ALPHA STUDY CLASS: 12TH

HALOGEN DERIVATIVES DATE: 24-03-23

CHEMISTRY TIME:

1. What are alkyl halides? How are they classified? 3

2. Give classification of halogen compounds on the basis of number of halogen 3
atoms.
3. What is Allylic halide. Give example. 2
4. What is Benzylic halide. Give example. 2
5. What is Vinylic halide. Give example. 2
6. What is Aryl Halide. Give example. 2
7. Write IUPAC names of the following compounds 1
a) a. 𝐶𝐻2 = CHCI b. Sec-butyl chloride c. Neopentyl bromide
b) d. t-butyl iodide e. Isopropyl bromide.
8. How is ethyl bromide prepared from …………….. 1
a. Ethyl alcohol b. Ethane c. Ethene
9. Write the preparation of isopropyl chloride using the following reagents… 1
a. 𝑃𝐶𝑙3 b. 𝑃𝐶l5 c. 𝐶𝑙2 d. HCI e. 𝑆𝑂𝐶𝑙2
10. How is -X group replaced by following functional groups … 1
a. −OH b. −CN c. −NC d. −𝑁𝐻2
11. Write a note on ………….. 2
a. Sandmeyer's reaction b. Wurtz reaction
c. Finkelstein reaction d. Fittig reaction
e. Friedel Craft alkylation reaction f. Friedel craft Acylation reaction.
12. The type of mono halogen derivative in which a halogen atom is bonded to sp 3 1
hybridized carbon atom next to carbon-carbon double bond is …………
a. alkyl halide b. allylic halide c. vinylic halide d . benzylic halide
13. For the isomeric dihalobenzenes, melting point of…………… 1
a. Ortho isomer is higher b. Meta isomer is higher
c. Para isomer is higher d. All isomers is nearly same
14. Optical activity of a molecule is associated with………….. 1
a. Plane polarized light b. 3-D structure of a molecule
c. Achiral molecule d. Superimposable mirror
images
15. Propane nitrile can be prepared by heating……………….. 1
 a. Ethyl bromide with alcoholic KCN b. Propyl bromide with alcoholic
KCN
c. Ethyl bromide with alcoholic AgCN d. Propyl bromide with
alcoholic AgCN
16. What is the action of : 1eac
h
a. HCl on ethanol b. NaBr + Conc H2SO4 on ethanol
c. NaI + H3PO4 on ethanol. d. phosphorous penta chloride
on ethanol
e. phosphorous tri chloride on ethanol f. Thionyl chloride on ethanol
g. Red P +I2 h. HBr on propene in presence of
peroxis
i. HBr on propen j. NaI on Chloro ethane
k. AgF on bromo ethane l. Br2 on tolnene in presence of Fe.
17. CH3−CH2 − Mg − Br + NH3→? 1
a. CH3−CH2−Mg−NH2 b. CH3−CH3
c. Mg – Br − NH2 d. CH3− CH2−Br
18. Write IUPAC name of the following. 1

19. Write the major product of the following reaction. 1

20. Write IUPAC name of the product ‘B’ in the following reaction sequence. 2

21. What is the action of 1eac

h
a. Aq. NaoH on ethyl bromide b. Alcoholic NH3 on ethyl bromide
c. Alc. KeN on ethyl bromide d. Alc. AgCN on ethyl bromide
e. KNO2 on ethyl bromide f. AgNO2
g. Sodium methoxide on ethyl bromide h. silver acetate on ethyl
bromide
i. Na on ethyl bromide j. Na on chloro benzene
k. Mg on bromo ethane l. Alcoholic KOH on 2-bromo
propane
 m. Cl2 on Chloro benzene in presence of Anhy FeCl3
n. Nitrating mixture on Chloro benzene o. Fuming H2SO4 on Chloro
benzene
p. Methyl Chloride on Chloro benzene q. Acetyl Chloride on Chloro
benzene
22. Nucleophilic substitution reaction of 2, 4-dinitrochlorobenzene is faster than p- 2
nitrochlorobenzene. Give reason.
23. Name the reagent used to convert alkyl halide to ester. 1
24. Write the correct order of increasing ease of dehydrohalogenation. 1
a . CH3− CH2−CH2−Cl b. CH3−CH(Cl)−CH3

c.
25. Explain. Aryl halides are less reactive than alkyl halides towards nucleophilic 3
substitution reactions.
26. Give reason for : Melting point of p-dichlorobenzene is greater than o & m 2
isomer.
27. Explain reactions of haloarenes with sodium metal. 2
28. Give reason. Though alkyl halides are moderately polar, they are insoluble in 2
water.
29. Define : a. Chiral Carbon atom b. PPL c. Optical 1eac
activity h
d. Dextro rotator substance e. Laevo rotatory Substance

f. Racemic mixture g. Enantiomer

30. Explain optical activity of 2-chlorobutane 2
31. Distinguish between SN1 and SN2 mechanism of substitution reaction. 2
32. Explain the factors affecting SN1 and SN2 mechanism. 2
33. Explain aqueous alkaline hydrolysis of tert. butyl bromide. 3
34. How are the following conversions carried out? propene to 1-iodopropane 2
35. How are the following conversions carried out? propene to 2-nitropropane 2
36. How are the following conversions carried out? benzene to biphenyl 1
37. What is Grignard reagent? How is it prepared? Why are they prepared under 3
anhydrous condition?
38. Write chemical equations indicating the action of following on bromobenzene. 1
fuming H2SO4
39. Write chemical equations indicating the action of following on bromobenzene. 1
conc. HNO3/conc. H2SO4
40. An organic compound A with molecular formula C4H10O on treatment with 3
phosphorus pentachloride gives alkyl chloride. Alkyl chloride on treatment with
Mg in presence of dry ether gives a highly reactive compound B. Compound B
reacts with water to give hydrocarbon C. Alkyl chloride on treatment with Na in
dry ether as a solvent gives alkane, 2,2,3,3-tetramethylbutane. Identify ‘A’, ‘B’,
‘C’
41. Write the equations for the preparation of ethyl chloride using 1eac
h
a. Hydrogen halide b. ethene c. Thionyl chloride
42. Which of these methods is preferred and why? 2
43. What is dehydrohalogenation? State the rule for the formation of the preferred 2
product of dehydrohalogenation.
44. Explain Saytzeff’s rule with example. 2
45. Predict all the alkenes that would be formed by dehydrohalogenation of the 2
following alkyl halide.
46. Give 2 uses of 1eac
h
a. Chloro forms b. Iodoform c. Dichloro methane

d. Carbon tetra Chloride e. freon

47. Give full name of DDT. Give its structure and its use. 3