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Recitation 8 Questions

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24 views2 pages

Recitation 8 Questions

Uploaded by

Dave Hu
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Recitation 8 Questions

1. (Petrucci Ch. 6 #35) A 0.418 g sample of gas has a volume of 115 mL at 66.3°C and 99.0 kPa.
What is the molar mass of this gas?
2. (Petrucci Ch. 6 #46) A particular gaseous hydrocarbon that is 82.7% C and 17.3% H by mass
has a density of 2.33 g/L at 23°C and 746 mmHg. What is the molecular formula of this
hydrocarbon?
3. (Petrucci Ch. 6 #61) A 2.00 L container is filled with Ar(g) at 752 mmHg and 35°C. A 0.728 g
sample of C6H6 vapor is then added. (a) What is the total pressure in the container? (b) What is
the partial pressure of Ar and C6H6?
4. (Petrucci Ch. 6 #67) A 1.65 g sample of Al reacts with excess HCl, and the liberated H2 is
collected over water at 25°C at a barometric pressure of 744 mmHg. What volume of gaseous
mixture, in liters, is collected?
2 Al(s) + 6 HCl(aq)  2AlCl3(aq) + 3 H2(g)
5. (Petrucci Ch. 6 #77) At what temperature will urms for neon gas be the same as urms for helium
at 300 K?
6. (Petrucci Ch. 6 #81) If 0.00484 mol N2O(g) effuses through an orifice in a certain period of
time, how much NO2 (g) would effuse in the same time under the same conditions?
7. (Petrucci Ch. 6 #99) A mixture of 1.00 g hydrogen and 8.60 g oxygen is introduced into a
1.500 L flask at 25 ̊C. When the mixture is ignited, an explosive reaction occurs in which water
is the only product. What is the total gas pressure when the flask is returned to 25°C? The vapor
pressure of water at 25°C is 23.8 mmHg.
8. (Petrucci Ch. 6 #114) The amount of ozone, O3, in a mixture of gases can be determined by
passing the mixture through a solution of excess potassium iodide, KI. Ozone reacts with the
iodide ion as follows:
O3(g) + I–(aq) + H2O(l) → O2(g) + I3–(aq) + OH–(aq)
The amount of I3– produced is then determined by titrating with the thiosulfate ion, S2O32–:
I3–(aq) + S2O32–(aq) → I–(aq) + S4O62– (aq)
A mixture of gases occupies a volume of 53.2 L at 18°C and 0.993 atm. The mixture is passed
slowly through a solution containing an excess of KI to ensure that all the ozone reacts. The
resulting solution requires 26.2 mL of 0.1359 M Na2S2O3 to titrate to the end point. Calculate the
mole fraction of ozone in the original mixture.
9. (Petrucci Ch. 6 #122) According to the CRC Handbook of Chemistry and Physics (95th
edition), the molar volume of O2(g) is 0.2168 L/mol at 280 K and 10 MPa (Note: 1 MPa = 1 x
106 Pa).
a. Use the van der Waal’s equation to calculate the pressure of one mole of O2(g) at 280
K if the volume is 0.2168 L. What is the percent error in the calculated pressure? The van
der Waal’s constants are a = 1.382 (bar x L2)/mol2 and b = 0.0319 L/mol.
b. Use the ideal gas equation to calculate the volume of one mole of O2(g) at 280 K and
10 MPa. What is the percent error in the calculated volume?
10. (Petrucci Ch. 7 #9) A 74.8 g sample of copper at 143.2°C is added to an insulated vessel
containing 165 mL of glycerol, C3H8O3(l) (d = 1.26 g/mL), at 24.8°C. The final temperature is
31.1 °C. The specific heat capacity of copper is 0.385 J/g °C. What is the heat capacity of
glycerol in J/mol °C?
11. (Petrucci Ch. 7 #19) The combustion of hydrogen-oxygen mixtures is used to produce very
high temperatures (approximately 2500°C) needed for certain types of welding operations.
Consider the reaction to be:
H2(g) + 1/2O2 (g) → H2O(g) ΔrH° = -241.8 kJ/mol
What is the quantity of heat evolved, in kilojoules, when a 180 g mixture containing equal parts
H2 and O2 by mass is burned?

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