GRADE XI /REVISION /CHEMISTRY/2023-24

Section A

Q.No 1 to 23 are MCQ and assertion and reasoning

1.What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL?
(a) 4 mol L–1
(b) 20 mol L–1
(c) 0.2 mol L–1
(d) 2 mol L–1

2.How many moles of methane are required to produce 22 g CO2 (g) after combustion?
(a) 1 mole
(b)0.5 mole
(c) 1.5 mole
(d) 2 mole

3. Which of the following statements are correct about CO3 2–?

(A) The hybridisation of central atom is sp3 .
(B) Its resonance structure has one C–O single bond and two C=O double bonds.
(C) The formal charge on each oxygen atom is 0 units.
(D) All C–O bond lengths are equal.

4.Though Cl is an electronegative element ,yet there is no H-bonding in HCl. Why?

(a) Small size of Cl atom
(b) Larger size of Cl atom
(c) High reactivity of Cl atom
(d) Low reactivity of Cl atom

5.Why does cane sugar (sucrose) melt on heating but common salt (sodium chloride) does not melt so
easily?
(a)Cane sugar has ionic bond, common salt has covalent bond
(b)Cane sugar has covalent bond, common salt has ionic bond

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 (c)Both has covalent bond
(d)Both has ionic bond

6.Number of significant Figures in the numer 1.065 1

(a) 3
(b) 4
(c) 2
(d) 1
7.Maximum number of electrons in a subshell with l = 2 and n = 4 is 1
(a)10
(b)12
(c)14
(d)16
8. Which of the following orbital has no radial nodes? 1
(a) 1S
(b) 2s
(c)3p
(d) 4d

9.In which of the following options order of arrangement does not agree with the variation of
property indicated against it?
(a) Al3+< Mg2+< Na+ < F– (increasing ionic size)
(b) B < C < N < O (increasing first ionisation enthalpy)
(c) I<Br<Cl<F(increasing electron gain enthalpy)
(d) Li < Na < K < Rb (increasing metallic radius) 1

10.The sp3d2 hybridization of central atom of a molecule would lead to-

(a)square planar geometry

(b)Tetrahedral geometry

(c)Trigonal bipyramidal geometry

(d)Octahedral geometry

11. A Compound contains 4.07 % hydrogen, 24.27 % carbon and 71.65 % chlorine. Its molar mass is 98.96 g.

What is its molecular formula?

(a) C3H4Cl2
(b) C2H4Cl2
(c) C2H5Cl2

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(d) C2H2Cl2
12.Which block does refer to all non-metal elements ?
(a) d block elements
(b) p block elements
(c) s block elements
(d) f block elements

13.Which is the correct order ?

(a) lone pair-lone pair repulsion > lone pair- bond pair repulsion >bond pair-bond pair repulsion
(b) lone pair- bond pair repulsion>bond pair-bond pair repulsion>lone pair- lone pair repulsion
(c) lone pair- bond pair repulsion>lone pair- lone pair repulsion > bond- bond pair repulsion
(d) bond- bond pair repulsion >lone pair-bond pair repulsion >lone pair- lone pair repulsion

Directions: In the following questions, the Assertions (A) and Reason(s) (R) have been put forward. Read both the
statements carefully and choose the correct alternative from the following:

(A) Both the Assertion and the Reason are correct and the Reason is the correct explanation of the Assertion.

(B) The Assertion and the Reason are correct but the Reason is not the correct explanation of the Assertion.

(C) Assertion is true but the Reason is false.

(D) Assertion is false but the Reason is true

14. Assertion (A) : Generally, ionisation enthalpy increases from left to right in a period.
Reason (R) : When successive electrons are added to the orbitals in the same principal quantum level, the
shielding effect of the inner core of the electrons does not increase very much to compensate for the increased
attraction of the electron to the nucleus. 1

15.Assertion : Molecular nitrogen is less reactive than molecular oxygen

Reason : Bond length in nitrogen molecules is more than the bond length in oxygen.

16.Assertion (A): Electron enters 4P orbitals and then it will enter in the 5s orbitals
Reason (R): Energy value of an orbital depends only on azimuthal quantum number.
17.Assertion : The diagonal relationship is observed between the elements present in 3rd period and 4th period..
Reason : Diagonally related elements have almost the same atomic radii and electronegativity value.
18. Assertion : Sigma bond is less stronger than pi bond.
Reason : Sigma bond by axial overlap of atomic orbitals and pi bond is formed by the sidewise overlap of
atomic orbitals.

Section B (2 marks each)

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19. Calculate the molarity of a solution of ethanol in water in which the mole fraction of ethanol is 0.040 (assume
the density of water to be one) 2

20.Which of the following pairs of elements would have a less negative electron gain enthalpy and why

(i) O & F (ii) F or Cl 2

21.Draw the shape of PCl5 and NH3.

22. Analysis the given data and identify the

i) most reactive non metal
ii) most reactive metal
iii) least reactive element

.23. Explain with reasons:

(i) Mg+2 ion is smaller than the O -2 ion, though both are isoelectronic.

(ii) Alkali metal does not form dipositive ions. 2

Section C (3 marks each)

24.3g of H2 reacts with 29 g O2 to yield H2O .Find the limiting reagent. Calculate maximum amount of water

that can be formed. Calculate the amount of one of the reactants which remains unreacted.

(Given H=1u, O=16u)

25.i) State the electronic configuration of potassium atom.

ii) The first, second and third ionisation energies of potassium are 418, 3070 and 4600kJmol–1,
respectively. Use this information to explain why potassium is in Group 1..

26.Use the molecular orbital energy level diagram to show that N2 would be expected to have a triple bond,

F2, a single bond and Ne2, no bond.

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 Section D

The electron configuration of an atom is the representation of the arrangement of electrons distributed among
the orbital shells and subshells. The valence electrons, electrons in the outermost shell, are the determining
factor for the unique chemistry of the element.The basic law governing modern periodic table states that the
properties of elements are periodic functions of their atomic number. These properties reappear at regular
intervals or follow a particular trend at regular intervals. This phenomenon is known as the periodicity of
elements.The periodic properties of elements occur due to the recurrence of similar electronic configuration that
is having the same number of electrons in the outermost orbit. In a particular group, the number of valence
electrons remains the same. On the other hand, the number of valence electrons increases, as we move from left
to right across a period. The chemical property of an element depends on the number of electrons in the valence
shell.

27. How is electronegativity related to the non-metallic property of an element ?

(a)Inversely related
(b)Directly related
(c) Not dependent
(d) All of the above
28. Name the group and period of the element having the atomic no 27
(a)9th group, 4th Period
(b)15th group, 2nd Period
(c) 14th group, 4th Period
(d)13rd group, 3rd Period
29. For most of the noble gases the radius which can be considered is-

(a) Metallic radius

(b) Covalent radius
(c) Non Metallic radius
(d)Van Der Waals radius

30. What would the IUPAC name and symbol for the element with atomic number 120 ?
(a)Unbinilium, Ubn
(b)Unbinilium, Unn
(c)Ununnilium, Ubn
(d)Untrinilium, Ubn
31. Elements from ___ to ___ atomic number are present in the lanthanide series-
(a) 57–71
(b) 89-103
(c) 61-76
(d) 88-102

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 Section E (5 marks each)
- 2+
32.I)What is meant by the term bond order? Calculate the bond order of: O2, O2 and O2 (Show the

Molecular electronic configuration in each case)

33. (i)Explain the formation of Sp3d2 hybridisation in SF6 and write its molecular shape.
( ii)How many sigma and pi bond are there in the following compounds-

34. (a)Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction,

CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l)

What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCl?

(Given, H=1u,Cl=35.5u, Ca=40u, C=12u, O=16u)

(b) How 0.50 mol Na2CO3 is different from 0.50 M Na2CO3? (Given Na=23u, C=12u,O=16u)

35. balance the following equation

a) H2SO4 + HI S +I2+ H2O (acidic medium ) by oxidation no. method

3+ 2+ - +
b) V +I2+ H2O VO +I + H (acidic medium) by electron exchange method

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