Variphob FC 12 RT - MSDS V3.0 - 2013.09.16

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
VARIPHOB FC 12 RT
Version 3.0 Revision Date 16.09.2013 Print Date 17.09.2013
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : VARIPHOB FC 12 RT
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Construction auxiliary
stance/Mixture
1.3 Details of the supplier of the safety data sheet

Manufacturer/Supplier
CHT R. BEITLICH GMBH BEZEMA AG

Bismarckstraße 102 Kriessernstrasse 20
72072 Tübingen 9462 Montlingen
Germany Switzerland
Tel.: +49(0)70 71 15 40 Tel.: +41(0)71 763 88 11
[email protected] [email protected]
CHEMISCHE FABRIK
TÜBINGEN (UK) LIMITED
Newby Road Ind. Estate
Hazel Grove Stockport
Cheshire SK7 5DA
United Kingdom
Tel.: +44(0)161 456 33 55
[email protected]
Importer : -
-
-
-
-
-
Responsible Department : CHT R. BEITLICH GMBH

BEZEMA AG
Product Safety
[email protected]
[email protected]
1.4 Emergency telephone number

Emergency telephone : +49(0)70 71 15 40 (Germany, 24 hours)
number +41(0)71 763 88 11 (Switzerland, 24 hours)
1 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
2. Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
Classification (67/548/EEC, 1999/45/EC)
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
Additional Labelling:
EUH210 Safety data sheet available on request.
2.3 Other hazards

According to our present knowledge the product does not contain persistent, bioaccumulative and
toxic substances (PBT substances) or very persistent and very bioaccumulative (vPvB substances)
as defined in Annex XIII of the Regulation (EG) No 1907/2006 (REACH), respectively.
3. Composition/information on ingredients
3.2 Mixtures
Chemical nature : Fluoralkylacrylate copolymer, aqueous emulsion
Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (REGULATION [%]
Registration (EC) No
number 1272/2008)
Poly(oxy-1,2- 9002-92-0 Xi; R36/38 Skin Irrit. 2; H315 >= 2 - < 3
ethanediyl), .alpha.- Polymer Eye Irrit. 2; H319
dodecyl-.omega.-
hydroxy-
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. First aid measures
4.1 Description of first aid measures

General advice : Take off all contaminated clothing immediately.
2 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
If inhaled : Move to fresh air.

If symptoms persist, call a physician.
In case of skin contact : Wash off immediately with soap and plenty of water.
In case of eye contact : Immediately flush eye(s) with plenty of water.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting.
Call a physician immediately.
4.2 Most important symptoms and effects, both acute and delayed
Risks : Refer to section 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No information available.
5. Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Carbon dioxide (CO2)
Water spray jet
Dry powder
Foam
5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : Hazardous decomposition products formed under fire condi-
fighting tions.
Can be released in case of fire:
Carbon oxides
acrylic monomeres
Hydrogen fluoride
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Further information : In case of fire do not inhale smoke, conflagration gases and
steams.
Use water spray to cool unopened containers.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
The product itself does not burn.
The residual polymer after volatilizing the watery phase is
combustible.
3 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment.
Contaminated surfaces will be extremely slippery.
6.2 Environmental precautions

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.
Pay attention to local or official regulations.
6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Close drains (risk of blockage caused by polymer precipita-
tion).
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Clean contaminated surface thoroughly.
Dispose of in accordance with local regulations.
6.4 Reference to other sections

Refer to protective measures listed in sections 7 and 8.
7. Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Advice on protection against : No special protective measures against fire required.

fire and explosion
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Do always store in containers which correspond to the original
areas and containers ones.
Keep container tightly closed.
Inappropriate material for containers and conduit:
Metals
Suitable material for containers and conduit:
Polyethylene
Further information on stor- : Protect from temperatures below + 5 °C.

age conditions Protect from temperatures over + 40 °C.
Stir well before use.
Advice on common storage : No special precautions required.

4 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
German storage class : 12 Non Combustible Liquids
7.3 Specific end use(s)

Note : Consult the technical guidelines for the use of this sub-
stance/mixture.
8. Exposure controls/personal protection
8.1 Control parameters

Contains no substances with occupational exposure limit values.
8.2 Exposure controls

Engineering measures
Provide sufficient air exchange and/or exhaust in work rooms.
Personal protective equipment

Respiratory protection : In case the work place is not ventilated sufficiently and during
spray processing, it is necessary to wear respiratory protective
equipment.
Recommended Filter type:
Combination filter A/P
Hand protection : Nitrile rubber

Protective index Class 6
Break through time: > 480 min
Glove thickness: >= 0,35 mm
: The choice of an appropriate glove does not only depend on

its material but also on other quality features and is different
from one producer to the other.
The obtained break through times according to EN 374 Part III
are not measured under normal operating conditions. There-
fore a maximum usage time of 50% of the break through time
is recommended.
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing.
Hygiene measures : Avoid contact with skin, eyes and clothing.

Do not breathe vapours, aerosols.
Take off all contaminated clothing immediately.
Handle in accordance with good industrial hygiene and safety
practice.
5 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
Environmental exposure controls

General advice : The product should not be allowed to enter drains, water
courses or the soil.
Pay attention to local or official regulations.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : liquid
Emulsion
Colour : milky
white
Odour : sweet
Flash point : not applicable
Lower explosion limit : not applicable
Upper explosion limit : not applicable
Oxidizing properties : not applicable
Auto-ignition temperature : not auto-flammable
pH : 3,0 - 4,2
at 20 °C
Melting point/range : no data available
Boiling point/boiling range : ca. 100 °C

at 1.013 hPa
Vapour pressure : ca. 23 hPa

Water
Density : 1,03 g/cm3

at 20 °C
Water solubility : miscible
Partition coefficient: n- : not applicable

octanol/water
Viscosity, dynamic : 10 - 80 mPa.s

at 20 °C
Brookfield RVT, 20 rpm, spindle 5
6 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
Relative vapour density : not applicable
Evaporation rate : not applicable
9.2 Other information

Conductivity : Not determined
10. Stability and reactivity
10.1 Reactivity
No hazards to be specially mentioned.
10.2 Chemical stability

The product is chemically stable.
10.3 Possibility of hazardous reactions

Hazardous reactions : No dangerous reaction known under conditions of normal use.
10.4 Conditions to avoid

Conditions to avoid : not applicable
10.5 Incompatible materials

Materials to avoid : not applicable
10.6 Hazardous decomposition products

Hazardous decomposition : No decomposition if stored and applied as directed.
products
Thermal decomposition : The thermal decomposition vapours of fluorinated polymers

may cause polymer fume fever with flu-like symptoms in hu-
mans, especially when smoking contaminated tobacco.
11. Toxicological information
11.1 Information on toxicological effects

Acute toxicity
Acute oral toxicity : LD50: > 2.000 mg/kg
Species: rat
Argument by analogy
Acute dermal toxicity : No data is available on the product itself.
7 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
Skin corrosion/irritation
Skin irritation : Prolonged skin contact may cause skin irritation.
Serious eye damage/eye irritation

Eye irritation : Contact with eyes may cause irritation.
Respiratory or skin sensitisation

Sensitisation : No known sensitising effect.
Further information : If used and handled according to specifications, the product

does not have any harmful effects according to our experience
and the information provided to us.
12. Ecological information
12.1 Toxicity
Toxicity to fish : No data is available on the product itself.
Toxicity to daphnia and other : EC50: > 1 - 10 mg/l

aquatic invertebrates Exposure time: 48 h
Species: Daphnia magna (Water flea)
Method: OECD Test Guideline 202
Argument by analogy
Toxicity to algae : No data is available on the product itself.
Toxicity to bacteria : EC50: > 1.000 mg/l

Species: activated sludge
Argument by analogy
12.2 Persistence and degradability

Biodegradability : DOC measuring
> 90 %
Method: OECD 302 B (elimination)
Argument by analogy
The product is "inherently biodegradable" according to the
criteria of the OECD.
Physico-chemical removabil- : Can be eliminated from water by precipitation.

ity
12.3 Bioaccumulative potential

8 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
Bioaccumulation : No data is available on the product itself.
12.4 Mobility in soil

Mobility : no data available
12.5 Results of PBT and vPvB assessment

According to our present knowledge the product does not contain persistent, bioaccumulative and
toxic substances (PBT substances) or very persistent and very bioaccumulative (vPvB substances)
as defined in Annex XIII of the Regulation (EG) No 1907/2006 (REACH), respectively.
12.6 Other adverse effects
Adsorbed organic bound : Fluorine compounds are not counted by AOX regulation as a
halogens (AOX) rule.
Additional ecological infor- : According to our knowledge, the product does not contain
mation heavy metals and other compounds of EC directive 2000/60
EC.
13. Disposal considerations
13.1 Waste treatment methods

Product : Pay attention to local or official regulations.
Contaminated packaging : Pay attention to local or official regulations.
14. Transport information
14.1 UN number
ADR : Not dangerous goods
IMDG : Not dangerous goods
IATA : Not dangerous goods
14.2 Proper shipping name

14.3 Transport hazard class

14.4 Packing group

9 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT

Segregation group : -
14.5 Environmental hazards

14.6 Special precautions for user

see chapter 6 - 8
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Remarks : not applicable
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Components In accordance : This product is not subject to the Regulation on Detergents.
with Regulation (EC) No.
648/2004 on detergents
15.2 Chemical Safety Assessment

This information is not available.
16. Other information

Full text of R-phrases referred to under sections 2 and 3
R36/38 Irritating to eyes and skin.
Full text of H-Statements referred to under sections 2 and 3.

H315 Causes skin irritation.
H319 Causes serious eye irritation.
Further information
Other information : This data sheet contains changes from the previous version in
section(s):
2
3
5
6
7
8
10 / 11
SAFETY DATA SHEET
VARIPHOB FC 12 RT
9
11
12
14
16
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not to
be considered a warranty or quality specification. The information relates only to the specific mate-
rial designated and may not be valid for such material used in combination with any other materi-
als or in any process, unless specified in the text.
This safety datasheet only contains information relating to safety and does not replace any prod-
uct information or product specification.
11 / 11

Variphob FC 12 RT - MSDS V3.0 - 2013.09.16

Uploaded by

Copyright:

Available Formats

Variphob FC 12 RT - MSDS V3.0 - 2013.09.16

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Variphob FC 12 RT - MSDS V3.0 - 2013.09.16

Uploaded by

Copyright:

Available Formats

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

CHT R. BEITLICH GMBH BEZEMA AG

Responsible Department : CHT R. BEITLICH GMBH

1.4 Emergency telephone number

2.1 Classification of the substance or mixture

2.2 Label elements

2.3 Other hazards

4. First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air.

In case of eye contact : Immediately flush eye(s) with plenty of water.

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

7. Handling and storage

7.1 Precautions for safe handling

Advice on protection against : No special protective measures against fire required.

7.2 Conditions for safe storage, including any incompatibilities

Further information on stor- : Protect from temperatures below + 5 °C.

Advice on common storage : No special precautions required.

German storage class : 12 Non Combustible Liquids

7.3 Specific end use(s)

8. Exposure controls/personal protection

8.1 Control parameters

8.2 Exposure controls

Personal protective equipment

Hand protection : Nitrile rubber

: The choice of an appropriate glove does not only depend on

Eye protection : Safety glasses

Skin and body protection : Wear suitable protective clothing.

Hygiene measures : Avoid contact with skin, eyes and clothing.

Environmental exposure controls

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Flash point : not applicable

Lower explosion limit : not applicable

Upper explosion limit : not applicable

Oxidizing properties : not applicable

Auto-ignition temperature : not auto-flammable

Melting point/range : no data available

Boiling point/boiling range : ca. 100 °C

Vapour pressure : ca. 23 hPa

Density : 1,03 g/cm3

Water solubility : miscible

Partition coefficient: n- : not applicable

Viscosity, dynamic : 10 - 80 mPa.s

Relative vapour density : not applicable

Evaporation rate : not applicable

9.2 Other information

10. Stability and reactivity