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Bhe Ea Registration Appendix B

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BEAR HEAD ENERGY GREEN HYDROGEN AND AMMONIA PRODUCTION, STORAGE AND

LOADING FACILITY

APPENDIX B
Landrie Lake Water Quality Data
Table 1 - Inorganics and Metals for Raw Water and Estimated for Reject Process Water

Assumed Reject
Raw Water Process Water
Water Plant -
Raw Water Raw WTP Raw Raw Raw Raw Average* Concentration**
CCME Water Quality Guidelines for the Protection of Aquatic Life - Marine Raw
(2017-2022) (Based on 3x
Average Raw Water)

Parameter Unit RDL 19-Oct-17 26-Sep-18 11-Dec-18 08-Oct-19 21-Oct-20 6-Nov-22 21-Dec-22
Inorganics
pH 7.0-8.7B 6.8 6.94 6.68 6.87 6.73 6.85 6.73 6.80 7.0-8.7***
Reactive Silica as SiO2 mg/L 0.5 0.6 - 1.4 0.6 0.8 0.94 1.70 1.01 3.03
Chloride mg/L 1 10 9 8 11 15 9.4 11.0 10.5 31.5
Fluoride mg/L 0.1 ND ND ND ND ND ND ND ND ND
Sulphate mg/L 2 5 4 5 4 5 4.1 7.1 4.9 14.7
Alkalinity mg/L 2 6 - ND ND ND 5 4.1 3.8 11.4
B
Narrative - The mean absorbance of filtered water samples at 456 nm shall not be significantly higher than the seasonally adjusted expected
True Color TCU 5 ND 24 37 18 10.2 27 30 21 63
value for the system under consideration.

NarrativeB - Clear flow:


Maximum increase of 8 NTUs from background levels for a short-term exposure (e.g., 24-h period). Maximum average increase of 2 NTUs
from background levels for a longer term exposure (e.g., 30-d period).
Turbidity NTU 0.1 1.8 1.9 1.7 1.9 1 0.89 1.00 1.46 4.38
High flow or turbid waters:
Maximum increase of 8 NTUs from background levels at any one time when background levels are between 8 and 80 NTUs. Should not
increase more than 10% of background levels when background is > 80 NTUs.

Electrical Conductivity uS/cm 1 61 - 62 69 73 58 58 64 192


Nitrate + Nitrite as N mg/L 0.05 ND - ND ND ND ND ND ND ND
A B
Nitrate as N mg/L 0.05 1,500 , 200 ND ND ND ND ND ND ND ND ND
Nitrite as N mg/L 0.05 ND - ND ND ND ND ND ND ND
Ammonia as N mg/L 0.05 ND - 0.04 0.04 0.05 ND 0.58 0.13 0.39
Total Organic Carbon mg/L 0.5 4.3 - 6.2 3.4 3.4 6.2 5.8 4.9 14.7
Ortho-Phosphate as P mg/L 0.01 ND - 0.01 ND 0.02 ND ND 0.01 0.03
Total Sodium mg/L 0.1 7.6 6.7 7.0 7.1 21.3
Total Potassium mg/L 0.1 0.3 - 0.3 0.4 0.4 0.29 0.29 0.33 0.99
Total Calcium mg/L 0.1 3.1 - 3 3.8 2.5 2.8 2.8 3.0 9.0
Total Magnesium mg/L 0.1 0.8 - 0.8 1 0.8 0.74 0.78 0.82 2.46
Bicarb. Alkalinity (as CaCO3) mg/L 1 6 - ND ND ND 5.0 4.1 3.8 11.4
Carb. Alkalinity (as CaCO3) mg/L 1 ND - ND ND ND ND ND ND ND
Hydroxide mg/L 5 ND - ND ND ND ND ND
Calculated TDS mg/L 1 31 20 24 30 32 29 34 29 87
Hardness mg/L 1 11 - 10.8 13.6 9.5 11 9.9 11.0 33
Langelier Index (@20C) NA -3.47 - -3.67 -3.39 -3.72 -3.26 -3.52 -3.51 -10.52
Langelier Index (@ 4C) NA -3.79 - -3.99 -3.71 -4.04 -3.51 -3.77 -3.80 -11.41
Saturation pH (@ 20C) NA 10.3 - 10.4 10.3 10.4 10.1 10.2 10.3 -
Saturation pH (@ 4C) NA 10.6 - 10.7 10.6 10.8 10.4 10.5 10.6 -
Anion Sum me/L 0.51 - 0.33 0.39 0.53 0.45 0.54 0.46 1.38
Cation sum me/L 0.57 - 0.53 0.72 0.58 0.56 0.54 0.58 1.74
B
Narrative - Clear flow:
Maximum increase of 25 mg/L from background levels for a short-term exposure (e.g., 24-h period). Maximum average increase of 5 mg/L
from background levels for a longer term exposure (e.g., 30-d period).
Total Suspended Solids mg/L 1 <1.0 <1.0 <1.0 <1.0
High flow or turbid waters:
Maximum increase of 25 mg/L from background levels at any one time when background levels are between 25 and 250 mg/L. Should not
increase more than 10% of background levels when background is ≥ 250 mg/L.

Total UV Transmittance %T 63 62 62.5 187.5


% Difference/ Ion Balance (NS) % 6.2 - 23.5 29.3 4.7 10.9 0 12.43 37.3

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Table 1 - Inorganics and Metals for Raw Water and Estimated for Reject Process Water

Assumed Reject
Raw Water Process Water
Water Plant -
Raw Water Raw WTP Raw Raw Raw Raw Average* Concentration**
CCME Water Quality Guidelines for the Protection of Aquatic Life - Marine Raw
(2017-2022) (Based on 3x
Average Raw Water)

Parameter Unit RDL 19-Oct-17 26-Sep-18 11-Dec-18 08-Oct-19 21-Oct-20 6-Nov-22 21-Dec-22
Metals
Total Aluminum ug/L 5 46 31 101 41 25 46 83 53 159

Total Antimony ug/L 2 ND ND ND ND ND ND ND ND ND


Total Arsenic ug/L 2 12.5B ND ND ND ND ND ND ND ND ND
Total Barium ug/L 1 5 ND 8 ND ND 5.7 7.0 6.43 19.275
Total Beryllium ug/L 0.1 ND - ND ND ND ND ND ND ND
Total Bismuth ug/L 2 ND - ND ND ND ND ND ND ND
Total Boron ug/L 50 7 9 8 8 6 ND ND 20 60
Total Cadmium ug/L 0.01 0.12B ND ND ND ND ND ND ND ND ND
Total Chromium (CrIII) ug/L 1 ND ND ND ND ND ND ND ND ND
Total Cobalt ug/L 0.4 ND - ND ND ND ND ND ND ND
Total Copper ug/L 1 66 56 39 26 54 0.55 ND 34.54 103.62
Total Iron ug/L 50 321 184 264 223 229 170 220 230 690
Total Lead ug/L 0.5 0.6 ND ND ND ND ND ND 0.50 1.5
Total Lithium ug/L 2 ND ND ND ND
Total Manganese ug/L 2 98 145 29 89 23 47 40 67 201
Mercury ug/L 0.013 0.016 ND ND ND ND ND
Total Molybdenum ug/L 2 ND - ND ND ND ND ND ND ND
Total Nickel ug/L 2 ND - ND ND ND ND ND ND ND
Total Phosphorous ug/L 100 Guidance FrameworkB 30 - ND 40 ND ND ND 65 195
Total Rubidium ug/L 2 ND ND ND ND
Total Selenium ug/L 0.5 1 - ND ND ND ND ND ND ND
Total Silicon ug/L 500 ND 660 580 1740
Total Silver ug/L 0.1 7.5A ND - ND ND ND ND ND ND ND
Total Strontium ug/L 2 15 - 14 18 15 12 12 14 42
Total Tellurium ug/L 2 ND ND ND ND
Total Thallium ug/L 0.1 ND - ND ND ND ND ND ND ND
Total Tin ug/L 2 ND - ND ND ND ND ND ND ND
Total Titanium ug/L 2 ND ND ND ND ND ND ND ND ND
Total Uranium ug/L 0.1 ND - ND ND ND ND ND ND ND
Total Vanadium ug/L 2 ND 11 ND ND ND ND ND 2.4 7.2
Total Zinc ug/L 5 9 - 8 7 5 ND ND 7.0 21

Notes:
RDL = Reported Detection Limit (for more recent 2022 samples provided in RDL column)
ND = not detected
bold = parameter concentration exceeds CCME Water Quality Guidelines for the Protection of Aquatic Life - Marine
A
= Canadian Environmental Quality Guidelines, Canadian Water Quality Guidelines for the Protection of Aquatic Life - Short Term
B
= Canadian Environmental Quality Guidelines, Canadian Water Quality Guidelines for the Protection of Aquatic Life - Long Term
*Average calculated only for analytically detected parameters and includes in the average the value equal to the RDL of that sample if undetected and to be conservative
**Assumes 3x concentration of the average for parameters analytically detected
***pH will be process adjusted to meet CCME guideline before discharge if required

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