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    Ino Sem 2

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    gpkhursa

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    Ino Sem 2

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    gpkhursa
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    ino sem 2

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    10 views2 pages

    Ino Sem 2

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    of 2

    M.Sc.(Chemistry) (Old and C.B.C.S.

    Pattern) Sem-II
    CHE-201 / psccht05 - Inorganic Chemistry Paper-V
    P. Pages : 2 GUG/S/19/11228
    Time : Three Hours *3168* Max. Marks : 80
    _____________________________________________________________________
    Notes : 1. Attempt all questions.
    2. All questions carry equal marks.

    1. a) Discuss orgel energy level diagram for d2 configuration in octahedral and Tetrahedral 8
    complexes and give its characteristics.

    b) i) Describe Tanabe Sugano diagram of octahedral complexes with d2 configuration. 8

    ii) Explain High spin-low spin cross over.

    OR

    c) Write a short note on charge transfer spectra. 4

    d) Explain spin-orbit (L-S) coupling scheme for energy terms. 4

    e) Explain how the magnetic and spectral data can be used for determination of structure of 4
    tetra halo-cobalt (II) complexes.

    f) What is abnormal magnetic behavior? Discuss it in octahedral complexes with suitable 4


    example.

    2. a) What is trans effect? Discuss the theories and uses of trans effect. 8

    b) What is electron transfer reactions. Discuss the bridge activated complex mechanism for 8
    electron transfer reaction with suitable example.

    OR

    c) Explain 4
    i) Tunneling effect.
    ii) Cross Reaction.

    d) Discuss the mechanism of substitution reaction in Pt (II) square planer complexes. 4

    e) Describe the mechanism of outer sphere mechanism with suitable example. 4

    f) Explain the complimentary and non-complimentary reactions with suitable example. 4

    3. a) What are metal carbonyl clusters? Explain in details. 8

    b) i) What are metal carbonyls? How they are classified? Give examples. 8

    ii) What is EAN rule? Calculate EAN for metal in the following
    1) Ni (CO)4 2) Fe2 (CO) 9 3) Mn2 (CO) 10

    GUG/S/19/11228 1 P.T.O
    OR

    c) Explain vibrational spectra of metal carbonyls. 4

    d) Explain the structure and bonding in Fe2 (CO)9  and CO2 (CO)8  in solution. 4

    e) Discuss the synergic bonding in metal carbonyls. 4

    f) Give an account of four important chemical reactions of metal carbonyls. 4

    4. a) i) What are metal nitrosyls? Give any three methods of their preparations? 8

    ii) Explain X-ray diffraction studies of transition metal nitrosyls.

    b) Give various nitrosylating agent for synthesis of metal nitrosyls. 8

    OR

    c) Explain dinitrogen complexes. 4

    d) Explain Wilkinson's catalyst. 4

    e) Write a note on Brown ring test. 4

    f) Give important reactions of metal nitrosyls. 4

    5. a) Write a note on Laporte orbital selection rule. 2

    b) Drive the term symbol for d2 configuration. 2

    c) Give any two synthetic applications of trans effect. 2

    d) Explain the effect of leaving group on the substitution reaction in square planar complexes. 2

    e) Explain the structure of  Mn 2 (CO)10  2

    f) How many metal-metal bonds are to be included in OS4 (CO)16 and CO4 (CO)12 in order 2
    to obey EAN rule.

    g) How are nitrosyl complexes useful in differentiating sulphide, sulphite and sulphate. 2

    h) Write a note on Vaska's compound. 2

    *********

    GUG/S/19/11228 2

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