MSDS1636 GB02 Be

Download as pdf or txt
Download as pdf or txt
You are on page 1of 13

Safety Data Sheet

According to Regulation (EC) No 1907/2006

Diverfoam SMS HD VF22


Revision: 2022-04-10 Version: 06.2

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Trade name: Diverfoam SMS HD VF22

UFI: DU04-Q057-X00F-GRRK

1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use: Foam cleaner.
Open plant cleaning chemical.
For industrial use only..
Uses advised against: Uses other than those identified are not recommended.

SWED - Sector-specific worker exposure description :


AISE_SWED_IS_8b_1
AISE_SWED_IS_4_1
AISE_SWED_IS_7_4
AISE_SWED_IS_7_5

1.3 Details of the supplier of the safety data sheet


Diversey Europe Operations BV, Maarssenbroeksedijk 2, 3542DN Utrecht, The Netherlands

Contact details
Diversey Ltd
Weston Favell Centre, Northampton NN3 8PD, United Kingdom
Tel: 01604 405311, Fax: 01604 406809
Regulatory Email: customerservice.uk@diversey.com

1.4 Emergency telephone number


Seek medical advice (show the label or safety data sheet where possible)
For medical or environmental emergency only:
call 0800 052 0185

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture

Skin Corr. 1A (H314)


Eye Dam. 1 (H318)

2.2 Label elements

Signal word: Danger.

Contains potassium hydroxide (Potassium Hydroxide), reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and sodium
hydroxide (Sodium Cociminodipropionate)

Hazard statements:
H314 - Causes severe skin burns and eye damage.

Precautionary statements:
P280 - Wear protective gloves, protective clothing and eye or face protection.
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.

Page 1 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

P310 - Immediately call a POISON CENTRE, doctor or physician.

2.3 Other hazards


No other hazards known.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Ingredient(s) EC number CAS number REACH number Classification Notes Weight


percent
potassium hydroxide 215-181-3 1310-58-3 01-2119487136-33 Skin Corr. 1A (H314) 3-10
Acute Tox. 4 (H302)
Met. Corr. 1 (H290)
reaction products of C12-18-(even 939-647-7 - 01-2119980672-29 Skin Irrit. 2 (H315) 3-10
numbered)-alkylamines and acrylic acid and sodium 290-476-8 01-2119976233-35 Eye Dam. 1 (H318)
hydroxide

Specific concentration limits


potassium hydroxide:
• Eye Dam. 1 (H318) >= 2% > Eye Irrit. 2 (H319) >= 1%
• Skin Corr. 1A (H314) >= 5% > Skin Corr. 1B (H314) >= 2% > Skin Irrit. 2 (H315) >= 0.5%
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and sodium hydroxide:
• Skin Irrit. 2 (H315) >= 30%
• Eye Dam. 1 (H318) >= 30% > Eye Irrit. 2 (H319) >= 1%

Workplace exposure limit(s), if available, are listed in subsection 8.1.


ATE, if available, are listed in section 11.
For the full text of the H and EUH phrases mentioned in this Section, see Section 16..

SECTION 4: First aid measures


4.1 Description of first aid measures
General Information: If unconscious place in recovery position and seek medical advice. Provide fresh air. If breathing is
irregular or stopped, administer artificial respiration. No mouth-to-mouth or mouth-to-nose
resuscitation. Use Ambu bag or ventilator.
Inhalation: Remove person to fresh air and keep comfortable for breathing. Get medical attention or advice if
you feel unwell.
Skin contact: Wash skin with plenty of lukewarm, gently flowing water for at least 30 minutes. Wash skin with
plenty of lukewarm, gently flowing water. Take off immediately all contaminated clothing and wash it
before reuse. Immediately call a POISON CENTRE, doctor or physician. If skin irritation occurs: Get
medical advice or attention.
Eye contact: Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE,
doctor or physician.
Ingestion: Rinse mouth. Immediately drink 1 glass of water. Never give anything by mouth to an unconscious
person. Do NOT induce vomiting. Keep at rest. Immediately call a POISON CENTRE, doctor or
physician.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.

4.2 Most important symptoms and effects, both acute and delayed
Inhalation: No known effects or symptoms in normal use.
Skin contact: Causes severe burns.
Eye contact: Causes severe or permanent damage.
Ingestion: Ingestion will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
oesophagus and stomach.

4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.

5.2 Special hazards arising from the substance or mixture


No special hazards known.

5.3 Advice for firefighters


As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.

Page 2 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
Wear suitable protective clothing. Wear eye/face protection. Wear suitable gloves.

6.2 Environmental precautions


Dilute with plenty of water. Do not allow to enter drainage system, surface or ground water.

6.3 Methods and material for containment and cleaning up


Dyke to collect large liquid spills. Use neutralising agent. Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust). Do
not place spilled materials back into the original container. Collect in closed and suitable containers for disposal.

6.4 Reference to other sections


For personal protective equipment see subsection 8.2. For disposal considerations see section 13.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Measures to prevent fire and explosions:
No special precautions required.
Measures required to protect the environment:
For environmental exposure controls see subsection 8.2.
Advices on general occupational hygiene:
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with
other products unless adviced by Diversey. Wash face, hands and any exposed skin thoroughly after handling. Take off immediately all
contaminated clothing. Wash contaminated clothing before reuse. Avoid contact with skin and eyes. Use only with adequate ventilation. See
chapter 8.2, Exposure controls / Personal protection.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local and national regulations. Store in a closed container. Keep only in original packaging.
For conditions to avoid see subsection 10.4. For incompatible materials see subsection 10.5.

7.3 Specific end use(s)


No specific advice for end use available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters
Workplace exposure limits

Air limit values, if available:


Ingredient(s) UK - Long term UK - Short term
value(s) value(s)
potassium hydroxide 2 mg/m3

Biological limit values, if available:

Recommended monitoring procedures, if available:

Additional exposure limits under the conditions of use, if available:

DNEL/DMEL and PNEC values


Human exposure
DNEL/DMEL oral exposure - Consumer (mg/kg bw)
Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
potassium hydroxide - - - -
reaction products of C12-18-(even numbered)-alkylamines and - - - 0.3
acrylic acid and sodium hydroxide

DNEL/DMEL dermal exposure - Worker


Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects (mg/kg bw) effects effects (mg/kg bw)
potassium hydroxide No data available - No data available -
reaction products of C12-18-(even numbered)-alkylamines and - - - 5.3
acrylic acid and sodium hydroxide

DNEL/DMEL dermal exposure - Consumer


Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects (mg/kg bw) effects effects (mg/kg bw)

Page 3 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

potassium hydroxide No data available - No data available -


reaction products of C12-18-(even numbered)-alkylamines and - - - 2.7
acrylic acid and sodium hydroxide

DNEL/DMEL inhalatory exposure - Worker (mg/m3)


Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
potassium hydroxide - - 1 -
reaction products of C12-18-(even numbered)-alkylamines and - - - 3.8
acrylic acid and sodium hydroxide

DNEL/DMEL inhalatory exposure - Consumer (mg/m3)


Ingredient(s) Short term - Local Short term - Systemic Long term - Local Long term - Systemic
effects effects effects effects
potassium hydroxide - - 1 -
reaction products of C12-18-(even numbered)-alkylamines and - - - 0.9
acrylic acid and sodium hydroxide

Environmental exposure
Environmental exposure - PNEC
Ingredient(s) Surface water, fresh Surface water, marine Intermittent (mg/l) Sewage treatment
(mg/l) (mg/l) plant (mg/l)
potassium hydroxide - - - -
reaction products of C12-18-(even numbered)-alkylamines and 0.03 0.003 0.042 9.9
acrylic acid and sodium hydroxide

Environmental exposure - PNEC, continued


Ingredient(s) Sediment, freshwater Sediment, marine Soil (mg/kg) Air (mg/m3)
(mg/kg) (mg/kg)
potassium hydroxide - - - -
reaction products of C12-18-(even numbered)-alkylamines and 0.108 0.0108 0.0041 -
acrylic acid and sodium hydroxide

8.2 Exposure controls

The following information applies for the uses indicated in subsection 1.2 of the Safety Data Sheet.
If available, please refer to the product information sheet for application and handling instructions.
Normal use conditions are assumed for this section.

Recommended safety measures for handling the undiluted product:

Appropriate engineering controls: If the product is diluted by using specific dosing systems with no risk of splashes or direct skin
contact, the personal protection equipment as described in this section is not required. Where
possible: use in automated/closed system and cover open containers. Transport over pipes. Filling
with automatic systems. Use tools for manual handling of product.
Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel.

REACH use scenarios considered for the undiluted product:


SWED - Sector-specific LCS PROC Duration ERC
worker exposure (min)
description
Automatic transfer and dilution AISE_SWED_IS_8b_1 IS PROC 8b 60 ERC4

Personal protective equipment


Eye / face protection: Safety glasses or goggles (EN 166). The use of a full-face shield or other full-face protection is
strongly recommended when handling open containers or if splashes may occur.
Hand protection: Chemical-resistant protective gloves (EN 374). Verify instructions regarding permeability and
breakthrough time, as provided by the gloves supplier. Consider specific local use conditions, such
as risk of splashes, cuts, contact time and temperature.
Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: ≥ 480 min Material
thickness: ≥ 0.7 mm
Suggested gloves for protection against splashes: Material: nitrile rubber Penetration time: ≥ 30 min
Material thickness: ≥ 0.4 mm
In consultation with the supplier of protective gloves a different type providing similar protection may
be chosen.
Body protection: No special requirements under normal use conditions. Wear chemical-resistant clothing and boots
in case direct dermal exposure and/or splashes may occur (EN 14605).
Respiratory protection: If exposure to liquid particles or splashes cannot be avoided use: half mask (EN 140) with particle
filter P2 (EN 143) or full-face mask (EN 136) with particle filter P1 (EN 143) Consider specific local
use conditions. In consultation with the supplier of respiratory protection equipment a different type
providing similar protection may be chosen. Specific applications tools may be available to limit
exposure. Please refer to the product information sheet for the possibilities. Apply technical

Page 4 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

measures to comply with the occupational exposure limits, if available

Environmental exposure controls: Should not reach sewage water or drainage ditch undiluted or unneutralised.

Recommended safety measures for handling the diluted product:

Recommended maximum concentration (% w/w): 5

Appropriate engineering controls: Provide a good standard of general ventilation. Ensure that foam equipment does not generate
respirable particles.
Appropriate organisational controls: No special requirements under normal use conditions.

REACH use scenarios considered for the diluted product:


SWED LCS PROC Duration ERC
(min)
Automatic application in a dedicated system AISE_SWED_IS_4_1 IS PROC 4 480 ERC8a
Foam spraying AISE_SWED_IS_7_4 IS PROC 7 480 ERC4
Spray application AISE_SWED_IS_7_5

Personal protective equipment


Eye / face protection: Safety glasses or goggles (EN 166) are always recommended for foam applications.
Hand protection: Chemical-resistant protective gloves (EN 374) are always recommended for foam applications.
Verify instructions regarding permeability and breakthrough time, as provided by the gloves
supplier. Consider specific local use conditions, such as risk of splashes, cuts, contact time and
temperature.
Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: ≥ 480 min Material
thickness: ≥ 0.7 mm
In consultation with the supplier of protective gloves a different type providing similar protection may
be chosen.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Information in this section refers to the product, unless it is specifically stated that substance data is listed

Method / remark
Physical state: Liquid
Colour: Clear , Brown
Odour: Product specific
Odour threshold: Not applicable
Melting point/freezing point (°C): Not determined Not relevant to classification of this product
Initial boiling point and boiling range (°C): Not determined See substance data

Substance data, boiling point


Ingredient(s) Value Method Atmospheric pressure
(°C) (hPa)
potassium hydroxide Not applicable to solids Method not given
or gases
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and sodium No data available
hydroxide

Method / remark
Flammability (solid, gas): Not applicable to liquids
Flammability (liquid): Not flammable.
Flash point (°C): > 100 °C closed cup
Sustained combustion: Not applicable.
( UN Manual of Tests and Criteria, section 32, L.2 )
Lower and upper explosion limit/flammability limit (%): Not determined

Substance data, flammability or explosive limits, if available:

Method / remark
Autoignition temperature: Not determined
Decomposition temperature: Not applicable.
pH: >= 11.5 (neat) ISO 4316
Dilution pH: > 11 (5 %) ISO 4316
Kinematic viscosity: ≈ 10 mPa.s (20 °C)
Solubility in / Miscibility with Water: Fully miscible

Page 5 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

Substance data, solubility in water


Ingredient(s) Value Method Temperature
(g/l) (°C)
potassium hydroxide No data available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and sodium No data available
hydroxide

Substance data, partition coefficient n-octanol/water (log Kow): see subsection 12.3

Method / remark
Vapour pressure: Not determined See substance data

Substance data, vapour pressure


Ingredient(s) Value Method Temperature
(Pa) (°C)
potassium hydroxide Negligible Method not given
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and sodium No data available
hydroxide

Method / remark
Relative density: ≈ 1.13 (20 °C) OECD 109 (EU A.3)
Relative vapour density: No data available. Not relevant to classification of this product
Particle characteristics: No data available. Not applicable to liquids.

9.2 Other information


9.2.1 Information with regard to physical hazard classes
Explosive properties: Not explosive.
Oxidising properties: Not oxidising.
Corrosion to metals: Not corrosive Weight of evidence

9.2.2 Other safety characteristics


Alkali reserve: ≈ 3.6 (g NaOH / 100g; pH=10)

SECTION 10: Stability and reactivity


10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability


Stable under normal storage and use conditions.

10.3 Possibility of hazardous reactions


No hazardous reactions known under normal storage and use conditions.

10.4 Conditions to avoid


None known under normal storage and use conditions.

10.5 Incompatible materials


Reacts with acids.

10.6 Hazardous decomposition products


None known under normal storage and use conditions.

SECTION 11: Toxicological information


11.1 Information on toxicological effects

Mixture data:.

Relevant calculated ATE(s):


ATE - Oral (mg/kg): >2000

Substance data, where relevant and available, are listed below:.

Acute toxicity
Acute oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure ATE
(mg/kg) time (h) (mg/kg)

Page 6 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

potassium hydroxide LD 50 333 Rat OECD 425 5100


reaction products of C12-18-(even numbered)-alkylamines and LD 50 31300 Rat OECD 401 (EU B.1) Not established
acrylic acid and sodium hydroxide

Acute dermal toxicity


Ingredient(s) Endpoint Value Species Method Exposure ATE
(mg/kg) time (h) (mg/kg)
potassium hydroxide No data Not established
available
reaction products of C12-18-(even numbered)-alkylamines and LD 50 > 5000 Rat Method not given Not established
acrylic acid and sodium hydroxide

Acute inhalative toxicity


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
potassium hydroxide No data
available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and No data
sodium hydroxide available

Acute inhalative toxicity, continued


Ingredient(s) ATE - inhalation, dust ATE - inhalation, mist ATE - inhalation, ATE - inhalation, gas
(mg/l) (mg/l) vapour (mg/l) (mg/l)
potassium hydroxide Not established Not established Not established Not established
reaction products of C12-18-(even numbered)-alkylamines and Not established Not established Not established Not established
acrylic acid and sodium hydroxide

Irritation and corrosivity


Skin irritation and corrosivity
Ingredient(s) Result Species Method Exposure time
potassium hydroxide Corrosive Rabbit Draize test
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and Not irritant Rabbit Read across OECD
sodium hydroxide 404 (EU B.4)

Eye irritation and corrosivity


Ingredient(s) Result Species Method Exposure time
potassium hydroxide Corrosive Rabbit Method not given
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and Irritant Rabbit Read across OECD
sodium hydroxide 405 (EU B.5)

Respiratory tract irritation and corrosivity


Ingredient(s) Result Species Method Exposure time
potassium hydroxide No data available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and No data available
sodium hydroxide

Sensitisation
Sensitisation by skin contact
Ingredient(s) Result Species Method Exposure time (h)
potassium hydroxide Not sensitising Guinea pig Method not given
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and No data available
sodium hydroxide

Sensitisation by inhalation
Ingredient(s) Result Species Method Exposure time
potassium hydroxide No data available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and No data available
sodium hydroxide

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)


Mutagenicity
Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method
(in-vitro) (in-vivo)
potassium hydroxide No evidence for mutagenicity, negative Method not No data available
test results given
reaction products of C12-18-(even No evidence for mutagenicity, negative OECD 471 (EU No data available
numbered)-alkylamines and acrylic acid and test results B.12/13) OECD
sodium hydroxide 476 (Chinese
Hamster
Ovary) OECD
473

Page 7 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

Carcinogenicity
Ingredient(s) Effect
potassium hydroxide No evidence for carcinogenicity, negative test results
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and No data available
sodium hydroxide

Toxicity for reproduction


Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other effects
(mg/kg bw/d) time reported
potassium hydroxide No data No evidence for reproductive
available toxicity
reaction products of NOEL Maternal toxicity 600 Rat OECD 422, No evidence for reproductive
C12-18-(even oral toxicity
numbered)-alkylamines
and acrylic acid and
sodium hydroxide

Repeated dose toxicity


Sub-acute or sub-chronic oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
potassium hydroxide No data
available
reaction products of C12-18-(even No data
numbered)-alkylamines and acrylic acid and sodium available
hydroxide

Sub-chronic dermal toxicity


Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
potassium hydroxide No data
available
reaction products of C12-18-(even No data
numbered)-alkylamines and acrylic acid and sodium available
hydroxide

Sub-chronic inhalation toxicity


Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
potassium hydroxide No data
available
reaction products of C12-18-(even No data
numbered)-alkylamines and acrylic acid and sodium available
hydroxide

Chronic toxicity
Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Remark
route (mg/kg bw/d) time organs affected
potassium hydroxide No data
available
reaction products of No data
C12-18-(even available
numbered)-alkylamines
and acrylic acid and
sodium hydroxide

STOT-single exposure
Ingredient(s) Affected organ(s)
potassium hydroxide No data available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and Not applicable
sodium hydroxide

STOT-repeated exposure
Ingredient(s) Affected organ(s)
potassium hydroxide No data available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and Not applicable
sodium hydroxide

Aspiration hazard
Substances with an aspiration hazard (H304), if any, are listed in section 3.

Potential adverse health effects and symptoms


Effects and symptoms related to the product, if any, are listed in subsection 4.2.

Page 8 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

11.2 Information on other hazards


11.2.1 Endocrine disrupting properties
Endocrine disrupting properties - Human data, if available:

11.2.2 Other information


No other relevant information available.

SECTION 12: Ecological information


12.1 Toxicity

No data is available on the mixture.

Substance data, where relevant and available, are listed below:

Aquatic short-term toxicity


Aquatic short-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
potassium hydroxide LC 50 80 Various Weight of evidence 24
species
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and LC 50 4.2 Oncorhynchus OECD 203 (EU C.1) 96
sodium hydroxide mykiss

Aquatic short-term toxicity - crustacea


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
potassium hydroxide EC 50 30 - 1000 Daphnia Weight of evidence
magna Straus
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and EC 50 1.71 Daphnia 84/449/EEC, C2 48
sodium hydroxide

Aquatic short-term toxicity - algae


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
potassium hydroxide No data
available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and E r C 50 9.3 Chlorella OECD 201 (EU C.3) 72
sodium hydroxide vulgaris

Aquatic short-term toxicity - marine species


Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (days)
potassium hydroxide No data
available
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and No data
sodium hydroxide available

Impact on sewage plants - toxicity to bacteria


Ingredient(s) Endpoint Value Inoculum Method Exposure
(mg/l) time
potassium hydroxide EC 50 22 Photobacteriu Method not given 15
m minute(s)
phosphoreum
reaction products of C12-18-(even numbered)-alkylamines and acrylic acid and EC 10 99 Activated OECD 209 3 hour(s)
sodium hydroxide sludge

Aquatic long-term toxicity


Aquatic long-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
potassium hydroxide No data
available
reaction products of C12-18-(even No data
numbered)-alkylamines and acrylic acid and sodium available
hydroxide

Aquatic long-term toxicity - crustacea


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
potassium hydroxide No data
available
reaction products of C12-18-(even NOEC 15 Daphnia OECD 211 21 day(s) No adverse effects observed
numbered)-alkylamines and acrylic acid and sodium magna

Page 9 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

hydroxide

Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
sediment)
potassium hydroxide No data
available
reaction products of C12-18-(even No data
numbered)-alkylamines and acrylic acid and sodium available
hydroxide

Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
potassium hydroxide No data
available

Terrestrial toxicity - plants, if available:


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
potassium hydroxide No data
available

Terrestrial toxicity - birds, if available:

Terrestrial toxicity - beneficial insects, if available:


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
potassium hydroxide No data
available

Terrestrial toxicity - soil bacteria, if available:


Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
potassium hydroxide No data
available

12.2 Persistence and degradability


Abiotic degradation
Abiotic degradation - photodegradation in air, if available:
Ingredient(s) Half-life time Method Evaluation Remark
potassium hydroxide No data available

Abiotic degradation - hydrolysis, if available:


Ingredient(s) Half-life time in fresh Method Evaluation Remark
water
potassium hydroxide No data available

Abiotic degradation - other processes, if available:

Ingredient(s) Type Half-life time Method Evaluation Remark


potassium hydroxide No data available

Biodegradation
Ready biodegradability - aerobic conditions
Ingredient(s) Inoculum Analytical DT 50 Method Evaluation
method
potassium hydroxide Not applicable (inorganic
substance)
reaction products of C12-18-(even Activated sludge, Method not given Readily biodegradable
numbered)-alkylamines and acrylic acid and sodium aerobe
hydroxide

Ready biodegradability - anaerobic and marine conditions, if available:

Degradation in relevant environmental compartments, if available:

Page 10 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

Ingredient(s) Medium & Type Analytical DT 50 Method Evaluation


method
potassium hydroxide No data available

12.3 Bioaccumulative potential


Partition coefficient n-octanol/water (log Kow)
Ingredient(s) Value Method Evaluation Remark
potassium hydroxide No data available Not relevant, does not
bioaccumulate
reaction products of C12-18-(even No data available
numbered)-alkylamines and acrylic acid
and sodium hydroxide

Bioconcentration factor (BCF)


Ingredient(s) Value Species Method Evaluation Remark
potassium hydroxide No data available
reaction products of No data available Not relevant, does not
C12-18-(even bioaccumulate
numbered)-alkylamines
and acrylic acid and
sodium hydroxide

12.4 Mobility in soil


Adsorption/Desorption to soil or sediment
Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation
coefficient coefficient type
Log Koc Log Koc(des)
potassium hydroxide No data available Low potential for adsorption
to soil
reaction products of C12-18-(even No data available
numbered)-alkylamines and acrylic acid and sodium
hydroxide

12.5 Results of PBT and vPvB assessment


Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3.

12.6 Endocrine disrupting properties


Endocrine disrupting properties - Environmental effects, if available:

12.7 Other adverse effects


No other adverse effects known.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Waste from residues / unused The concentrated contents or contaminated packaging should be disposed of by a certified handler
products: or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging
material is suitable for energy recovery or recycling in line with local legislation.
European Waste Catalogue: 20 01 15* - alkalines.

Empty packaging
Recommendation: Dispose of observing national or local regulations.
Suitable cleaning agents: Water, if necessary with cleaning agent.

SECTION 14: Transport information

Land transport (ADR/RID), Sea transport (IMDG), Air transport (ICAO-TI / IATA-DGR)
14.1 UN number: 1814
14.2 UN proper shipping name:
Potassium hydroxide solution
14.3 Transport hazard class(es):
Transport hazard class (and subsidiary risks): 8
14.4 Packing group: II
14.5 Environmental hazards:

Page 11 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

Environmentally hazardous: No
Marine pollutant: No
14.6 Special precautions for user: None known.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code: The product is not transported in bulk tankers.

Other relevant information:


ADR
Classification code: C5
Tunnel restriction code: E
Hazard identification number: 80
IMO/IMDG
EmS: F-A, S-B

The product has been classified, labelled and packaged in accordance with the requirements of ADR and the provisions of the IMDG Code
Transport regulations include special provisions for certain classes of dangerous goods packed in limited quantities.

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations :
• Regulation (EC) 1907/2006 - REACH (UK amended)
• Regulation (EC) 1272/2008 - CLP (UK amended)
• Regulation (EC) 648/2004 - Detergents regulation (UK amended)
• Delegated Regulation (EU) 2017/2100 and Regulation (EU) 2018/605 (UK amended)
• Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)
• International Maritime Dangerous Goods (IMDG) Code

Authorisations or restrictions (Regulation (EC) No 1907/2006, Title VII respectively Title VIII): Not applicable.

Ingredients according to Detergents Regulation


amphoteric surfactants, phosphonates, non-ionic surfactants <5%

The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) 648/2004 on
detergents (UK amended). Data to support this assertion are held at the disposal of the competent authorities of the UK and will be made
available to them, at their direct request or at the request of a detergent manufacturer.

Comah - classification: Not classified

15.2 Chemical safety assessment


A chemical safety assessment has not been carried out on the mixture

SECTION 16: Other information

The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract

SDS code: MSDS1636 Version: 06.2 Revision: 2022-04-10

Reason for revision:


This data sheet contains changes from the previous version in section(s):, 2, 3, 4, 6, 7, 8, 9, 11, 12, 16

Classification procedure
The classification of the mixture is in general based on calculation methods using substance data, as required by Regulation (EC) No
1272/2008. If for certain classifications data on the mixture is available or for example bridging principles or weight of evidence can be used for
classification, this will be indicated in the relevant sections of the Safety Data Sheet. See section 9 for physical chemical properties, section 11
for toxicological information and section 12 for ecological information.

Full text of the H and EUH phrases mentioned in section 3:


• H290 - May be corrosive to metals.
• H302 - Harmful if swallowed.
• H314 - Causes severe skin burns and eye damage.
• H315 - Causes skin irritation.
• H318 - Causes serious eye damage.

Abbreviations and acronyms:


• AISE - The international Association for Soaps, Detergents and Maintenance Products
• ATE - Acute Toxicity Estimate
• DNEL - Derived No Effect Limit
• EC50 - effective concentration, 50%
• ERC - Environmental release categories

Page 12 / 13
Safety Data Sheet
Diverfoam SMS HD VF22

• EUH - CLP Specific hazard statement


• LC50 - Lethal Concentration, 50% / Median Lethal Concentration
• LCS - Life cycle stage
• LD50 - Lethal Dose, 50% / Median Lethal dose
• NOAEL - No observed adverse effect level
• NOEL - No observed effect level
• OECD - Organisation for Economic Cooperation and Development
• PBT - Persistent, Bioaccumulative and Toxic
• PNEC - Predicted No Effect Concentration
• PROC - Process categories
• REACH number - REACH registration number, without supplier specific part
• vPvB - very Persistent and very Bioaccumulative

End of Safety Data Sheet

Page 13 / 13

You might also like