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Form 4 Chemistry - Paper 1 - Question Paper

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CHEMISTRY 233/1

Form 4- Paper 1

Term 1 - 2024

Time: 2 Hours

Name: …………………………………………………………. Adm No: ……………….


School: ……………………………………………………….. Class: …………………..
Signature: …………………………………… Date: …………………...

INSTRUCTIONS TO CANDIDATES

 Write your Name, Index Number and School in the spaces provided above.
 Answer all the questions in the spaces provided after each question.
 KNEC Mathematical tables and silent non-programmable electronic calculators may be
used.
 ALL working must be clearly shown where necessary.
 Candidate should check the question paper to ascertain that all the pages are printed
and that no questions are missing.
 Candidates should answer the questions in English.
FOR EXAMINER’S USE ONLY

QUESTIONS MAX SCORE CANDIDATE’S SCORE

1 – 27 80

This paper consists of 11 printed pages. Candidates should check to ascertain that all pages are
printed as indicated and that no questions are missing.

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1. The set-up below shows the catalytic oxidation of ammonia in the laboratory.

(a) State and explain the observation made. (2marks)

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(b) Write a chemical equation for the first reaction taking place in the conical flask. (1 mark)

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2. When sulphur is heated in a boiling tube in the absence of air, the yellow crystals melts
into a golden yellow mobile liquid at 113°C. The liquid changes at 180°C into a dark
brown liquid that is very viscous. Heating at 400°C produces a brown less viscous
liquid.)
(a) Draw the molecular structure of sulphur in the yellow liquid. (1 mark)

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(b) Name two allotropes of sulphur. (2 marks)

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3. Iron (III) oxide was found to be contaminated with copper (II) sulphate. Describe how a
pure sample of iron (III) oxide can be obtained. (3 marks)
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4. Study the diagram below then use it to answer the questions that follow.

w o o d en sp lin t

a) Draw the wooden splint at the end of the experiment. If it was slipped, then removed
quickly.
(1
mark)

b) Explain the appearance of the wooden splint in (a) above. (2 marks)

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5. Identify the acid in the following reaction. Give a reason. (2 marks)


NH4+ (aq) + OH- (aq) → NH3 (aq) + H2O (l)

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6. State two methods that can be used to remove water hardness. (1 mark)

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7. (a) Define the term solubility. (1 mark)

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(b) In an experiment to determine the solubility of solid Q in water at 50oC, the following
data was obtained.
Mass of empty evaporating dish = 46.5 g
Mass of evaporating dish + saturated solution = 62.5 g
Mass of evaporating dish + dry solid Q = 50.4 g

Use the data to calculate the solubility of solid Q. (2 marks)

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8. What is meant by lattice energy? (1 mark)

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(b) Use the information below to calculate the heat of solution of calcium chloride.
(2 marks)

Lattice energy of CaCl2 -2195 kJ/mol


Hydration energy of Ca2+ (g) -189 kJ/mol
Hydration energy of Cl- (g) -384 kJ/mol

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9. (a) State Boyle’s law. (1 mark)

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(b) A gas occupies 500 cm3 at 37oC and 100,000 Pa. What will be its volume at 10oC and
101,325Pa? (2 marks)

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10. Describe how a solid sample of copper (II) carbonate can be prepared starting with
copper metal. (3 marks)

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11. (a) Give the name of the 3rd member of the alkene homologous series. (1 mark)

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(b) Draw and name all isomers of butane. (2 marks)

12. Draw a diagram to illustrate the electrolysis of molten aluminium oxide. (3 marks)

13. (a) A molecule of a compound has a mass of 7.34 x 10-23 g. Calculate its RMM.
L = 6.023 x 1023 (2 marks).

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(b) State Avogadro’s law. (1 mark)

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14. The diagram below represents a set of apparatus used to study the properties of chlorine
water.

(a) Name gas X. (1 mark)

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(b) Write an equation for the reaction that produces gas X. (1 mark)

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(c) Give one use of chlorine. (1 mark)

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15. (a) What is the meaning of polymerization? (1 mark)

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(b) Draw and name the structure of polymer formed from propene. (2 marks)

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16. A sample of 0.63g of lead powder were dissolved in excess nitric (V) acid to form lead
(II) nitrate solution. All the lead (II) nitrate was then reacted with sodium sulphate
solution.
(a) Write an ionic equation for the reaction between sodium sulphate solution and
lead (II) nitrate solution. (1 mark)

(b) Determine the mass of the lead salt formed in the reaction in (a) above. (2 marks)

(Pb = 207, S = 32, O = 16)

17. For each of the following experiments, give the observations and the type of change that
occurs (temporary physical or temporary chemical) (3 marks)

Experiment Observation Type of change

A few drops of
water are added to
small amount of
anhydrous copper
(ii) sulphate

A few crystals of
iodine are heated
gently in a test
tube

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18. What is the role of the following parts during the fractional distillation of a mixture of
water and ethanol?

(i) Fractionating column (1 mark)


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(ii) Glass beads in the fractionating column (1 mark)
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(iii) State any one application of fractional distillation process. (1 mark)
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19. (a) Carbon (IV) oxide does not support combustion but burning magnesium continues to
burn in carbon (IV) oxide. Explain. (2 marks)

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(b) Write an equation for the reaction in (a) above. (1 mark)

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20. The diagram below is a section of a model of the structure of element T.

+ + + + KEY

+ + + + + C h arg ed nu cleu s
+ + + + A n ele ctron

a) State the type of bonding that exists in T. (1 mark)

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b) In which group of the periodic table does element T belong? Give a reason. (2 marks)

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21. Below are pH values of some solutions.

Solution Z Y X W

pH 6.5 13.5 2.2 7.2

i) Which solution is likely to be

I. acidic rain………………………………........ (1 mark)

II. Potassium hydroxide ……………………………… (1 mark)

ii) Substance V reacted with both solutions Y and X. What is the nature of V. (1 mark)

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22. Draw a set up that can be used to prepare dry hydrogen gas in the laboratory. (3 marks)

23. The grid below represents a part of the periodic table. Study it and answer the questions
that follow. Letters are not actual symbols of elements.

F I M O

G J K L N P

H Q

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(a) How does the atomic radius of K compare to that of L? Explain. (2 marks)

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(b) Element R forms an oxide of the formula RO2 and belongs to period 2. Indicate in the
grid the position of R. (1 mark)

(c) Write down the formula of the compound formed between K and P. (1 mark)

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24. When Na2CO3.XH2O is heated strongly it loses 63.20% of its mass. Calculate the value of
X. (Na=23.0, C=12.0,O=16.0,H=1.0) (3marks)

25. (a) Give the meaning of the term prescription. (1 mark)

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(b) A patient was given tablets with prescription 2 x 3 on the envelope. Clearly outline how
the patient should take the tablets.
(1 mark)
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(c) State two long-term effects of drug abuse. (1 mark)

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26. Describe a chemical test that can be used to distinguish between aqueous solutions of
sodium carbonate and sodium hydrogen carbonate. (3 marks)

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27. To which homologous series do the following general formulae conform to? ( 3marks)

CnH2n………………………………………… .

CnH2n-2…………………………………………

CnH2n+2 .…………………………………………

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