Volume of CO2 (g) obtained at STP by 167. An element X exist in three isotopic forms. If
complete decomposition of 0.1 mol NaHCO3 percentage composition of 150 X, 148 X and
is 151
X are 40%, 20% and 40% respectively
1) 2 L then, the average atomic weight of X will be
2) 1.12 L 1) 150.0 u
3) 2.24 L 2) 149.5 u
4) 1.5 L 3) 150.4 u
4) 150.6 u
162. If 3.01 × 1023 molecules of sugar are
present in 24.5 mol of water then mole 168. The equivalent weight of NaH2 PO4 in the
fraction of sugar in solution is reaction
1) 0.08 N a H2 P O4 + KOH → N aKHP O4 + H2 O

2) 0.04 is
3) 0.2 (Given Atomic masses: Na = 23, K = 39, P =
31)
4) 0.02
1) 158
2) 60
3) 97
4) 120

13
chemistry 14

169. If Avogadro number (NA) is changed to 175. Equivalent mass of an acid

6.022 × 1022 mol–1 then this would change 1) Depends on the number of oxygen
1) The ratio of number of atoms of atoms present
different elements in a compound 2) Depends on the reaction involved with
2) The ratio of stoichiometric coefficients base
of chemical species in a balanced 3) Is always constant
equation 4) Molecular Mass
Is equal to
3) The law of conservation of mass No. of H-atoms

4) The mass of 1 g-atom of carbon

176. A gaseous mixture contains equal mass of
170. Two element A(at.wt = 40) and B(at.wt = 25) O2 and SO2 .The mole fraction of SO2 in the
combine to give compound having 80% of A. mixture is (Atomic mass of S = 32 u)
What is the formula of compound? 1) 1
3
1) A2 B3
2) 2

2) A3 B2 3

3) A5 B2 3) 1

4) A7 B3 4) 1

171. A : 1 L of O2 (g) and 1 L of SO2 (g) contain

177. Equivalent mass of a trivalent metal is 9.
same number of moles under identical Find molecular mass of its oxide
conditions.
R : Under identical conditions, 1 L of O2 (g) 1) 70
and 1 L of SO2 (g) contain same number of 2) 43
atoms. 3) 27
1) Both Assertion & Reason are true and 4) 102
the reason is the correct explanation of
the assertion
178. Which of the following statement is incorrect
2) Both Assertion & Reason are true but with respect to normality?
the reason is not the correct
1) Normality is number of g-equivalents
explanation of the assertion
dissolved per litre of solution
3) Assertion is true statement but Reason
2) It is a temperature dependent quantity
is false
3) Normality does not hold any
4) Both Assertion and Reason are false
mathematical relation with molarity
statements
4) Both (1) & (2)

172. The concentration term that gets affected by

temperature is 179. If the equivalent weight of a metal hydride is
1) Molality 13, then the equivalent weight of metal oxide
is
2) Normality
1) 10
3) Mole fraction
2) 18
4) (wt/wt) percent
3) 19
4) 20
173. If molality of urea in an aqueous solution is 5
then the mass percentage of urea in the
solution will be nearly 180. Atomic mass of an element is 4 × 10–23
1) 30% gram. The number of gram-atoms in 24 kg of
2) 23% this element is nearly
3) 27% 1) 24

4) 20% 2) 1000
3) 1
4) 2400
174. 4 mol of A are mixed with 8 mol of B as per
the reaction.
2A + B → 3C
The maximum moles of C formed is
1) 4
2) 6
3) 8
4) 10

14
chemistry 14

181. 10 g of KClO3 is strongly heated in a vessel 187. If mole fraction of solvent in aq. H2 SO4
which partially decomposes as, 2KClO3 solution is 0.85 then number of moles of
⟶ 2KCl + 3O2 and rest as 4KClO3 solute present in 2 kg of solvent is
⟶ 3KClO4 + KCl. If 9.52 g of solid residue 1) 6.66
is left in vessel by end of reaction, then how 2) 5.66
much oxygen gas has escaped out? 3) 0.15
1) 0.48 g 4) 19.6
2) 0.24 g
3) 9.6 g
188. 56 g of nitrogen and 20 g of hydrogen reacts
4) 0.89 g in a closed vessel to form ammonia.
Maximum amount of ammonia produced in
182. What volume of NH3 (g) at STP is required to this reaction is
be passed through 100 mL of 2 M H2 SO4 1) 17 g
solution to bring down its concentration to 2) 34 g
0.5 M? (Assume no volume change) 3) 68 g
1) 6.72 L 4) 51 g
2) 4.48 L
3) 2.24 L 189. If 0.2 equivalent of H2 C2 O4 undergo
4) 33.6 L complete dissociation, what will be number
of equivalents of H+ produced into solution?
183. 20 ml of 0.1 N BaCl2 is mixed with 30 ml of 1) 0.4
0.2 N Al2 (SO4 )3 . The mass of BaSO4 formed 2) 0.2
is (Molar mass of BaSO4 = 233 g/mole) 3) 0.8
1) 233 g 4) 0.6
2) 2.33 g
3) 0.233 g 190. 0.5 M, 20 ml H3 PO4 solution is diluted to
4) 23.3 g obtain 0.1N H3 PO4 solution. The volume of
water required for this dilution is
184. In which of the following, central atom is sp3 1) 300 ml
hybridised 2) 280 ml
1) BeF2 3) 160 ml
2) NH
+ 4) 250 ml
4

3) ⊕

CH3 191. 40 ml of 0.1 M CaCl2 solution is mixed with

4) XeF4 50 ml of 0.2 M AgNO3 solution. Mole of AgCl
formed in the reaction is
1) 10–2 mol
185. Volume of 0.2 M acidified Cr2 O7 2– solution
2) 4 × 10–3 mol
required to oxidise 50 ml, 0.3 M C2 O4 2–
solution is 3) 8 × 10–3 mol
1) 150 ml 4) 0.2 mol
2) 75 ml
3) 25 ml 192. A sample of drinking water contains
4) 12.5 ml chloroform (CHCl3 ) at a level of 15 ppm (by
mass). The percentage by mass of
chloroform in the sample is
186. The mole fraction of urea in its semimolal 1) 15 × 10–4
aqueous solution is
1) 0.007 2) 1.5 × 10–4
2) 0.009 3) 15 × 10–6
3) 0.03 4) 15 × 10–3
4) 0.25

15
chemistry 14

193. In 1 molal aqueous solution of urea, the 200. Find out the correct statement for the
mole fraction of urea is following reaction
1) 0.018 H3 PO4 + M(OH)2 → MHPO4 + 2H2 O
2) 0.15 1) Resulting solution require ½ mole of
3) 0.025 NaOH for complete neutralisation.

4) 0.001 2) Minimum 1 mole of M(OH)2 is required

for complete neutralisation of MHPO4
3) 98
194. Equivalent mass of crystalline oxalic acid in EH
3
PO4 =
3

complete neutralisation process is 4) Molecular weight of base

E
1) 45 base = 2

2) 63
3) 126 201. 44.8 L of N2 reacts with 112 L of H2 at STP,
4) 90 then identify the correct statement(s)
1) 3.33 mol of NH3 is formed
195. Which of the following term depends on 2) 0.33 mol of N2 is left in excess
temperature? 3) H2 is completely used up in the
1) (w/w)% reaction
2) Molarity 4) All of these
3) Molality
4) Mole fraction 202. Consider the reaction, A + 2B + 3C → 4D +
5E. Starting with 3 mole of A, 4 mole of B
196. If equivalent mass of a metal is 31.5, then and 4.5 mole of C, the number of moles of
the products D and E formed would be
the equivalent mass of respective metal
respectively
chloride is
1) 12 and 15
1) 102.5
2) 8 and 10
2) 94.5
3) 6 and 7.5
3) 67
4) 16 and 20
4) 134

203. In the reaction, 2A + 3B ⟶ 2AB3 if 300

197. When 2 g of H2 reacts with 32 g of O2 during 2

an explosion at 500 K, the final gaseous atoms of A react with 300 molecules of B2 ,
mixture will contain then the number of molecules of the product
1) H2 , O2 and H2 O formed is
1) 2
2) O2 only
2) 300
3) H2 O only
3) 600
4) O2 and H2 O only 4) 200

198. If in a metal oxide, oxygen is present 16% by 204. How many grams of glucose is required to
mass then equivalent weight of metal oxide prepare 3m solution weighing 5 kg?
is
1) 753.65
1) 42
2) 1250.55
2) 84
3) 1753.25
3) 50
4) 2700.45
4) 56

205. A certain compound has the molecular

199. Mass percentage of solute in 1 molal formula M4 O6 . If 5.0 g of the compound
aqueous glucose solution is approximately contains 2.81 g of M, then the atomic mass
1) 20.0% of M is
2) 15.2% 1) 30.6 u
3) 22.0% 2) 6.8 u
4) 25.8% 3) 62.8 u
4) 24 u

16
chemistry 14

206. The equivalent weight of H3 PO4 in the given 213. Suppose the elements X and Y combine to
reaction is form two compounds X2 Y and X3 Y4 . 0.1
2 NaOH + H3 PO4 → Na2 HPO4 + 2 H2 O mole of X2 Y weighs 10 g and 0.05 mole of
1) 49 X3 Y4 weighs 15 g, the atomic masses of X
2) 98 and Y respectively are
3) 24.5 1) 20 u and 60 u
4) 32.67 2) 50 u and 30 u
3) 60 u and 20 u
4) 30 u and 50 u
207. 50 g of an impure calcium carbonate sample
decomposes on heating to give carbon
dioxide and 22.4 g calcium oxide. The 214. If 3.01 × 1023 molecules of sugar are
percentage purity of calcium carbonate in present in 24.5 mol of water then mole
the sample is fraction of sugar in solution is
1) 60% 1) 0.08
2) 80% 2) 0.04
3) 90% 3) 0.2
4) 70% 4) 0.02

208. Number of significant figures in 0.420 g is 215. For the hypothetical reaction
1) 4 2A + 3B + 4C → 2D
2) 2 Maximum moles of D formed when 10 moles
3) 3 of A reacts with 9 moles of B and 16 moles of
C are
4) 1
1) 8
2) 6
209. Equivalent weight of a metal, x g of which 3) 4
reacts with 2 eq. of an acid, is
4) 2
1) 1
2) 2x
3) x 216. 100 ml of 0.2 M Na2 SO4 solution is mixed
with 400 ml of 0.1 M Al2 (SO4 )3 solution. The
4) x
2
molar concentration of SO4 2– ion in the final
solution is
210. 0.23 g of a metal on treatment with an acid 1) 0.12
gives 112 ml of hydrogen gas at STP. 2) 0.28
Equivalent mass of the metal is
3) 0.24
1) 46
4) 2.8
2) 23
3) 12
4) 11.5 217. Suppose the elements X and Y combine to
form two compounds X2 Y and X3 Y4 . 0.1
mole of X2 Y weighs 10 g and 0.05 mole of
211. The number of atoms in 0.25 mole of a tetra- X3 Y4 weighs 15 g, the atomic masses of X
atomic gas is (NA = Avogadro number) and Y respectively are
1) 4 NA 1) 20 u and 60 u
2) 2 NA 2) 50 u and 30 u
3) NA 3) 60 u and 20 u
4) 3 NA 4) 30 u and 50 u

212. In a reaction A2 + B → A2 B 218. The mass of precipitate (Ag2 CO3 ) formed,

If 200 molecules of A2 is reacted with 300 when 50 ml of 21.2% (w/v) solution of
Na2 CO3 is mixed with 100 ml of 17% (w/v)
atoms of B to complete the reaction, then the
correct statement is AgNO3 solution is (molar mass: AgNO3 =
1) B is limiting reactant 170 g mol–1 , Na2 CO3 = 106 g mol–1 and
2) 200 atoms of B remain unreacted Ag2 CO3 = 276 g mol–1 )
3) 100 molecules of A2 remain unreacted 1) 25.9 g
4) 200 molecules of A2 B is formed 2) 16.7 g
3) 31.4 g
4) 13.8 g

17
chemistry 14

219. Two elements A and B reacts to form 2 226. 1 g of a gas occupies 0.35 L at NTP. The
compounds A3 B4 and A2 B3 . If 0.08 mole of molar mass (g/mol) of the gas is
A3 B4 weighs 18.56 g and 0.2 mole of A2 B3 1) 32
weighs 32 g, then the atomic weights of A 2) 64
and B respectively are
3) 44
1) 27 u, 16 u
4) 80
2) 56 u, 16 u
3) 54 u, 14 u
227. The number of significant figures in 0.06,
4) 63.5 u, 14 u
2.005 and 4.0 × 104 respectively are
1) 1, 4, 6
220. Volume occupied by 1 mole water (density = 2) 1, 4, 2
1 g cm–3 ) is
3) 2, 4, 2
1) 10 mL
4) 3, 2, 2
2) 18 mL
3) 18000 mL
228. One mole sample of FeO is heated in air
4) 54 mL until it is completely converted into Fe2 O3 .
The percentage increase in weight of
221. An organic compound contains carbon, sample is [Given: Atomic mass of Fe = 56]
hydrogen and oxygen. Its elemental analysis 1) 10.58%
gave C, 40% and H, 6.67% by mass. The 2) 20.28%
empirical formula of the compound will be
3) 35.35%
1) CHO
4) 11.11%
2) CH2 O
3) CH2 O2
229. If the mole fraction of acetone in ethyl
4) CH4 O alcohol is 0.3, then the molality of acetone in
the solution is
222. Among the following, maximum number of 1) 4.5 m
molecules are present in 2) 6.2 m
1) 10 g H2 3) 8.3 m
2) 10 gram-molecules O2 4) 9.3 m
3) 8 moles CO2
4) 64 g SO2 230. The concentration of an aqueous solution of
H2 SO4 is 98% (w/w) and its density 1.8 g/ml.
The volume of this acid required to make
223. If mass ratio of N2 and O2 is 2 : 5, then the 500 ml of 0.2 M H2 SO4 solution is
ratio of their number of molecules will be 1) 11.55 ml
1) 7 : 8 2) 55.5 ml
2) 2 : 5 3) 25.5 ml
3) 16 : 35 4) 5.55 ml
4) 2 : 3
231. Which of the following samples contains the
224. If four volume of dinitrogen react with 6 largest number of atoms?
volume of dihydrogen gas then the volume 1) 1 g of LiF(s)
of ammonia produced will be
2) 1 g of C8 H18 (l)
1) 4 volume
3) 1 g of CO2 (g)
2) 8 volume
4) 1 g of C2 H6 (g)
3) 6 volume
4) 2 volume
232. Mass of KOH solution required (50% (w/w))
to neutralize 2 litre of 1 M HCl solution is
225. Molality of an aqueous solution having 0.9
mole fraction of solvent is 1) 112 g
1) 6.17 m 2) 224 g
2) 4.25 m 3) 56 g
3) 3.10 m 4) 62 g
4) 5.11 m

18
chemistry 14

233. Total number of atoms present in 6 moles of 239. The volume of CO2 obtained from
ammonia is decomposition of 10g CaCO3 at STP is
1) 6 NA 1) 22.4 L
2) 24 NA 2) 10 L
3) 18 NA 3) 4.4 L
4) 12 NA 4) 2.27 L

234. Among the following, maximum number of 240. An element, X has the following isotopic
atoms are present in composition, 100 X : 80% and 102 X : 20%.
1) 14 g N2 The weighted average atomic mass of the
naturally occurring element X is closest to
2) 64 g SO2
1) 100.9
3) 88 g CO2 2) 100.4
4) 8 g H2 3) 101.2
4) 101.8
235. Given below are two statements : one is
labelled as Assertion A and the other is 241. An element exist in three isotopic forms 15 A,
labelled as Reason R : 17 A and 18 A. If the percentage abundance of
Assertion (A) : 1 g atom of iron (Fe) weigh
lesser than 2 moles of carbon. heaviest and lightest isotope are 40% and
Reasons (R) : 1 mole of atoms = 6.022 × 10% respectively then the average atomic
1023 g atoms. mass of the element is
In the light of the above statements, choose 1) 16.8 u
the correct answer from the options given 2) 17.0 u
below : 3) 17.2 u
1) Both Assertion & Reason are true and 4) 17.4 u
the reason is the correct explanation of
the assertion
2) Both Assertion & Reason are true but 242. If true value of a result is 10.00 g and a
the reason is not the correct student takes two measurements 9.95 and
explanation of the assertion 9.94 then these measurements are
3) Assertion is true statement but Reason 1) Accurate only
is false 2) Precise only
4) Both Assertion and Reason are false 3) Accurate and precise both
statements 4) Neither accurate nor precise

236. In the synthesis of ammonia, 42 g of nitrogen 243. 100 gm of a mixture of CaCO3 and Na2 CO3
gas is reacted with 8 g of hydrogen gas. was ignited strongly which forms 11.2 L of
Mass of ammonia produced in the process is
CO2 at STP. Then the mass ratio of Na2 CO3
1) 50 g and CaCO3 in the mixture will be
2) 36.5 g 1) 1 : 4
3) 45.3 g 2) 4 : 1
4) 48 g 3) 2 : 1
4) 1 : 1
237. Number of moles of neutrons in 18 g H2 O is
1) 10 244. A certain amount of metal whose equivalent
2) 4 weight is 20, displaces 5.6 litres of
3) 8 hydrogen, measured at NTP, from an acid.
The amount of metal is
4) 5
1) 40 g
2) 20 g
238. A jug contains 10 L of milk. Calculate the
3) 10 g
volume of milk in m3 .
4) 5 g
1) 1 m3
2) 10–2 m3
3) 10 m3
4) 10–1 m3

19
chemistry 14

245. Potassium salt of a monobasic organic acid 252. A : Equal volumes of different gases contain
has 13% potassium by mass. The minimum equal number of atoms at same temperature
molecular weight of the salt is (Atomic and pressure.
weight of K = 39) R : 100 ml of hydrogen combine with 100 ml
1) 130 of oxygen to form 100 ml of water vapours.
2) 360 1) Both Assertion & Reason are true and
the reason is the correct explanation of
3) 300 the assertion
4) 320 2) Both Assertion & Reason are true but
the reason is not the correct
246. Which of the following has maximum explanation of the assertion
number of atoms? 3) Assertion is true statement but Reason
1) 22.4 L of CO2 at STP is false
2) 44.8 L of O2 at STP 4) Both Assertion and Reason are false
statements
3) 1 L of H2 O at 4°C
4) 11.2 L of SO3 at STP
253. A : Scientific notation for 0.00016 can be
written as 1.6 × 10–4 .
247. A mixture of methanol and water contains R : Zeros preceding to first non-zero digit are
32% methanol by mass, the molality of not significant.
methanol in the solution is 1) Both Assertion & Reason are true and
1) 14.7 m the reason is the correct explanation of
2) 11.5 m the assertion
3) 9.7 m 2) Both Assertion & Reason are true but
the reason is not the correct
4) 12.3 m explanation of the assertion
3) Assertion is true statement but Reason
248. Percentage purity of 150 g of CaCO3 sample is false
which gives 5.6 litre CO2 at STP on 4) Both Assertion and Reason are false
complete decomposition is statements
1) 11.33%
2) 16.67% 254. If mass percentage of zinc in an enzyme is
3) 23.77% 0.5% then the minimum molecular weight of
4) 33.33% the enzyme will be. [Atomic wt. of Zn = 65]
1) 16250
2) 13000
249. The molecular mass of CH3 COOH is same
as the molecular mass of 3) 165
1) C6 H12 O6 4) 1682

2) NH2 CONH2
255. How much maximum copper can be
3) SO3 obtained from 100 mL of 1 M CuSO4
4) H2 CO3 solution? (At. mass of Cu = 63.5 u)
1) 63.5 g
250. The formula mass is applicable for 2) 15.95 g
1) NH3 3) 6.35 g
2) H2 4) 159.5 g
3) Na2 SO4
4) CO2 256. A mixture of formic acid and oxalic acid is
heated with conc. H2 SO4 . The gas produced
is collected and on its treatment with KOH
251. If the mass ratio of O2 and N2 is 4 : 7, then solution, the volume of the gas decreases by
1
the ratio of their moles is 6
. The molar ratio of the two acids, formic
1) 4 : 7 acid and oxalic acid respectively in the
2) 1 : 2 original mixture is
3) 3 : 5 1) 4 : 1
4) 4 : 5 2) 1 : 4
3) 1 : 1
4) 2 : 1

20
chemistry 14

257. A hydrocarbon contains 80% carbon. The 263. If vapour density is defined with respect to
empirical formula of the compound is He, what will be the vapour density of
1) CH4 oxygen?
2) CH3 1) 16
2) 8
3) CH2
3) 32
4) CH
4) 64

258. In a binary solution of methyl alcohol and

water, if the mass of methyl alcohol and 264. If the mass percentage of methyl alcohol in
water are 48 g and 81 g respectively, then aqueous solution is 16% then molality of the
the mole fraction of methyl alcohol in the solution will be
solution is 1) 7.25 m
1) 0.5 2) 3.15 m
2) 0.25 3) 8.23 m
3) 0.33 4) 5.95 m
4) 0.15
265. Number of significant figures in the sum of
259. A : Vapour density depends upon the 3.26 and 0.023 is
molecular state of the substance in vapour 1) 1
phase. 2) 2
R : Vapour density of sulphur vapour relative
3) 3
to oxygen is 2 because sulphur atom is twice
as heavy as that of oxygen atom. 4) 4
1) Both Assertion & Reason are true and
the reason is the correct explanation of 266. Number of significant figures in the sum of
the assertion 3.26 and 0.023 is
2) Both Assertion & Reason are true but 1) 1
the reason is not the correct 2) 2
explanation of the assertion
3) 3
3) Assertion is true statement but Reason
is false 4) 4
4) Both Assertion and Reason are false
statements 267. Total number of electrons present in 6 g of
carbon is
260. The number of electrons in oxygen atom in 1) 6 NA
0.3 g-molecule of Mohr's salt (FeSO4 . 2) 2 NA
(NH4 )2 SO 4 .6H2 O) is 3) 4 NA
1) 4.2 NA
4) 3 NA
2) 42 NA
3) 25.2 NA 268. Mass of NaOH solution required (50% (w/w))
4) 33.6 NA to neutralize 2 litre of 1 M H2 SO4 solution is
1) 160 g
261. An ethanolic solution of naphthalene 2) 320 g
contains 0.25 mole fraction of solute. 3) 80 g
Molality of solution is 4) 40 g
1) 5.92 m
2) 3.39 m
269. If mole fraction of NaOH in an aqueous
3) 7.25 m solution of NaOH is 0.2 then molality of
4) 9.47 m solution is
1) 10.80 m
262. How many grams of maximum zinc chloride 2) 11.40 m
will be formed from a reaction between 6.5 g 3) 8.65 m
of Zn and 3.2 g of HCl? 4) 13.87 m
(Atomic weight of Zn = 65 and Cl = 35.5)
1) 5.96 g
2) 3.97 g
3) 7.97 g
4) 2.97 g

21
chemistry 14

270. The amount of magnesium required to 277. 4 g calcium is burnt with 3.2 g O2 in a closed
produce 112 ml of H2 at STP by treatment vessel. Which reactant is left in excess and
with dilute H2 SO4 will be how much? (atomic weight: Ca = 40, O = 16)
1) 2.1 g 1) Ca, 10 g
2) 0.12 g 2) O2 , 1.6 g
3) 1.2 g 3) Ca, 20 g
4) 0.21 g 4) O2 , 0.8 g

271. If the equivalent weight of a metal oxide is 278. 20.0 g of an impure sample of calcium
20, then equivalent weight of its nitride will carbonate decomposes on heating to give
be 8.4 g calcium oxide. What is the percentage
1) 24 purity of calcium carbonate sample? (At. Wt.
2) 16.67 : Ca = 40)
3) 26.66 1) 50

4) 19 2) 75
3) 85
4) 95
272. If 0.1 mol of a gas sample contains 1.806 ×
1023 atoms, the atomicity of gas is
1) 1 279. The mass percentage of oxygen in H2 SO4 is
2) 2 1) 15.23
3) 3 2) 65.31
4) 4 3) 17.15
4) 23.24
273. Which of the following is independent on the
temperature? 280. Find out the correct statement(s)
1) Normality (a) Mass of 3.01 × 1023 molecules of
2) (w/v)% methane is 8 gram
(b) A pure compound has always a fixed
3) Molality
proportion of masses of its constituents
4) Molarity (c) 18 gram of water and 18 gram of ice will
contain same number of molecules.
274. Volume of CO2 (g) obtained at STP by 1) (a), (b) and (c)
complete decomposition of 0.1 mol NaHCO3 2) (a) and (c) only
is 3) (a) and (b) only
1) 2 L 4) (b) and (c) only
2) 1.12 L
3) 2.24 L 281. A : The reactant which gets completely
4) 1.5 L consumed in chemical reaction is called
limiting reagent.
R : The reactant which gets consumed, limits
275. If the vapour density of gas is 5.6 then the amount of product formed.
volume occupied by 11.2 g of gas at N.T.P is
1) Both Assertion & Reason are true and
1) 5.6 L the reason is the correct explanation of
2) 11.2 L the assertion
3) 22.4 L 2) Both Assertion & Reason are true but
4) 44.8 L the reason is not the correct
explanation of the assertion
3) Assertion is true statement but Reason
276. How many grams of concentrated sulphuric is false
acid (80% w/w) should be used to prepare
100 mL of one molar H2 SO4 solution? 4) Both Assertion and Reason are false
statements
1) 10 g
2) 12.25 g
282. 192 g ‘x’ gas has same number of atoms as
3) 15 g 67.2 L NH3 at STP. The gas ‘x’ is
4) 17.5 g 1) O3
2) CO2
3) NO2
4) SO2

22
chemistry 14

283. How many grams of concentrated sulphuric 290. Among the following which has maximum
acid solution [80% (w/w)] should be used to number of molecules?
prepare 500 ml of 1 M H2 SO4 ? 1) 49 g of H3 PO4
1) 49 g 2) 45 g of C6 H12 O6
2) 51.50 g 3) 28 g N2
3) 61.25 g
4) 36 g H2 O
4) 71 g

291. Molecular weight of a compound containing

284. Counting numbers of objects, for example 15% Be by mass is 2700 u. The number of
200 books has Be atoms present in one molecule of
1) One significant figure compound is (atomic mass of Be is 9 u)
2) Two significant figures 1) 40
3) Infinite significant figures 2) 45
4) Three significant figures 3) 35
4) 30
285. The mass of element x found in one mole of
each of four different compounds are 28 g, 292. Calculate the atomic mass of ‘X’ whose one
42 g, 56 g and 70 g respectively. The
possible atomic weight of x is atom weighs 1.8 × 10–22 g
1) 8 1) 98.8
2) 14 2) 54.18
3) 28 3) 108.39
4) 42 4) 111

286. The answer of the given addition upto 293. The charge on 1 mole of electrons (in
correct significant figures is 3.1421 + 0.241 + coulomb) is
0.09 = 1) 1.6 × 10–19 × NA
1) 3.47 2) 1.6×10
−19

× NA
2) 3.4731 2

3) 3.473 3) 2 × 1.6 × 10–19 × NA

4) 3.4 4) 1.6 × 10–19

287. According to following reaction. 294. The number of atoms present in 0.48 g of O3
XY + O2 → X2 O3 + Y2 O3
is (NA = 6 × 1023 )
The number of moles of Y2 O3 produced if 1
mole of XY is burnt with 1 mole of O2 is 1) 6 × 1021
1) 3 2) 1.8 × 1023
2) 1 3) 6 × 1024
3) 1/3 4) 1.8 × 1022
4) 2/3

295. Number of electrons lost during complete

288. It 0.1 g of a metal on reaction with dilute acid electrolysis of 0.355g of Cl– ions is (NA =
gives 24.8 ml of hydrogen gas at STP then
equivalent weight of metal will be Avogadro's Number)
1) 32.9 1) 0.01
2) 45.16 2) 0.01 NA

3) 16.39 3) 0.02 NA
4) 44.8 4) 0.01

2 NA

289. Carbon occurs in nature in the form of 12 C

and 13 C. If the average atomic mass of
carbon is 12.011 then the percentage
abundance of heavier isotope of carbon is
1) 1.1%
2) 2.3%
3) 0.11%
4) 11%

23
chemistry 14

296. A mass of 18 gram of compound M2 CO3 . 302. At STP, the density of O2 in g/L will be
xH2 O (molar mass of M = 24 g mol–1 ) is 1) 2.25 g/L
dissolved in 500 mL water and titrated 2) 0.71 g/L
against 0.5 M HCl solution. If the volume of 3) 1.21 g/L
HCl consumed is 500 mL, the value of x is
4) 1.43 g/L
1) 5
2) 7
303. Number of Fe atoms in 22.4 g Haemoglobin
3) 2
if it contains 0.25% Fe by mass (Atomic
4) 6 mass of Fe = 56 u) is
1) 6.02 × 1021
297. Which of the following acts as limiting 2) 6.02 × 1020
reagent if 3 mole of A, 1 mole of B, 2 mole of
C and 3 mole of D react according to given 3) 3.01 × 1020
equation? 4) 3.01 × 1021
2A + 4B + 5C + D → 4x + y + 3z
1) A
2) B 304. Volume of O2 required for the complete
3) C combustion of 11.2 L of CH4 at S.T.P. is
4) D 1) 11.2 L
2) 22.4 L
298. Number of oxygen atoms in 224 ml of CO2 at 3) 33.6 L
STP is 4) 44.8 L
1) 10–3 NA
305. Number of electrons in 0.2 gram ion of P3–
2) 4 × 10–2 NA
ion is
3) 2 × 10–2 NA 1) 0.6 NA
4) 10–2 NA 2) 1.6 NA
3) 3.6 NA
299. 20.0 g of an impure sample of calcium 4) 3 NA
carbonate decomposes on heating to give
8.4 g calcium oxide. What is the percentage
purity of calcium carbonate sample? (At. Wt. 306. On dissolving 3.0 g of a metal in sulphuric
: Ca = 40) acid, 5.51 g of the metal sulphate was
formed. If the specific heat capacity of the
1) 50
metal is 0.057 cal g–1 °C–1 . Then the valency
2) 75 of the metal is approx
3) 85 1) 3
4) 95 2) 2
3) 1
300. Hydrated aluminium sulphate contains 4) 5
8.10% aluminium by mass. The number of
H2 O molecules per aluminium atom present
in hydrated aluminium sulphate is 307. A compound is made up of two elements A
1) 18 and B in which A constitutes 70% by mass.
The atomic weight of A and B are 56 and 16
2) 16 respectively. The formula of the compound is
3) 9 1) AB3
4) 8 2) A3 B2
3) AB2
301. If percentage of Zn (atomic mass = 65.38) in
a biomolecule is 0.75% by weight, then the 4) A2 B3
minimum molar mass (in g mol–1 ) of
biomolecule will be 308. Which among the following concentration is
1) 10243.45 incorrect for 49% (wt/wt)aq. sulphuric acid
2) 9483.29 solution. (Density of solution = 1.09 g mL–1 )
3) 8012.12 1) 5.45 M
4) 8717.33 2) 9.80 m
3) 10.9 N
4) Mole fraction of H2 SO4 = 0.92

24
chemistry 14

309. The volume occupied by one molecule of 316. Two elements P and Q combine to form two
ethanol is (density of ethanol = 0.8 g/cm3 ) different compounds in stoichiometric ratios
1) 9.55 × 10–23 cm3 of 1 : 2 and 1 : 3. If 0.25 mole of 1st
compound weighs 16 g and 0.05 mole of
2) 6.30 × 10–23 cm3
2nd compound weighs 4 g, then the atomic
3) 13.60 × 10–23 cm3 weights of P and Q respectively are
4) 2.94 × 10–23 cm3 1) 8 and 32
2) 16 and 16
3) 16 and 32
310. CaCO3 on heating gives CaO and CO2 .
Equivalent mass of CaCO3 is 4) 32 and 16

1) 50
2) 100 317. The maximum number of atoms is present in
1) 224 ml of CH4 at STP
3) 25
4) 200 2) 18 g of glucose (C6 H12 O6 )
3) 22 g of CO2
311. Select the incorrect statement regarding 4)
Dalton’s atomic theory 0.2 mole of urea
1) Matter consists of indivisible atoms
2) All atoms of a given element have
identical properties
3) Compounds are formed when atoms of 318. Find the incorrect equality among the
different elements combine in fixed following
ratio 1) 1.6 g CH4 = NA electrons of CH4
4) Atoms are created or destroyed in 2) 100 u He = 25 atoms of He
chemical reactions
3) 1 g-atom of He = 1 g He
4) Mass of one Ca atom = 40 g
312. 112 g water is saturated with NH3 gas to N A

form a solution whose concentration is 30%

by mass and density is 0.93 g ml–1 . 319. A solution containing 2 g per 100 mL of urea
Calculate the volume of solution formed? (molecular mass = 60 g mol–1 ) is isotonic
1) 150 ml with a 5% (w/v) solution of a non-volatile
2) 160 ml solute. The molecular mass of this non-
3) 172 ml volatile solute is
1) 175 g mol–1
4) 184 ml
2) 200 g mol–1
313. Calculate the number of gram atoms in 40 3) 350 g mol–1
kg of an element whose one atom weighs 4) 150 g mol–1
6.64 × 10–23 g.
1) 500
320. If mass of three wood blocks are 7.497, 6.29
2) 400
and 4.6 g, then the total combined mass of
3) 1000 all the three blocks in appropriate significant
4) 40 figures is
1) 18.387 g
314. Which of the following possess 40% carbon 2) 18.39 g
by mass? 3) 18.4 g
1) HCHO 4) 18 g
2) C6 H12 O6
3) C12 H22 O11 321. Which of the following is correct relation?
4) Both (1) and (2) 1) 1 L = 1000 mL
2) 1 g = 10–3 mg
315. 0.25 gram atom of an element weighs 25 g. 3) 1 nm = 10 cm
The atomic mass of the elements is 4) 1 Å = 10–8 m
1) 50
2) 100
3) 200
4) 25

25
chemistry 14

322. A : The number of molecules in 1 cm3 of gas 328. SI unit of amount of substance is
at STP is known as loschmidt number. 1) Kilogram
R : Charge on one mole of electron is nearly 2) Mole
96500 coulomb.
3) amu
1) Both Assertion & Reason are true and
the reason is the correct explanation of 4) Gram
the assertion
2) Both Assertion & Reason are true but 329. 0.5 moles of BaCI2 are mixed with 0.2 moles
the reason is not the correct of Na3 PO4 . The maximum number of moles
explanation of the assertion of Ba3 (PO4 )2 that can be formed is
3) Assertion is true statement but Reason 1) 0.2
is false
2) 0.3
4) Both Assertion and Reason are false
statements 3) 0.1
4) 0.5
323. A metal oxide has the formula X2 O3 . It can
be reduced by hydrogen to give free metal 330. A steel vessel containing 10 g H2 and 64 g
and water. 0.3192 g of metal oxide requires O2 was taken and mixture was allowed to
6 mg of hydrogen for complete reduction. react. The maximum moles of H2 O produced
The atomic mass of metal in amu is in the reaction is
1) 135.6 1) 8
2) 271.2 2) 7
3) 180.6 3) 4
4) 319.2 4) 5

324. An element E has following three isotopes 331. 50 ml of 1N HCl, 50 ml of N

100 H2 SO4 and 50

E : 80%, 99 E : 16%, 101 E : 4%. N
2

The average atomic mass of element E is ml of 3 HNO3 are mixed together and the
approximately volume made to one litre. The normality of
1) 97.9 the resulting solution is approximately
2) 96.8 1) N
10

3) 98.8 2) N

4) 99.9 15

3) N

325. Which concentration term is independent of 4) N

temperature? 5

1) Molarity
2) Mole fraction 332. A : Mass percent of glucose whose 2 g is
3) (w/v)% dissolved in 18 g of water will be 10%.
R : Mass percent is mass of component in
4) Normality grams per 100 g mass of solvent.
1) Both Assertion & Reason are true and
326. Minimum volume of O2 at STP required for the reason is the correct explanation of
the complete combustion of 22.0 g of C3 H8 the assertion
is 2) Both Assertion & Reason are true but
1) 11.2 L the reason is not the correct
explanation of the assertion
2) 22.4 L
3) Assertion is true statement but Reason
3) 44.8 L is false
4) 56 L 4) Both Assertion and Reason are false
statements
327. 111 g sample of a mixture of calcium
chloride and sodium chloride is treated with 333. If mole fraction of glucose in its aqueous
Na2 CO3 to precipitate calcium as calcium solution is 0.05 then molality of this solution
carbonate. This calcium carbonate on will be
heating gives 14 g of CaO. Percentage of 1) 2.92 m
NaCl present in original mixture is
2) 9.26 m
1) 70%
3) 4.63 m
2) 65%
4) 1.21 m
3) 80%
4) 75%

26
chemistry 14

334. Two elements A and B combine to form two 340. A mixture is made by mixing equal mass of
compounds A2 B and A2 B5 . If 0.2 mol of A2 B CH4 and O2 . The mole fraction of CH4 in the
weighs 8.8 g and 0.1 mol of A2 B5 weighs mixture is
10.8 g, then atomic weight of A and B 1) 1
respectively are 5

1) 16 u, 12 u 2) 2

2) 12 u, 16 u 3) 1

3) 14 u, 16 u 2

4) 1
4) 16 u, 14 u 3

335. If the equivalent weight of metal is 12, then 341. Correct decreasing order of mass of NaOH
the equivalent weight of its oxide will be in the following solutions is
1) 16 a. 50 g of 40% (w/w) NaOH
2) 28 b. 50 ml of 50% (w/v) NaOH
c. 50 g of 15 M NaOH with density 1 g mL–1
3) 20
1) a > b > c
4) 24
2) c > b > a
3) b > c > a
336. Which concentration term is independent of
temperature? 4) b > a > c
1) Molarity
2) Mole fraction 342. The normality of a 500 ml Ca(OH)2 solution
3) (w/v)% which contains 9.033 × 1022 hydroxide ions,
4) Normality is
1) 1 N
4

337. A piece of iron when exposed to air 2) 3

N
increases its weight by 8.56%. The 10

percentage of iron that has been rusted is 3) 1

N
5

1) 42.8% 4) 3
N
2) 20% 7

3) 10%
4) 25% 343. Give below are two statements, one is
labelled as Assertion (A) and other is
labelled as Reason (R).
338. One AVOGRAM is numerically equal to Assertion (A) : Equivalent mass of a base
(Given, NA = Avogadro's number) Molecular mass
=
1) NA Basicity
Reason (R) : Basicity is the number of
2) 1

√NA replaceable OH– ions in one molecule of the

base.
3) 1

N
A
In light of the above statements, choose the
−−
− correct answer from the options given below.
4) √NA
1) Both Assertion & Reason are true and
the reason is the correct explanation of
339. 32 g of methane is burnt in the presence of the assertion
32 g oxygen to give CO2 and H2 O. The 2) Both Assertion & Reason are true but
volume of CO2 obtained at S.T.P. is the reason is not the correct
explanation of the assertion
1) 11.2 L
3) Assertion is true statement but Reason
2) 22.4 L is false
3) 33.6 L 4) Both Assertion and Reason are false
4) 44.8 L statements

344. 3.01 × 1023 molecules of glucose are

present in 500 ml of solution. The molarity of
the solution is
1) 0.5 M
2) 1 M
3) 2 M
4) 1.5 M

27
chemistry 14

345. The mass of zinc required to produce 2.24 L 352. A biomolecule contains 0.2% Fe by mass.
of hydrogen gas at STP on treatment with The minimum molecular mass possible for
excess of dilute HCl is (Atomic mass of Zn = the biomolecule is (At. Mass of Fe = 56 u)
65.4 u) 1) 14000 u
1) 13.0 g 2) 28000 u
2) 6.54 g 3) 5600 u
3) 3.25 g 4) 2800 u
4) 19.54 g
353. Which of the following is a unitless quantity?
346. 0.5 g NaNO3 on heating gives 44.8 ml of O2 1) Mole fraction
at STP. The percentage purity of NaNO3 is 2) Molarity
(molar mass of NaNO3 = 85 g/mol)
3) Molality
1) 50%
4) (w/V)%
2) 68%
3) 76%
354. An organic compound contains carbon,
4) 36% hydrogen and oxygen. Its elemental analysis
gave C, 40% and H, 6.67% by mass. The
347. 0.00016 can be written in scientific notation empirical formula of the compound will be
as 1) CHO
1) 0.16 × 10–3 2) CH2 O
2) 1.6 × 10–4 3) CH2 O2
3) 16.0 × 10–5 4) CH4 O

4) 160 × 10–6
355. Which of the following term is unitless?
1) Molarity
348. A gaseous oxide contains 28% nitrogen as
well as one nitrogen atom per molecule. The 2) Molality
density of gaseous oxide relative to oxygen 3) Mole fraction
will be 4) Normality
1) 1.44
2) 0.64 356. The molecular mass of CaSO4 .2H2 O is (At.
3) 1.56 mass of Ca = 40, S = 32)
4) 2.2 1) 190 u
2) 240 u
349. Which of the following values possess 3) 172 u
maximum number of significant zeros? 4) 120 u
1) 0.00007
2) 0.0070
357. By Burning 10 g of hydrogen with 90 g of
3) 20.000 oxygen, the maximum mass of water formed
4) 0.800 is
1) 40 g
350. The conclusion that “in all physical and 2) 80 g
chemical changes, there is no net change in 3) 90 g
mass during the process”, leads to 4) 100 g
1) Law of definite proportions
2) Law of multiple proportions
358. The number of fundamental particles
3) Avogadro’ law –2
present in 16 g of O2 .
4) Law of conservation of mass
1) 25 NA
2) 50 NA
351. SI unit of density is
1) g cm–3 3) 5.0 NA

2) kg m–3 4) 2.5 NA

3) kg cm–3
4) g m–3

28
chemistry 14

359. Mass of 4 atoms of He in gram is 366. The concentration term which depends on
1) 16 temperature is
2) 16 1) Mole fraction
1.66×10
–24
2) Molality
3) 16 × 1.66 3) ( w )%
w
4) 16 × 1.66 × 10–24
4) Molarity

360. Weight of lime (CaO) that can be prepared

367. A : One volume of N2 require three volumes
by heating 100 kg of 90% (w/w) pure
limestone (CaCO3 ) is of hydrogen to form two volumes of
ammonia gas.
1) 50.4 kg R : Equal volume of all gases under similar
2) 25.2 kg condition of temperature and pressure
3) 56 kg contain equal number of molecules.
4) 28 kg 1) Both Assertion & Reason are true and
the reason is the correct explanation of
the assertion
361. Law of conservation of mass does not hold 2) Both Assertion & Reason are true but
good for the reason is not the correct
1) Exothermic reactions explanation of the assertion
2) Neutralisation reactions 3) Assertion is true statement but Reason
3) Nuclear reactions is false
4) Endothermic reactions 4) Both Assertion and Reason are false
statements

362. How many atoms are present in 200 u of

He? 368. Which of the following is a unitless quantity?
1) 25 1) Normality
2) 50 2) Molality
3) 100 3) Molarity
4) 50 NA 4) Mole fraction

363. 10 L Hydrogen gas and 20 L Chlorine gas 369. Law of conservation of mass is not
combine in suitable conditions to produce applicable in
hydrogen chloride gas. The composition of 1) Physical change
resultant gaseous mixture is 2) Chemical reaction
1) 5 L Chlorine and 25 L Hydrogen 3) Nuclear reaction
Chloride
4) Both (1) & (3)
2) 5 L Hydrogen, 10 L Chlorine and 10 L
Hydrogen Chloride
3) 10 L Hydrogen and 20 L Hydrogen 370. A : Molarity and molality for very dilute
Chloride aqueous solution is approximately equal.
R : Molarity is number of moles of solute
4) 10 L Chlorine and 20 L Hydrogen present in 1 litre of solution while molality is
Chloride number of moles of solute present in 1 kg of
solvent.
364. The minimum energy required to remove an 1) Both Assertion & Reason are true and
electron from the ground state of Li2+ is the reason is the correct explanation of
the assertion
1) 122.4 eV
2) Both Assertion & Reason are true but
2) 40.8 eV the reason is not the correct
3) 54.4 eV explanation of the assertion
4) 13.6 eV 3) Assertion is true statement but Reason
is false
365. Law of conservation of mass is not 4) Both Assertion and Reason are false
applicable for statements
1) Phase transformation
2) Combustion reaction
3) Neutralisation reaction
4) Nuclear fission

29
chemistry 14

371. The weight of one molecule of a compound 377. A : Significant figure are meaningful digits
C12 H22 O11 is which are known with certainty.
1) 342 g R : Exact numbers have infinite significant
figures.
2) 342 u
1) Both Assertion & Reason are true and
3) 342 NA u the reason is the correct explanation of
4) 342 NA g the assertion
2) Both Assertion & Reason are true but
the reason is not the correct
372. A : Atoms can neither be created nor explanation of the assertion
destroyed.
R : Under similar condition of temperature 3) Assertion is true statement but Reason
and pressure, equal volume of gases is false
contain equal number of atoms. 4) Both Assertion and Reason are false
1) Both Assertion & Reason are true and statements
the reason is the correct explanation of
the assertion 378. The incorrect statement according to
2) Both Assertion & Reason are true but Dalton's atomic theory is
the reason is not the correct 1) Matter is made up of externally small,
explanation of the assertion indivisible particles called atoms
3) Assertion is true statement but Reason 2) Atoms of a given elements are identical
is false in all respect
4) Both Assertion and Reason are false 3) Atoms of different elements are
statements different in all respects
4) Atoms can be created as well as
373. A solution is 4 ppm by weight of solute. The destroyed in a chemical reaction
weight percentage of solute in this solution
is
379. If mole fraction of glucose in its aqueous
1) 4 × 10–4 % solution is 0.02 then molality of this solution
2) 4 % is
3) 4 × 104 % 1) 1.1 m
4) 4 × 10–2 % 2) 0.02 m
3) 4.5 m
4) 2.7 m
374. How many moles of ethane are required to
produce 44 g of CO2 (g), after the
combustion of ethane? 380. Give below are two statements, one is
1) 2 labelled as Assertion (A) and other is
labelled as Reason (R).
2) 1 Assertion (A) : Molecular weight of a
3) 0.5 compound is 60 if it’s vapour density is 30.
Molecular weight
4) 0.25 Reason (R) : Vapour density = 2

In light of the above statements, choose the

375. The available nitrogen in a 100 kg urea correct answer from the options given below.
sample is found to be 35% (by weight). The 1) Both Assertion & Reason are true and
actual urea content in the sample is the reason is the correct explanation of
1) 80 kg the assertion
2) 70 kg 2) Both Assertion & Reason are true but
3) 60 kg the reason is not the correct
explanation of the assertion
4) 75 kg
3) Assertion is true statement but Reason
is false
376. Mass of single carbon-12 atom is equal to 4) Both Assertion and Reason are false
1) 12 amu statements
2) 12 g
3) 1/NA amu 381. Mass percentage of hydrogen in natural
4) 1.66 × 10–27 kg sample of water and synthetic sample is
11.11% each. This supports
1) Law of conservation of mass
2) Law of definite proportion
3) Law of multiple proportion
4) Avogadro's law

30
chemistry 14

382. Copper has two naturally occurring isotopes 386. At same temperature and pressure 3 L of N2
63
Cu and 65 Cu. If the average atomic mass and 2 L of H2 will form
of copper is 63.546 u, then natural N2 (g) + 3H2 (g) → 2N H3 (g)
abundance of lighter isotope of Cu will be
1) 1
L of NH3
1) 46.4% 3

2) 27.3% 2) 4
L of NH3
3

3) 54.2%
3) 3
L of NH3
4) 72.7% 2

4) 2
L of NH3
3

383. Give below are two statements, one is

labelled as Assertion (A) and other is
labelled as Reason (R). 387. Number of atoms present in 120 a.m.u. of Ca
Assertion (A) : Boiling point of water is 212° is
on Fahrenheit scale. 1) 3 NA
Reason (R) : Freezing point of water is 0°C. 2) 6 NA
In light of the above statements, choose the
correct answer from the options given below. 3) 3
1) Both Assertion & Reason are true and 4) 6
the reason is the correct explanation of
the assertion 388. The correct scientific notation for 231.508 is
2) Both Assertion & Reason are true but 1) 2.31508 × 102
the reason is not the correct
explanation of the assertion 2) 2.31508 × 10–2
3) Assertion is true statement but Reason 3) 0.231508 × 103
is false
4) 0.231508 × 10–3
4) Both Assertion and Reason are false
statements
389. Number of valence electrons present in 16
mg of oxygen atoms is
384. Given below are two statements, one is
labelled as Assertion A and the other is 1) 6.02 × 1021
labelled as Reason (R). 2) 6.02 × 1020
Assertion (A) : The mass of the products
formed in a reaction depends upon the 3) 3.6 × 1021
limiting reactant. 4) 3.6 × 1020
Reason (R) : Limiting reactant reacts
completely in the reaction.
In light of the above statements, choose the 390. The oxide of an element have molecular
correct answer from the options given below. formula M2 O3 . If the equivalent mass of the
1) Both Assertion & Reason are true and metal M in its oxide is 9, then the atomic
the reason is the correct explanation of mass of the metal will be
the assertion 1) 27
2) Both Assertion & Reason are true but 2) 9
the reason is not the correct 3) 45
explanation of the assertion
4) 18
3) Assertion is true but Reason is false
4) Both Assertion and Reason are false
statements 391. The mass of 80% pure CaCO3 required to
produce 11.2 L of CO2 at STP.
CaCO3(s) → CaO(s) + CO2(g)
385. A mixture of 2.3 g formic acid and 4.5 g
oxalic acid is treated with conc. H2 SO4 . The 1) 50 g
evolved gaseous mixture is passed through 2) 40 g
KOH pellets. Weight (in g) of the remaining 3) 60 g
gaseous product at STP will be
4) 62.5 g
1) 1.4
2) 3.0
3) 4.4
4) 2.8

31
chemistry 14

392. Consider the following statements about 398. The pair of compounds in which law of
Dalton’s atomic theory multiple proportions is not applicable, is
a. All atoms of a given element have 1) SO2 and SO3
identical mass
b. Matter consists of indivisible atoms 2) H2 O and H2 S
c. Atoms are neither created nor destroyed 3) CO and CO2
in a chemical reaction
4) NO2 and NO
Which of the following is/are postulates of
Dalton's atomic Theory?
1) a and b only 399. If mass percentage of hydrogen in a
2) a and c only hydrocarbon is 14.29% then the empirical
formula of the compound will be
3) a, b and c
1) CH3
4) a only
2) C2 H3

393. The molecular mass of NaOH is (Atomic wt. 3) CH4

of Na = 23 u, O = 16 u, H = 1 u) 4) CH2
1) 37 u
2) 35 u 400. 6.022 × 1023 atoms of oxygen are present in
3) 40 u
1) 1 mole of O
4) 42 u
2) 1 mole of O2
3) 1 mole of O3
394. A : Empirical formula of ethane is CH3 .
R : Empirical formula gives the simplest 4) All of these
whole number ratio of various elements
present in a molecule. 401. Among the following concentration terms,
In the light of above statements, select the choose the one(s) which remain(s)
correct option. unaffected with temperature change.
1) Both (A) and (R) are true and (R) is the 1) Molarity
correct explanation of (A).
2) Normality
2) Both (A) and (R) are true but (R) is not
3) Molality
the correct explanation of (A).
4) (w/v)%
3) (A) is true statement but (R) is false.
4) Both (A) and (R) are false statements.
402. The temperature at which molality of pure
water is equal to its molarity is
395. For the chemical reaction 1) 273 K
X + 2Y ⟶ Z
2) 277 K
4 mole of X and 6 mole of Y will produce,
maximum 3) 298 K
1) 4 mole of Z 4) 300 K
2) 3 mole of Z
3) 8 mole of Z 403. If the mass percentage of magnesium in a
4) 12 mole of Z biomolecule is 0.04%, then the minimum
molecular weight of biomolecule is
1) 6000
396. The mass percentage of sulphur in sulphuric
acid is 2) 60000
1) 32.65% 3) 30000
2) 54.32% 4) 12000
3) 15.68%
4) 39.75% 404. The total number of significant figures in the
11.86×2.5
result of 0.09
is
397. How much Na can be obtained from 100 g of 1) 1
pure Na3 PO4 ? [Na = 23, P = 31, O = 16] 2) 2
1) 69 g 3) 4
2) 11.3 g 4) 3
3) 42 g
4) 33 g

32
chemistry 14

405. Which among the following is an elementary 412. If true value of a result is 4.75 m and
molecule? experimental values are 4.74 m and 4.76 m,
1) H2 then these values are
1) Accurate only
2) H2 O
2) Precise only
3) C
3) Accurate and precise both
4) NaCl
4) Neither accurate nor precise

406. In which of the following pairs law of multiple

proportion is applicable? 413. An example of homogeneous mixture is
1) C6 H6 and C2 H4 1) Copper
2) CO2 and SO2 2) Oil and water
3) Alloy
3) KOH and NaOH
4) Carbon dioxide
4) O2 and O3

414. Correct scientific notation is

407. Which of the following is the incorrect
1) 0.000473
match?
Prefix Multiple 2) 0.473 × 10–3
(1) Milli 10–3 3) 4.73 × 10–4
(2) Pico 10–12 4) 473 × 10–6
(3) Nano 10–9
(4) Micro 10–4 415. Natural and synthetic sample of cupric
carbonate both contain 51.35% of copper.
1) (1) This data is in accordance with
2) (2) 1) Law of conservation of mass
3) (3) 2) Law of constant proportion
4) (4) 3) Law of multiple proportion
4) Gay-Lussac’s law
408. A sample of CaCO3 has Ca = 40%, C = 12%
and O = 48%. If the law of constant 416. Which among the following is not a pure
proportion is true, then the mass of O in 15 g substance?
CaCO3 from another source will be
1) Air
1) 5g 2) Copper
2) 7.2 g 3) Gold
3) 6g 4) Glucose
4) 4.8 g

417. The pair of compounds in which law of

409. The correct scientific notation for 231.508 is multiple proportions is not applicable is
1) 2.31508 × 102 1) H2 O and H2 O2
2) 2.31508 × 10–2 2) SO2 and SO3
3) 0.231508 × 103 3) NO2 and NH3
4) 0.231508 × 10–3 4) CO2 and CO

410. Number of significant figures in 100 pens is 418. Number of significant figures in 98.020500
1) 1 1) 8
2) 2 2) 2
3) 3 3) 6
4) ∞ 4) 4

411. S.I. unit of density is 419. Mole of O2 required to produce 160 g SO3
1) kg m–3 from SO2 is
2) kg L–1 1) 0.5
2) 1
3) g L–1
3) 2.5
4) g dm–3
4) 2

33
chemistry 14

420. The ratio of molecular formula mass to 425. 20 ml of O2 and 50 ml of H2 are taken in a
empirical formula mass of acetic acid is vessel and sparked till the reaction is
1) 1 : 2 completed to form H2 O(l). Assuming
2) 2 : 1 temperature and pressure constant, the
reduction in volume of gases after reaction
3) 2 : 3
is
4) 3 : 2 1) 50 ml
2) 60 ml
421. 1 L volume is equivalent to 3) 70 ml
1) 1 dm3
4) 10 ml
2) 100 mL
3) 100 cm3 426. 2 mole of ammonia reacts with 5 mole of
4) 1000 m3 oxygen to form nitric oxide and water. The
moles of water and nitric oxide respectively
produced during the reaction are
422. Statement I : The maximum number of 1) 3 mol of NO and 4 mol of H2 O
electrons those can be accommodated in a
3p orbital is 6. 2) 4 mol of NO and 2 mol of H2 O
Statement II : The electron density in a 3) 2 mol of NO and 3 mol of H2 O
dx −y
2 2orbital is maximum along x and y 4) 2 mol of NO and 4 mol of H2 O
axes.
In the light of above statements, choose the
correct option 427. The mole fraction of solute in aqueous
1) Both the statements I and II are correct solution containing 42.5% (w/w) NaNO3 is
2) Both the statements I and II are 1) 0.251
incorrect 2) 0.053
3) Statement I is correct and statement II is 3) 0.215
incorrect 4) 0.135
4) Statement I is incorrect and statement II
is correct
428. Which of the following possess highest
mass?
423. A gaseous mixture contains H2 and CO2 1) 22.4 L H2 at STP
gases in the ratio of 1 : 11 (w/w). The ratio of
number of atoms of H2 to CO2 in the mixture 2) 5 g of H2
is 3) 0.3 mole of H2
1) 4 4) 1.204 × 1024 molecules of H2
3

2) 2

5
429. Volume of CO2 obtained at STP by the
3) 1

3 complete decomposition of 10 g of lime

4) 2 stone (90% pure) is nearly
7
1) 1.7 litre
2) 3.8 litre
424. What weight of CaCO3 must be 3) 2 litre
decomposed to produce the sufficient 4) 2.6 litre
quantity of carbon dioxide to convert 21.2 kg
of Na2 CO3 completely into NaHCO3 . [Atomic
mass of Na = 23, Ca = 40] 430. The percentage loss of mass by Na2 SO4 ·10
CaCO3 → CaO + CO2 H2 O to become anhydrous is
Na2 CO3 + CO2 + H2 O → 2NaHCO3 1) 72.5%
1) 100 kg 2) 45.2%
2) 20 kg 3) 55.9%
3) 120 kg 4) 65.2%
4) 30 kg

34
chemistry 14

431. 50 ml of 1 N NaOH is mixed with 150 ml of 2 438. 28 g of nitrogen gas has same number of
N Ca(OH)2 . The molarity of OH– ions in the atoms as in
resulting solution will be [Consider complete 1) 32 g of oxygen gas
dissociation of NaOH and Ca(OH)2 ] 2) 28 g of carbon monoxide
1) 2.5 M 3) 48 g of ozone gas
2) 1.75 M 4) Both (1) and (2)
3) 1.25 M
4) 1.50 M 439. Which of the following expressions is
correct? [n = Number of moles of the gas, NA
432. If vapour density of a gas is 44 then the = Avogadro constant, m = Mass of one
volume occupied by the 0.88 g of gas at STP molecule of gas, N = Number of molecules
is of the gas]
1) 2240 ml 1) n = mNA
2) 112 ml 2) n = m

NA

3) 224 ml 3) NA = nN
4) 1120 ml 4) N = nNA

433. 1 kg of coal is burnt in 640 g of oxygen in a

closed vessel. If the percentage of carbon 440. An enzyme contains 0.01% Mg by mass.
and sulphur in the coal sample is 12% and The minimum molecular mass of enzyme
10% respectively and rest of the coal content will be
does not burn, then the ratio of the amount of 1) 2.4 × 103 u
CO2 produced to that of SO2 produced is 2) 1.2 × 105 u
(Consider SO2 will not oxidise further)
3) 2.4 × 105 u
1) 11 : 8
4) 3.6 × 106 u
2) 8 : 11
3) 5 : 11
4) 11 : 5 441. 0.5 g NaNO3 on heating gives 44.8 ml of O2
at STP. The percentage purity of NaNO3 is
(molar mass of NaNO3 = 85 g/mol)
434. An organic compound containing C, H and
O gave the following analysis C = 40%, O = 1) 50%
53.33%. Its possible molecular formula is 2) 68%
1) C2 H4 O2 3) 76%
2) C2 H4 O 4) 36%
3) C2 H6 O
4) C2 H6 O2 442. Minimum number of atoms are present in
1) 4 g of H2

435. IUPAC official name of Unnilunium is 2) 50 g of CaCO3

1) Mendelevium 3) 40 g of SO3
2) Lawrencium 4) 8 g of CH4
3) Nobelium
4) Bohrium 443. If mole fraction of ethanol (molar mass = 46
g/mole) in its aqueous solution is 0.2 then
436. The molality of aqueous solution of urea in molality of ethanol in the solution is
which mole fraction of urea is 0.1, is 1) 13.89 m
1) 6.17 m 2) 12.52 m
2) 5.24 m 3) 15.11 m
3) 6.98 m 4) 22.22 m
4) 5.78 m
444. The formula mass of sodium sulphate is
437. For the reaction, A + 2 B → C, 5 moles of A 1) 142 u
and 8 moles of B will produce maximum 2) 58.5 u
1) 5 moles of C 3) 50 u
2) 4 moles of C 4) 48 u
3) 8 moles of C
4) 12 moles of C

35
chemistry 14

445. Two isotopes of an element have atomic 451. The spectrum of Li++ is expected to be
masses M and (M + 1) respectively. If the similar to that of
average atomic mass of the element is (M + 1) He
0.5), then the ratio of % occurrence of M and
(M + 1) is 2) He+
1) 1 : 1 3) Be++
2) 4 : 1 4) Na+
3) 3 : 2
4) 2 : 1
452. A : For the maximum yield of ammonia, the
total amount of mixture N2 and H2 should be
446. The atomic weights of two elements A and B taken in 3 : 1 mole ratio.
are 16 and 48 respectively. If x g of A R : The yield of product becomes minimum
contains y atoms, then how many atoms are when the reactants are taken in their
present in 2x g of B? stoichiometric amount.
1) 2y 1) Both Assertion & Reason are true and
2) 3y the reason is the correct explanation of
the assertion
3) 2 y
3 2) Both Assertion & Reason are true but
4) 3
y
the reason is not the correct
2 explanation of the assertion
3) Assertion is true statement but Reason
447. A silver coin weighing 2.4 g is dissolved in is false
excess HNO3 and then further treated with 4) Both Assertion and Reason are false
HCl solution in excess. The weight of AgCl statements
formed is 2.87 g. The percentage of silver in
the coin is (Atomic weight of Ag = 108, Cl =
35.5) 453. A : The mass of a substance is constant
whereas its weight may vary from on place
1) 85%
to another.
2) 88% R : Weight changes with change in gravity.
3) 92% 1) Both Assertion & Reason are true and
4) 90% the reason is the correct explanation of
the assertion
2) Both Assertion & Reason are true but
448. If the mole fraction of acetone in ethanol is
the reason is not the correct
0.2 then molality of acetone in ethanol will
explanation of the assertion
be
1) 5.4 m 3) Assertion is true statement but Reason
is false
2) 6.8 m
4) Both Assertion and Reason are false
3) 4.5 m statements
4) 7.2 m
454. A : If monochromatic light of frequency v
449. If the value of Avogadro number is 6.023 × greater than Threshold frequency is incident
1023 mol–1 and the value of Boltzmann on a metal surface then photoelectrons are
constant is 1.38 × 10–23 JK–1 then the ejected from the metal surface.
number of significant digits in the calculated R : The kinetic energies of these ejected
value of the universal gas constant is electrons increase with the increase of
frequency of the light used.
1) Four
1) Both Assertion & Reason are true and
2) Two the reason is the correct explanation of
3) Three the assertion
4) Infinite 2) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
450. If 0.1 g atom of calcium is allowed to react
with 2 g molecule of oxygen then which 3) Assertion is true statement but Reason
among the following is correct for given is false
equation? 4) Both Assertion and Reason are false
2Ca(s) + O2 (g) ⟶ 2CaO(s) statements
1) 0.5 mole of oxygen remains in excess
2) Calcium is the limiting reagent
3) Oxygen is the limiting reagent
4) 0.02 moles of calcium oxide are formed

36
chemistry 14

455. What is the empirical formula of hydrocarbon 461. Which among the following contains
whose 3.6 g is burnt to produce 11.9 g of minimum number of atoms?
CO2 and 3.25 g H2 O? 1) 34.2 g of sugar (C12 H22 O11 )
1) C2 H2 2) 16 g of methanol (CH3 OH)
2) C2 H4 3) 36 g of glucose (C6 H12 O6 )
3) C3 H8 4) 20 g of urea (NH2 CONH2 )
4) C3 H4
462. A : Number of atoms present in a molecule is
456. How much water is to be added to dilute 50 called its atomicity.
mL of 5 N HCl to make it seminormal? R : Atomicity of methane is 5.
1) 500 mL 1) Both Assertion & Reason are true and
2) 350 mL the reason is the correct explanation of
the assertion
3) 450 mL
2) Both Assertion & Reason are true but
4) 550 mL the reason is not the correct
explanation of the assertion
457. Equal masses of S2 , S4 and S8 are taken. 3) Assertion is true statement but Reason
Highest number of sulphur atoms are is false
present in 4) Both Assertion and Reason are false
1) S2 statements
2) S4
3) S8 463. Number of oxygen molecules present in 1
equivalent of oxygen are (NA : Avogadro's
4) All have equal number of atoms
number)
1) 2 NA
458. A : When 200 mL of 0.5 M H2 SO4 is mixed
2) 3 NA
with 200 mL 1 M NaOH, then the resulting
solution will be neutral. 3) NA

R : Before mixing number of moles of H2 SO4 2

are equal to that of NaOH in above 4) NA

4
statement.
1) Both Assertion & Reason are true and
the reason is the correct explanation of 464. A : Second is SI unit of time.
the assertion R : Infinite number of significant figures are
present in 60 s.
2) Both Assertion & Reason are true but
the reason is not the correct 1) Both Assertion & Reason are true and
explanation of the assertion the reason is the correct explanation of
the assertion
3) Assertion is true statement but Reason
is false 2) Both Assertion & Reason are true but
the reason is not the correct
4) Both Assertion and Reason are false explanation of the assertion
statements
3) Assertion is true statement but Reason
is false
459. If in a metal oxide, oxygen is present 16% by 4) Both Assertion and Reason are false
mass then equivalent weight of metal oxide statements
is
1) 42
465. A 40 mL mixture of CO, CH4 and He gases
2) 84
is exploded by an electric discharge at room
3) 50 temperature with excess of oxygen. The
4) 56 volume contraction is found to be 26 mL. A
further contraction of 28 mL occurs when the
residual gas is treated with KOH. The
460. Equal volume of 20% (
v
) of HCl is mixed composition of the original mixture in terms
v
v
with 20% ( v ) NaOH solution. If density of of volume percentage of CO(g), CH4 (g), and
pure NaOH solution is 2.5 times that of pure He(g) is respectively
HCl solution then the resultant solution will 1) 50, 30, 20
be 2) 50, 20, 30
1) Alkaline 3) 30, 20, 50
2) Weakly acidic 4) 50, 40, 10
3) Neutral
4) Strongly acidic

37
chemistry 14

466. Which of the following statements represent 471. 1.67 × 10–27 kg represents
Avogadro's law? 1) 1 amu
1) Equal volumes of all gases contain
2) Mass of electron
equal number of molecules under
similar conditions of pressure and 3) Mass of α-particle
temperature 4) Mass of carbon atom
2) Molar mass = 2 × vapour density (for
gas phase) 472. For the complete neutralisation of one gram
3) The volume of 1 mole of gas at NTP is mixture of Na2 CO3 and NaHCO3 , y
22.4 L equivalents of HCl are required. How many
4) All of these equivalents of HCl are required for complete
neutralisation of residue obtained by strong
heating of one gram given mixture?
467. If Avogadro number (NA) is changed from
1) y equivalents
6.022 × 1023 mol–1 to 6.022 × 1021 mol–1 ,
then following will be changed 2) 2y equivalents
1) Definition of mass in units of gram 3) y equivalents
2

2) Relative ratio of elements in a 4) 3y

compound 2
equivalents

3) Mass of one mole of carbon

4) Ratio of chemical species to each other 473. Three isotopes of an element having mass
in a balanced equation number x, x + 1, x + 2, show atomic mass of
element of x + 0.5.
Ratio of their abundance in the order x, x +
468. Which of the following is not affected by the 1, x + 2 can be
temperature?
1) 1 : 2 : 3
1) Molality
2) 1 : 2 : 2
2) Normality
3) 4 : 1 : 1
3) Mole fraction
4) 1 : 3 : 4
4) Both (1) and (3)

474. Sulphate of a metal contains 40% of metal

469. 15 moles A, 18 moles of B and 20 moles of by mass. Equivalent wt. of metal will be
C reacted together according to the reaction
1) 16
A + 2B + 4C ⟶ AB2 C4 . The moles of
AB2 C4 formed is 2) 32
1) 5 3) 35
2) 9 4) 64
3) 15
4) 20 475. Propane occupies 112 L volume at STP.
Calculate the number of molecules removed
if final volume of propane is 22.4 L.
470. Find out the correct matching of columns. 1) 3.011 × 1024
(I) Efflorescence (i) Mole
2) 12.044 × 1023
1
mass of C-12
(II) Alloy (ii) 12 3) 24.08 × 1023
atom
4) 18.06 × 1023
Tendency to lose
(III) One Dalton (iii) water of
crystallisation 476. Phosphorous forms two chlorides PCl3 and
Amount of Homogeneous PCl5 . Which law can be proved by the
(IV) (iv)
substance mixture weights of P and Cl?
(I) (II) (III) (IV) 1) Law of conservation of mass
(1) (iv) (iii) (ii) (i) 2) Law of constant composition
(2) (ii) (iii) (iv) (i) 3) Avogadro’s law
(3) (iii) (iv) (ii) (i) 4) Law of multiple proportions
(4) (i) (ii) (iv) (iii)
1) (1)
2) (2)
3) (3)
4) (4)

38
chemistry 14

477. Which of the following is least quantity? 483. A : Normality and molarity of a given solution
1) 14 × 10–3 mg are always different.
R : Only the aqueous solution of a polybasic
2) 1.5 × 10–4 g acid can have same molarity and normality.
3) 1.98 × 10–5 kg 1) Both Assertion & Reason are true and
the reason is the correct explanation of
4) 1.2 × 103 μg
the assertion
2) Both Assertion & Reason are true but
478. An oxide of nitrogen contains 69.5% oxygen, the reason is not the correct
empirical formula of oxide is explanation of the assertion
1) N2 O 3) Assertion is true statement but Reason
2) N2 O3 is false
4) Both Assertion and Reason are false
3) NO2 statements
4) N2 O5
484. Possible number of CO2 molecules if
479. Which has maximum number of atoms? oxygen exist in three isotopic forms (O16 ,
1) 4 g H2 O17 , O18 ) and carbon exists in two isotopic
2) 36 g H2 O forms (C12 , C13 ) will be
3) 44 g CO2 1) 3
4) 50 g CaCO3 2) 6
3) 12
4) 18
480. Number of gram atom in 9.6 g of oxygen
atoms is
1) 0.6 485. Which among the following is an incorrect
2) 0.3 statement?
1) Avogadro number = 6.022 × 1022
3) 0.6 NA
−
−−−
4) 0.3 NA 2) 3RT
Root mean square speed = √
M

3) The average speed of the gas

481. 4 kg of 75% pure limestone is reacted as molecules can be calculated by the
follows CaCO3 + 2HCl ⟶ CaCl2 + CO2 + 8RT
1/2

H2 O, volume of CO2 produced at STP is formula ( πM

)

1) 6.72 L 4) Total kinetic energy for one mole of gas

2) 672 L =
3
RT
2
3) 22.4 L
4) 448 L
486. Which of the following species has highest
number of molecules?
482. A : Combustion of one mole of methane 1) 2 g H2
gives 44 g of CO2 and 36 g of water.
2) 6 g I2
R : For the combustion of one mole
methane, five moles of O2 is consumed. 3) 18 g N2
1) Both Assertion & Reason are true and 4) 16 g O2
the reason is the correct explanation of
the assertion
487. The molarity of glucose solution whose
2) Both Assertion & Reason are true but concentration is approximately 180 mg/100
the reason is not the correct ml is
explanation of the assertion
1) 1 × 10–3 M
3) Assertion is true statement but Reason
is false 2) 5 M
4) Both Assertion and Reason are false 3) 1 × 10–2 M
statements 4) 5 × 10–2 M

39
chemistry 14

488. 20 mL of gaseous hydrocarbon on complete 493. A : Law of conservation of mass is not valid
combustion gives 80 mL of CO2 (g) and 100 for nuclear fission, fusion and disintegration.
mL of H2 O(vap). The hydrocarbon is R : According to law of conservation of mass,
mass is neither created nor destroyed in a
1) C8 H16
reaction.
2) C5 H10 1) Both Assertion & Reason are true and
3) C4 H8 the reason is the correct explanation of
the assertion
4) C4 H10
2) Both Assertion & Reason are true but
the reason is not the correct
489. Correct statement for the given chemical explanation of the assertion
reaction is 3) Assertion is true statement but Reason
2Al(s) + 6HCl(aq.) ⟶ 2Al2+ (aq.) + 6Cl– is false
(aq) + 3H2 (g) 4) Both Assertion and Reason are false
1) 11.2 L H2 (g) at STP is produced for statements
every mole of HCl(aq.) consumed
2) 17.2 L H2 (g) at STP is produced for 494. A : 1 g O2 and 1 g O3 contain equal number
every mole of HCl(aq) consumed of atoms.
3) 33.6 L H2 (g) is produced regardless of R : Mass of 1 mole atom is equal to gram
temperature and pressure for every atomic mass.
mole Al that reacts 1) Both Assertion & Reason are true and
4) 6 L HCl(aq.) is consumed for every 3L the reason is the correct explanation of
H2 (g) produced the assertion
2) Both Assertion & Reason are true but
the reason is not the correct
490. Relative atomic mass of sodium is 23. Its explanation of the assertion
gram atomic mass is 3) Assertion is true statement but Reason
1) 23 amu is false
2) 23 g 4) Both Assertion and Reason are false
3) 23 × 1.66 × 10–24 g statements
4) 23 × 1.66 × 10–27 g
495. A : One amu is the mass of one atom of 12 C
isotope.
491. A : Equivalent weight of an element is
variable. R : Mass of one atom of 12 C is 12 g.
R : The valency of an element is variable. 1) Both Assertion & Reason are true and
1) Both Assertion & Reason are true and the reason is the correct explanation of
the reason is the correct explanation of the assertion.
the assertion 2) Both Assertion & Reason are true but
2) Both Assertion & Reason are true but the reason is not the correct
the reason is not the correct explanation of the assertion.
explanation of the assertion 3) Assertion is true statement but Reason
3) Assertion is true statement but Reason is false.
is false 4) Both Assertion and Reason are false
4) Both Assertion and Reason are false statements.
statements
496. A : Number of g-molecules of SO2 Cl2 in 13.5
492. A : 10–2 moles of H2 are present in 0.224 L g of sulfuryl chloride is 0.1.
R : One g-molecule of SO2 Cl2 contains 5
of H2 at STP.
mole molecules.
R : 22.4 L of H2 at STP contain 6.023 × 1023 1) Both Assertion & Reason are true and
gram molecules of H2 . the reason is the correct explanation of
1) Both Assertion & Reason are true and the assertion
the reason is the correct explanation of 2) Both Assertion & Reason are true but
the assertion the reason is not the correct
2) Both Assertion & Reason are true but explanation of the assertion
the reason is not the correct 3) Assertion is true statement but Reason
explanation of the assertion is false
3) Assertion is true statement but Reason 4) Both Assertion and Reason are false
is false statements
4) Both Assertion and Reason are false
statements

40
chemistry 14

497. The number of hydrogen atoms in 3.2 g of 504. The number of moles of electrons in 1.1 mg
CH4 is (NA = 6.0 × 1023 ) of electrons is (NA = 6.02 × 1023 mol–1 )
1) 1.2 × 1023 (mass of electron = 9.1 × 10–31 kg)
2) 4.8 × 1023 1) 3 mol
2) 1 mol
3) 3.6 × 1023
3) 4 mol
4) 2.4 × 1023
4) 2 mol

498. The volume of O2 required at STP for the 505. What volume of O2 at NTP is required to
complete combustion of 5.8 g of butane is burn 420 g of cyclopropane completely?
1) 14.56 L 1) 1120 L
2) 11.2 L 2) 2016 L
3) 5.6 L 3) 1008 L
4) 18.50 L 4) 2240 L

499. Mass of lime (CaO) that can be produced by 506. Heterogeneous mixture among the following
heating 10 kg of limestone (CaCO3 ) which is is/are
75% pure, is 1) Mixture of O2 (g) and N2 (g)
1) 5.6 kg
2) Sugar solution
2) 4.2 kg
3) Brass
3) 6.5 kg
4) Mixture of grains and pulses
4) 2.4 kg

507. Number of significant figures in 0.050 is

500. On heating 216 g of mercuric oxide, we get x
g of mercury and 16 g of oxygen. The value 1) 1
of x is 2) 2
[ Atomic mass of mercury is 200 u ] 3) 3
1) 300 g 4) 4
2) 200 g
3) 400 g 508. In which of the following formula mass is
4) 180 g prefered over molecular mass
1) H2 O
501. An element X has the following isotopic 2) NaCl
composition: 3) CH4
39 X : 1%, 41 X : 4%, 40 X : 95%.
4) NH3
The average atomic weight of the naturally
occurring element X is closest to
1) 42 u 509. Molecular mass of glucose C6 H12 O6
2) 40 u molecule is
3) 39 u 1) 80 g
4) 43 u 2) 180 u
3) 96 g
502. If 10 g of H2 reacts with 42 g of N2 , then 4) 96 u
identify the correct statement.
1) 1 mol of H2 is left in excess 510. Correct scientific notation is
2) N2 is the limiting reagent 1) 0.000473
3) 2.5 mol of NH3 is formed 2) 0.473 × 10–3
4) 0.5 mol of N2 is left in excess 3) 4.73 × 10–4
4) 473 × 10–6
503. Which of the following pair does not obey
law of multiple proportion?
1) CO and CO2
2) N2 O and NO
3) CH4 and CO2
4) SO2 and SO3

41
chemistry 14

511. One gram of metal hydroxide gives x g of the 517. If two different containers hold same number
metal oxide then equivalent weight of metal of moles of a gas at STP and volume of first
is container is 10 L then the volume of other
1) 8 container will be
1−x
1) 20 L
2) 17x
2) 5 L
1−x

3) 17x−8 3) 11.2 L
1−x
4) 10 L
4) 17x+8

1+x

518. The molar mass of a compound having

512. P and Q are two elements which form two vapour density 28 is
compounds P2 Q3 and PQ2 . If 0.15 mole of 1) 18 g/mole
P2 Q3 weighs 15.9 g and 0.15 mole of PQ2 2) 28 g/mole
weighs 9.3 g, then what are atomic mass of 3) 56 g/mole
P and Q? 4) 15 g/mole
1) P = 18 u
Q = 26 u
519. Among the following which value is not
2) P = 26 u
equal to 1 u?
Q = 18 u
1) 1.66 × 10–24 g
3) P = 62 u
Q = 36 u 2) 6.022 × 1023 atoms / ions / molecules
4) P = 31 u 3) Mass of a hydrogen atom
Q = 40 u 4) th
1
( ) mass of C – 12 atom
12

513. A hydrocarbon contains 80% carbon. What

is the empirical formula of the compound? 520. A compound of iodine (Atomic mass = 127)
1) CH2 and oxygen contains 40 g iodine and 17.6 g
2) C2 H3 oxygen. The formula of iodine oxide is
1) I2 O3
3) CH3
2) I2 O5
4) CH4
3) I2 O
4) I2 O7
514. Mass percentage of solute in a solution
prepared by adding 4 g of a substance in 16
g of water is 521. If the volume of acetic acid is 10 ml and its
1) 10% density is 0.6 g/cm3 , then the number of
2) 20% hydrogen atoms are
3) 25% 1) 0.6 NA
4) 50% 2) 0.4 NA
3) 10 NA
515. Mass percentage of sulphur in SO3 is 4) NA
(Atomic mass of sulphur = 32 u)
1) 25%
522. 68.4 g of Al2 (SO4 )3 is dissolved in enough
2) 60%
water to make 500 mL of solution. If
3) 50% Aluminium sulphate dissociates completely
4) 40% then molar concentration of Aluminium ions
(Al3+) and sulphate ions (SO2− 4
) in the

516. In which of the following pairs law of multiple solution are respectively (molar mass of
proportion is not applicable? Al2 (SO4 )3 = 342 g mol–1 )
1) CO and CO2 1) 0.8 M and 1.2 M
2) CH4 and C2 H6 2) 0.4 M and 1.2 M
3) NO and NO2 3) 0.8 M and 1.6 M
4) H2 and H2 O 4) 1.2 M and 0.8 M

42
chemistry 14

523. Two moles of oxygen gas at NTP occupy a 529. 100 ml of propane gas undergoes
volume of combustion with 100 ml of oxygen. The total
1) 44.8 Litres volume of the reaction mixture after the
combustion (All the measurements are taken
2) 11.2 Litres
at STP):
3) 22.4 Litres 1) 100 ml
4) 2 Litres 2) 220 ml
3) 140 ml
524. 5 g impure NaOH is completely neutralised 4) 130 ml
by one litre 0.1 M HCl. The percentage purity
of NaOH sample is
1) 80% 530. If total number of electrons in a sample of
2) 60% CO2 is 4.4× 1026 then total number of atoms
3) 40% present in the sample is
1) 6 × 1026
4) 20%
2) 6 × 1025
525. A chemist wants to prepare 0.35 M HCl. 3) 2 × 1026
Commercial HCl is 15.5 M. How many 4) 4.5 × 1026
millilitres of the commercial acid does the
chemist require to make up 1.8 L of the
dilute acid of 0.35 molarity? 531. 2 g of metal carbonate (M2 CO3 ) on
1) 4.06 ml treatment with dil. HCl produces 0.02 mole
2) 40.6 ml of CO2 . The molar mass (g mole–1 ) of metal
3) 112.3 ml carbonate is
4) 1.12 ml 1) 100
2) 50
526. At SATP, 1 mole of O2 occupies volume 24.7 3) 200
L. Volume occupied by 1 equivalent of O2 at 4) 115
SATP is [SATP : 25°C temperature and 1 atm
pressure] 532. 3 g of an oxide of metal is converted
1) 24.7 L completely into its chloride having mass 5 g.
2) 22.4 L Equivalent weight of metal will be
3) 12.35 L 1) 8
4) 6.175 L 2) 40
3) 35.55
527. How many moles of CH4 are required to 4) 33.25
produce 44 g CO2 (g) after combustion?
1) 1 mole 533. 100 ml of 20.8% (w/v) BaCl2 (aq) and 100
2) 2 mole mL of 14.7% (w/v) H2 SO4 (aq) solutions are
3) 0.5 mole mixed. Molarity of SO4 2– ions in the resulting
4) 1.5 mole solution is [Molar mass of BaCl2 = 208]
1) 0.5 M
528. Consider the following reactions. 2) 0.1 M
(i) H3 PO4 + NaOH → NaH2 PO4 + H2 O 3) Zero
(ii) H3 PO4 + Ba(OH)2 → Ba(HPO4 )2 + H2 O 4) 0.25 M
What will be the difference of equivalent
mass of H3 PO4 (Molar mass = M) in two
534. The percentage of nitrogen in 66% pure
reactions?
(NH4 )2 SO4 sample is
1) 3M
2
1) 14
2) M 2) 28
1
3) 32
3) M
4) 7
2

4) M
3

43
chemistry 14

535. The ratio of oxygen atoms in Ca3 (PO4 )2 and 542. Number of moles of oxygen atom present in
Na2 HPO3 containing same number of 0.1 mole of Al2 (SO4 )3 are
phosphorous atoms, respectively is 1) 12 mole
1) 3 : 4 2) 1.2 mole
2) 2 : 1 3) 0.4 mole
3) 4 : 3 4) 0.3 mole
4) 2 : 3
543. Which of the following is independent of
536. Number of electrons in 180 mg of glucose is temperature?
1) 9.6 × 10–2 NA 1) Percentage by mass
2) Mass fraction
2) 96 NA
3) Mole fraction
3) 9.6 × 10–3 NA
4) All of these
4) 96 × 10–19 NA
544. Which of the following does not change with
537. 11200 ml of water vapour, when condensed the dilution of solution?
to water at NTP, occupies an approximate 1) Density
volume of 2) Molarity
1) 11200 ml 3) Normality
2) 560 ml 4) Milliequivalent
3) 18 ml
4) 9 ml 545. Which of the following has maximum
number of molecules?
538. Hydrated sodium carbonate weighting 4 g, 1) 1 g N2
contains 2.52 g of water of crystallisation. 2) 1 g O2
The formula of hydrated salt is
3) 1 g O3
1) Na2 CO3 ·2H2 O
4) All have same molecules
2) Na2 CO3 ·8H2 O
3) Na2 CO3 ·10H2 O
546. Specific heat of metal is 0.24 cal/g. The
4) Na2 CO3 ·7H2 O metal is
1) Ca
539. 24 g of Mg will react completely with HCl to 2) Mg
give 3) Zn
1) 1 mole of H2 4) Al
2) 2 moles of H2
3) 0.5 mole of H2 547. Which of the following has highest average
4) 2.5 moles of H2 molecular mass?
1) Dry air
2) Moist air
540. From 44 mg CO2 , 1020 molecules are
3) Air contains CO impurity
removed calculate the moles of CO2 left
4) Air contains SO2 impurity
(Use NA = 6 × 1023 )
1) 4.25 × 10–4
548. A human body needs at least 1 × 10–2 mole
2) 8.3 × 10–4 O2 every minute. If all of these oxygen is
3) 1.6 × 10–2 used for the cellular respiration reaction that
4) 4.4 × 10–2 breaks down glucose, then how many grams
of glucose does the human body consume
each minute (MM of glucose = 180)?
541. An element X has two isotopes 41 X and 43 X. 1) 0.18 g
If percentage abundance of lighter isotope is 2) 1.8 g
30% then the average atomic mass of the 3) 0.3 g
element X will be
4) 30 g
1) 41.8 u
2) 42.4 u
3) 41.6 u
4) 42.2 u

44
chemistry 14

549. Which of the following possess maximum 556. In the reaction

weight? F e2 ( C2 O4 )
3
→ Fe
+3 −
, equi
+ CO2 + e

1) 1 L H2 O at STP (d = 1 g/mL) valent mass of reactant is [Molar mass of

2) 1 L C2 H5 OH (d = 0.09 g/mL) Fe2 (C2 O4 )3 is M]
3) 1 L H2 O2 at STP (d = 1.45 g/mL) 1) M

4) 1 L O3 at STP 2) M

3) M

550. Stoichiometric coefficients of reactants and 3

products in a chemical reaction represent 4) M

1
their respective
1) Number of moles
2) Number of g-atoms 557. A compound made up of carbon and
nitrogen contains carbon 46.2% by mass.
3) Number of atoms The empirical formula of compound is
4) Weight in gram 1) C3 N2
2) C2 N3
551. The mass of potassium chlorate, KClO3 3) CN
(molar mass = 122.5 g/mol) which releases
6.72 L of O2 at NTP is 4) CN2

1) 24.5 g
2) 0.245 g 558. Mass of four atoms of helium is
3) 48 g 1) 4 NA
4) 3.47 g 2) 4 u
3) 16 u
552. Weight of 1 mole of Mg2+ ion will be 4) 16 g
1) 22 g
2) 22 amu 559. If the stopping potential energy required for
photoelectron is twice of the work function of
3) 24 g metal then the energy of incident photon is
4) 24 amu 1) 1 × stopping potential energy
2) 2 × stopping potential energy
553. 3 g of a metal 'M' combines with 2 g of 3) 3 × work function
oxygen to form its metal oxide. 0.03
4) 4 × work function
equivalent of this metal oxide is dissolved in
500 ml of water to form 0.01 molar aqueous
solution. Molar mass of metal oxide is 560. Empirical formula and molecular formula is
(assuming no change in volume of solution) same for
1) 180 g 1) CH3 COOH
2) 160 g 2) H3 PO4
3) 140 g 3) H2 C2 O4
4) 120 g
4) H2 S2 O8

554. The mass of 80% pure H2 SO4 required to

neutralise 106 g of Na2 CO3 is 561. Total number of unpaired electrons in
chromium atom is (Atomic number of Cr =
1) 78.4 g 24)
2) 122.5 g 1) 4
3) 98 g 2) 5
4) 80 g 3) 6
4) 3
555. The empirical formula of monosodium
glutamate (MSG) a food-flavor enhancer is
C5 H8 O4 NNa. If its vapour density is 84.5
then number of atoms in one molecule of
MSG is
1) 17
2) 20
3) 18
4) 19

45
chemistry 14

562. The species to which Bohr's theory is not

applicable is
1) He+
2) Li2+
3) Be3+
4) H+

563. How many mole of product will be formed

when 1 mole of A, 0.6 mole of B and 0.72
mole of C react in the following reaction?
A + B + C → A4 B2 C3

1) 0.12
2) 0.24
3) 0.3
4) 0.25

46